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11. 发明专利

ES2347452T3 PROCESO PARA PRODUCIR UN POLIMERO DE PROPILENO. 未知
公开(公告)号：ES2347452T3
公开(公告)日：2010-10-29
申请号：ES05777099
申请日：2005-08-29
申请人： MITSUI CHEMICALS INC
发明人： FUNAYA MUNEHITO , HIROTA NARITOSHI , HIWARA MAYUMI , TOHI YASUSHI , KAWAI KOJI , MORI RYOJI
IPC分类号： C08F4/645 , C07F7/00 , C07F17/00 , C08F10/06
摘要： Un proceso para producir un polímero de propileno, en donde la polimerización se realiza en un sistema seleccionado de un sistema de propileno solo o un sistema de tres componentes de propileno, etileno y α-olefina que tiene 4 o más átomos de carbono en presencia de un catalizador para la polimerización de olefinas que comprende: (A) un compuesto metaloceno con puente representado por la siguiente fórmula general (I), y (B) uno o más compuesto(s) seleccionado(s) de (b-1) un compuesto organoaluminoxi (b-2) un compuesto de reacciona con el compuesto metaloceno con puente (A) para formar un par iónico, y (b-3) un compuesto organoaluminio: **(Ver fórmula)** en donde R1 y R3 es cada uno hidrógeno R2 se selecciona del grupo que consiste en un grupo tert-butilo, un grupo metilciclohexilo y un grupo metiladamantilo, R4 es un grupo hidrocarburo que tiene de 2 a 4 átomos de carbono, R5, R6, R7, R8, R9, R10, R11 y R12, cada uno de los cuales se selecciona de hidrógeno, un grupo hidrocarburo y un grupo que contiene silicio, pueden ser iguales o diferentes entre sí, y los grupos adyacentes pueden estar unidos entre sí para formar un anillo, R13 y R14, cada uno de los cuales se selecciona de un grupo fenilo y un grupo fenilo sustituido que tiene de 6 a 10 átomos de carbono, pueden ser iguales o diferentes entre sí, M es Ti, Zr o Hf, Y es carbono o silicio, Q se puede seleccionar de halógeno, un grupo hidrocarburo, un ligando aniónico y un ligando neutro capaz de coordinarse con un único par de electrones, que se puede seleccionar en la misma combinación o diferente combinación, y j es un número entero de 1 a 4.

12. 发明专利

DE602005021980D1 VERFAHREN ZUR HERSTELLUNG VON PROPYLENPOLYMER 未知
公开(公告)号：DE602005021980D1
公开(公告)日：2010-08-05
申请号：DE602005021980
申请日：2005-08-29
申请人： MITSUI CHEMICALS INC
发明人： FUNAYA MUNEHITO , HIROTA NARITOSHI , HIWARA MAYUMI , TOHI YASUSHI , KAWAI KOJI , MORI RYOJI , OKAMOTO MASAHIKO , IKENAGA SHIGENOBU , MARUBAYASHI HIROMASA
IPC分类号： C08F4/645 , C07F7/00 , C07F17/00 , C08F10/06

13. 发明专利

DE602004026410D1 未知
公开(公告)号：DE602004026410D1
公开(公告)日：2010-05-20
申请号：DE602004026410
申请日：2004-02-03
申请人： MITSUI CHEMICALS INC
发明人： MORI RYOJI , NAKAGAWA TAKASHI , TODO AKIRA
IPC分类号： C08L23/00 , C08L23/12 , C08L23/14 , C08L23/16
摘要： A syndiotactic propylene-based polymer composition which retains the inherent features of the conventional non-crosslinked or partially crosslinked olefin-based thermoplastic elastomer, and also has excellent abrasion resistance and flexibility. The syndiotactic propylene-based polymer composition comprises 1 to 40 parts by weight of the syndiotactic polypropylene (B), and 5 to 60 parts by weight of the syndiotactic structured propylene- alpha -olefin copolymer (C) comprising 95 to 65 mol% of a syndiotactic structured propylene component and 5 to 35 mol% of an alpha -olefin (except propylene) component having 2 to 20 carbon atoms, based on 100 parts by weight of the non-crosslinked or partially crosslinked olefin-based thermoplastic elastomer (A).

14. 发明专利

DE602004024643D1 未知
公开(公告)号：DE602004024643D1
公开(公告)日：2010-01-28
申请号：DE602004024643
申请日：2004-01-16
申请人： MITSUI CHEMICALS INC
发明人： MORI RYOJI , NAKAGAWA TAKASHI , KAGAMI MAMORU , TODO AKIRA
IPC分类号： C08L23/10 , A61M5/14 , A61M25/00 , A61M39/08 , C08L23/14
摘要： The invention provides a propylene polymer composition well balanced and excellent in transparency, flexibility, heat resistance, scratch resistance and rubber elasticity, and a medical tube made from the propylene polymer composition. The propylene polymer composition satisfies all the following properties (A), (B), (C) and (D): (A) the composition shows a loss tangent (tan´) peak at a temperature in the range of -20 to 25°C according to dynamic viscoelasticity measurement (10 rad/s) in a torsion mode, and the peak is 0.5 or above; (B) the storage elastic modulus G' at 20°C from the dynamic viscoelasticity measurement is in the range of 1.0x10 7 to 4.9x10 8 dyn/cm 2 ; (C) the penetration temperature (°C) determined in accordance with JIS K 7196 is in the range of 60 to 160°C; and (D) the composition has a permanent set of not more than 30% as determined after the composition fixed between chucks 30 mm apart is 100% strained at a stress rate of 30 mm/min, maintained for 10 minutes and released for 10 minutes. The medical tube is made from the propylene polymer composition.

15. 发明专利

AU2009200068A1 Propylene copolymer, polypropylene composition, use thereof, transition metal compounds, and catalysts for olefin polymerization 未知
公开(公告)号：AU2009200068A1
公开(公告)日：2009-02-05
申请号：AU2009200068
申请日：2009-01-07
申请人： MITSUI CHEMICALS INC
发明人： KANEYOSHI HIROMU , HIROTA NARITOSHI , INOUE NORIHIDE , OKADA KEIJI , MORI RYOJI , KAWAHARA NOBUO , FUNAYA MUNEHITO , KASHIWA NORIO , TAKAYASU HIROSHI , KAWAI KOJI , KOJOH SHINICHI , IKENAGA SHIGENOBU
IPC分类号： C08F210/06 , C08F4/64 , C08F4/6592 , C08L23/14
摘要： The present invention provides a propylene/1-butene random copolymer (PBR) having excellent flexibility, impact resistance, heat resistance and low-temperature heat-seal properties, a polypropylene composition containg the copolymer, a sheet, film or stretched film comprising the composition and a composite film having a layer of the composition. The propylene/1-butene random copolymer contains 60 to 90 mol% of propylene units and 10 to 40 mol% of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5 %, a molecular weight distribution (Mw/Mn) of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point (Tm) of from 40 to 120°C, and satisfies the following relation wherein Tm represents a melting point and M (mol%) represents a content of 1-butene constituent units. The invention, further, provides a transition metal compound useful as an olefin polymerization catalyst and an olefin polymerization catalyst containing the transition metal compound. The transition metal compound is represented by the following formula (2a): wherein each of R 1 and R 3 is hydrogen, R 2 and R 4 are selected from a hydrocarbon group and silicon-containing group, R 5 to R 13 are selected from hydrogen, a hydrocarbon group and silicon-containing group, and adjacent substituent groups R 5 to R 12 may be linked to form a ring. R 14 is an aryl group, and R 13 and R 14 may be linked to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q is halogen, etc, and j is an integer of 1 to 4.

16. 发明专利

MY137481A ETHYLENE COPOLYMER AND ETHYLENE/ALPHA-OLEFIN COPOLYMER COMPOSITION AND PROPYLENE POLYMER COMPOSITION BOTH CONTAINING THE ETHYLENE COPOLYMER 未知
公开(公告)号：MY137481A
公开(公告)日：2009-01-30
申请号：MYPI20013327
申请日：2001-07-12
申请人： MITSUI CHEMICALS INC
发明人： MORI RYOJI , KIZU KOUICHI , OKADA KEIJI , TAKIMOTO KAZUYUKI
摘要： THE PRESENT INVENTION RELATES TO AN ETHYLENE BASED COPOLYMER USEFUL AS A MODIFIER FOR RESINS,E.G., POLYPROPYLENE, AND AN ETHYLENE/A -OLEFIN COPOLYMER COMPOSITION CONTAINING THE SAME ETHYLENE-BASED COPOLYMER.@THE ETHYLENE-BASED COPOLYMER (1) OF THE PRESENT INVENTION IS CHARACTERIZED BY:@(a-1) HAVING TEMPERATURE (tM) AT THE MAXIMUM PEAK IN THE ENDOTHERNIC CURVE, MEASURED BY A DIFFERENTIAL SCANNINGCALORIMETER(DSC), OF 40 TO 90423C,@(a-2) CONTAINING THE COMPONENT SOLUBLE IN DECANE AT NORMAL TEMPERATURE AT 1 TO 70BY WEIGHT, AND@(a-0 CONTAINING THE COMPONENT SOLUBLE IN DECANE AT NORMAL TEMPERATURE WHICH COMPRISES (i) A RECURRING UNIT DERIVED FROM ETHYLENE AND (ii) A RECURRING UNIT DERIVED FROM AN a-OLEFIN OF 4 OR MORE CARBON ATOMS, AND IN WHICH A CONTENT OF (i) THE RECURRING UNIT DERIVED FROM ETHYLENE IS 50 TO 75BY MOLE. THE ETHYLENE BASED COPOLYMER COMPOSITION [II] OF THE PRESENT INVENTION IS CHARACTERIZED BY CONTAINING THE ETHYLENE-BASED COPOLYMER WHICH SATISFIES THE FOLLOWING CONDITIONS (b-1) TO (b-3):@(b-1) HAVING TEMPERATURE (Tm) AT THE MAXIMUM PEAK IN THE ENDOTHERMIC CURVE OF THE COMPONENT SOLUBLE IN DECANE AT 64423C, MEASURED BY A DIFFERENTIAL SCANNING CALORIMETER (DSC), OF40 TO 90423C,@(b-2) CONTAINING THE COMPONENT SOLUBLE IN DECANE AT 64423C WHICH CONTAINS THE COMPONENT SOLUBLE IN DECANE AT NORMAL TEMPERATURE AT 1 TO 70BY WEIGHT, AND@(b-3) CONTAINING THE COMPONENTSOLUBLE IN DECANE AT NORMAL TEMPERRATURE WHICH COMPRISES (i) A RECURRING UNIT DERIVED FROM ETHYLENE AND (ii) A RECURRING UNIT DERIVED FROM AN A-OLEFIN OF 4 OR MORE CARBON ATOMS, AND IN WHICH A CONTENT OF (i) THE RECURRING UNIT DERIVED FROM ETHYLENE IS 50 TO 75BY MOLE.

17. 发明专利

DE60034308T2 未知
公开(公告)号：DE60034308T2
公开(公告)日：2007-12-20
申请号：DE60034308
申请日：2000-10-05
申请人： MITSUI CHEMICALS INC
发明人： KAWAI KOJI , YAMASHITA MASAHIRO , TOHI YASUSHI , KAWAHARA NOBUO , MICHIUE KENJI , KANEYOSHI HIROMU , MORI RYOJI
IPC分类号： C07F17/00 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06
摘要： The metallocene compound according to the invention and the olefin polymerization catalyst containing the compound are intended to produce a catalyst capable of preparing an isotactic polymer with a high polymerization activity. The metallocene compound contains a substituted cyclopentadienyl group and a (substituted) fluorenyl group and has a structure wherein these groups are bridged by a hydrocarbon group or the like. The process for preparing a metallocene compound according to the invention is intended to selectively prepare a specific metallocene compound so as not to produce an isomer, and in this process an intermediate product is synthesized by a specific method. The process for preparing a polyolefin according to the invention is intended to prepare a polyolefin having excellent impact resistance and transparency, and this process comprises homopolymerizing an alpha -olefin of 3 to 8 carbon atoms or copolymerizing an olefin of 3 to 8 carbon atoms and another alpha -olefin in the presence of an olefin polymerization catalyst containing the above-mentioned metallocene compound.

18. 发明专利

SG10201504180VA CATALYST FOR OLEFIN POLYMERIZATION, METHOD FOR PRODUCING OLEFIN POLYMER, METHOD FOR PRODUCING PROPYLENE-BASED COPOLYMER, PROPYLENE POLYMER, PROPYLENE-BASED POLYMER COMPOSITION, AND USE OF THOSE 未知
公开(公告)号：SG10201504180VA
公开(公告)日：2015-07-30
申请号：SG10201504180V
申请日：2006-05-18
申请人： MITSUI CHEMICALS INC
发明人： TOHI YASUSHI , OKAMOTO MASAHIKO , MORI RYOJI , NAKAMURA TATSUYA , YUKITA TAKASHI , NAKAGAWA TAKASHI , KONNO MIYUKI , YAMAMURA YUICHI , IKENAGA SHIGENOBU , HIWARA MAYUMI , HIROTA NARITOSHI , MARUBAYASHI HIROMASA , NAGAHASHI KOUJI , OTSUZUKI SHIRO , YAMAGUCHI TOMOHIRO , HIGUCHI MASASHI , ICHIKI YASUO
摘要： Provided is a propylene-based polymer comprising constituent units derived from propylene in an amount of more than 90 mol % (provided that the total amount of constituent units in the polymer is 100 mol %), and satisfying the following requirements [1] and [2-1]: [1] the syndiotactic pentad fraction (rrrr fraction) as measured by 13 C-NMR is 85% or greater; and [2-1] the melting point (Tm) determined by differential scanning calorimetry (DSC) is 145°C or higher.

19. 发明专利

DE60331613D1 未知
公开(公告)号：DE60331613D1
公开(公告)日：2010-04-15
申请号：DE60331613
申请日：2003-12-26
申请人： MITSUI CHEMICALS INC
发明人： IKENAGA SHIGENOBU , OKADA KEIJI , TAKAYASU HIROSHI , INOUE NORIHIDE , HIROTA NARITOSHI , KANEYOSHI HIROMU , FUNAYA MUNEHITO , KAWAI KOJI , KAWAHARA NOBUO , KOJOH SHINICHI , KASHIWA NORIO , MORI RYOJI
IPC分类号： C08F210/06 , C08F4/64 , C08F4/6592 , C08J5/18 , C08L23/10 , C08L23/14
摘要： The present invention provides a propylene/1-butene random copolymer (PBR) having excellent flexibility, impact resistance, heat resistance and low-temperature heat-seal properties, a polypropylene composition containg the copolymer, a sheet, film or stretched film comprising the composition and a composite film having a layer of the composition. The propylene/1-butene random copolymer contains 60 to 90 mol% of propylene units and 10 to 40 mol% of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5 %, a molecular weight distribution (Mw/Mn) of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point (Tm) of from 40 to 120°C, and satisfies the following relation wherein Tm represents a melting point and M (mol%) represents a content of 1-butene constituent units. The invention, further, provides a transition metal compound useful as an olefin polymerization catalyst and an olefin polymerization catalyst containing the transition metal compound. The transition metal compound is represented by the following formula (2a): wherein each of R 1 and R 3 is hydrogen, R 2 and R 4 are selected from a hydrocarbon group and silicon-containing group, R 5 to R 13 are selected from hydrogen, a hydrocarbon group and silicon-containing group, and adjacent substituent groups R 5 to R 12 may be linked to form a ring. R 14 is an aryl group, and R 13 and R 14 may be linked to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q is halogen, etc, and j is an integer of 1 to 4.

20. 发明专利

DE60331378D1 未知
公开(公告)号：DE60331378D1
公开(公告)日：2010-04-01
申请号：DE60331378
申请日：2003-12-26
申请人： MITSUI CHEMICALS INC
发明人： IKENAGA SHIGENOBU , OKADA KEIJI , TAKAYASU HIROSHI , INOUE NORIHIDE , HIROTA NARITOSHI , KANEYOSHI HIROMU , FUNAYA MUNEHITO , KAWAI KOJI , KAWAHARA NOBUO , KOJOH SHINICHI , KASHIWA NORIO , MORI RYOJI
IPC分类号： C08F210/06 , C08F4/64 , C08F4/6592 , C08J5/18 , C08L23/10 , C08L23/14
摘要： The present invention provides a propylene/1-butene random copolymer (PBR) having excellent flexibility, impact resistance, heat resistance and low-temperature heat-seal properties, a polypropylene composition containg the copolymer, a sheet, film or stretched film comprising the composition and a composite film having a layer of the composition. The propylene/1-butene random copolymer contains 60 to 90 mol% of propylene units and 10 to 40 mol% of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5 %, a molecular weight distribution (Mw/Mn) of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point (Tm) of from 40 to 120°C, and satisfies the following relation wherein Tm represents a melting point and M (mol%) represents a content of 1-butene constituent units. The invention, further, provides a transition metal compound useful as an olefin polymerization catalyst and an olefin polymerization catalyst containing the transition metal compound. The transition metal compound is represented by the following formula (2a): wherein each of R 1 and R 3 is hydrogen, R 2 and R 4 are selected from a hydrocarbon group and silicon-containing group, R 5 to R 13 are selected from hydrogen, a hydrocarbon group and silicon-containing group, and adjacent substituent groups R 5 to R 12 may be linked to form a ring. R 14 is an aryl group, and R 13 and R 14 may be linked to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q is halogen, etc, and j is an integer of 1 to 4.

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