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11. 发明申请

WO2004048424A1 BUTENE-1 COPOLYMERS AND PROCESS FOR THEIR PREPARATION 审中-公开
标题翻译： BUTENE-1共聚物及其制备方法
公开(公告)号：WO2004048424A1
公开(公告)日：2004-06-10
申请号：PCT/EP2003/012233
申请日：2003-11-03
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni , BIGIAVI, Daniele , PELLICONI, Anteo , GARAGNANI, Enea , BAITA, Pietro
发明人： MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni , BIGIAVI, Daniele , PELLICONI, Anteo , GARAGNANI, Enea , BAITA, Pietro
IPC分类号： C08F210/08
CPC分类号： C08L23/04 , C08F10/00 , C08F210/08 , C08L23/14 , C08L23/22 , C08L2666/06 , C08F4/651 , C08F4/6543 , C08F4/6465 , C08F210/06 , C08F2500/15 , C08F2500/03 , C08F2500/17 , C08F2500/11 , C08F2500/20 , C08F210/16 , C08F2/001
摘要： The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived characterized by the following properties: d) Product of the reactivity ratios rl·r2≤2; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.
摘要翻译：本发明涉及含有至多40摩尔％乙烯和/或丙烯的丁烯-1共聚物，其特征在于以下性质：d）反应性比率r r.r2 <= 2的产物; e）全同立构五元组（mmmm）形式的丁烯-1单元含量> 98％; 和f）不存在4,1个丁烯单元的插入。

12. 发明申请

WO2011107371A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2011107371A1
公开(公告)日：2011-09-09
申请号：PCT/EP2011/052566
申请日：2011-02-22
申请人： BASELL POLIOLEFINE ITALIA SRL , GUIDOTTI, Simona , PIEMONTESI, Fabrizio , PATER, Jochemm, T., M. , MORINI, Giampiero
发明人： GUIDOTTI, Simona , PIEMONTESI, Fabrizio , PATER, Jochemm, T., M. , MORINI, Giampiero
IPC分类号： C08F4/651 , C08F110/06 , C08F4/654 , C08F4/646
CPC分类号： C08F110/06 , C08F4/6545 , C08F4/651 , C08F4/6465 , C08F2500/15
摘要： Catalyst component for the polymerization of olefins CH 2 =CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected those of formula (I) wherein: R 2 , equal to or different from each other, are hydrogen atoms or C 1 -C 20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the periodic table of the elements or alkoxy groups of formula -OR 1 , two or more of the R 2 groups can be connected together to form a cycle; R 1 , equal to or different from each other, are C 1 -C 20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the periodic table of the elements, with the proviso that at least one of R 2 is -OR 1 and the other being selected from succinates of formula (II): wherein the radicals R 1 and R II , equal to or different from each other, are a C 1 -C 20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms; the radicals R III to R IV equal to or different from each other, are hydrogen or a C 1 - C 20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms, and the radicals R III to R VI which are joined to the same carbon atom of the succinate chain can be linked together to form a cycle.
摘要翻译：用于烯烃CH 2 = CHR的聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和两个电子给体化合物，其中一个选自式（I）的那些，其中：R 2 彼此相同或不同的是氢原子或任选含有属于式-OR1的元素或烷氧基的周期表第13-17族的杂原子的C1-C20烃基，R2基中的两个或更多个可以连接在一起形成一个循环; R1彼此相同或不同的是C1-C20烃基，其任选地含有属于元素周期表第13-17族的杂原子，条件是R 2中的至少一个为-OR 1且另一个选自来自式（II）的琥珀酸盐：其中基团R 1和R II彼此相同或不同，为任选含有杂原子的C 1 -C 20直链或支链烷基，烯基，环烷基，芳基，芳基烷基或烷基芳基; RIII至RIV彼此相同或不同的基团是氢或任选含有杂原子的C 1-20直链或支链烷基，烯基，环烷基，芳基，芳基烷基或烷基芳基，以及RIII至RVI基团连接至琥珀酸酯链的相同碳原子可以连接在一起形成循环。

13. 发明申请

WO2011107370A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2011107370A1
公开(公告)日：2011-09-09
申请号：PCT/EP2011/052563
申请日：2011-02-22
申请人： BASELL POLIOLEFINE ITALIA SRL , GUIDOTTI, Simona , PIEMONTESI, Fabrizio , PATER, Jochem T. M. , MORINI, Giampiero
发明人： GUIDOTTI, Simona , PIEMONTESI, Fabrizio , PATER, Jochem T. M. , MORINI, Giampiero
IPC分类号： C08F4/651 , C08F110/06 , C08F4/654 , C08F4/646
CPC分类号： C08F110/06 , C08F4/6545 , C08F4/6465 , C08F4/651 , C08F2500/15
摘要： Catalyst component for the polymerization of olefins CH 2 =CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected from alkoxybenzenes and the other being selected from those of formula (II) where R 1 and R II are the same or different and are hydrogen or linear or branched C 1 -C 18 hydrocarbon groups which can also form one or more cyclic structures; R III groups, equal or different from each other, are hydrogen or C 1 -C 18 hydrocarbon groups; R IV groups equal or different from each other, have the same meaning of R III except that they cannot be hydrogen; each of R I to R IV groups can contain heteroatoms selected from halogens, N, O, S and Si.
摘要翻译：用于烯烃CH 2 = CHR聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和两个电子给体化合物，其中一种选自烷氧基苯，另一种选自那些其中R 1和R II相同或不同并且是氢或可以形成一个或多个环状结构的直链或支链C 1 -C 18烃基; 相同或不同的RIII基团是氢或C 1 -C 18烃基; RIV基团相同或不同，具有与RIII相同的含义，不同之处在于它们不能是氢; 每个RI至RIV基团可以含有选自卤素，N，O，S和Si的杂原子。

14. 发明申请

WO2010012587A1 ETHYLENE POLYMERS 审中-公开
标题翻译：乙烯聚合物
公开(公告)号：WO2010012587A1
公开(公告)日：2010-02-04
申请号：PCT/EP2009/058993
申请日：2009-07-14
申请人： BASELL POLYOLEFINE ITALIA S.R.L. , BALBONI, Davide , ESPOSITO, Simona , MORINI, Giampiero , PIEMONTESI, Fabrizio
发明人： BALBONI, Davide , ESPOSITO, Simona , MORINI, Giampiero , PIEMONTESI, Fabrizio
IPC分类号： C08F210/18 , C08F4/6592
CPC分类号： C08F210/02 , C08F4/65912 , C08F210/18 , C08F4/65927 , C08F210/06 , C08F236/20 , C08F2500/25 , C08F2500/17
摘要： A process for copolymerizing ethylene, one or more non-conjugated cyclic diene and optionally one or more alpha olefins of formula CH 2 =CHT wherein T is a C 1 -C 20 alkyl radical comprising the step of contacting the monomers under polymerization conditions in the presence of a catalyst system comprising a metallocene compound of formula (I) wherein: M is titanium zirconium or hafnium; X, is a hydrogen atom, a halogen atom, a R, OR, OR'O, OSO 2 CF 3 , OCOR, SR, NR 2 or PR 2 group wherein R is an hydrocarbon radical and R' is a C 1 -C 20 -alkylidene, C 6 -C 20 -arylidene, C 7 -C 20 -alkylarylidene, or C 7 -C 20 -arylalkylidene radical; R 1 , is a C 1 -C 20 -alkyl radical; R 2 , R 3 , R 4 , R 5 , R 6 and R 7 are hydrogen atoms, or C 1 -C 20 hydrocarbon radicals or two or more R 2 , R 3 , R 4 , and R 5 can also be joined to form a C 3 -C 10 ring; L is a divalent C 1 -C 40 hydrocarbon radical.
摘要翻译：共聚乙烯，一种或多种非共轭环状二烯和任选一种或多种式CH 2 = CHT的α-烯烃的方法，其中T是C 1 -C 20烷基，其包括在聚合条件下，在催化剂体系包含式（I）的茂金属化合物，其中：M是钛锆或铪; X，是氢原子，卤素原子，R，OR，OR'O，OSO 2 CF 3，OCOR，SR，NR 2或PR 2基团，其中R是烃基，R'是C 1 -C 20亚烷基，C 6 -C 20 亚芳基，C 7 -C 20 - 亚烷基亚芳基或C 7 -C 20 - 芳基亚烷基; R1是C1-C20烷基; R2，R3，R4，R5，R6和R7是氢原子，或C1-C20烃基或两个或更多个R2，R3，R4和R5也可以连接形成C 3 -C 10环; L是二价C1-C40烃基。

15. 发明申请

WO2004106388A2 PROCESS FOR THE PREPARATION OF A CATALYST COMPONENT AND COMPONENTS THEREFROM OBTAINED 审中-公开
标题翻译：制备催化剂组分和获得的组分的方法
公开(公告)号：WO2004106388A2
公开(公告)日：2004-12-09
申请号：PCT/EP2004/005186
申请日：2004-05-07
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , MORINI, Giampiero , DALL'OCCO, Tiziano , PIEMONTESI, Fabrizio , SPOTO, Rosa , VINCENZI, Paolo , VITALE, Gianni
发明人： MORINI, Giampiero , DALL'OCCO, Tiziano , PIEMONTESI, Fabrizio , SPOTO, Rosa , VINCENZI, Paolo , VITALE, Gianni
IPC分类号： C08F4/651
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6367 , C08F4/651 , C08F210/08 , C08F2500/12 , C08F4/6555 , C08F4/6492 , C08F4/6545 , C08F4/6565
摘要： A process for preparing a catalyst component, comprising a Mg compound a Ti compound and an electron donor compound (ED) selected from alcohol, glycols, esters, ketones, amines, amides, nitriles, alkoxysilanes and aliphatic ethers as essential compounds, comprising two or more steps of reaction involving the use of at least one of said essential compounds as fresh reactant alone or in a mixture in which it constitutes the main component, said process being characterized by the fact that in the last of said one or more reaction steps the essential compound used as a fresh reactant is the ED compound.
摘要翻译：一种制备催化剂组分的方法，包括Mg化合物，Ti化合物和选自醇，二醇，酯，酮，胺，酰胺，腈，烷氧基硅烷和脂族醚作为必需化合物的电子给体化合物（ED），包括两个或更多的反应步骤涉及使用至少一种所述必需化合物作为新鲜反应物或其构成主要组分的混合物，所述方法的特征在于在所述一个或多个反应步骤的最后一个步骤中，用作新鲜反应物的必需化合物是ED化合物。

16. 发明申请

WO2004085495A1 MAGNESIUM DICHLORIDE-ALCOHOL ADDUCTS AND CATALYST COMPONENTS OBTAINED THEREFROM 审中-公开
标题翻译：二氯化碳 - 醇溶液和催化剂组分
公开(公告)号：WO2004085495A1
公开(公告)日：2004-10-07
申请号：PCT/EP2004/002519
申请日：2004-03-09
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , MORINI, Giampiero , BALBONTIN, Giulio , PIEMONTESI, Fabrizio , FUSTO, Maria , VITALE, Gianni , PRINI, Giansiro
发明人： MORINI, Giampiero , BALBONTIN, Giulio , PIEMONTESI, Fabrizio , FUSTO, Maria , VITALE, Gianni , PRINI, Giansiro
IPC分类号： C08F4/02
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F4/6543 , C08F4/651 , C08F2500/12 , C08F4/65
摘要： The present invention relates to MgCl 2 .(EtOH), m (ROH) n (H 2 0) p adduct in which R is a Cl-C15 hydrocarbon group different from ethyl, n and m are indexes, higher than 0, satisfying the equations (n+m) ≥.7 and 0.05 ≤n/(n+m) ≤0.95 and p is a number ranging from 0 to 0.7 with the proviso that when R is methyl and (n+m) is in the range of 0.7 to 1, the value of n/(n+m) ranges from 0.05 to 0.45. The catalyst components obtained from the adducts of the present invention are capable to give catalysts for the polymerization of olefins characterized by enhanced activity with respect to the catalysts prepared from the adducts of the prior art.
摘要翻译：本发明涉及MgCl 2（EtOH），m（ROH）n（H 2 O）p加合物，其中R是不同于乙基的C 1 -C 15烃基，n和m是指数，高于0，满足等式（n + m）> = 7和0.05 <= n /（n + m）<= 0.95，p为0至0.7的数，条件是当R为甲基且（n + m）为 0.7〜1，n /（n + m）的值为0.05〜0.45。从本发明的加合物得到的催化剂组分能够产生用于烯烃聚合的催化剂，其特征在于相对于由现有技术的加合物制备的催化剂具有增强的活性。

17. 发明申请

WO2019015949A1 PROPYLENE COPOLYMERS 审中-公开
公开(公告)号：WO2019015949A1
公开(公告)日：2019-01-24
申请号：PCT/EP2018/067900
申请日：2018-07-03
申请人： BASELL POLIOLEFINE ITALIA S.R.L.
发明人： MASSARI, Paola , CATHELIN, Caroline , CAVALIERI, Claudio , CIARAFONI, Marco , PANTALEONI, Roberto , MORINI, Giampiero , VITALE, Gianni , PIEMONTESI, Fabrizio , COLLINA, Gianni , GADDI, Benedetta
IPC分类号： C08F210/06 , C08F4/657 , C08J5/18
摘要： A propylene 1-hexene copolymer containing from 5.7 to 7.7% by weight, of 1-hexene derived units having: a) solubility in xylene at 25° C ranging from 7.0 wt% to 15.0 wt%; b) the melting temperature, measured by DSC ranging from 143.0 °C to 148.0° C; c) Melt Flow Rate (MFR, measured according to ASTM D 1238, 230°C/2.16 kg, from 3.5 to 8.0 g/10 min. d) content of 1-hexene derived units in the fraction soluble in xylene at 25°C ranging from 13.5 wt% to 18.5 wt%

18. 发明申请

WO2017021136A1 COMPOSITION COMPRISING PROPYLENE-ETHYLENE-1-BUTENE TERPOLYMERS 审中-公开
标题翻译：包含丙烯 - 乙烯-1-丁烯共聚物的组合物
公开(公告)号：WO2017021136A1
公开(公告)日：2017-02-09
申请号：PCT/EP2016/067141
申请日：2016-07-19
申请人： BASELL POLIOLEFINE ITALIA S.R.L.
发明人： MASSARI, Paola , PIEMONTESI, Fabrizio , VITALE, Gianni , CATHELIN, Caroline , MORINI, Giampiero , CAVALIERI, Claudio , CIARAFONI, Marco , PANTALEONI, Roberto
IPC分类号： C08J5/18 , C08L23/14
CPC分类号： C08L23/142 , C08J5/18 , C08J2323/16 , C08J2423/16 , C08L23/14 , C08L2201/10 , C08L2203/162 , C08L2205/025 , C08F210/06 , C08F4/6574 , C08F4/6492 , C08F2/001 , C08F4/6465 , C08F210/16 , C08F2500/12 , C08F2500/26
摘要： A polyolefin composition comprising: A) from 19 wt% to 50 wt% of a propylene ethylene copolymer having an ethylene derived units content ranging from 1.5 wt% to 6.0 wt% B) from 50 wt% to 81 wt% of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from 1.5 wt% and 6.0 wt% and 1-butene derived units content of between 4.8 wt% and 12.4 wt%; the sum of the amount of component A) and B) being 100; the composition being characterized by the following features: - molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; - the creep and recovery curve measured on the polymer fuse at 200°C measured accordingto the procedure reported in the characterizing section shows a maximum value between 600 and 200 seconds lower than 53x10 -4 1/Pa.
摘要翻译：一种聚烯烃组合物，其包含：A）19重量％至50重量％的乙烯衍生单元含量范围为1.5重量％至6.0重量％的丙烯乙烯共聚物B）50重量％至81重量％的丙烯乙烯1 乙烯衍生单元含量为1.5重量％至6.0重量％，1-丁烯衍生单元含量为4.8重量％至12.4重量％的丁烯三元共聚物; 组分A）和B）的量的总和为100; 该组合物的特征在于以下特征： - 以Mw / Mn表示的分子量分布（MWD）大于4.0; - 根据在特征部分中报道的程序测量的在200℃下聚合物保险丝上测得的蠕变和恢复曲线显示出低于53×10 -4 1 / Pa的600至200秒的最大值。

19. 发明申请

WO2018219583A1 HETEROPHASIC PROPYLENE COPOLYMERS 审中-公开
公开(公告)号：WO2018219583A1
公开(公告)日：2018-12-06
申请号：PCT/EP2018/061306
申请日：2018-05-03
申请人： BASELL POLIOLEFINE ITALIA S.R.L.
发明人： VITALE, Gianni , PIEMONTESI, Fabrizio , GADDI, Benedetta , COLLINA, Gianni , MORINI, Giampiero , CATHELIN, Caroline , CIARAFONI, Marco , FERRARO, Gianpiero , CAVALIERI, Claudio , MASSARI, Paola , GRAZZI, Michele
IPC分类号： C08L23/12 , C08L23/14 , C08F2/00
摘要： Polypropylene composition comprising: A) from 50 wt% to 90 wt%; of a propylene homopolymer; B) from 10 wt% to 50wt%; %; of a copolymer of propylene and ethylene having from 30.0 wt% to 70.0wt%, of ethylene derived units; the composition having: i) an intrinsic viscosity of the fraction soluble in xylene at 25 °C comprised between 2.2 and 4.0 dl/g; ii) a MFR L from 0.5 to 100 g/10 min; iii) a xylene soluble fraction ranging from 10 wt% to 50 wt%;

20. 发明申请

WO2013182474A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF BUTENE-1 审中-公开
标题翻译：催化剂组分对于BUTENE-1的聚合
公开(公告)号：WO2013182474A1
公开(公告)日：2013-12-12
申请号：PCT/EP2013/061158
申请日：2013-05-30
申请人： BASELL POLIOLEFINE ITALIA S.R.L.
发明人： MIGNOGNA, Alessandro , ESPOSITO, Simona , GUIDOTTI, Simona , MORINI, Giampiero , PATER, Joachim T. M. , PIEMONTESI, Fabrizio , VITALE, Gianni
IPC分类号： C08F110/08 , C08F4/651
CPC分类号： C08F4/52 , C08F4/10 , C08F4/16 , C08F110/08 , C08F4/651 , C08F2500/15 , C08F2500/17 , C08F110/06 , C08F2500/12
摘要： Process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I), In which the R groups equal to or different from each other, are C 1 -C 15 hydrocarbon groups, the R 1 -R 2 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0; (b) An aluminium alkyl cocatalyst and (c) an external electron donor
摘要翻译：在催化剂存在下进行的丁烯-1的聚合方法，包括（a）包含Mg，Ti和下式（I）的电子给体化合物的固体催化剂组分，其中R基团等于或不同彼此相同的是C 1 -C 15烃基，R 1 -R 2基彼此相同或不同，是氢，卤素或C 1 -C 15烃基，任选地含有选自卤素，P，S，N的杂原子和 Si，n和m为0-3的整数，条件是它们中的至少一个不同于0; （b）烷基铝助催化剂和（c）外电子给体

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