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11. 发明公开

KR1020130096772A 에테르화 반응용 금속산화물 촉매, 그 촉매의 제조방법, 및 그 촉매를 이용한 선형 폴리글리세린의 제조방법 无效
标题翻译：用于加成反应的金属氧化物催化剂，其制备方法和使用该方法生产线性聚合物的方法
公开(公告)号：KR1020130096772A
公开(公告)日：2013-09-02
申请号：KR1020107024084
申请日：2010-10-25
申请人： 주식회사 케이씨아이 , 한국화학연구원
发明人： 한요한 , 김형록 , 한인선 , 김현식
IPC分类号： B01J23/02 , B01J23/10 , C07C31/22
CPC分类号： C07C41/09 , B01J23/007 , B01J23/10 , B01J37/06 , C07C43/13
摘要： PURPOSE: A basic ternary system metallic oxide catalyst for etherification of glycerine, a manufacturing method thereof, and a manufacturing method of polyglycerine using the same are provided to prevent a color change of the product and bad smell, to suppress production of ring type polyglycerine even under a warm reacting condition, and to obtain linear type polyglycerine in a high content. CONSTITUTION: A basic ternary system metallic oxide catalyst for etherification of glycerine is indicated as (CaO)a·(CaLaAl3O7)b·(La2O3)c. In the chemical formula above, a, b, and c indicates weight ratio of CaO, CaLaAl3O7, and La2O3 to 100 wt% of the total catalyst. A manufacturing method of the metallic oxide catalyst comprises the steps of: producing precipitate of mixed metal hydroxide type by adding aqueous solution containing calcium salt, aluminum salt, and landthanum salt, and alkaline precipitation agent aqueous solution to sodium chloride aqueous solution; stirring at 40-80 deg C; obtaining hydrotalcite type metal hydroxide powder by separating, washing, and drying the precipitate; and plasticizing the metal hydroxide powder at 400-800 deg C among the air. [Reference numerals] (AA) Content (weight%); (BB) POLYGLYCERINE polymerizing degree
摘要翻译：目的：提供用于甘油醚化的碱性三元体系金属氧化物催化剂及其制造方法和使用其的聚甘油的制造方法，以防止产品的颜色变化和不良气味，以抑制环型聚甘油的生产甚至在温热反应条件下，得到高含量的线型聚甘油。构成：用于甘油醚化的碱性三元体系金属氧化物催化剂表示为（CaO）a·（CaLaAl 3 O 7）b·（La 2 O 3）c。在上述化学式中，a，b和c表示CaO，CaAl 3 O 7和La 2 O 3与总催化剂的100重量％的重量比。金属氧化物催化剂的制造方法包括以下步骤：通过向氯化钠水溶液中加入含有钙盐，铝盐和陆地盐的水溶液和碱性沉淀剂水溶液来生产混合金属氢氧化物型沉淀物; 在40-80℃下搅拌; 通过分离，洗涤和干燥沉淀得到水滑石型金属氢氧化物粉末; 并在400-800℃的空气中使金属氢氧化物粉末增塑。（附图标记）（AA）含量（重量％）; （BB）聚合度聚合度

12. 发明公开

KR1020130007937A 고산가 바이오오일로부터 바이오디젤을 제조하는 반응에 사용되는 균일촉매 有权
标题翻译：用于从高酸值生物油制备生物柴油的均质催化剂
公开(公告)号：KR1020130007937A
公开(公告)日：2013-01-21
申请号：KR1020110068615
申请日：2011-07-11
申请人： 한국화학연구원 , (주)에스엠피오티
发明人： 김형록 , 한요한 , 이정호 , 유혜민 , 유정우 , 형희준 , 장혜련
IPC分类号： B01J31/12 , C10G3/00 , C10L1/02
CPC分类号： Y02E50/13 , Y02P30/20 , B01J31/1616 , B01J31/2226 , B01J2531/12 , B01J2531/16 , B01J2531/22 , B01J2531/23 , B01J2531/26 , B01J2531/842 , B01J2531/847 , C10G3/44
摘要： PURPOSE: A homogenous catalyst used in a reaction of manufacturing a biodiesel from a bio oil with a high oxidation number is provided to reduce costs of the biodiesel by extending a range of a raw material of the biodiesel from a high quality bio oil to a low quality bio oil as the homogenous catalyst is capable of converting a low quality bio oil with a high oxidation number to a high quality biodiesel. CONSTITUTION: A homogeneous catalyst used in a reaction of manufacturing a biodiesel from a bio oil with a high oxidation number includes a divalent metal ion(M^2+). The divalent metal ion is one or a mixture of at least two selected from the group consisting of Mg^2+, Ca^2+, Cu^2+, Fe^2+, Ni^2+, Co^2+, Mn^2+, and Zn^2+. A method for manufacturing the biodiesel comprises reacting the bio oil having an oxidation number of 5 or greater with methanol in the presence of the homogenous catalyst including the divalent metal ion. [Reference numerals] (AA) Conversion rate %; (BB) Selectivity %; (CC) Non-catalyst; (DD) Catalyst
摘要翻译：目的：提供用于制造生物柴油与高氧化数的生物柴油的反应中使用的均匀催化剂，以通过将生物柴油的原料范围从高品质的生物油延伸至低温来降低生物柴油的成本作为均匀催化剂的优质生物油能够将具有高氧化数的低质量生物油转化为高质量的生物柴油。构成：用于制造具有高氧化数的生物油的生物柴油的反应中使用的均相催化剂包括二价金属离子（M 2+）。二价金属离子是选自Mg 2+，Ca 2+，Cu 2+，Fe 2+，Ni 2+，Co 2+，Mn中的至少两种之一或其混合物 ^ 2 +和Zn ^ 2 +。制造生物柴油的方法包括在包含二价金属离子的均匀催化剂的存在下使氧化数为5以上的生物油与甲醇反应。（标号）（AA）转化率％（BB）选择性％; （CC）非催化剂; （DD）催化剂

13. 发明公开

KR1020120089918A 산-염기 복합 촉매계를 이용하여 고산가 바이오 오일로부터 바이오 디젤을 제조하는 방법 有权
标题翻译：使用酸碱催化剂组合的高酸值生物油制备生物柴油的方法
公开(公告)号：KR1020120089918A
公开(公告)日：2012-08-16
申请号：KR1020100132124
申请日：2010-12-22
申请人： 한국화학연구원
发明人： 한요한 , 김형록 , 유혜민 , 이정호
IPC分类号： C10G3/00 , C10L1/02 , C11C3/10 , B01J29/04
CPC分类号： Y02E50/13 , Y02P30/20 , C10G3/00 , B01J29/04 , C10L1/02 , C11C3/10
摘要： PURPOSE: A producing method of bio-diesel from high acid-value bio-oil using an acid-base composite catalyst is provided to improve the selectivity and the reaction stability of the bio-diesel. CONSTITUTION: A producing method of bio-diesel from high acid-value bio-oil using an acid-base composite catalyst comprises a step of reacting the high acid-value bio-oil and methanol using a composite catalyst to obtain the bio-diesel. The composite catalyst contains 5-50wt% of solid acid catalyst, 5-50wt% of solid base catalyst, and 10-50wt% of alumina sol, silica sol, or their compound. The solid acid catalyst is selected from acidic zeolite, acidic clay, heteropoly acid, or acidic composite metal oxide. The solid base catalyst is selected from alkaline earth metal oxide, rare earth metal oxide, basic zeolite, or hydrotalcite.
摘要翻译：目的：提供使用酸碱复合催化剂的高酸值生物油生物柴油的生产方法，以提高生物柴油的选择性和反应稳定性。构成：使用酸碱复合催化剂的高酸值生物油生物柴油的生产方法包括使用复合催化剂使高酸值生物油和甲醇反应以获得生物柴油的步骤。复合催化剂含有5-50重量％的固体酸催化剂，5-50重量％的固体碱催化剂和10-50重量％的氧化铝溶胶，二氧化硅溶胶或其化合物。固体酸催化剂选自酸性沸石，酸性粘土，杂多酸或酸性复合金属氧化物。固体碱催化剂选自碱土金属氧化物，稀土金属氧化物，碱性沸石或水滑石。

14. 发明授权

KR101033660B1 젖산 에스테르의 탈수 반응용 인산칼슘-실리카 촉매 및 그의 제조방법 및 이를 이용하여 젖산 에스테르로부터 아크릴계 화합물을 제조하는 방법 有权
标题翻译：用于乳酸脱水反应的磷酸钙二氧化硅催化剂及其制备方法以及从乳酸盐制备丙烯酸类化合物的方法
公开(公告)号：KR101033660B1
公开(公告)日：2011-05-12
申请号：KR1020090079685
申请日：2009-08-27
申请人： 한국화학연구원
发明人： 한요한 , 장종산 , 김선현 , 황영규 , 전종열 , 김형록
IPC分类号： B01J27/182 , C07C51/09 , C07C57/04
摘要： 본 발명은 젖산 에스테르의 탈수 반응용 인산칼슘-실리카 촉매 및 그의 제조방법과, 상기 촉매를 이용하여 젖산 에스테르를 탈수하여 아크릴계 화합물인 아크릴산과 아크릴산 에스테르를 제조하는 방법에 관한 것으로, 인산칼슘-실리카 촉매의 존재 하에 탄소수가 1~4인 알킬기를 가진 젖산 에스테르를 탈수 반응시켜 아크릴산과 아크릴산 에스테르를 고수율로 제조할 수 있다.
본 발명의 인산칼슘-실리카 촉매는 인산칼슘 50 내지 98 중량% 및 실리카 2 내지 50 중량%로 이루어지고, 상기 인산칼슘은 Ca
3 (PO
4 )
2, Ca
2 P
2 O
7 , Ca
5 (P
3 O
10 )
2 및 Ca
3 (PO
3 )
6 로 이루어진 군으로부터 선택되는 하나 이상이다.
인산칼슘 촉매, 탈수반응, 젖산 에스테르, 아크릴산, 아크릴산 에스테르

15. 发明公开

KR1020110022235A 젖산 에스테르의 탈수 반응용 인산칼슘 촉매 및 그의 제조방법 및 이를 이용하여 젖산 에스테르로부터 아크릴계 화합물을 제조하는 방법 有权
标题翻译：用于脱水反应的磷酸钙催化剂，其制备方法以及从拉脱维酮制备丙烯酸酯化合物的方法
公开(公告)号：KR1020110022235A
公开(公告)日：2011-03-07
申请号：KR1020090079736
申请日：2009-08-27
申请人： 한국화학연구원
发明人： 한요한 , 장종산 , 김선현 , 황영규 , 전종열 , 김형록
IPC分类号： B01J27/18 , C07C51/09 , C07C57/04
CPC分类号： B01J27/1806 , B01J37/0018 , C07C51/09
摘要： PURPOSE: Calcium phosphate catalysts for the dehydration reaction of lactates, a method for preparing the same, and a method for preparing acrylic compounds based on the lactates are provided to improve the selectivity and the reaction stability of dehydration reaction using phosphoric acid precursors and calcium precursors. CONSTITUTION: Calcium phosphate catalysts for the dehydration reaction of lactates contains one or more calcium phosphate selected from a group including Ca_3(PO_4)_2, Ca_2P_2O_7, Ca_5(P_3O_10)_2, and Ca_3(PO_3)_6. A method for preparing the calcium phosphate catalysts contains the following: Calcium phosphate slurry is prepared by mixing a phosphate aqueous solution and a calcium salt aqueous solution. The calcium phosphate slurry is filtered and cleaned to form powder. The power is sintered in air with 300 to 700 degrees Celsius of temperature.
摘要翻译：目的：提供乳酸脱水反应的磷酸氢钙催化剂，其制备方法，以及制备基于乳酸的丙烯酸类化合物的方法，以提高使用磷酸前体和钙前体的脱水反应的选择性和反应稳定性。构成：用于乳酸盐脱水反应的磷酸钙催化剂含有选自Ca_3（PO_4）_2，Ca_2P_2O_7，Ca_5（P_3O_10）_2和Ca_3（PO_3）_6的一种或多种磷酸钙。制备磷酸钙催化剂的方法包括以下：通过混合磷酸盐水溶液和钙盐水溶液制备磷酸钙浆料。将磷酸钙浆料过滤并清洗以形成粉末。功率在空气中在300至700摄氏度的温度下烧结。

16. 发明公开

KR1020110022214A 젖산 에스테르의 탈수 반응용 인산칼슘-실리카 촉매 및 그의 제조방법 및 이를 이용하여 젖산 에스테르로부터 아크릴계 화합물을 제조하는 방법 有权
标题翻译：用于脱水反应的磷酸二钙催化剂，其制备方法以及从拉脱维酮制备丙烯酸酯化合物的方法
公开(公告)号：KR1020110022214A
公开(公告)日：2011-03-07
申请号：KR1020090079685
申请日：2009-08-27
申请人： 한국화학연구원
发明人： 한요한 , 장종산 , 김선현 , 황영규 , 전종열 , 김형록
IPC分类号： B01J27/182 , C07C51/09 , C07C57/04
CPC分类号： B01J27/1806 , B01J37/0018 , C07C51/09 , C07C57/04
摘要： PURPOSE: Calcium phosphate-silica catalysts for the dehydration reaction of lactates, a method for preparing the same, and a method for preparing acrylic compounds based on the lactates are provided to improve the yield of acrylic acids and acrylic esters by continuously dehydrating the lactates. CONSTITUTION: Calcium phosphate-silica catalysts contains 50 to 98 weight% of Calcium phosphate and 2 to 50 weigh% of silica. The calcium phosphate is selected from a group containing Ca_3(PO_4)_2, Ca_2P_2O_7, Ca_5(P_3O_10)_2, and Ca_3(PO_3)_6. The method for preparing the calcium phosphate-silica catalysts contains the following: Calcium phosphate is prepared by mixing a phosphate aqueous solution and a calcium salt aqueous solution. Silica slurry is prepared by mixing silicon salt aqueous solution and an acid aqueous solution. The silicon slurry is mixed with the calcium phosphate. The mixed slurry is filtered and cleaned to form powder. The power is sintered.
摘要翻译：目的：提供乳酸盐脱水反应的磷酸钙 - 二氧化硅催化剂，其制备方法，以及制备基于乳酸盐的丙烯酸类化合物的方法，以通过连续脱水乳酸来提高丙烯酸和丙烯酸酯的产率。构成：磷酸钙 - 二氧化硅催化剂含有50至98重量％的磷酸钙和2至50重量％的二氧化硅。磷酸钙选自含有Ca_3（PO_4）_2，Ca_2P_2O_7，Ca_5（P_3O_10）_2和Ca_3（PO_3）_6的组。制备磷酸钙 - 二氧化硅催化剂的方法包括以下：通过混合磷酸盐水溶液和钙盐水溶液制备磷酸钙。通过混合硅盐水溶液和酸性水溶液制备二氧化硅浆料。硅浆与磷酸钙混合。将混合的浆料过滤并清洗以形成粉末。功率烧结。

17. 发明授权

KR100989121B1 불포화 지방산 알킬 에스테르를 연속적으로 수소화하는 방법 有权
标题翻译：连续氢化不饱和脂肪酸烷基酯的方法
公开(公告)号：KR100989121B1
公开(公告)日：2010-10-20
申请号：KR1020080085180
申请日：2008-08-29
申请人： 한국화학연구원 , 에이케이홀딩스 주식회사
发明人： 한요한 , 김형록 , 전종열 , 김선현 , 김정곤 , 이종화 , 신철 , 윤성호
IPC分类号： C07C5/00 , C07C5/02
摘要： 본 발명은 불포화 지방산 알킬 에스테르를 연속적으로 수소화하는 방법에 관한 것으로, 하기 화학식 1로 표시되는 4성분계 금속산화물 촉매의 존재 하에 탄소수가 8~24인 불포화 지방산 알킬 에스테르를 수소화 반응시켜 고정상 반응기에서 연속적으로 제조하는 본 발명에 따른 방법은 요오드값이 0.1이하인 포화 지방산 알킬 에스테르를 고수율로 제조할 수 있다 :
[화학식 1]
(NiO)
a ·(MgO)
b ·(ZnO)
c ·(Al
2 O
3 )
d
상기 화학식 1에서, a, b, c 및 d는 촉매 총 중량에 대한 함량을 의미하며, a는 40 내지 80중량%이고, b는 1 내지 20중량%이고, c는 0.5 내지 10중량%이고, d는 10 내지 40중량%이다.
니켈 촉매, 펠렛형 니켈 촉매, 수소화, 불포화 지방산 알킬 에스테르

18. 发明公开

KR1020100041000A 에테르화 반응용 금속산화물 촉매, 이 촉매의 제조방법, 및이 촉매를 이용한 선형 폴리글리세롤의 제조방법 失效
标题翻译：用于加热反应的金属氧化物催化剂，其方法和使用其生产线性聚合物的方法
公开(公告)号：KR1020100041000A
公开(公告)日：2010-04-22
申请号：KR1020080099955
申请日：2008-10-13
申请人： 한국화학연구원 , 주식회사 케이씨아이
发明人： 한요한 , 김형록 , 한인선 , 최현웅 , 김현식 , 안소영 , 윤영호
IPC分类号： B01J21/04 , B01J23/02
CPC分类号： B01J23/02 , B01J23/002 , B01J35/002 , B01J37/031 , B01J2523/00 , C01F7/164 , C01F11/02 , C01P2002/72 , C07C41/09 , C08G65/34 , B01J2523/23 , B01J2523/31 , C07C43/135
摘要： PURPOSE: A metal oxide catalyst for etherification reaction is provided to obtain high content of linear polyglycerol using basic binary based metal oxide catalyst for the etherification reaction and to be used for manufacturing polyglyerol suitable for cosmetics and food additives. CONSTITUTION: A binary based metal oxide catalyst for etherification reaction of glycerol is marked as a chemical formula 1. [Chemical formula 1] (CaO)_a · (Ca_12Al_14O_33)_(100-a). In the chemical formula 1, a is weight ratio of CaO to catalyst 100.0, a is in a range of 30-70. A method for manufacturing the metal oxide catalyst comprises the following steps: creating a precipitate of a mixed metal hydroxide by simultaneously adding solution including calcium salt and aluminum salt and alkaline precipitation agent to solution of sodium chloride; mixing the precipitate at 40-80°C; obtaining hydrocalumite metal hydroxide powder through separation and washing of the precipitate; and plasticizing the metal hydroxide powder at 400-800°C.
摘要翻译：目的：提供用于醚化反应的金属氧化物催化剂，以获得高含量的线性聚甘油，使用碱性二元基金属氧化物催化剂进行醚化反应，并用于制备适用于化妆品和食品添加剂的聚二醇。构成：用于甘油醚化反应的二元金属氧化物催化剂被标记为化学式1. [化学式1]（CaO）_a·（Ca_AlAl_14O_33）_（100-a）。在化学式1中，a为CaO与催化剂100.0的重量比，a为30〜70的范围。制造金属氧化物催化剂的方法包括以下步骤：通过在氯化钠溶液中同时加入包括钙盐和铝盐和碱性沉淀剂的溶液来产生混合金属氢氧化物的沉淀物; 在40-80℃下混合沉淀物; 通过分离和洗涤沉淀物获得氢氧化钙金属氢氧化物粉末; 并在400-800℃下使金属氢氧化物粉末增塑。

19. 发明公开

KR1020100026249A 불포화 지방산 알킬 에스테르를 연속적으로 수소화하는 방법 有权
标题翻译：连续加氢不饱和脂肪酸酯的工艺
公开(公告)号：KR1020100026249A
公开(公告)日：2010-03-10
申请号：KR1020080085180
申请日：2008-08-29
申请人： 한국화학연구원 , 에이케이홀딩스 주식회사
发明人： 한요한 , 김형록 , 전종열 , 김선현 , 김정곤 , 이종화 , 신철 , 윤성호
IPC分类号： C07C5/00 , C07C5/02
摘要： PURPOSE: A continuous hydrogenation method of unsaturated fatty alkyl ester is provided to ensure mild reaction conditions, excellent reaction stability, and long-period reaction using a nickel-based catalyst. CONSTITUTION: A continuous hydrogenation method of unsaturated fatty alkyl ester comprises a step of preparing saturated fatty acid alkylester by hydrogenating C8-24 unsaturated fatty acid alkylester in the presence of a quaternary metallic oxide catalyst represented by chemical formula 1: (NiO)a·(MgO)b·(ZnO)c·(Al2O3)d. In chemical formula 1, a, b, c and d represent the content based on the total weight of a catalyst, wherein a is 40-80 weight%, b is 1-15 weight%, c is 0.5-5 weight%, and d is 20-50 weight%.
摘要翻译：目的：提供不饱和脂肪烷基酯的连续氢化方法，以确保温和的反应条件，优异的反应稳定性和使用镍基催化剂的长时间反应。构成：不饱和脂肪烷基酯的连续氢化方法包括在化学式1表示的季金属氧化物催化剂的存在下，使C8-24不饱和脂肪酸烷基酯氢化制备饱和脂肪酸烷基酯的步骤：（NiO）a·（ MgO）的·b·（ZnO）的C·（氧化铝）天。在化学式1中，a，b，c和d表示基于催化剂总重量的含量，其中a为40-80重量％，b为1-15重量％，c为0.5-5重量％，和 d为20-50重量％。

20. 发明授权

KR100644246B1 동·식물유로부터 지방산 알킬 에스테르를 제조하는 방법 有权
标题翻译： 동식물식물유로부지지방산알킬에스테르를제조하는방법
公开(公告)号：KR100644246B1
公开(公告)日：2006-11-10
申请号：KR1020050078854
申请日：2005-08-26
申请人： 한국화학연구원
发明人： 이정호 , 김형록 , 한요한 , 전종열
IPC分类号： C07C67/00
摘要： Provided are a method for preparing a fatty acid alkyl ester from animal and vegetable oils easily without post-processing such as washing or distillation, and a transesterification composite catalyst used in the preparation. The method comprises the step of reacting an animal and/or vegetable oil with a low molecular weight alcohol of C1-C4 in the presence of a catalyst represented by xMgOÀyZnOÀZnAl2O4 in a fixed bed reactor to prepare a fatty acid alkyl ester continuously, wherein x and y represent a molar ratio to ZnAl2O4; x is 1-3; y is 0-2; and ZnAl2O4 is a zinc aluminate having a spinel structure. Preferably the animal and/or vegetable oil comprises at least one selected from the group consisting of a soybean oil, a rapeseed oil, a sunflower seed oil, a corn oil, a palm oil, tallow, and their mixture.
摘要翻译：本发明提供一种从动植物油中容易地制备脂肪酸烷基酯而无需洗涤或蒸馏等后处理以及制备中使用的酯交换复合催化剂的方法。所述方法包括在固定床反应器中在由xMgO＆Agrave; yZnO＆Agrave; ZnAl 2 O 4表示的催化剂存在下使动物油和/或植物油与C1-C4的低分子量醇反应以连续制备脂肪酸烷基酯的步骤其中x和y代表与ZnAl 2 O 4的摩尔比; x是1-3; y是0-2; ZnAl2O4是具有尖晶石结构的铝酸锌。优选地，动物油和/或植物油包含选自大豆油，菜籽油，葵花籽油，玉米油，棕榈油，牛油及其混合物中的至少一种。

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