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11. 发明授权

US5996976A Gas humidification system using water permeable membranes 失效
标题翻译：使用透水膜的气体加湿系统
公开(公告)号：US5996976A
公开(公告)日：1999-12-07
申请号：US641210
申请日：1996-04-30
申请人： Oliver J. Murphy , G. Duncan Hitchens , Alan J. Cisar , Anuncia Gonzalez-Martin
发明人： Oliver J. Murphy , G. Duncan Hitchens , Alan J. Cisar , Anuncia Gonzalez-Martin
IPC分类号： B01D53/22 , B01D53/32 , B01F3/02 , B01J8/00 , B01J19/24 , C02F1/00 , C02F1/461 , C25B1/13 , C25B9/08 , C25B13/02 , H01M8/02 , H01M8/04 , H01M8/10 , H01M8/18 , B01F3/04
CPC分类号： C25B1/13 , B01D53/22 , B01D53/326 , B01F3/022 , B01J19/2475 , B01J8/009 , C02F1/4618 , C25B13/02 , C25B9/08 , H01M8/04119 , H01M8/1007 , H01M8/1023 , H01M8/1039 , H01M8/1065 , B01J2208/00061 , B01J2208/00132 , B01J2208/00256 , B01J2208/00539 , B01J2208/00584 , B01J2219/00058 , B01J2219/00063 , B01J2219/00067 , B01J2219/00069 , B01J2219/00081 , B01J2219/00099 , B01J2219/00103 , B01J2219/00135 , B01J2219/00162 , B01J2219/00171 , B01J2219/00184 , C02F2001/46142 , C02F2101/30 , C02F2303/04 , C02F2305/023 , H01M2300/0082 , H01M8/0202 , H01M8/04291 , H01M8/186 , Y02C20/30 , Y02E60/528
摘要： The present invention provides a gas humidifier for the humidification of reactant gases supplied to electrochemical devices such as electrolyzers and fuel cells. The humidifier provides a water permeable member, such as a polymer membrane in the form of a tube, sheet, tubulated sheet and the like, that can be saturated with water to allow evaporation of water into a gas stream passing over a water permeable member. The humidifier is compact and lightweight, yet provides efficient humidification of gases at flow rates as low as about 0.1 grams per minute of water.
摘要翻译：本发明提供一种用于加湿供应到电化学装置如电解槽和燃料电池的反应气体的气体加湿器。加湿器提供可渗透的构件，例如管，片，管状片等形式的聚合物膜，其可以被水饱和，以允许水蒸发成通过透水构件的气流。加湿器结构紧凑，重量轻，而且以低于每分钟0.1克/分钟的流速提供有效的气体加湿。

12. 发明授权

US06804949B2 Water sources for automotive devices 失效
标题翻译：汽车设备用水源
公开(公告)号：US06804949B2
公开(公告)日：2004-10-19
申请号：US10226361
申请日：2002-08-22
申请人： Craig C. Andrews , Alan J. Cisar , Carlos Salinas , Oliver J. Murphy , A. John Appleby
发明人： Craig C. Andrews , Alan J. Cisar , Carlos Salinas , Oliver J. Murphy , A. John Appleby
IPC分类号： F01N300
CPC分类号： C25B15/08 , F01N2240/22 , F02B43/10 , F02B47/02 , F02B2043/106 , Y02T10/121 , Y02T10/32 , Y02T90/42
摘要： The present invention provides a self-replenishing liquid water source onboard an automobile for supplying liquid water to an electrolyzer, such as an on-board hydrogen generator useful for the suppression of unwanted emissions. While automobiles typically have water reservoirs resupplied by a person, the invention provides a passive means of water collection for reliable replenishment due to operations of the automobile itself. The invention provides condensate from the engine exhaust gas by cooling a region of the exhaust system using cooling fluid from the engine coolant system. The cooling fluid is circulated during a period following the engine cold start event when the heat load on the engine coolant system is low.
摘要翻译：本发明提供了一种用于向电解器供应液体水的汽车上的自补充液体水源，例如可用于抑制不期望的排放物的板上氢气发生器。虽然汽车通常具有由人员补充的储水器，但是由于汽车本身的操作，本发明提供了一种被动的水收集装置，用于可靠的补给。本发明通过使用来自发动机冷却剂系统的冷却流体冷却排气系统的区域来提供来自发动机废气的冷凝物。当发动机冷启动事件发动机冷却系统的热负荷低时，冷却液循环。

13. 发明授权

US6040072A Apparatus and method for compressing a stack of electrochemical cells 失效
标题翻译：用于压缩电化学电池堆的装置和方法
公开(公告)号：US6040072A
公开(公告)日：2000-03-21
申请号：US974384
申请日：1997-11-19
申请人： Oliver J. Murphy , Carlos Salinas , Alan J. Cisar
发明人： Oliver J. Murphy , Carlos Salinas , Alan J. Cisar
IPC分类号： C25B9/18 , H01M8/24
CPC分类号： C25B9/18 , H01M8/247
摘要： The present invention provides an apparatus and method for assembling an electrochemical cell stack, or an assemblage of components which need to be clamped together, especially where minimizing the size and weight of the clamping mechanism is advantageous. The invention encompasses combining a band or strap to transmit load to a plurality of components. A metal link is provided to apply greater tension to the band than could normally be achieved with the band alone. The invention may provide a band having a spiral screw clamp wherein the screw portion is used to apply and control tension in the band and the band is used to transmit the tension to a plurality of components. The invention also provides systems that improve the distribution of the force over a portion of the assembly, preferably the entire area of at least one face of the assembly. The invention encompasses a system with straps surrounding a fuel cell stack placed between two end plates, with raised ridges placed under the strapping system to concentrate the compressive force at selected points on the endplates. The invention also encompasses a device comprising an array of adjustable elements that control the distribution of the compressive load.
摘要翻译：本发明提供一种用于组装电化学电池堆的装置和方法，或需要夹紧在一起的组件的组合，特别是在最小化夹紧机构的尺寸和重量的情况下是有利的。本发明包括组合带或带以将负载传输到多个组件。提供金属连接件以对带宽施加比通常可以单独实现的带宽更大的张力。本发明可以提供具有螺旋螺旋夹具的带，其中螺钉部分用于施加和控制带中的张力，并且带用于将张力传递到多个部件。本发明还提供了改善组件部分上的力的分布的系统，优选组件的至少一个面的整个区域。本发明包括具有围绕放置在两个端板之间的燃料电池堆的带的系统，其具有放置在捆扎系统下方的凸脊，以将压缩力集中在端板上的选定点处。本发明还包括一种包括控制压缩载荷分布的可调元件阵列的装置。

14. 发明授权

US06232010B1 Unitized barrier and flow control device for electrochemical reactors 有权
标题翻译：用于电化学反应器的单元化屏障和流量控制装置
公开(公告)号：US06232010B1
公开(公告)日：2001-05-15
申请号：US09307410
申请日：1999-05-08
申请人： Alan J. Cisar , Oliver J. Murphy , King-Tsai Jeng , Carlos Salinas , Stan Simpson , Dacong Weng , Homayoun Moaddel
发明人： Alan J. Cisar , Oliver J. Murphy , King-Tsai Jeng , Carlos Salinas , Stan Simpson , Dacong Weng , Homayoun Moaddel
IPC分类号： H01M486
CPC分类号： H01M8/0258 , H01M4/8605 , H01M4/9083 , H01M4/96 , H01M8/0202 , H01M8/0204 , H01M8/0206 , H01M8/0228 , H01M8/0232 , H01M8/0234 , H01M8/0239 , H01M8/0243 , H01M8/0245 , H01M8/0267 , H01M8/0297 , H01M8/241 , H01M2008/1095
摘要： The invention provides for reducing the number of parts and the number of interfaces found in certain types of chemical reactors, particularly in electrochemical reactors, and especially in the type or reactor known as a fuel cell or fuel cell stack. This reduction comes from the use of a unified structure that combines the functions normally carried out by several components in the unit, particularly by combining the functions of the gas distribution structure and the gas diffusion structure, the gas distribution structure and the gas barrier structure, or all three structures into a single, unitary, metallic part. This offers the advantages of simplified design, better performance, and lighter weight.
摘要翻译：本发明提供减少在某些类型的化学反应器中发现的部件数量和接头数量，特别是在电化学反应器中，特别是在称为燃料电池或燃料电池堆的型式或反应器中。这种减少来自使用将通常由单元中的几个部件执行的功能组合的统一结构，特别是通过组合气体分配结构和气体扩散结构，气体分配结构和气体阻隔结构的功能，或所有三种结构成为单一，单一的金属部分。这提供了简化设计，更好的性能和更轻的重量的优点。

15. 发明授权

US5958616A Membrane and electrode structure for methanol fuel cell 失效
标题翻译：甲醇燃料电池膜和电极结构
公开(公告)号：US5958616A
公开(公告)日：1999-09-28
申请号：US19733
申请日：1998-02-06
申请人： Carlos Salinas , Stanley F. Simpson , Oliver J. Murphy , Kryzysztof Franaszczuk , Homayoun Moaddel , Dacong Weng
发明人： Carlos Salinas , Stanley F. Simpson , Oliver J. Murphy , Kryzysztof Franaszczuk , Homayoun Moaddel , Dacong Weng
IPC分类号： H01M8/02 , H01M8/10 , H01M8/24 , H01M4/86
CPC分类号： H01M8/1093 , H01M8/0289 , H01M8/1023 , H01M8/1039 , H01M8/1065 , H01M2300/0082 , H01M8/1009 , H01M8/2455 , Y02P70/56
摘要： The invention provides devices and techniques for reducing or eliminating fuel crossover from the anode to the cathode in fuel cells using organic fuels. The invention particularly provides proton exchange membranes having passages or channels with or without a catalyst layer active for the electrochemical oxidation of a fuel. The invention reduces fuel crossover by providing void spaces within the membrane where the fuel may be sequestered as it diffuses through the membrane from the anode to the cathode. The sequestered fuel may be removed physically and/or electrochemically. The invention provides for physical removal of the sequestered fuel by means of flowing a gas stream or a liquid stream through the passages thus evacuating the fuel before it diffuses to the cathode. Electrochemical removal of the fuel involves coating the inner walls of the passages with a catalyst, electronically connecting the catalyst with the anode, and electrooxidation of the crossover fuel sequestered in contact with the catalyst which is active for this oxidation process.
摘要翻译：本发明提供了用于减少或消除使用有机燃料的燃料电池中从阳极到阴极的燃料交叉的装置和技术。本发明特别提供了具有或不具有用于燃料的电化学氧化活性的催化剂层的通道或通道的质子交换膜。本发明通过在膜内提供空隙来减少燃料交叉，其中燃料可以通过膜从阳极扩散到阴极而被隔离。隔离燃料可以物理和/或电化学去除。本发明提供了通过使气体流或液体流流过通道从而物理去除隔离燃料，从而在燃料扩散到阴极之前抽空燃料。燃料的电化学去除包括用催化剂涂覆通道的内壁，将催化剂与阳极电连接，并与与该氧化过程有活性的催化剂相接触的交换燃料电氧化。

16. 发明授权

US06562507B1 Unitized barrier and flow control device for electrochemical reactors 失效
标题翻译：用于电化学反应器的单元化屏障和流量控制装置
公开(公告)号：US06562507B1
公开(公告)日：2003-05-13
申请号：US09680377
申请日：2000-10-05
申请人： Alan J. Cisar , Oliver J. Murphy , King-Tsai Jeng , Carlos Salinas , Stan Simpson
发明人： Alan J. Cisar , Oliver J. Murphy , King-Tsai Jeng , Carlos Salinas , Stan Simpson
IPC分类号： H01M486
CPC分类号： H01M8/0258 , H01M4/8605 , H01M4/9083 , H01M4/96 , H01M8/0202 , H01M8/0204 , H01M8/0206 , H01M8/0228 , H01M8/0232 , H01M8/0234 , H01M8/0239 , H01M8/0243 , H01M8/0245 , H01M8/0267 , H01M8/0297 , H01M8/241 , H01M2008/1095
摘要： The invention provides for reducing the number of parts and the number of interfaces found in certain types of chemical reactors, particularly in electrochemical reactors, and especially in the type or reactor known as a fuel cell or fuel cell stack This reduction comes from the use of a unified structure that combines the functions normally carried out by several components in the unit, particularly by combining the functions of the gas distribution structure and the gas diffusion structure, the gas distribution structure and the gas barrier structure, or all three structures into a single, unitary, metallic part. This offers the advantages of simplified design, better performance, and lighter weight.
摘要翻译：本发明提供减少在某些类型的化学反应器，特别是在电化学反应器中，特别是在称为燃料电池或燃料电池堆的类型或反应器中发现的界面的数量以及接触的数量。这种减少来自使用结合了通常由单元中的几个部件执行的功能的统一结构，特别是通过将气体分配结构和气体扩散结构，气体分布结构和气体阻隔结构的功能，或所有三种结构组合成单个一体，金属部分。这提供了简化设计，更好的性能和更轻的重量的优点。

17. 发明授权

US07641889B1 Hydrogen generator 失效
标题翻译：氢发生器
公开(公告)号：US07641889B1
公开(公告)日：2010-01-05
申请号：US10845971
申请日：2004-05-14
申请人： Carlos Salinas , Alan Cisar , Eric Clarke , Oliver J. Murphy , Brad Fiebig
发明人： Carlos Salinas , Alan Cisar , Eric Clarke , Oliver J. Murphy , Brad Fiebig
IPC分类号： C01B3/00 , C01B3/08 , C01B3/02 , B01J7/00 , H01M8/06
CPC分类号： C01B3/065 , B01J4/001 , B01J4/02 , Y02E60/362
摘要： An apparatus and method apply water to a hydrogen-containing composition, such as a hydride, in the presence of a catalyst that promotes hydrolysis to generate hydrogen in a controlled manner. The amount of catalyst used can be carefully tailored so that the reaction rate is limited by the amount of catalyst present (passive control) or it can be sufficiently large so that the reaction is controlled by the rate of water addition (active control).
摘要翻译：一种装置和方法，在催化剂存在下，将水用于含氢组合物如氢化物，催化剂以受控的方式促进水解产生氢。可以仔细地调整所用催化剂的量，使得反应速度受到存在的催化剂量（被动控制）的限制，或者可以足够大以使反应受添加速率（主动控制）的控制。

18. 发明授权

US07608350B2 Preparation and storage of membrane and electrode assemblies 失效
标题翻译：膜和电极组件的制备和储存
公开(公告)号：US07608350B2
公开(公告)日：2009-10-27
申请号：US10828507
申请日：2004-04-19
申请人： Oliver J. Murphy , Carlos Salinas
发明人： Oliver J. Murphy , Carlos Salinas
IPC分类号： H01M8/00 , H01M8/10 , H01M4/82 , H01M6/00
CPC分类号： H01M8/1004 , C25B9/10 , H01M4/881 , H01M4/90 , H01M8/0271 , H01M8/0289 , H01M8/04067 , Y10T29/49108
摘要： Protecting a membrane and electrode assembly in an electrochemical cell having one or more electrocatalysts in intimate contact with the membrane during storage or shipment of the cell. The membrane may be provided in either the non-proton form of a dry or hydrated cation exchange membrane, such as an alkali metal cation form or an ammonium cation form; the wet or dry precursor form of a cation exchange membrane, such as the non-ionically conducting sulfonyl-fluoride polymer membrane; or the dry proton form of a cation exchange membrane. These membrane surfaces are not acidic under open circuit conditions experienced during storage or shipment of the cell. Since some electrocatalysts are degraded during contact with the acidic surface of a hydrated membrane, the non-acidic surface of the membrane protects these electrocatalysts. The method may be used on newly assembled electrochemical cells, on cells being taken out of service, and on membrane and electrode assemblies.
摘要翻译：在具有一个或多个电催化剂的电化学电池中保护膜和电极组件，在电池的存储或运输期间与膜紧密接触。膜可以以非质子形式的干或水合阳离子交换膜提供，例如碱金属阳离子形式或铵阳离子形式; 阳离子交换膜的湿或干前体形式，例如非离子导电的磺酰氟聚合物膜; 或阳离子交换膜的干质子形式。这些膜表面在储存或运输电池过程中经历的开路条件下不是酸性的。由于一些电催化剂在与水合膜的酸性表面接触期间降解，膜的非酸性表面保护这些电催化剂。该方法可用于新组装的电化学电池，电池被取出使用，以及膜和电极组件上。

19. 发明授权

US06464854B2 Water sources for automotive electrolyzers 失效
标题翻译：汽车电解槽水源
公开(公告)号：US06464854B2
公开(公告)日：2002-10-15
申请号：US09494679
申请日：2000-01-31
申请人： Craig C. Andrews , A. John Appleby , Alan J. Cisar , Carlos Salinas , Oliver J. Murphy
发明人： Craig C. Andrews , A. John Appleby , Alan J. Cisar , Carlos Salinas , Oliver J. Murphy
IPC分类号： C25C102
CPC分类号： C25B15/08 , F01N2240/22 , F02B43/10 , F02B47/02 , F02B2043/106 , Y02T10/121 , Y02T10/32 , Y02T90/42
摘要： The present invention provides a self-replenishing liquid water source onboard an automobile for supplying liquid water to an electrolyzer, such as an on-board hydrogen generator useful for the suppression of unwanted emissions. While automobiles typically have water reservoirs resupplied by a person, the invention provides a passive means of water collection for reliable replenishment due to operations of the automobile itself. The invention provides condensate from the engine exhaust gas by cooling a region of the exhaust system using cooling fluid from the engine coolant system. The cooling fluid is circulated during a period following the engine cold start event when the heat load on the engine coolant system is low.
摘要翻译：本发明提供了一种用于向电解器供应液体水的汽车上的自补充液体水源，例如可用于抑制不期望的排放物的板上氢气发生器。虽然汽车通常具有由人员补充的储水器，但是由于汽车本身的操作，本发明提供了一种被动的水收集装置，用于可靠的补给。本发明通过使用来自发动机冷却剂系统的冷却流体冷却排气系统的区域来提供来自发动机废气的冷凝物。当发动机冷启动事件发动机冷却系统的热负荷低时，冷却液循环。

20. 发明授权

US06426161B1 Lightweight metal bipolar plates and methods for making the same 失效
标题翻译：轻质金属双极板及其制作方法
公开(公告)号：US06426161B1
公开(公告)日：2002-07-30
申请号：US09699308
申请日：2000-10-25
申请人： Alan J. Cisar , Oliver J. Murphy , King-Tsai Jeng , Carlos Salinas , Stan Simpson , Dacong Weng
发明人： Alan J. Cisar , Oliver J. Murphy , King-Tsai Jeng , Carlos Salinas , Stan Simpson , Dacong Weng
IPC分类号： H01M214
CPC分类号： H01M8/0228 , H01M8/0206 , H01M2008/1095 , Y02P70/56 , Y10T29/49115
摘要： Thin, light weight bipolar plates for use in electrochemical cells are rapidly, and inexpensively manufactured in mass production by die casting, stamping or other well known methods for fabricating magnesium or aluminum parts. The use of a light metal, such as magnesium or aluminum minimizes weight and simultaneously improves both electrical and thermal conductivity compared to conventional carbon parts. For service in electrochemical cells these components must be protected from corrosion. This is accomplished by plating the surface of the light weight metal parts with a layer of denser, but more noble metal. The protective metal layer is deposited in one of several ways. One of these is deposition from an aqueous solution by either electroless means, electrolytic means, or a combination of the two. Another is deposition by electrolytic means from a non-aqueous solution, such as a molten salt.
摘要翻译：用于电化学电池的薄型，轻质双极板快速地通过压铸，冲压或用于制造镁或铝部件的众所周知的方法批量生产制造。使用诸如镁或铝的轻金属最小化重量，并且与传统的碳部件相比同时提高了导电和导热性。为了在电化学电池中使用，这些组件必须防止腐蚀。这是通过用更致密，但更贵重的金属层对轻质金属部件的表面进行电镀来实现的。保护金属层以几种方式之一沉积。其中之一是通过无电解装置，电解装置或两者的组合从水溶液中沉积。另一种是通过电解方法从非水溶液如熔融盐沉积。

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