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11. 发明申请

WO2008025710A1 1-BUTENE PROPYLENE COPOLYMER COMPOSITIONS 审中-公开
标题翻译： 1-BOTENE丙烯共聚物组合物
公开(公告)号：WO2008025710A1
公开(公告)日：2008-03-06
申请号：PCT/EP2007/058730
申请日：2007-08-22
申请人： BASELL POLYOLEFINE GMBH , PELLEGATTI, Giampaolo , BIGIAVI, Daniele , MARTELLI, Rita , TONTI, Maria Silvia , RESCONI, Luigi , GUIDOTTI, Simona
发明人： PELLEGATTI, Giampaolo , BIGIAVI, Daniele , MARTELLI, Rita , TONTI, Maria Silvia , RESCONI, Luigi , GUIDOTTI, Simona
IPC分类号： C08L23/20 , C08F210/08
CPC分类号： C08F210/08 , C08F4/65912 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08L23/20 , C08L2205/02 , C08L2314/06 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08L2666/06 , C08F210/06 , C08F2500/03 , C08F2500/20 , C08F2500/15 , C08F2500/17
摘要： A 1-butene/propylene copolymer composition having a content of propylene derived units from 1 to 4% by weight, wherein at least 50% of the crystalline polymer is present in the thermodynamically stable, trigonal Form I (detected by DSC analysis) after 100 hours of the first melting at room temperature comprising: b) from 5% by weight to 95% by weight of an atactic 1-butene propylene copolymer having the following features: i) distribution of molecular weight Mw/Mn equal to or lower than 4; ii) no enthalpy of fusion detectable at a differential scanning calorimeter (DSC); and iii) infrared crystallinity lower than 0.5%; b) from 5% by weight to 95% by weight of an isotactic 1-butene propylene copolymer having the following features: isotactic pentads (mmmm) measured by 13 C-NMR, higher than 80%; i) ii) melting point (Tm(II)) higher than 70°C; and iii) distribution of molecular weight Mw/Mn equal to or lower than 4.
摘要翻译：具有1至4重量％的丙烯衍生单元含量的1-丁烯/丙烯共聚物组合物，其中至少50％的结晶聚合物存在于热力学稳定的三角形式I（通过DSC分析检测）后100 包括：b）5重量％至95重量％的具有以下特征的无规立构1-丁烯丙烯共聚物：i）分子量Mw / Mn等于或低于4的分布 ; ii）在差示扫描量热计（DSC）处不可检测到融合焓; 和iii）红外结晶度低于0.5％; b）5重量％至95重量％的具有以下特征的全同立构1-丁烯丙烯共聚物：通过13 C-NMR测定的全同立构五单元组（mmmm）高于80％; i）ii）高于70℃的熔点（Tm（II））; 和iii）等于或低于4的分子量Mw / Mn的分布。

12. 发明申请

WO2006117285A1 PROCESS FOR THE POLYMERIZATION OF ALPHA OLEFINS 审中-公开
标题翻译： ALPHA OLEFINS聚合方法
公开(公告)号：WO2006117285A1
公开(公告)日：2006-11-09
申请号：PCT/EP2006/061545
申请日：2006-04-12
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , GUIDOTTI, Simona , SANTORIELLO, Iolanda
发明人： RESCONI, Luigi , GUIDOTTI, Simona , SANTORIELLO, Iolanda
IPC分类号： C08F10/00 , C08F4/6592 , C07F17/00 , C07F7/08
CPC分类号： C07F7/0818 , C07F17/00 , C08F4/65912 , C08F10/00 , C08F10/08 , C08F110/06 , C08F110/08 , C08F210/08 , Y10S526/943 , C08F4/65927 , C08F2/02 , C08F2500/17 , C08F210/16
摘要： A process for preparing 1-butene polymers, comprising polymerizing 1-butene or copolymerizing 1-butene with ethylene, propylene or an alpha-olefin of formula CHT 2 =CHT wherein T is a C 3 -C 10 alkyl group, in the presence of a catalyst system obtainable by contacting: A) a metallocene compound belonging to formula (I): wherein M is zirconium titanium or hafnium; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a a hydrocarbon radical, optionally containing heteroatoms; R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 are hydrogen atoms, or C 1 -C 4O hydrocarbon radicals optionally containing heteroatoms; R 1 , R 2 and R 3 , are linear or branched, C 1 -C 2o -alkyl radicals, optionally containing heteroatoms; B) a Jumoxane or a compound capable of forming an alkyl metallocene cation; and optionally C) organo aluminum compound.
摘要翻译：一种制备1-丁烯聚合物的方法，包括将1-丁烯或1-丁烯与乙烯，丙烯或式CHT 2 CH = CHT的α-烯烃聚合，其中T是C 3 在可以通过下述方法获得的催化剂体系存在下进行：A）属于式（I）的茂金属化合物：其中M是锆钛或铪; X，彼此相同或不同，是氢原子，卤素原子，烃基，任选地含有杂原子; R 4，R 5，R 6，R 7，R 8， R 9，R 10，R 11，R 12和R 13是氢原子或任选含有杂原子的C 1 -C 40烃基; R 1，R 2和R 3是直链或支链的C 1 -C 2 O 任选地含有杂原子的烷基; B）可以形成烷基茂金属阳离子的Jumoxane或化合物; 和任选的C）有机铝化合物。

13. 发明申请

WO2005105865A1 PROCESS FOR THE PREPARATION OF ATACTIC 1-BUTENE POLYMERS 审中-公开
标题翻译：制备单层1-丁烯聚合物的方法
公开(公告)号：WO2005105865A1
公开(公告)日：2005-11-10
申请号：PCT/EP2005/004506
申请日：2005-04-25
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , GUIDOTTI, Simona
发明人： RESCONI, Luigi , GUIDOTTI, Simona
IPC分类号： C08F10/08
CPC分类号： C08F10/08 , C08F4/65912 , C08F110/08 , C08F210/02 , C08F210/08 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/03 , C08F2500/20 , C08F2500/15 , C08F210/06 , C08F210/16
摘要： A process for obtaining atactic 1-butene polymer optionally containing at least one comonomer selected from ethylene, propylene or an alpha-olefin of formula CH2=CHR, wherein R is a linear or branched C3-C 20 alkyl group, comprising the step of polymerizing 1-butene and optionally ethylene, propylene or said alpha-olefin, in the presence of a catalyst system obtainable by contacting: a) at least one metallocene compound of formula (I) in its meso or meso-like form wherein M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group; L is a divalent C 1 -C 40 hydrocarbon radical optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; R' and R 2 , are C 1 -C 40 hydrocarbon radicals; T, equal to or different from each other, is a moiety of formula (IIa) or (Ilb) wherein R 3 is a C I -C 40 hydrocarbon radical; R 4 and R 6 , are hydrogen atoms or C 1 -C 40 hydrocarbon radicals; R 5 is a C I -C 40 hydrocarbon radical; R 7 and R 8 , equal to or different from each other, are hydrogen atoms or C 1 -C 40 hydrocarbon radicals; and b) an alumoxane or a compound capable of forming an alkyl metallocene cation.
摘要翻译：获得任选含有选自乙烯，丙烯或式CH 2 = CHR的α-烯烃的至少一种共聚单体的无规性1-丁烯聚合物的方法，其中R是直链或支链C 3 -C 20烷基，其包括聚合1 丁烯和任选的乙烯，丙烯或所述α-烯烃在催化剂体系的存在下，可通过以下步骤获得： - ）至少一种其中间或内消旋形式的式（I）金属茂化合物，其中M是过渡金属; p是0至3的整数; X相同或不同，是氢原子，卤素原子或烃基; L是任选含有属于元素周期表第13-17族的杂原子的二价C 1 -C 40烃基; R'和R 2是C1-C40烃基; T为相同或不同的式（IIa）或（IIb）的部分，其中R 3为C 1 -C 40烃基; R 4和R 6是氢原子或C 1 -C 40烃基; R 5是C 1 -C 40烃基; R 7和R 8彼此相同或不同，是氢原子或C 1 -C 40烃基; 和b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

14. 发明申请

WO2002100908A1 PROCESS FOR THE POLYMERIZATION OF 1-BUTENE 审中-公开
标题翻译： 1-BOTENE聚合方法
公开(公告)号：WO2002100908A1
公开(公告)日：2002-12-19
申请号：PCT/EP2002/006574
申请日：2002-06-11
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi
发明人： RESCONI, Luigi
IPC分类号： C08F10/08
CPC分类号： C08F110/08 , C08F4/65912 , C08F10/08 , C08F210/08 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/12 , C08F2500/15 , C08F2500/20 , C08F2500/03 , C08F210/16
摘要： A process for polymerizing 1-butene comprising the step of contacting under polymerization conditions 1-butene and optionally from 0 to 20% by mol of an alpha olefin with a catalyst system obtainable by contacting a bridget metallocene compound of formula (I) wherein R 1 and R 2 are an hydrocarbon radical A is a carbon atom, a germanium atom or a silicon atom; m is 1, 2; M is a metal of group 4 of the Periodic Table of the Elements; X, is hydrogen, a halogen atom, or a group R, OR, OSO 2 CF 3 , OCOR, SR, NR 2 or PR 2 , wherein the substituents R are hydrocarbon radical; L is a moiety of formula (IIa) or (IIb) wherein T is an oxigen (O) or sulphur (S) atom or a CH 2 group; and R 3 and R 4 are hydrogen atoms or hydrocarbon radicals; one or more alumoxanes or compounds able to form an alkylmetallocene cation; and optionally an organo aluminium compound.
摘要翻译：一种聚合1-丁烯的方法，包括在聚合条件下使1-丁烯和任选的0至20摩尔％的α-烯烃与可通过使式（I）的桥连金属茂化合物（其中R 1， 1>和R 2是烃基A是碳原子，锗原子或硅原子; m为1,2; M是元素周期表第4族的金属; X是氢，卤素原子或基团R，OR，OSO 2 CF 3，OCOR，SR，NR 2或PR 2，其中取代基R是烃基; L是式（IIa）或（IIb）的部分，其中T是氧原子（O）或硫（S）原子或CH 2基团; R 3和R 4是氢原子或烃基; 一种或多种能够形成烷基茂金属阳离子的铝氧烷或化合物; 和任选的有机铝化合物。

15. 发明申请

WO2006008212A1 PROCESS FOR PRODUCING FRACTIONABLE 1-BUTENE POLYMERS 审中-公开
标题翻译：生产可分离的1-丁烯聚合物的方法
公开(公告)号：WO2006008212A1
公开(公告)日：2006-01-26
申请号：PCT/EP2005/052690
申请日：2005-06-10
申请人： BASELL POLYOLEFINE GMBH , TONTI, Maria, Silvia , RESCONI, Luigi
发明人： TONTI, Maria, Silvia , RESCONI, Luigi
IPC分类号： C08F10/08
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65927 , C08F110/08 , Y10S526/943 , C08F4/65904 , C08F2500/03 , C08F2500/17 , C08F2500/20 , C08F2/001
摘要： A process for producing a 1-butane polymer comprising the step of polymerizing 1-butene in the presence of a catalyst system obtainable by contacting: a) at least a metallocene compound of formula (Ia) in the meso or meso-like form, wherein M is an atom of a transition metal p is an integer from 0 to 3, X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group. L is a divalent C 1 -C 40 hydrocarbon radical R 1 and R 2 , equal to or different from each other, are C 1 -C 40 hydrocarbon radicals; T, equal to or different from each other, is a moiety of formula (IIa), (IIb) or (IIc), wherein R 3 and R 5 are a C 1 -C 40 hydrocarbon radical; R 4 and R 6 , equal to or different from each other, are hydrogen atoms or C 1 -C 40 hydrocarbon radicals and R 7 and R 8 , equal to or different from each other, arc hydrogen atoms or C 1 -C 40 hydrocarbon radicals; b) at least a metallocene compound of formula (Ib) in the racemic (rac) or racemic - like form; c) an alumoxane or a compound capable of forming an alkyl metallocenc cation.
摘要翻译：一种制备1-丁烷聚合物的方法，包括在催化剂体系存在下聚合1-丁烯的步骤，所述催化剂体系可以通过以下步骤获得：a）至少一种以中间或内消旋形式的式（Ia）金属茂化合物，其中 M为过渡金属的原子，p为0〜3的整数，X相同或不同，为氢原子，卤素原子或烃基。 L是二价C

16. 发明申请

WO2006008211A1 1-BUTENE POLYMERS COMPOSITION 审中-公开
标题翻译： 1-BOTENE聚合物组合物
公开(公告)号：WO2006008211A1
公开(公告)日：2006-01-26
申请号：PCT/EP2005/052688
申请日：2005-06-10
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , PELLICONI, Anteo , SPATARO, Stefano , MOSCARDI, Gilberto
发明人： RESCONI, Luigi , PELLICONI, Anteo , SPATARO, Stefano , MOSCARDI, Gilberto
IPC分类号： C08L23/18
CPC分类号： C08L23/18 , C08L23/20 , C08L2205/02 , Y10S526/943 , C08L2666/04
摘要： A 1-butene polymer composition comprising: a) from 5% by weight to 95% by weight of an atactic 1-butene-based polymer, having the following features: - distribution of molecular weight Mw/Mn equal to or lower than 4; - rr triads, measured by 13 C-NMR comprised between 5% and 50%; - no enthalpy of fusion detectable at a differential scanning calorimeter (DSC); - intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135°C comprised between 0.85 dl/g and 5 dl/g; and - infrared crystallinity lower than 0.5%; b) from 5% by weight to 95% by weight of an isotactic 1-butene-based polymer having the following features: - isotactic pentads (mmmm) measured by 13 C-NMR, higher than 80%; melting point higher than 80°C; and - intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135°C comprised between 0.1 dl/g and 5 dl/g.
摘要翻译： 1-丁烯聚合物组合物，其包含：a）5重量％至95重量％的无规立构1-丁烯基聚合物，具有以下特征： - 分子量Mw / Mn等于或低于4的分布; - 通过13 C-NMR测量的rr三单元组份在5％至50％之间; - 差示扫描量热仪（DSC）可检测不到融合焓; - 在135℃下在四氢萘（THN）中测得的特性粘度（Ⅳ）为0.85dl / g至5dl / g; 红外结晶度低于0.5％; b）5重量％至95重量％的具有以下特征的全同立构1-丁烯基聚合物： - 通过13 C-NMR测量的全同立构五单元组（mmmm），高于80％ ; 熔点高于80℃; 和在135℃下四氢萘（THN）中测得的特性粘度（Ⅳ）为0.1dl / g至5dl / g。

17. 发明申请

WO2005095468A3 CATALYST SYSTEM FOR THE POLYMERIZATION OF OLEFIN 审中-公开
公开(公告)号：WO2005095468A3
公开(公告)日：2005-10-13
申请号：PCT/EP2005/002479
申请日：2005-03-08
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , MOSCARDI, Gilberto , FAIT, Anna
发明人： RESCONI, Luigi , MOSCARDI, Gilberto , FAIT, Anna
IPC分类号： C08F110/08 , C08F4/602
摘要： A catalyst system solution obtainable by a process comprising the following steps: a) contacting a solution of methylalumoxane in an aromatic solvent (solvent a) with a solution of one or more organ-aluminium in a solvent (solvent b), or a solution of one or more alumoxanes different from methylalumoxane in a solvent (solvent b); (b) when solvent b) is an aromatic solvent or if solvent b) has a boiling point lower than solvent a) add to the solution formed in step a) an alifatic solvent (solvent c) having a boiling point higher than solvent a) and solvent b); or (c) solubilizing a metallocene compound in the solution obtained in step a) or in step b); and (d) substantially removing solvent a) or solvent a) and solvent b) from the solution.

18. 发明申请

WO2005063828A1 METALLOCENE COMPOUNDS 审中-公开
标题翻译：金属化合物
公开(公告)号：WO2005063828A1
公开(公告)日：2005-07-14
申请号：PCT/EP2004/012984
申请日：2004-11-16
申请人： BASELL POLYOLEFINE GMBH , NIFANT'EV, Ilya, E. , IVCHENKO, Pavel, V. , TAJDAKOV, Ilya, V. , RESCONI, Luigi
发明人： NIFANT'EV, Ilya, E. , IVCHENKO, Pavel, V. , TAJDAKOV, Ilya, V. , RESCONI, Luigi
IPC分类号： C08F10/00
CPC分类号： C07D495/04 , C07F17/00 , C08F4/65912 , C08F10/00 , C08F110/02 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/17
摘要： A metallocene compound of formula (I) wherein: M is an atom of a transition metal; X, same or different, is a hydrogen atom, a halogen atom, or a R, OR, OSO 2 CF 3 , OCOR, SR, NR 2 or PR 2 group, wherein R is C 1 -C 40 hydrocarbon group; L is a divalent bridging group; R 1 , is a C 1 -C 40 hydrocarbon group; R 3 is a C 1 -C 40 hydrocarbon group; R 2 , R 4 , R 5 , R 6 , R 7 and R 8 , equal to or different from each other, are hydrogen atoms or C 1 -C 40 hydrocarbon groups.
摘要翻译：式（I）的茂金属化合物，其中：M是过渡金属的原子; X相同或不同，为氢原子，卤素原子或R，OR，OSO 2 CF 3，OCOR，SR，NR 2或PR 2基团，其中R为C 1 -C 40烃基; L是二价桥基; R 1是C 1 -C 40烃基; R 3是C 1 -C 40烃基; R 2，R 4，R 5，R 6，R 7和R 8彼此相同或不同，是氢原子或C 1 -C 40烃基。

19. 发明申请

WO2003070778A1 PROCESS FOR THE COPOLYMERIZATION OF ETHYLENE 审中-公开
标题翻译：乙烯共聚方法
公开(公告)号：WO2003070778A1
公开(公告)日：2003-08-28
申请号：PCT/EP2003/001296
申请日：2003-02-10
申请人： BASELL POLYOLEFINE GMBH , FAIT, Anna , KOEPPL, Alexander , RESCONI, Luigi
发明人： FAIT, Anna , KOEPPL, Alexander , RESCONI, Luigi
IPC分类号： C08F4/642
CPC分类号： C08F210/02 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F4/65927 , C08F210/14 , C08F2500/08 , C08F2500/17
摘要： A process for producing a polymer of ethylene containing from 0.1 to 50 % by weight of one or more derived units of alpha-olefins fo formula CH 2 =CHR, wherein R is a C 2 -C 20 alkyl radical, comprising contacting, under ploymerization conditions, ethylene and one or more alpha-olefins in the presence of a catalyst system obtainable by contacting: a) a metallocene compound of formula (I) wherein: M is zirconium, titanium or hafminum, X, equal to or different from each other, is hydrogen halogen or an hydrocarbyl radical, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 , equal to or different from each other are hydrogen atoms, halogen atoms, or hydrocarbyl radicals; and b) an alumoxane or a compound capable of forming an alkyl metallocene cation.
摘要翻译：一种乙烯聚合物的制备方法，该聚合物含有0.1至50重量％的一种或多种衍生的式CH 2 = CHR的α-烯烃单元，其中R是C 2 -C 20烷基，包括在聚合条件下使乙烯和一种或多种α-烯烃，在催化剂体系存在下可通过使下列物质接触而获得的催化剂体系：其中：M是锆，钛或者Hafminum，X彼此或彼此不同的金属茂化合物是氢卤素或烃基氢原子，卤原子或烃基相同或不同的基团，R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8和R 9，b是铝氧烷或能够形成烷基茂金属的化合物阳离子。

20. 发明申请

WO2003042258A1 PROCESS FOR POLYMERIZING 1-BUTENE AND 1-BUTENE POLYMERS 审中-公开
标题翻译：聚合1-丁烯和1-丁烯聚合物的方法
公开(公告)号：WO2003042258A1
公开(公告)日：2003-05-22
申请号：PCT/EP2002/012731
申请日：2002-11-08
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi
发明人： RESCONI, Luigi
IPC分类号： C08F10/08
CPC分类号： C08F10/08 , C08F4/65912 , C08F110/08 , C08F4/65927 , C08F2500/17 , C08F2500/15 , C08F2500/03 , C08F2500/20
摘要： A process for polymerizing 1-butene, optionally with up to 30% by mol of ethylene, propylene or an alpha olefin of formula CH 2 =CHT wherein T is a C 3 -C l0 alkyl group, in the presence of a catalyst system obtainable by contacting a metallocene compound having C 1 symmetry with an alumoxane and/or a compound capable of forming an alkyl metallocene cation.
摘要翻译：聚合1-丁烯的方法，任选地含有至多30摩尔％的乙烯，丙烯或式CH 2 = CHT的α-烯烃，其中T是C 3 -C 10烷基，在催化剂体系存在下，可通过将具有与铝氧烷和/或能够形成烷基金属茂阳离子的化合物具有C1对称性的茂金属化合物。

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