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11. 发明授权

US07786200B2 Sulfur-containing silane, filled elastomeric compositions containing same and articles made therefrom 有权
公开(公告)号：US07786200B2
公开(公告)日：2010-08-31
申请号：US12221175
申请日：2008-07-31
申请人： Lesley Hwang , Antonio Chaves , Eric R. Pohl
发明人： Lesley Hwang , Antonio Chaves , Eric R. Pohl
IPC分类号： B60C1/00 , C07F7/04
CPC分类号： C07F7/1804
摘要： Sulfur-containing silane and its partially to substantially complete hydrolyzate(s) are useful as additives for filled elastomeric compositions for tires and other cured rubber articles.

12. 发明申请

US20100174019A1 Silated Cyclic Core Polysulfides, Their Preparation And Use In Filled Elastomer Compositions 有权
标题翻译：硅酸化环状核心多硫化物，其制备和用于填充弹性体组合物
公开(公告)号：US20100174019A1
公开(公告)日：2010-07-08
申请号：US12706193
申请日：2010-02-16
申请人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Prashant Joshi
发明人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Prashant Joshi
IPC分类号： C08K5/548 , C07F7/08
CPC分类号： C08K5/548 , C07F7/1804
摘要： This invention relates to novel sulfur-containing silane coupling agents, and organic polymers containing carbon-carbon double bonds. These novel silanes can be carried on organic and inorganic fillers. The invention also relates to articles of manufacture, particularly tires, made from the elastomer compositions described herein.
摘要翻译：本发明涉及新型含硫硅烷偶联剂和含有碳 - 碳双键的有机聚合物。这些新型硅烷可以带有机和无机填料。本发明还涉及由本文所述的弹性体组合物制成的制品，特别是轮胎。

13. 发明申请

US20080161459A1 Silated cyclic core polysulfides, their preparation and use in filled elastomer compositions 有权
标题翻译：硅酸化的环状核心多硫化物，它们的制备和在填充的弹性体组合物中的用途
公开(公告)号：US20080161459A1
公开(公告)日：2008-07-03
申请号：US11647901
申请日：2006-12-28
申请人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Prashant Joshi
发明人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Prashant Joshi
IPC分类号： C08G77/06 , C08J3/05
CPC分类号： C08K5/548 , C07F7/1804
摘要： This invention relates to novel sulfur-containing silane coupling agents, and organic polymers containing carbon-carbon double bonds. These novel silanes can be carried on organic and inorganic fillers. The invention also relates to articles of manufacture, particularly tires, made from the elastomer compositions described herein.
摘要翻译：本发明涉及新型含硫硅烷偶联剂和含有碳 - 碳双键的有机聚合物。这些新型硅烷可以带有机和无机填料。本发明还涉及由本文所述的弹性体组合物制成的制品，特别是轮胎。

14. 发明授权

US5714532A Composition of epoxysilane emulsion additives in water based reactive polymer dispersions and methods of preparation 失效
标题翻译：环氧硅烷乳液添加剂在水性反应性聚合物分散体中的组成及制备方法
公开(公告)号：US5714532A
公开(公告)日：1998-02-03
申请号：US735055
申请日：1996-11-07
申请人： Frederick D. Osterholtz , Eric R. Pohl , Ming J. Chen , Antonio Chaves
发明人： Frederick D. Osterholtz , Eric R. Pohl , Ming J. Chen , Antonio Chaves
IPC分类号： C08K5/54 , C08K5/15 , C08K5/5435 , C08L83/06 , C08L101/00 , C09D133/06 , C09D183/06 , C09D201/00
CPC分类号： C08K5/5435 , C09D133/064 , C09D183/06
摘要： The present invention provides stable epoxy silane emulsions and methods for the preparation of a stable epoxy-silane emulsions comprising: (I) a water insoluble or slightly soluble epoxysilane; (II) an emulsifier; (III) water; and (IV) a water dispersible polymer containing a functional group with an active hydrogen. Also provided are two part systems such that an epoxysilane emulsion comprising components (I)-(III) are combined and the component (IV) may be added upon use of components (I) to (III). Moreover, additional components (V), such as catalysts and pH buffers may be added. Said compositions may be used for, among other things, coatings, adhesives and sealants. The water dispersible or slightly soluble epoxy functional silane for use herein are of the general structure R.sup.1.sub.a R.sup.2.sub.b Si(OR.sup.3).sub.4-a-b where R.sup.1 is an epoxy substituted alkyl or aralkyl group, where the alkyl may have from four to thirty carbon atoms, R.sup.3 is an alkyl or alkoxy-substituted alkyl, aryl or aralkyl group having from two to ten carbon atoms, R.sup.2 is an alkyl group or alkoxy substituted alkyl, aryl or aralkyl group having from one to ten carbon atoms, a is one to three, and b is zero to two, with the proviso that a+b is 1, 2, or 3. R.sup.1, R.sup.2, and R.sup.3 group may be cyclic, branched or linear.
摘要翻译：本发明提供稳定的环氧硅烷乳液和制备稳定的环氧硅烷乳液的方法，包括：（I）水不溶性或微溶环氧硅烷; （II）乳化剂; （三）水; 和（IV）含有具有活性氢的官能团的水分散性聚合物。还提供了两部分系统，使得包含组分（I） - （III）的环氧硅烷乳液组合，并且组分（IV）可以在使用组分（I）至（III）时加入。此外，可以加入另外的组分（V），例如催化剂和pH缓冲剂。除其他外，所述组合物可用于涂料，粘合剂和密封剂。用于本文的水分散性或微溶性环氧官能化硅烷具有通式结构R1aR2bSi（OR3）4-ab，其中R1是环氧取代的烷基或芳烷基，其中烷基可以具有4至30个碳原子，R 3是烷基或烷氧基取代的烷基，具有2至10个碳原子的芳基或芳烷基，R 2是烷基或烷氧基取代的烷基，具有1至10个碳原子的芳基或芳烷基，a是1至3，b是 0至2，条件是a + b为1,2或3.R 1，R 2和R 3基团可以是环状，支链或直链的。

15. 发明授权

US08188174B2 Silated core polysulfides, their preparation and use in filled elastomer compositions 有权
标题翻译：硅酸盐核心多硫化物，其制备和用于填充弹性体组合物
公开(公告)号：US08188174B2
公开(公告)日：2012-05-29
申请号：US12702971
申请日：2010-02-09
申请人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Prashant Joshi
发明人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Prashant Joshi
IPC分类号： B60C1/00 , C08K5/24 , C08K3/34
CPC分类号： C08K5/548 , C07F7/1804 , C08L21/00
摘要： This invention relates to novel sulfur-containing silane coupling agents, and organic polymers containing carbon-carbon double bonds. These novel silanes can be carried on organic and inorganic fillers. The invention also relates to articles of manufacture, particularly tires, made from the elastomer compositions described herein.
摘要翻译：本发明涉及新型含硫硅烷偶联剂和含有碳 - 碳双键的有机聚合物。这些新型硅烷可以带有机和无机填料。本发明还涉及由本文所述的弹性体组合物制成的制品，特别是轮胎。

16. 发明申请

US20110213074A1 DIOL-DERIVED ORGANOFUNCTIONAL SILANE AND COMPOSITIONS CONTAINING SAME 有权
标题翻译：二元衍生的有机硅烷及其组合物
公开(公告)号：US20110213074A1
公开(公告)日：2011-09-01
申请号：US13105297
申请日：2011-05-11
申请人： Antonio Chaves , Richard W. Cruse , Eric R. Pohl
发明人： Antonio Chaves , Richard W. Cruse , Eric R. Pohl
IPC分类号： C08L9/00 , C07F7/18
CPC分类号： C08K5/54 , C07F7/1804 , C08K5/549 , C08L21/00
摘要： Described are diol-derived organofunctional silanes in which the silanes contain cyclic and bridged alkoxy groups derived from hydrocarbon-based diols and methods for the preparation of the silanes. Also described are rubber compositions containing the diol-derived organofunctional silanes, methods for the preparation of the rubber compositions and articles of manufacture containing the rubber compositions, in particular, automotive tires and components thereof.
摘要翻译：描述了二醇衍生的有机官能硅烷，其中硅烷含有源自烃基二醇的环状和桥连烷氧基以及制备硅烷的方法。还描述了含有二醇衍生的有机官能硅烷的橡胶组合物，制备橡胶组合物的方法和含有橡胶组合物，特别是汽车轮胎及其组分的制品。

17. 发明授权

US08383850B2 Blocked mercaptosilane coupling agents, process for making and uses in rubber 有权
标题翻译：封闭的巯基硅烷偶联剂，橡胶制造和使用过程
公开(公告)号：US08383850B2
公开(公告)日：2013-02-26
申请号：US12820198
申请日：2010-06-22
申请人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Tiberiu L. Simandan , Prashant Joshi
发明人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Tiberiu L. Simandan , Prashant Joshi
IPC分类号： C07F7/02 , C07F7/04 , C07F7/08
CPC分类号： C08K5/548 , C07F7/1804 , Y02T10/862 , C08L21/00
摘要： The invention relates to sulfur silane coupling agents containing multiple blocked mercapto groups which are in a state of reduced activity until activated. The coupling agents are advantageously used in rubber formulations, for example, for fabricating tires with low rolling resistance.
摘要翻译：本发明涉及含有多个封闭的巯基的硫硅烷偶联剂，它们在活化之前处于活性降低的状态。偶联剂有利地用于橡胶制剂中，例如用于制造具有低滚动阻力的轮胎。

18. 发明授权

US08097744B2 Free flowing filler composition comprising mercapto-functional silane 有权
标题翻译：包含巯基官能的硅烷的自由流动填料组合物
公开(公告)号：US08097744B2
公开(公告)日：2012-01-17
申请号：US11505055
申请日：2006-08-14
申请人： Antonio Chaves , Eric R. Pohl , Christopher M. Hartshorn
发明人： Antonio Chaves , Eric R. Pohl , Christopher M. Hartshorn
IPC分类号： C07F7/08
CPC分类号： C09C3/12 , C01P2006/22 , C08K5/549 , C09C1/3081 , C08L21/00
摘要： The disclosure herein relates to organofunctional silanes and mixtures of organofunctional silanes possessing mercaptan and hydrocarbyl and/or heterocarbyl functionality. These silanes reduce or eliminate the generation of volatile organic compounds (VOC's) during use, aid in the processing of filled elastomeric materials and enhance the end-use properties of the filled elastomer. The present disclosure relates to a free flowing filler composition comprising these silanes.
摘要翻译：本文的公开内容涉及有机官能硅烷和具有硫醇和烃基和/或杂碳原子官能团的有机官能硅烷的混合物。这些硅烷在使用过程中减少或消除挥发性有机化合物（VOC）的产生，有助于填充弹性体材料的加工，并增强填充弹性体的最终用途性能。本发明涉及包含这些硅烷的自由流动填料组合物。

19. 发明授权

US08067491B2 Silated cyclic core polysulfides, their preparation and use in filled elastomer compositions 有权
标题翻译：硅酸化的环状核心多硫化物，它们的制备和在填充的弹性体组合物中的用途
公开(公告)号：US08067491B2
公开(公告)日：2011-11-29
申请号：US12706193
申请日：2010-02-16
申请人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Prashant Joshi
发明人： Richard W. Cruse , W. Michael York , Eric R. Pohl , Antonio Chaves , Prashant Joshi
IPC分类号： B60C1/00 , C08K5/24 , C08K3/34 , C08K3/04
CPC分类号： C08K5/548 , C07F7/1804
摘要： This invention relates to novel sulfur-containing silane coupling agents, and organic polymers containing carbon-carbon double bonds. These novel silanes can be carried on organic and inorganic fillers. The invention also relates to articles of manufacture, particularly tires, made from the elastomer compositions described herein.
摘要翻译：本发明涉及新型含硫硅烷偶联剂和含有碳 - 碳双键的有机聚合物。这些新型硅烷可以带有机和无机填料。本发明还涉及由本文所述的弹性体组合物制成的制品，特别是轮胎。

20. 发明授权

US08008519B2 Process for making mercapto-functional silane 有权
标题翻译：制备巯基官能硅烷的方法
公开(公告)号：US08008519B2
公开(公告)日：2011-08-30
申请号：US11505166
申请日：2006-08-14
申请人： Antonio Chaves , Eric R. Pohl , Christopher M. Hartshorn
发明人： Antonio Chaves , Eric R. Pohl , Christopher M. Hartshorn
IPC分类号： C07F7/04 , C07F7/08
CPC分类号： C07F7/188 , C07F7/1804 , C08K5/548 , C08K5/549 , C08L21/00
摘要： The disclosure herein relates to organofunctional silanes and mixtures of organofunctional silanes possessing mercaptan and hydrocarbyl and/or heterocarbyl functionality. These silanes reduce or eliminate the generation of volatile organic compounds (VOC's) during use, aid in the processing of filled elastomeric materials and enhance the end-use properties of the filled elastomer. The present disclosure relates to the processes of making a composition of these silanes.
摘要翻译：本文的公开内容涉及有机官能硅烷和具有硫醇和烃基和/或杂碳原子官能团的有机官能硅烷的混合物。这些硅烷在使用过程中减少或消除挥发性有机化合物（VOC）的产生，有助于填充弹性体材料的加工，并增强填充弹性体的最终用途性能。本公开涉及制备这些硅烷的组合物的方法。

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