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11. 发明公开

EP2457639A4 METHOD FOR REMOVING MERCURY FROM COMBUSTION GAS, AND COMBUSTION GAS CLEANER 失效转让
标题翻译：工艺除汞从燃烧的煤气和助燃气体净化器
公开(公告)号：EP2457639A4
公开(公告)日：2013-01-02
申请号：EP10837264
申请日：2010-12-13
申请人： BABCOCK HITACHI KK
发明人： KATO YASUYOSHI , KAI KEIICHIRO , IKEMOTO SEIJI
IPC分类号： B01D53/50 , B01D53/64 , B01D53/75 , B01D53/86 , B03C3/017
CPC分类号： B01D53/75 , B01D53/501 , B01D53/64 , B01D53/8625 , B01D2251/2062 , B01D2251/2067 , B01D2255/20707 , B01D2255/20723 , B01D2255/20769 , B01D2255/2092 , B01D2255/30 , B01D2257/602 , B01D2258/0283 , B03C3/017 , Y02A50/2349
摘要： A method for removing mercury in a combustion exhaust gas according to the present invention comprises: injecting ammonia or urea as a reducing agent into a combustion exhaust gas containing nitrogen oxides, sulfur dioxide, metallic mercury, and hydrogen halides, and then introducing the combustion exhaust gas to a denitration apparatus 7 filled with a denitration catalyst to cause a denitration reaction and oxidize the metallic mercury to produce mercury halide; and introducing the combustion exhaust gas through an air preheater 11 and an electric dust collector 13 to a wet desulfurization apparatus 15, thereby removing sulfur dioxides and the mercury halide, wherein the ammonia concentration of the combustion exhaust gas at an exit of the denitration apparatus 7 is maintained at 5 ppm or higher, and the mercury halide is adsorbed or precipitated onto combustion ash and collected by the electric dust collector 13 to discharge the mercury halide out of a system. Consequently, the rate of mercury removal in the combustion exhaust gas can be improved.

12. 发明公开

EP1938899A4 BASE FOR CATALYST, CATALYST AND METHODS FOR PRODUCING THOSE 有权转让
标题翻译：基础催化剂，催化剂及其制造方法
公开(公告)号：EP1938899A4
公开(公告)日：2010-01-20
申请号：EP06783088
申请日：2006-08-28
申请人： BABCOCK HITACHI KK
发明人： KATO YASUYOSHI , IMADA NAOMI
IPC分类号： B01J35/02 , B01D53/94 , B01J23/30 , B01J35/04 , B01J37/02 , F01N3/10 , F01N3/28
CPC分类号： F01N3/28 , B01D53/8628 , B01D2255/20707 , B01D2255/20723 , B01D2255/20769 , B01D2255/20776 , B01J21/063 , B01J23/30 , B01J31/06 , B01J35/04 , B01J35/1019 , B01J35/1033 , B01J37/0018 , B01J37/0219 , B01J37/0225 , B01J37/024

13. 发明公开

EP2044997A4 APPARATUS FOR REMOVING OF TRACE OF TOXIC SUBSTANCE FROM EXHAUST GAS AND METHOD OF OPERATING THE SAME 有权转让
标题翻译：从废气中去除有毒物质痕迹的装置及其操作方法
公开(公告)号：EP2044997A4
公开(公告)日：2009-08-05
申请号：EP06781656
申请日：2006-07-26
申请人： BABCOCK HITACHI KK
发明人： NAGAI YOSHINORI , KATSUBE TOSHIO , MORITA ISATO , KIKKAWA HIROFUMI , KATO YASUYOSHI
IPC分类号： B01D46/02 , B01D53/64 , B01D53/86 , B01D53/94 , B01J23/28
CPC分类号： B01D53/75 , B01D46/0027 , B01D46/02 , B01D53/501 , B01D53/8625 , B01D53/8665 , B01D2257/2045 , B01D2257/602 , B01J23/22 , B01J23/28 , B01J23/30 , B01J35/06 , B01J37/0036 , B01J37/0063 , B01J37/0215
摘要： An apparatus for removing of traces of toxic substances from exhaust gas, comprising, disposed in sequence from the upstream side in a flow channel of exhaust gas emitted from combustion equipment, a denitration unit including a denitration catalyst layer capable of removing nitrogen oxides from the exhaust gas and capable of oxidizing metallic mercury; an air preheater adapted for heat exchange between air for combustion in the combustion equipment and the exhaust gas; a dust removal unit having a bag filter containing a catalyst for metallic mercury oxidation; and a desulfurization unit for removing sulfur oxide from the exhaust gas. The bag filter may be disposed in advance of the desulfurization unit. Thus, there can be provided an apparatus for removing of traces of toxic substances from exhaust gas that is stable over a prolonged period of time and is highly reliable; and provided a method of operating the same.

14. 发明公开

EP2127743A4 EXHAUST GAS PURIFICATION CATALYST AND METHOD FOR PRODUCTION THEREOF 有权转让
标题翻译：排放物控制催化剂和方法生产同样
公开(公告)号：EP2127743A4
公开(公告)日：2013-09-18
申请号：EP08710637
申请日：2008-01-30
申请人： BABCOCK HITACHI KK
发明人： KATO YASUYOSHI , KAI KEIICHIRO , IMADA NAOMI
IPC分类号： B01J23/31 , B01D53/86 , B01J23/28 , B01J23/30 , B01J27/199 , B01J37/04
CPC分类号： B01J23/31 , B01D53/8665 , B01D2251/2062 , B01D2255/20707 , B01D2255/20723 , B01D2255/20769 , B01D2255/20776 , B01D2257/404 , B01D2257/602 , B01J23/002 , B01J23/28 , B01J23/30 , B01J27/199 , B01J35/06 , B01J37/28 , B01J2523/00 , B01J2523/47 , B01J2523/54 , B01J2523/55 , B01J2523/69 , B01J2523/68
摘要： The invention realizes a catalyst which is hardly deteriorated even when volatile catalyst-poisoning compounds such as P and As are accumulated and which can reduce the rate of oxidation of SO 2 to a level as low as a fraction of that of the catalyst in the prior art, and provides an exhaust gas purification catalyst which can maintain a high activity and a low rate of oxidation of SO 2 for a long time even with any diversified coal, a method of producing the same, and an exhaust gas purification method using the same. Disclosed is an exhaust gas purification catalyst having a composition comprising oxides of titanium (Ti), molybdenum (Mo) and/or tungsten (W), vanadium (V) and bismuth (Bi), wherein the atomic ratio of Ti : (Mo and/or W) : V is 75 to 98.9 : 1 to 15 : 0.1 to 10 and the atomic ratio of Bi/(Mo and/or W) is 0.1 to 0.8.

15. 发明公开

EP2269732A4 EXHAUST GAS PURIFICATION CATALYST ON WHICH INFLUENCE OF IRON COMPOUND HAS BEEN SUPPRESSED 有权转让
标题翻译：排放物控制催化剂抑制铁连接的影响
公开(公告)号：EP2269732A4
公开(公告)日：2013-01-02
申请号：EP09725440
申请日：2009-03-25
申请人： BABCOCK HITACHI KK
发明人： KATO YASUYOSHI , IMADA NAOMI , KAI KEIICHIRO
IPC分类号： B01J27/199 , B01D53/86 , B01D53/94 , B01J23/22 , B01J23/28 , B01J23/30 , B01J37/04 , B01J37/08 , B01J37/28
CPC分类号： B01J27/199 , B01D53/64 , B01D53/8628 , B01D53/8665 , B01D2255/20707 , B01D2255/20723 , B01D2255/20769 , B01D2255/20776 , B01J21/063 , B01J23/22 , B01J23/28 , B01J23/30 , B01J35/06 , B01J37/0225 , B01J37/04 , B01J37/28
摘要： There are provided an exhaust gas purification catalyst which can suppress an increase in SO 2 oxidation with an increase in a Fe component in the catalyst with the lapse of time attributable to internal and external causes and, even in exhaust gases of fuels having a high Fe content such as high S coals, can realize operation at a low SO 2 oxidation rate for a long period of time, and a process for producing the same. The exhaust gas purification catalyst containing titanium oxide as a main component and an oxide of one element or two or more elements selected from the group consisting of tungsten (W), molybdenum (Mo), and vanadium (V) as an active component, wherein the exhaust gas purification catalyst contains phosphoric acid or a water soluble phosphoric acid compound so that the atomic ratio of phosphorus (P) to a catalytically active component represented by the following formula is more than 0 and 1.0 or less; P / catalytically active component atomic ratio = number of moles of P / number of moles of W + number of moles of Mo + number of moles of V

16. 发明公开

EP2075060A4 CATALYST FOR OXIDATION OF METAL MERCURY 审中-公开
标题翻译：催化剂氧化的金属汞
公开(公告)号：EP2075060A4
公开(公告)日：2010-05-19
申请号：EP07807748
申请日：2007-09-21
申请人： BABCOCK HITACHI KK
发明人： KAI KEIICHIRO , KATO YASUYOSHI
IPC分类号： B01J23/28 , B01D53/86 , B01J23/22 , B01J23/30
CPC分类号： B01J23/28 , B01D53/8665 , B01D2255/20723 , B01D2255/20769 , B01D2255/20776 , B01J23/002 , B01J23/30 , B01J35/002 , B01J37/0225 , B01J37/0244 , B01J2523/00 , B01J2523/55 , B01J2523/68

17. 发明公开

EP1314698A4 PROCESS AND APPARATUS FOR TREATING AMMONIA-CONTAINING WASTE WATER 有权
标题翻译： VERFAHREN UND VORRICHTUNG ZUR BEHANDLUNG VON AMMONIAKHALTIGEM ABWASSER
公开(公告)号：EP1314698A4
公开(公告)日：2004-07-07
申请号：EP01917738
申请日：2001-03-30
申请人： BABCOCK HITACHI KK
发明人： KIKKAWA HIROFUMI , KATO YASUYOSHI , TAKAMOTO SHIGEHITO , NAKAMOTO TAKANORI
IPC分类号： B01D3/38 , B01J21/06 , B01J23/648 , B01J23/652 , C01C1/10 , C02F1/02 , C02F1/20 , B01D53/86 , C02F1/58
CPC分类号： B01J23/652 , B01D3/38 , B01J21/063 , B01J23/6482 , B01J23/6527 , C01C1/10 , C02F1/02 , C02F1/20 , C02F2101/16 , C02F2209/14 , C02F2209/40 , Y02P20/52 , Y02P20/584
摘要： A process for treating an ammonia-containing wastewater, which comprises the steps of contacting an ammonia-containing wastewater A with steam C (carrier gas) in a stripping column (7) to transfer NH3 to a gas phase from the ammonia-containing wastewater A; heating the resultant gas containing NH3 in a preheater (11)and then contacting the gas with a catalyst layer (13) to decompose NH3 into nitrogen and water; measuring the NOx (or N2O) content of the gas generated in the above decomposition step; and adjusting, based on the measured values of the NOx (or N2O) content, one or more of (a) the feed rate of the ammonia-containing wastewater, (b) the NH3 content of the ammonia-containing wastewater and (c) the flow rate of the gas containing NH3 to be contacted with the catalyst layer [when the N2O content is measured, one or more of the flow rate of the carrier gas, the flow rate of an added gas such as air, and the flow rate of the part of the gas generated in the above decomposition step to be recycled to the catalyst layer]. The process is advantageous in that an extremely small amount of hazardous substances such as NOx is discharged even at the start of an apparatus for the process or when the NH3 content of a gas is considerably changed.
摘要翻译：公开了用于处理含氨废水的方法和装置，其中在开始操作装置时形成的有害物质如NOx形成的量甚至在气体中的氨（NH 3）浓度为经受NH3分解步骤（如下所述）变化极小; 在该方法中，含NH 3的流出物A和蒸气（载气）C在汽提塔7中接触以将NH 3从流出物转移到气相，含有在塔中汽提的NH 3的气体用预热器1 然后与催化剂13接触以将NH 3分解成氮和水，确定包含在气体中的NO x（或N 2 O）在NH 3分解步骤中的浓度，并且参数（a）中的一个或多个供应到汽提步骤的流出物，（b）流出物中所含的NH 3的浓度，和（c）与催化剂接触的含NH 3的气体的流量（当确定N 2 O浓度时，一个或多个（e'）载气的流量，（f'）要添加到含NH 3气体中的气体的量（f'），（g'）一部分气体的量 NH 3分解步骤并循环）根据NOx（或N 2 O）的浓度来调节）。

18. 发明公开

EP2474349A4 METHOD FOR PROCESSING EXHAUST GAS OF CO2 COLLECTOR 审中-公开
标题翻译：一种用于处理二氧化碳收集设备的废气的
公开(公告)号：EP2474349A4
公开(公告)日：2014-07-23
申请号：EP10806411
申请日：2010-08-02
申请人： BABCOCK HITACHI KK
发明人： KATO YASUYOSHI , FUJISAWA MASATOSHI
IPC分类号： B01D53/62 , C01B32/50
CPC分类号： B01D53/1475 , B01D53/8621 , B01D53/90 , B01D2251/10 , B01D2252/204 , B01D2255/20707 , B01D2255/20723 , B01D2255/20769 , B01D2255/20776 , B01D2257/30 , B01D2257/404 , B01D2257/504 , F23J2215/50 , F23J2219/40 , Y02A50/2342 , Y02C10/04 , Y02C10/06
摘要： Provided is a method capable of removing a low concentration of amines contained in an exhaust gas that is discharged from a CO 2 recovery process, at low temperature with high efficiency. A method of treating an exhaust gas containing carbon dioxide, the method including absorbing and removing CO 2 by bringing an exhaust gas containing carbon dioxide (CO 2 ) and nitrogen oxides, into contact with a CO 2 absorbent liquid containing amines, subsequently bringing the resultant into contact with a catalyst comprising titanium oxide and an oxide of vanadium (V), or from titanium oxide, an oxide of vanadium (V) and an oxide of molybdenum (Mo) or tungsten (W), at a temperature of 130°C to 250°C, and thereby oxidizing and removing the amines.

19. 发明公开

EP2548640A4 METHOD AND DEVICE FOR TREATING GAS DISCHARGED FROM A CARBON DIOXIDE RECOVERY DEVICE 审中-公开
标题翻译：方法和装置的二氧化碳从恢复装置释放的气体处理
公开(公告)号：EP2548640A4
公开(公告)日：2014-03-05
申请号：EP11756164
申请日：2011-03-10
申请人： BABCOCK HITACHI KK
发明人： FUJISAWA MASATOSHI , MORITA ISATO , KATO YASUYOSHI
IPC分类号： B01J23/28 , B01D53/54 , B01D53/86 , B01J20/06 , B01J23/22 , B01J23/30
CPC分类号： B01D53/1493 , B01D53/1475 , B01D53/8621 , B01D2251/102 , B01D2255/20707 , B01D2255/20723 , B01D2255/20769 , B01D2255/20776 , B01J21/063 , B01J23/22 , B01J23/28 , B01J35/04 , B01J37/0203 , B01J37/0215 , Y02A50/2342 , Y02C10/06
摘要： An object of the present invention is to provide a method and a device, which can suppress poisoning due to CO and efficiently remove a low concentration of amines contained in a gas discharged from a CO 2 recovery device that uses various absorbing liquids of CO 2 even at low temperature. A dischraged gas treatment method for removing amines as absorbent contained in a gas discharged from a CO 2 removal device, in which the CO 2 removal device has used the amines, the method comprising alternatively performing the step of passing the discharged gas through a catalyst-packed bed which is packed with a catalyst composed of titanium oxide and an oxide of vanadium (V) or titanium oxide, an oxide of vanadium and an oxide of molybdenum (Mo) or tungsten (W), to adsorb and remove the amines contained in the discharged gas; and the step of passing heated air through the catalyst-packed bed wherein the amines are adsorbed thereon to heat the catalyst, and at the same time performing elimination and oxidative decomposition of the adsorbed amines.

20. 发明公开

EP2517772A4 METHOD FOR CLEANING USED DENITRATION CATALYST 有权转让
标题翻译：使用的脱硝催化剂的方法RENIGUNG
公开(公告)号：EP2517772A4
公开(公告)日：2013-08-14
申请号：EP10839314
申请日：2010-12-17
申请人： BABCOCK HITACHI KK
发明人： IKEMOTO SEIJI , KATO YASUYOSHI , KAI KEIICHIRO
IPC分类号： B01D53/94 , B01D53/64 , B01D53/96 , B01J20/02 , B01J20/06 , B01J20/08 , B01J20/14 , B01J20/20 , B01J23/92 , B01J38/48 , B01J38/62
CPC分类号： B01J23/92 , B01D53/64 , B01D53/8625 , B01D53/88 , B01D53/9409 , B01D53/96 , B01D2255/106 , B01D2257/602 , B01J20/0233 , B01J20/06 , B01J20/08 , B01J20/14 , B01J20/20 , B01J20/28016 , B01J20/28045 , B01J20/3204 , B01J20/3236 , B01J20/34 , B01J20/345 , B01J21/20 , B01J38/62 , B01J2220/56
摘要： Provided is a method for cleaning a used denitration catalyst, which prevents release of mercury to the atmosphere by collecting and removing mercury which would have been released to the atmosphere in the process of cleaning the used denitration catalyst. The method comprises immersing the used denitration catalyst mainly composed of titanium oxide and having been used in exhaust gas containing mercury in a cleaning liquid, and stirring the cleaning liquid to dissolve and remove catalyst poisons including the mercury from the used denitration catalyst, wherein a waste gas generated in the step of stirring the cleaning liquid is conducted to a flue having a mercury removal device so as to remove the mercury, and then vented to the atmosphere.

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