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11. 发明授权

US6013777A Process for the preparation of fluorescent pigments 失效
标题翻译：荧光颜料的制备方法
公开(公告)号：US6013777A
公开(公告)日：2000-01-11
申请号：US095618
申请日：1998-06-10
申请人： Zhimin Hao , John S. Zambounis , Abul Iqbal
发明人： Zhimin Hao , John S. Zambounis , Abul Iqbal
IPC分类号： C09B1/00 , C09B1/22 , C09B5/62 , C09B7/02 , C09B7/08 , C09B19/00 , C09B19/02 , C09B29/00 , C09B47/12 , C09B47/16 , C09B47/20 , C09B47/26 , C09B48/00 , C09B57/04 , C09B67/20 , C09B67/28 , C09B69/00 , C09B69/08 , C09K11/06 , G03G5/06 , G03G9/06 , G03G9/09 , C07D209/77 , C07D221/18 , C07D403/02 , C07D471/04 , C07D487/22
CPC分类号： C09B68/443 , C09B1/005 , C09B19/02 , C09B29/0033 , C09B47/12 , C09B47/26 , C09B48/00 , C09B5/62 , C09B57/04 , C09B67/0077 , C09B68/46 , C09B68/4677 , C09B69/08 , C09B7/02 , C09K11/06 , G03G9/0908 , G03G9/0912 , G03G9/0918 , G03G9/092 , G03G9/0924 , G03G9/0926 , G03G5/0696
摘要： Compounds of formulaA(B).sub.x, (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m and n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.
摘要翻译：式A（B）x，（I）的化合物，其中x是1至4的整数，A是喹吖啶酮，蒽醌，苝，靛蓝，喹酞酮，异吲哚啉酮，异吲哚啉，二恶嗪，酞菁或偶氮的发色团的基团该基团包含与B连接的x个N原子，优选与至少一个直接相邻或共轭的羰基，B是式的基团，如果x是2,3或4，也可以是一个，两个或三个氢原子。符号Q，R1，R2，R3，R4，X，Y，Z，m和n如权利要求1中所定义。这些含氨基甲酸酯基团的可溶性发色团的特征在于UV范围内的优异的固态荧光，以及通过它们可以将它们转化成它们所掺入的底物中的相应颜料。

12. 发明授权

US5973146A Process for the preparation of aminated diketobis (aryl or heteroaryl)pyrrolopyrroles and the use thereof as photoconductive substances 失效
标题翻译：胺基二酮基（芳基或杂芳基）吡咯并吡咯的制备方法及其作为光导物质的用途
公开(公告)号：US5973146A
公开(公告)日：1999-10-26
申请号：US128332
申请日：1993-09-29
申请人： Alain Claude Rochat , Olof Wallquist , Abul Iqbal , Jin Mizuguchi
发明人： Alain Claude Rochat , Olof Wallquist , Abul Iqbal , Jin Mizuguchi
IPC分类号： C07D487/04 , C09B57/00 , G03G5/06
CPC分类号： C07D487/04 , C09B57/004 , G03G5/0648 , G03G5/0661
摘要： A process for the preparation of compounds of formula I ##STR1## by reacting a pyrrolopyrrole of formula ##STR2## wherein X.sub.1 is a group selected from ##STR3## X.sub.2 is a group selected from ##STR4## or has the same meaning as X.sub.1, with a secondary amine of formula ##STR5## in the molar ratio 1:2, in the presence of an anhydrous dipolar aprotic solvent and of an amount 0.1 to 15 times in excess of stoichiometric proportion, based on the amine of formula III, of an anhydrous organic base, in the temperature range from 50.degree. to 230.degree. C. and under a pressure from 0 to 10 bar.The substituents R.sub.1 to R.sub.8, Y and Hal are as defined in claim 1.The compounds of formula I are especially suitable for use as photoconductive substances.
摘要翻译：通过使下式的吡咯并吡咯反应来制备式I化合物的方法，其中X1是选自X2的基团是选自或具有与X1相同的基团，与式的仲胺的摩尔比为1:2 在无水有机碱的存在下，在无水有机碱的存在下，在50-230℃的温度范围内，在无水偶极非质子传递溶剂存在下，其量为0.1至15倍，超过化学计量比。并在0至10巴的压力下进行。取代基R 1至R 8，Y和Hal如权利要求1所定义。式I化合物特别适合用作光电导物质。

13. 发明授权

US5874580A Fluorescent perylene pigments 失效
标题翻译：荧光苝颜料
公开(公告)号：US5874580A
公开(公告)日：1999-02-23
申请号：US89143
申请日：1998-06-02
申请人： Zhimin Hao , John S. Zambounis , Abul Iqbal
发明人： Zhimin Hao , John S. Zambounis , Abul Iqbal
IPC分类号： C09B1/00 , C09B1/22 , C09B5/62 , C09B7/02 , C09B7/08 , C09B19/00 , C09B19/02 , C09B29/00 , C09B47/12 , C09B47/16 , C09B47/20 , C09B47/26 , C09B48/00 , C09B57/04 , C09B67/20 , C09B67/28 , C09B69/00 , C09B69/08 , C09K11/06 , G03G5/06 , G03G9/06 , G03G9/09 , C07D221/18
CPC分类号： C09B68/443 , C09B1/005 , C09B19/02 , C09B29/0033 , C09B47/12 , C09B47/26 , C09B48/00 , C09B5/62 , C09B57/04 , C09B67/0077 , C09B68/46 , C09B68/4677 , C09B69/08 , C09B7/02 , C09K11/06 , G03G9/0908 , G03G9/0912 , G03G9/0918 , G03G9/092 , G03G9/0924 , G03G9/0926 , G03G5/0696
摘要： Compounds of formulaA(B).sub.x, (I),wherein x is an integer from 1 to 4, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2,3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m und n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.
摘要翻译：式A（B）x，（I）的化合物，其中x是1至4的整数，A是喹吖啶酮，蒽醌，苝，靛蓝，喹酞酮，异吲哚啉酮，异吲哚啉，二恶嗪，酞菁或偶氮的发色团的基团该基团含有连接到B上的x个N原子，优选与至少一个直接相邻的或共轭的羰基相连，B是下式的基团：（III）（IV）和如果x是2,3或4，也可以是一个，两个或三个氢原子。符号Q，R 1，R 2，R 3，R 4，X，Y，Z，m和n如权利要求1中所定义。这些含氨基甲酸酯基团的可溶性发色团的特征在于UV范围内的突出的固态荧光，以及通过它们可以将它们转化成它们所掺入的底物中的相应颜料。

14. 发明授权

US5808094A Preparation of mixed crystals and solid solutions of 1,4-diketopyrrolopyrroles 失效
标题翻译：制备1,4-二酮吡咯并吡咯的混晶和固溶体
公开(公告)号：US5808094A
公开(公告)日：1998-09-15
申请号：US898140
申请日：1997-07-22
申请人： Jin Mizuguchi , Zhimin Hao , Olof Wallquist , Abul Iqbal
发明人： Jin Mizuguchi , Zhimin Hao , Olof Wallquist , Abul Iqbal
IPC分类号： C07D487/04 , C08K5/3415 , C09B67/22 , C07D209/02 , C07D405/14 , C07D409/14
CPC分类号： C08K5/3415 , C09B67/0039
摘要： A process for the preparation of mixed crystals of 1,4-diketopyrrolo�3,4-c!pyrroles, consisting of 1 mol each of two different compounds of formula ##STR1## by heating a corresponding mixture in solid form to the temperature range from 220.degree. to 380.degree. C. A and B are, for example, each a group of formula ##STR2## wherein R.sub.1 and R.sub.2 are each independently hydrogen, chloro, bromo, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylamino, phenyl or --CN, G is --O--, --NR.sub.7 --, --N.dbd.N-- or --SO.sub.2 --, R.sub.3 and R.sub.4 are hydrogen, and R.sub.7 is hydrogen, methyl or ethyl.The mixed crystals and solid solutions obtained are excellently suited for pigmenting high molecular weight material.
摘要翻译：制备1,4-二酮吡咯并[3,4-c]吡咯的混合物的方法，由两种不同的固体形式的化合物1摩尔至220℃至380℃的温度范围。和B是例如各自为一组式（II）的化合物，其中R 1和R 2各自独立地为氢，氯，溴，C 1 -C 4烷基，C 1 -C 6烷氧基，C 1 -C 6烷基氨基，苯基或-CN ，G是-O-，-NR7-，-N = N-或-SO2-，R3和R4是氢，R7是氢，甲基或乙基。获得的混合晶体和固溶体非常适合于着色高分子量材料。

15. 发明授权

US5750723A Polymerizable diketopyrrolopyrroles and polymers prepared therewith 失效
标题翻译：可聚合的二酮吡咯并吡咯和其制备的聚合物
公开(公告)号：US5750723A
公开(公告)日：1998-05-12
申请号：US789895
申请日：1997-01-29
申请人： Sameer Hosam Eldin , Abul Iqbal , Zhimin Hao , Bernd Lamatsch
发明人： Sameer Hosam Eldin , Abul Iqbal , Zhimin Hao , Bernd Lamatsch
IPC分类号： C07D487/04 , C08F16/28 , C08F20/36 , C08F26/02 , C08G18/32 , C08G73/06 , C09B57/00 , C09B69/10
CPC分类号： C07D487/04 , C09B57/004 , C09B69/109
摘要： 1,4-diketopyrrolopyrroles of the formula ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen, C.sub.12 -C.sub.24 alkyl, C.sub.6 -C.sub.24 alkyl which is interrupted one or more times by O or S, or are a group of the formula ##STR2## in which R.sub.5 is C.sub.4 -C.sub.18 alkyl or C.sub.5 -C.sub.10 cycloalkyl, R.sub.3 is a polymerizable reactive group, R.sub.4, if R.sub.1 and R.sub.2 are hydrogen, is C.sub.6 -C.sub.24 alkyl which is attached directly or by way of O or S to the benzene ring and is uninterrupted or is interrupted one or more times by O or S, and R.sub.4, if R.sub.1 and/or R.sub.2 are C.sub.12 -C.sub.24 alkyl, is C.sub.6 -C.sub.24 alkyl which is interrupted one or more times by O or S or is a group ##STR3## hydrogen, halogen, methyl, methoxy, CN or phenyl, or is the same as R.sub.3.
摘要翻译：其中R 1和R 2彼此独立的式（I）的1,4-二酮吡咯并吡咯为氢，被O或S间隔一次或多次的C 12 -C 24烷基，C 6 -C 24烷基，或者是其中R 5是C 4 -C 18烷基或C 5 -C 10环烷基的式“IMAGE”，R 3是可聚合反应基团，如果R 1和R 2是氢，则R 4是直接或通过O或S连接到C 6 -C 24烷基的C 6 -C 24烷基，苯环并且不间断或被O或S中断一次或多次，如果R 1和/或R 2为C 12 -C 24烷基，R 4为被O或S间隔一次或多次的C 6 -C 24烷基，或者是基团氢，卤素，甲基，甲氧基，CN或苯基，或与R3相同。

16. 发明授权

US5527922A Pyrrolo[3,4-c]pyrroles containing cyanimino groups 失效
标题翻译：含有氰氨基的吡咯并[3,4-c]吡咯
公开(公告)号：US5527922A
公开(公告)日：1996-06-18
申请号：US407746
申请日：1995-03-21
申请人： John S. Zambounis , Zhimin Hao , Abul Iqbal
发明人： John S. Zambounis , Zhimin Hao , Abul Iqbal
IPC分类号： C07D487/04 , C08K5/3412 , C08K5/3415 , C08L101/00 , C09B57/00 , C09K11/06
CPC分类号： C07D487/04 , C09B57/004
摘要： The invention relates to pyrrolo[3,4-c]pyrroles of formula ##STR1## wherein D and E are each independently of the other hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.7 -C.sub.10 aralkyl, unsubstituted phenyl or phenyl which is substituted by chloro, bromo, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.4 alkoxy, trifluoromethyl or nitro, or --COO--C.sub.1 -C.sub.5 alkyl or a group --COOR.sub.8,wherein R.sub.8 is benzyl, piperidyl or a group ##STR2## and X and Y are N--CN or O, with the proviso that at least one of X or Y N--CN must be N--CN.These pyrrolo[3,4-c]pyrroles are preeminently suitable for use as colorants, i.e. as pigments or as polymer-soluble dyes, for colouring high molecular weight organic material. They are distinguished by unexpectedly high solid-state fluorescence.The substituents A and B are as defined in claim 1.
摘要翻译：本发明涉及式（I）的吡咯并[3,4-c]吡咯，其中D和E各自独立地为另一个氢，C 1 -C 18烷基，C 2 -C 4链烯基，C 7 -C 10芳烷基，未取代的苯基或苯基，被氯，溴，C 1 -C 6烷基，C 1 -C 4烷氧基，三氟甲基或硝基或-COO-C 1 -C 5烷基或-COOR 8基团取代，其中R 8是苄基，哌啶基或基团，X和Y是N -CN或O，条件是X或Y N-CN中的至少一个必须是N-CN。这些吡咯并[3,4-c]吡咯非常适合用作着色剂，即作为颜料或作为聚合物可溶性染料用于着色高分子量有机材料。它们的突出特征是出乎意料的高固态荧光。取代基A和B如权利要求1中所定义。

17. 发明授权

US5502196A Pyrrolo 3,4-c!pyrroles containing amine oxide groups 失效
标题翻译：含有氧化胺基团的吡咯并[3,4-c]吡咯
公开(公告)号：US5502196A
公开(公告)日：1996-03-26
申请号：US404012
申请日：1995-03-14
申请人： Zhimin Hao , Abul Iqbal , Rudolf Kirchmayr
发明人： Zhimin Hao , Abul Iqbal , Rudolf Kirchmayr
IPC分类号： C07D487/04 , C08K5/3412 , C08K5/3415 , C09B57/00 , G03G5/06 , C07D211/10
CPC分类号： C07D487/04 , G03G5/0648 , G03G5/0661
摘要： The invention relates to pyrrolo 3,4-c!pyrroles of formula ##STR1## wherein A and B are each independently of the other a group of formula ##STR2## or Q, wherein Q is a 5- or 6-membered heterocyclic aromatic amine oxide radical which is unsubstituted or substituted by one, two or three C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or ##STR3## and which may contain one or two fused benzene rings, R.sub.1 and R.sub.2 are each independently of the other hydrogen, halogen, C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy, C.sub.1 -C.sub.18 alkylmercapto, --CN, --NO.sub.2 or trifiuoromethyl, D and E are each independently of the other hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.7 -C.sub.10 aralkyl, unsubstituted phenyl or phenyl which is substituted by chloro, bromo, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.4 alkoxy, trifiuoromethyl or nitro, with the proviso that at least one of the sustituents A and B is an amine oxide radical Q.These novel diketopyrrolo 3,4-c!pyrroles are suitable for use as pigments, but especially as photoconductive substances in electrophotographic photoreceptors.
摘要翻译：本发明涉及式（I）的吡咯并[3,4-c]吡咯，其中A和B各自独立地为下式的基团：其中Q为5- 或6元杂环芳族氧化胺基团，其未被取代或被一个，两个或三个C 1 -C 18烷基，C 1 -C 18烷氧基或者可以含有一个或两个稠合苯环的取代基，R 1和R 2各自独立地为其它氢，卤素，C 1 -C 18烷基，C 1 -C 18烷氧基，C 1 -C 18烷基巯基，-CN，-NO 2或三氟甲基，D和E各自独立地为C 1 -C 18烷基，C 2 -C 4链烯基，C 7 -C 10芳烷基，或被氯，溴，C 1 -C 6烷基，C 1 -C 4烷氧基，三氟甲基或硝基取代的苯基，条件是至少一个取代基A和B是氧化胺基团Q.这些新型二酮吡咯并[3,4- c]吡咯适合用作颜料，特别是作为电子照相感光体中的光导物质。

18. 发明授权

US4914211A Pigment compositions 失效
公开(公告)号：US4914211A
公开(公告)日：1990-04-03
申请号：US231324
申请日：1988-08-12
申请人： Max Jost , Abul Iqbal , Alain C. Rochat
发明人： Max Jost , Abul Iqbal , Alain C. Rochat
IPC分类号： C07D487/04 , C08K5/3415 , C08K5/3442 , C08K5/3445 , C08L101/00 , C09B57/00 , C09B63/00 , C09B67/20 , C09B67/22
CPC分类号： C07D487/04 , C08K5/3415 , C09B57/004 , C09B63/005 , C09B67/0039
摘要： Compositions comprising(a) a pyrrolopyrrole of formula I ##STR1## wherein A and B are identical or different alkyl, arlkyl, aryl or heterocyclic aromatic radicals, R.sub.1 and R.sub.2 are hydrogen atoms, unsubstituted or substituted alkyl radicals, and also alkenyl, alkynyl, aralkyl, cycloalkyl, carbamoyl, alkylcarbamoyl, arylcarbamoyl, alkoxycarbonyl, aryl, alkanoyl or aroyl groups, and X is an --O-- or --S-- atom, and(b) a pyrrolopyrrole of the above formula I that contains at least one group of formula --SO.sub.3 L, --CO.sub.2 L, --PO.sub.3 (L).sub.2, --N(R.sub.4)(R.sub.5), ##STR2## or --NHCOR wherein L is --H, a group of formula ##EQU1## or N.sup.+ H(R.sub.3)(R.sub.4)(R.sub.5), M is monovalent, divalent or trivalent metal cation, n is 1, 2 or 3, R.sub.3, R.sub.4 and R.sub.5 are each independently --H or alkyl, aralkyl, C.sub.5 -C.sub.6 cycloalkyl or aryl radicals, or R.sub.4 and R.sub.5, together with the nitrogen atom to which they are attached, form a 5-- or 6-membered heterocyclic radical, q is an integer from 0 to 4, r is an integer from 3 to 5 and R is aryl or C.sub.1 -C.sub.4 alkyl, are suitable for coloring high molecular organic material.

19. 发明授权

US4613669A Preparation of 1,4-diketopyrrolo-[3,4-c]pyrroles 失效
标题翻译：制备1,4-二酮基吡咯并[3,4-c]吡咯
公开(公告)号：US4613669A
公开(公告)日：1986-09-23
申请号：US512074
申请日：1983-07-08
申请人： Luigi Cassar , Abul Iqbal , Alain C. Rochat
发明人： Luigi Cassar , Abul Iqbal , Alain C. Rochat
IPC分类号： C07D487/04 , C07F3/00 , C08K5/3415 , C09B57/00 , C07D403/14 , C07D407/14 , C07D409/14
CPC分类号： C07D487/04 , C07F3/003 , C08K5/3415 , C09B57/004
摘要： A process for the preparation of 1,4-diketopyrrolo-[3,4-c]pyrroles of the formula ##STR1## wherein each of R.sub.1 and R.sub.2 independently of the other is an isocyclic aromatic or non-basic heterocyclic aromatic radical, which process comprises reacting 1 mole of the compound of formula ##STR2## wherein M is a metal atom, Z is alkyl or aryl, X is halogen or acetate, and m is a value from 0 to 2, with 1 mole of a compound of the formulaYCH.sub.2 COOZ (III)wherein Y is halogen, and with 1 mole of a nitrile of the formulaR.sub.1 --CN (IV) or R.sub.2 --CN (V)in an organic solvent and at elevated temperature, and isolating the compound of formula I.The compounds obtained according to the invention are suitable for pigmenting organic material of high molecular weight.
摘要翻译：制备式（I）的1,4-二酮吡咯并[3,4-c]吡咯的方法，其中R 1和R 2各自独立地为环状芳族或非碱性杂环芳族基团该方法包括使1摩尔的式（II）化合物其中M为金属原子，Z为烷基或芳基，X为卤素或乙酸酯，m为0至2的值，1摩尔的式YCH 2 COOZ（III）的化合物，其中Y是卤素，并且在有机溶剂中和在升高的温度下与1摩尔的式R 1 -CN（Ⅳ）或R2-CN（Ⅴ）的腈反应，并将根据本发明获得的化合物适用于着色高分子量有机材料。

20. 发明授权

US4540791A Production of .beta.-amino-.alpha.,.beta.-unsaturated carboxylic acid esters 失效
标题翻译： β-氨基-α，β-不饱和羧酸酯的生产
公开(公告)号：US4540791A
公开(公告)日：1985-09-10
申请号：US512058
申请日：1983-07-08
申请人： Luigi Cassar , Abul Iqbal , Alain C. Rochat
发明人： Luigi Cassar , Abul Iqbal , Alain C. Rochat
IPC分类号： C07C227/10 , C07C229/30 , C07C229/34 , C07C255/58 , C07D213/38 , C07D213/55 , C07D333/24 , C09B23/00 , C09B57/00 , C07D211/70 , C07C101/02 , C07C121/78
CPC分类号： C07C255/00 , C07D213/55 , C07D333/24 , C09B57/00
摘要： A process for producing a compound of the formula ##STR1## wherein A is aryl or alkyl, R.sub.1 is an aromatic radical and R.sub.2 is hydrogen, alkyl, aryl, cyano, --COOalkyl or --COOaryl, which process comprises reacting 1 mol of an aromatic nitrile of the formula R.sub.1 --CN (II) with 1 mol of an acetic ester of the formula (X)(R.sub.2)CH--COOA (III) in which X is halogen, in the presence of zinc, in an inert organic solvent and at a temperature of less than 80.degree. C.; hydrolyzing in an alkaline medium the formed reaction product; and then isolating the compound of the formula I.The compounds of the formula I are valuable intermediates for producing heterocyclic compounds.
摘要翻译：制备式（I）的化合物的方法，其中A是芳基或烷基，R 1是芳基，R 2是氢，烷基，芳基，氰基，-COO烷基或-COO芳基，该方法包括使1mol 的式R 1 -C CN（II）的芳族腈与1摩尔式（X）（R2）CH-COOA（III）的乙酸酯反应，其中X是卤素，在锌的存在下，在惰性有机溶剂，温度低于80℃。在碱性介质中水解形成的反应产物; 然后分离式I化合物。式I化合物是制备杂环化合物的有价值的中间体。

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