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11. 发明授权

US6146612A Method for recovering sulfuric acid from sulfate salts 有权
标题翻译：从硫酸盐中回收硫酸的方法
公开(公告)号：US6146612A
公开(公告)日：2000-11-14
申请号：US206948
申请日：1998-12-08
申请人： Hans Albrecht Hasseberg , Hans Joachim Hasselbach , Klaus Huthmacher , Volker Hafner , Harald Heinzel
发明人： Hans Albrecht Hasseberg , Hans Joachim Hasselbach , Klaus Huthmacher , Volker Hafner , Harald Heinzel
IPC分类号： B01D53/34 , B01D53/50 , B01D53/77 , C01B17/58 , C01B17/74 , C07C319/20 , C07C319/28 , C07C323/52 , C07C323/60
CPC分类号： C07C319/20 , C01B17/585 , C01B17/745 , C07C319/28
摘要： A process is provided for the recovery of sulfuric acid from NH.sub.4 HSO.sub.4 and (NH.sub.4).sub.2 SO.sub.4 salts produced from the sulfuric acid hydrolysis of methylmercaptopropionaldehyde (MMP) cyanohydrin to produce 2-hydroxy-4-methylthiobutyric acid (MHA), which can be used as an additive in animal feed. The sulfate salts are combusted in a furnace to produce sulfur dioxide; the sulfur dioxide is contacted with an aqueous solution containing sulfuric acid and hydrogen peroxide, where the sulfur dioxide is converted into sulfuric acid. The product sulfuric acid is recovered.
摘要翻译：提供了从甲基巯基丙醛（MMP）氰醇的硫酸水解产生的NH 4 HSO 4和（NH 4）2 SO 4盐中回收硫酸以产生2-羟基-4-甲硫基丁酸（MHA）的方法，其可以用作动物饲料添加剂。硫酸盐在炉中燃烧以产生二氧化硫; 二氧化硫与含有硫酸和过氧化氢的水溶液接触，其中二氧化硫被转化成硫酸。产物硫酸被回收。

12. 发明授权

US5976609A Process for recovering 2-hydroxy-4-methylthiobutyric acid (MHA), MHA and its use 失效
标题翻译： 2-羟基-4-甲硫基丁酸（MHA），MHA及其用途的回收方法
公开(公告)号：US5976609A
公开(公告)日：1999-11-02
申请号：US776217
申请日：1997-01-13
申请人： Hans-Albrecht Hasseberg , Klaus Huthmacher , Herbert Tanner , Volker Hafner , Harald Heinzel
发明人： Hans-Albrecht Hasseberg , Klaus Huthmacher , Herbert Tanner , Volker Hafner , Harald Heinzel
IPC分类号： A23K1/16 , C07C319/20 , C07C319/28 , C07C323/52 , C07C323/60 , A23L1/305 , A23L1/28 , C15C315/02 , C15C315/06
CPC分类号： C07C319/28 , A23K20/105 , C07C319/20 , Y10S426/807
摘要： It is known to isolate MHA from a reaction mixture obtained by the addition of hydrocyanic acid (HCN) to methyl mercaptopropionic aldehyde (MMP) and the hydrolysis of the methyl mercapto propionic aldehyde cyanohydrine (MMP-CH) obtained thereby with sulphuric acid, in which the reaction mixture is brought into contact with a substantially non-water-miscible organic solvent, in order to form an extraction solution having the solvent and MHA transferred from the reaction mixture, and the MHA is obtained as an extract from this extraction solution by concentration. The simplest and most economical process of the invention concerning the processing of the reaction product which facilitates the production of a highly concentrated product with an extremely low dimer, oligomer and by-product content, is characterised in that the concentration is conducted in such a way that the remaining extract contains less than 4 wt % and preferably less than 2 wt % of water. Animal feed supplement, mixtures for supplementing animal feed, e.g. with methionine or ammonium-MHA.
摘要翻译： PCT No.PCT / EP95 / 02515 Sec。 371日期1997年1月13日 102（e）日期1997年1月13日PCT提交1995年6月28日PCT公布。公开号WO96 / 01809 日本1996年1月25日已知通过将氢氰酸（HCN）加入到甲基巯基丙醛（MMP）中获得的反应混合物和由此获得的甲基巯基丙醛氰基氢醌（MMP-CH）的水解来分离MHA 硫酸，其中使反应混合物与基本上不与水混溶的有机溶剂接触，以形成从反应混合物中转移有溶剂和MHA的提取溶液，并且获得MHA作为该提取液通过浓缩。关于有助于生产具有极低二聚体，低聚物和副产物含量的高浓缩产物的反应产物的加工的本发明的最简单和最经济的方法的特征在于以这种方式进行浓缩剩余的提取物含有小于4重量％，优选小于2重量％的水。动物饲料补充剂，补充动物饲料的混合物。与甲硫氨酸或铵-MAA。

13. 发明授权

US08057749B2 Device for carrying out chemical reactions 失效
标题翻译：进行化学反应的装置
公开(公告)号：US08057749B2
公开(公告)日：2011-11-15
申请号：US12088864
申请日：2006-09-18
申请人： Achim Fischer , Harald Heinzel , Christoph Weckbecker , Klaus Huthmacher
发明人： Achim Fischer , Harald Heinzel , Christoph Weckbecker , Klaus Huthmacher
IPC分类号： B01J8/02 , B01J35/02 , B01J19/00 , B01J8/00 , B01J10/00 , B01J8/04 , B01J19/30
CPC分类号： B01J19/249 , B01J8/008 , B01J8/0278 , B01J8/0453 , B01J8/048 , B01J8/0484 , B01J8/0492 , B01J8/065 , B01J8/067 , B01J2208/00212 , B01J2208/00221 , B01J2219/0002 , B01J2219/2462 , B01J2219/2496 , C07C319/08 , C07C321/04
摘要： A device for carrying out exothermal chemical reactions wherein a gas phase is guided across a fixed bed and allowed to react, comprising a housing and an exchangeable unit wherein the reaction takes place.
摘要翻译：用于进行放热化学反应的装置，其中气相被引导穿过固定床并允许反应，包括壳体和其中发生反应的可交换单元。

14. 发明授权

US07833508B2 Reaction vessel and process for its use 有权
标题翻译：反应容器及其使用方法
公开(公告)号：US07833508B2
公开(公告)日：2010-11-16
申请号：US12501114
申请日：2009-07-10
申请人： Hubert Redlingshöfer , Jan-Olaf Barth , Caspar-Heinrich Finkeldei , Hans Joachim Hasselbach , Stephan Kretz , Harald Heinzel , Christoph Weckbecker
发明人： Hubert Redlingshöfer , Jan-Olaf Barth , Caspar-Heinrich Finkeldei , Hans Joachim Hasselbach , Stephan Kretz , Harald Heinzel , Christoph Weckbecker
IPC分类号： B01J10/00 , C01B17/16
CPC分类号： B01J8/025 , B01J10/005 , B01J19/246 , C01B17/162
摘要： The invention relates to a reaction vessel in which hydrogen sulphide is prepared from sulphur and hydrogen, wherein the reaction vessel consists partly or entirely of a material which is resistant to the reaction mixture, its compounds or elements and retains its resistance even at high temperatures.
摘要翻译：本发明涉及一种其中由硫和氢制备硫化氢的反应容器，其中反应容器部分或全部由对反应混合物，其化合物或元素具有抗性并且甚至在高温下也保持其电阻的材料组成。

15. 发明申请

US20100015037A1 REACTION VESSEL AND PROCESS FOR ITS USE 有权
标题翻译：反应容器及其使用方法
公开(公告)号：US20100015037A1
公开(公告)日：2010-01-21
申请号：US12501114
申请日：2009-07-10
申请人： Hurbert Redlingshöfer , Jan-Olaf Barth , Caspar-Heinrich Finkeldei , Hans Joachim Hasselbach , Stephan Kretz , Harald Heinzel , Christoph Weckbecker
发明人： Hurbert Redlingshöfer , Jan-Olaf Barth , Caspar-Heinrich Finkeldei , Hans Joachim Hasselbach , Stephan Kretz , Harald Heinzel , Christoph Weckbecker
IPC分类号： C01B17/16 , B01J7/00
CPC分类号： B01J8/025 , B01J10/005 , B01J19/246 , C01B17/162
摘要： The invention relates to a reaction vessel in which hydrogen sulphide is prepared from sulphur and hydrogen, wherein the reaction vessel consists partly or entirely of a material which is resistant to the reaction mixture, its compounds or elements and retains its resistance even at high temperatures.
摘要翻译：本发明涉及一种其中由硫和氢制备硫化氢的反应容器，其中反应容器部分或全部由对反应混合物，其化合物或元素具有抗性并且甚至在高温下也保持其电阻的材料组成。

16. 发明授权

US6140536A Process for obtaining 2-hydroxy-4-methylthiobutyric acid (MHA) 有权
标题翻译：获得2-羟基-4-甲硫基丁酸（MHA）的方法
公开(公告)号：US6140536A
公开(公告)日：2000-10-31
申请号：US91796
申请日：1998-09-01
申请人： Hans Albrecht Hasseberg , Hans Joachim Hasselbach , Klaus Huthmacher , Volker Hafner , Harald Heinzel , Barbara Jager
发明人： Hans Albrecht Hasseberg , Hans Joachim Hasselbach , Klaus Huthmacher , Volker Hafner , Harald Heinzel , Barbara Jager
IPC分类号： C07C319/20 , C07C319/28 , C07C323/52 , C07C315/00
CPC分类号： C07C319/28 , C07C319/20
摘要： A method for the isolation of 2-hydroxy-4-methylthiobutyric acid (MHA), wherein MHA is isolated from a reaction mixture obtained by addition of hydrogen cyanide (HCN) to methylmercaptopropionaldehyde (MMP) and hydrolysis by sulphuric acid of the methylmercaptopropionaldehyde cyanohydrin (MMP-CH) thus obtained. The reaction mixture is brought into contact in a liquid/liquid extraction system with an organic solvent substantially immiscible with water, in order to form an extraction solution which contains the solvent and the MHA transferred out of the reaction mixture. By bringing the salt content of the reaction mixture, prior to the liquid/liquid extraction, to a concentration of about >50 wt. % (wt./wt.), preferably >55 wt. %, referred to the sum of the inorganic constituents of the reaction mixture, the coordinated use of energy in the total system is improved, the evaporation of strongly corrosive solutions is avoided, the efficiency of the hydrolysis step is increased and the distribution coefficients during the extraction are improved. The MHA is isolated as the extract from this extraction solution by evaporation, and may be used as animal feed supplement.
摘要翻译： PCT No.PCT / EP96 / 05437 Sec。 371日期：1998年9月1日 102（e）1998年9月1日PCT PCT 1996年12月5日PCT公布。公开号WO97 / 23452 日期1997年7月3日分离2-羟基-4-甲硫基丁酸（MHA）的方法，其中MHA是通过将氰化氢（HCN）加入到甲基巯基丙醛（MMP）中并通过硫酸水解而获得的反应混合物中分离的的甲基巯基丙醛氰醇（MMP-CH）。使反应混合物在液/液萃取系统中与基本上与水不混溶的有机溶剂接触，以形成含有溶剂和从反应混合物中转移的MHA的萃取溶液。通过使液体/液体萃取之前的反应混合物的盐含量达到约> 50wt。％（重量/重量），优选> 55重量％％，是指反应混合物的无机成分之和，改善了总体系中能量的协调使用，避免了强腐蚀性溶液的蒸发，提高了水解步骤的效率，提高了分散系数提取提高。通过蒸发将MHA作为来自该提取溶液的提取物分离，并且可以用作动物饲料添加剂。

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