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11. 发明公开

EP2052002A2 COPOLYMÈRE DE FLUORURE DE VINYLIDÈNE FONCTIONALISÉ PAR GREFFAGE PAR IRRIDIATION D'UN MONOMÈRE POLAIRE INSATURÉ 审中-公开
标题翻译：不饱和极性单体官能偏氟乙烯共聚物辐射加工
公开(公告)号：EP2052002A2
公开(公告)日：2009-04-29
申请号：EP07823697.3
申请日：2007-08-07
申请人： ARKEMA FRANCE
发明人： BONNET, Anthony , LAPPRAND, Aude , SEBIRE, Pascal
IPC分类号： C08F259/08 , C09D127/16 , B32B27/16 , H01M4/46 , C08L51/06
CPC分类号： B32B27/08 , B32B27/16 , C08F259/08 , C08L27/16 , C08L51/003 , H01M4/13 , H01M4/621 , H01M4/623 , H01M10/052 , Y10T428/1352 , Y10T428/1393 , Y10T428/31507 , Y10T428/3154 , C08L2666/24
摘要： The invention relates to a VDF copolymer and at least one monomer copolymerisable with the VDF having at least 50% of its weight in VDF, preferably at least 75%, onto which at least one unsaturated polar monomer is radiation-grafted, characterized in that, prior to grafting, the VDF copolymer has the following characteristics: a crystallization temperature Tc (measured by DSC as per the ISO Standard 11357-3) ranging between 50°C and 120°C, preferably from 85°C to 110°C; a constraint to the σy threshold ranging from 10 to 40 MPa, preferably from 10 to 30 MPa; a viscosity v in the molten state (measured with a capillary rheometer at 230°C at 100 s-1) ranging from 100 to 1500 Pa s, preferably from 400 to 1200 Pa s. The invention further relates to a mixture comprising said modified copolymer and a PVDF. Said modified copolymer or the mixture may also be associated with a thermoplastic polymer, an elastomer or an inorganic material.

12. 发明公开

EP2099631A2 STRUCTURE MULTICOUCHE A BASE D'UN POLYMERE BARRIERE EVENTUELLEMENT RENFORCE A L'IMPACT 审中-公开
标题翻译：选择性地对影响的阻挡层聚合物被加强，将含有多层结构
公开(公告)号：EP2099631A2
公开(公告)日：2009-09-16
申请号：EP07858673.2
申请日：2007-11-07
申请人： ARKEMA FRANCE
发明人： BONNET, Anthony , LAPPRAND, Aude
IPC分类号： B60K15/03 , F16L11/04
CPC分类号： B32B27/08 , F16L2011/047 , Y10T428/1352 , Y10T428/1383 , Y10T428/1393 , Y10T428/3154
摘要： The invention relates to a multi-layered structure comprising from the inside to the outside: a layer C1 containing at least one functionalised 5 fluorinated polymer optionally mixed with at least one compatible fluorinated polymer; a layer C2 containing at least one adhesion binder; a layer C3 containing at least one polyolefine, preferably a polyethylene; a layer C4 containing at least one adhesion binder; a barrier layer C5 containing at least one barrier polymer optionally reinforced against impacts; the layers are arranged against each other in the above-mentioned order. The invention also relates to the use of this multi-layered structure for storing or transferring fuel.

13. 发明公开

EP2049332A2 TUBE MULTICOUCHE POUR LE TRANSPORT D'EAU OU DE GAZ. 有权
标题翻译：多层管用于输送水或气体
公开(公告)号：EP2049332A2
公开(公告)日：2009-04-22
申请号：EP07823699.9
申请日：2007-08-07
申请人： ARKEMA FRANCE
发明人： BONNET, Anthony , LAPPRAND, Aude , SEBIRE, Pascal
IPC分类号： B32B27/30 , B32B1/08 , F24D3/14
CPC分类号： B32B27/30 , B32B1/08 , B32B27/32 , C08L27/12 , F24D3/146 , C08L2666/24
摘要： The invention relates to a multilayer tube comprising (in the order starting from the inside to the outside of the tube) layers arranged one on top of the other: an optional layer L1 comprising at least one fluorinated polymer, preferably a PVDF; a layer L2 comprising at least one functionalized PVDF, obtained by radiation grafting of at least one unsaturated polar monomer onto a PVDF; an optional layer L3 of an adhesive binder; a layer L4 comprising at least one polyolefin optionally mixed with at least one functionalized polyolefin; an optional barrier layer L5; an optional layer L6 comprising at least polyolefin, optionally in a mixture with at least one functionalized polyolefin; characterized in that the PVDF onto which the unsaturated polar monomer is grafted is a VDF copolymer whose weight content is at least 50%, preferably at least 75% and at least one monomer copolymerisable with the VDF, having the following characteristics: a crystallization temperature Tc (measured by DSC as per the ISO Standard 11357-3) ranging from 50 to 120°C, preferably from 85 to 110°C; a constraint to the y threshold ranging from 10 to 40 MPa, preferably from 10 to 30 MPa; a viscosity v in the molten state (measured with a capillary rheometer at 230°C at 100 s-1) ranging from 100 to 1,500 Pa s, preferably from 400 to 1200 Pa s.

14. 发明公开

EP2007577A1 STRUCTURE MULTICOUCHE A BASE DE POLYMERE FLUORE FONCTIONNALISE PAR IRRADIATION ET DE PVC 审中-公开
标题翻译：多层结构基于通过辐照官能化氟乙烯类聚合物和PVC
公开(公告)号：EP2007577A1
公开(公告)日：2008-12-31
申请号：EP07731779.0
申请日：2007-03-20
申请人： ARKEMA FRANCE
发明人： BONNET, Anthony , BEAUME, François , LAPPRAND, Aude , VANDEKERCKHOVE, Frank
IPC分类号： B32B27/30 , B32B1/08
CPC分类号： F16L11/04 , B32B1/02 , B32B1/08 , B32B27/08 , B32B27/28 , B32B27/304 , B32B27/322 , B32B2250/24 , B32B2439/40 , B32B2439/60 , Y10T428/1352 , Y10T428/3154
摘要： The invention relates to a multi-layer structure including placed one against the other, at least one layer of fluoride polymer onto which at least one unsaturated monomer has been grafted by irradiation and at least one layer of PVC. According to a 1st form, the multi-layer structure may include in order placed one against the other: • possibly a layer of fluoride polymer • a layer of fluoride polymer grafted by irradiation • a layer of PVC. According to a 2nd form, the multi-layer structure includes in order placed one against the other: • possibly a layer of fluoride polymer • a layer of fluoride polymer grafted by irradiation • a layer of PVC • a layer of fluoride polymer grafted by irradiation • possibly a layer of fluoride polymer. According to a 3rd form, the multi-layer structure includes in order placed one against the other: • a layer of PVC • a layer of fluoride polymer grafted by irradiation • a layer of PVC. Said structure may be shaped into films, bottles, tanks, containers, pipes and containers of all kinds.

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