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11. 发明授权

US5580497A Oxygen ion-conducting dense ceramic 失效
标题翻译：氧离子导电致密陶瓷
公开(公告)号：US5580497A
公开(公告)日：1996-12-03
申请号：US212251
申请日：1994-03-18
申请人： Uthamalingam Balachandran , Mark S. Kleefisch , Thaddeus P. Kobylinski , Sherry L. Morissette , Shiyou Pei
发明人： Uthamalingam Balachandran , Mark S. Kleefisch , Thaddeus P. Kobylinski , Sherry L. Morissette , Shiyou Pei
IPC分类号： B01D53/22 , B01D71/02 , B01J12/00 , B01J19/24 , C01B13/02 , C01G51/00 , C04B35/01 , C04B35/26 , H01M8/12 , H01B1/06
CPC分类号： B01D67/0041 , B01D53/22 , B01D53/228 , B01D71/024 , B01J12/007 , B01J19/2475 , B01J19/2485 , C01B13/0203 , C01B13/0255 , C01G49/0018 , C01G49/009 , C01G51/006 , C04B35/01 , C04B35/2633 , H01M8/1231 , H01M8/1246 , B01D2257/104 , B01D2325/26 , B01J2219/00051 , B01J2219/00186 , C01B2210/0046 , C01B2210/0051 , C01B2210/0071 , C01B2210/0075 , C01P2002/20 , C01P2002/34 , C01P2002/54 , C01P2002/72 , C01P2002/74 , C01P2002/77 , C01P2002/78 , C01P2006/80 , Y02E60/525 , Y02P70/56
摘要： Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented bySr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta.where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.
摘要翻译：描述了至少包含锶，钴，铁和氧的混合金属氧化物组合物的制备，结构和性质。本发明的结晶混合金属氧化物组合物具有例如由α（Fe1-xCox）α+βOδ表示的结构，其中x是0.01至约1的范围内的数，α是从约1至约4，β是从0至约20的范围内的数字，并且δ是使化合物电荷为中性的数，并且其中所述组合物具有非钙钛矿结构。介绍了在氧离子导电性和选择性氧分离的密集陶瓷膜中使用混合金属氧化物，以及它们在与含氧气体混合物中分离氧气的用途。

12. 发明授权

US4717702A Catalyst for conversion of synthesis gas to diesel fuel and process for preparation of such catalyst 失效
标题翻译：将合成气转化为柴油的催化剂及其制备方法
公开(公告)号：US4717702A
公开(公告)日：1988-01-05
申请号：US876458
申请日：1986-06-20
申请人： Harold Beuther , Charles L. Kibby , Thaddeus P. Kobylinski , Richard B. Pannell
发明人： Harold Beuther , Charles L. Kibby , Thaddeus P. Kobylinski , Richard B. Pannell
IPC分类号： B01J23/75 , B01J23/83 , B01J35/10 , C07C1/04 , B01J21/04 , B01J23/10 , B01J23/74
CPC分类号： C07C1/0445 , B01J23/75 , B01J23/83 , B01J35/002 , B01J35/0053 , B01J35/023 , C07C2521/04 , C07C2521/06 , C07C2523/10 , C07C2523/12 , C07C2523/75
摘要： A catalyst for the conversion of synthesis gas comprising cobalt on a high surface area, high purity, low acidity alumina support of gamma-alumina, eta-alumina or mixtures thereof, whereby the catalyst is prepared by (A) impregnation of the alumina support with a non-aqueous, organic solvent impregnation solution of cobalt nitrate containing sufficient amounts of a Group IIIB or IVB metal salt to provide said catalyst with from about 0.05 to about 100 parts by weight of a Group IIIB or IVB metal oxide per 100 parts by weight cobalt, (B) reduction of the impregnated alumina support by heating, in the presence of hydrogen, at a heating rate of from about 0.5.degree. to about 5.degree. C. per minute to a maximum temperature in the range of 180.degree. to about 220.degree. C. for a hold time of 6 to about 24 hours and thereafter heating the impregnated alumina support in the presence of hydrogen while heating up to a maximum hold temperature of from about 250.degree. to about 400.degree. C. for a hold time of 6 to about 65 hours.
摘要翻译：用于在高表面积上转化包含钴的合成气的催化剂，γ-氧化铝，η-氧化铝或其混合物的高纯度，低酸度氧化铝载体，由此通过（A）将氧化铝载体浸渍含有足够量的IIIB或IVB族金属盐的硝酸钴的非水性有机溶剂浸渍溶液，以使所述催化剂每100重量份提供约0.05至约100重量份的IIIB或IVB族金属氧化物钴，（B）在氢存在下，以每分钟约0.5℃至约5℃的加热速率加热浸渍的氧化铝载体的还原，至180℃至约220℃的最高温度保持时间为6至约24小时，然后在氢气存在下加热浸渍的氧化铝载体，同时加热至约250℃至约400℃的最大保持温度，保持时间为6 t 约65小时。

13. 发明授权

US4541916A Coal liquefaction process using low grade crude oil 失效
标题翻译：采用低档原油的煤液化工艺
公开(公告)号：US4541916A
公开(公告)日：1985-09-17
申请号：US662357
申请日：1984-10-18
申请人： Harold Beuther , Thaddeus P. Kobylinski , Win-Chung Lee , Bruce K. Schmid
发明人： Harold Beuther , Thaddeus P. Kobylinski , Win-Chung Lee , Bruce K. Schmid
IPC分类号： C10G1/04 , C10G1/00 , C10G47/00
CPC分类号： C10G1/042
摘要： A process for converting coal to liquid hydrocarbonaceous products involving a liquefaction reaction in the presence of a coal derived recycle slurry and a non-coal derived solvent comprising a hydrocarbonaceous oil or distillation bottom residue thereof intrinsically contaminated with greater than 300 ppm total of vanadium and nickel. The liquefaction reaction is performed under hydrogen pressure (approximately 500-4000 psi) and under elevated temperature (approximately 300.degree.-500.degree. C.) using a weight ratio of non-coal derived solvent to coal of about 1/1 or less. The conversion of coal to liquids is greatly enhanced by the use of such a non-coal derived solvent under these conditions.
摘要翻译：在煤衍生的再循环浆料和非煤衍生的溶剂的存在下，将煤转化为液化烃产物的方法，该方法包括含烃油或蒸馏塔底残余物，其本身被大于总共含有的钒和镍总量的300ppm污染。液化反应在氢气压力（约500-4000psi）和升高的温度（约300-500℃）下进行，使用非煤衍生的溶剂与煤的重量比约为1/1以下。在这些条件下，通过使用这种非煤衍生的溶剂，大大提高了煤到液体的转化。

14. 发明授权

US4409404A Process for producing ethanol using said novel catalyst system 失效
标题翻译：使用所述新型催化剂体系生产乙醇的方法
公开(公告)号：US4409404A
公开(公告)日：1983-10-11
申请号：US352807
申请日：1982-02-26
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： B01J31/20 , B01J31/26 , C07C27/00 , C07C29/32 , C07C31/08 , C07C67/00 , C07C29/00
CPC分类号： B01J31/0231 , B01J31/0234 , B01J31/0259 , B01J31/0267 , B01J31/20 , B01J31/26 , C07C29/32 , C07C31/08 , C12C11/02 , B01J2231/34 , B01J2231/641 , B01J2531/821 , B01J2531/845
摘要： A novel process for selectively producing ethanol which comprises introducing into a reaction zone (1) methanol, (2) hydrogen, (3) carbon monoxide, (4) a cobalt carbonyl, a hydrido cobalt carbonyl or a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, (5) a tertiary organo Group VA compound of the Periodic Table, (6) an iodine compound and (7) a ruthenium compound; and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time sufficient to convert methanol to ethanol.
摘要翻译：一种用于选择性生产乙醇的新方法，其包括将甲醇，（2）氢气，（3）一氧化碳，（4）羰基钴，羰基钴或含钴材料转化为反应区羰基钴或羰基钴氢化物，（5）周期表的叔有机基团VA化合物，（6）碘化合物和（7）钌化合物; 然后使所述反应区的内容物处于升高的温度和升高的压力下一段足以将甲醇转化成乙醇的时间。

15. 发明授权

US4339610A Process for selective formation of C.sub.4 compounds and thiol-containing catalyst system used therein 失效
标题翻译：用于选择性形成C4化合物和其中使用的含硫醇催化剂体系的方法
公开(公告)号：US4339610A
公开(公告)日：1982-07-13
申请号：US215555
申请日：1980-12-11
申请人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
发明人： Wayne R. Pretzer , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： C07C29/32 , C07C45/49 , C07C27/22 , C07C45/50
CPC分类号： C07C29/32 , C07C45/49 , C12C11/02 , Y02P20/52
摘要： C.sub.4 compounds including n-butanol and n-butanal are produced by reacting methanol, hydrogen, and carbon monoxide, in the presence of a cobalt catalyst selected from the group consisting of (a) a cobalt carbonyl, (b) a hydrido cobalt carbonyl and (c) a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, an iodine promotor and a thiol defined by the formula:RSHwherein R is selected from the group consisting of saturated or unsaturated, straight or branched chain alkyl radicals having from one to 24 carbon atoms, cycloalkyl radicals having from three to 40 carbon atoms, aryl radicals having from six to 20 carbon atoms, aralkyl and alkaryl radicals having from six to 40 carbon atoms and halogen substituted derivatives thereof. A high degree of selectivity towards the formation of butanol and butanal is provided by using the cobalt entity and the thiol in a molar ratio in the range of about 2:1 to about 10:1, based on elemental cobalt and sulfur. The reaction is conducted at elevated temperature and pressure conditions for a time sufficient to convert methanol to n-butanol and n-butanal.
摘要翻译：包括正丁醇和正丁醛的C 4化合物通过甲醇，氢气和一氧化碳在钴催化剂存在下制备，所述钴催化剂选自（a）羰基钴，（b）羰基钴和（c）可转化为羰基钴或羰基钴的钴的物质，碘促进剂和由下式定义的硫醇：其中R选自饱和或不饱和的直链或支链烷基具有1至24个碳原子，具有3至40个碳原子的环烷基，具有6至20个碳原子的芳基，具有6至40个碳原子的芳烷基和烷芳基及其卤素取代的衍生物。基于元素钴和硫，通过使用钴实体和硫醇以约2:1至约10:1的摩尔比来提供对形成丁醇和丁醛的高度选择性。反应在升高的温度和压力条件下进行足以将甲醇转化为正丁醇和正丁醛的时间。

16. 发明授权

US4311864A Method for preparing synthetic hydrocarbon fluids 失效
标题翻译：制备合成烃流体的方法
公开(公告)号：US4311864A
公开(公告)日：1982-01-19
申请号：US168523
申请日：1980-07-14
申请人： John P. Pellegrini, Jr. , David L. Beach , Thaddeus P. Kobylinski
发明人： John P. Pellegrini, Jr. , David L. Beach , Thaddeus P. Kobylinski
IPC分类号： C07C2/22 , C08F10/10 , C10M107/08 , C07C2/02
CPC分类号： C10M107/08 , C07C2/22 , C08F10/10 , C07C2527/1206 , C07C2527/132 , C10M2205/00 , C10M2205/026 , C10N2220/02 , C10N2240/08 , Y02P20/582
摘要： A synthetic hydrocarbon fluid is prepared by oligomerizing an olefin reactant in the presence of a catalyst prepared by reacting tungsten hexafluoride and hydrogen fluoride at a moderate temperature. For example, 1-butene is oligomerized at a temperature of about 40.degree. C. in the presence of a catalyst obtained by reacting tungsten hexafluoride and hydrogen fluoride in a four to one mol ratio. The liquid oligomer product is then hydrogenated to remove residual unsaturation.
摘要翻译：通过在适度的温度下在六氟化钨和氟化氢反应制备的催化剂存在下使烯烃反应物低聚来制备合成烃流体。例如，1-丁烯在约40℃的温度下，通过六氟化钨和氟化氢以四至一摩尔的比例反应获得的催化剂存在下进行低聚。然后将液体低聚物产物氢化以除去残余不饱和度。

17. 发明授权

US4308409A Preparation of propylene glycol from propylene 失效
标题翻译：从丙烯制备丙二醇
公开(公告)号：US4308409A
公开(公告)日：1981-12-29
申请号：US172859
申请日：1980-07-28
申请人： Ching-Yong Wu , Thaddeus P. Kobylinski , John E. Bozik
发明人： Ching-Yong Wu , Thaddeus P. Kobylinski , John E. Bozik
IPC分类号： C07C29/03 , C07C29/48 , C07C29/04
CPC分类号： C07C29/48 , C07C29/03
摘要： Propylene is converted to propylene glycol at high selectivity in a process in which ethylbenzene hydroperoxide and water are reacted with propylene in the presence of osmium tetroxide catalyst and a base at a pH of about 14.
摘要翻译：在四氧化锇催化剂和碱约14的pH下，乙苯氢过氧化物和水与丙烯反应的过程中，丙烯以高选择性转化为丙二醇。

18. 发明授权

US4293725A Use of metal modified refractory metal oxide/silica supported nickel cluster catalyst to oligomerize ethylene 失效
$Use of metal modified refractory metal oxide/silica supported nickel cluster catalyst to oligomerize ethylene$
标题翻译：使用金属改性的难熔金属氧化物/二氧化硅负载的镍簇催化剂使乙烯低聚
公开(公告)号：US4293725A
公开(公告)日：1981-10-06
申请号：US151952
申请日：1980-05-21
申请人： David L. Beach , Thaddeus P. Kobylinski
发明人： David L. Beach , Thaddeus P. Kobylinski
IPC分类号： B01J31/20 , C07C2/34 , C07C2/02 , C07C2/26
CPC分类号： B01J31/26 , B01J31/1616 , B01J31/20 , B01J31/2295 , C07C2/34 , B01J21/12 , B01J2231/20 , B01J2531/007 , B01J2531/0211 , B01J2531/847 , B01J31/04 , B01J31/2234 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2531/22 , Y02P20/588
摘要： Ethylene is oligomerized by intimately contacting ethylene with a metal modified catalyst. The catalyst is produced by contacting (a) a refractory metal oxide/silica support, such as alumina/silica wherein the silica content of the support is from about 2 to about 95 weight percent and the metal oxide content of the support is from about 5 to about 98 percent with (b) a solution of a basic metal and then (c) contacting the resulting metal modified support with a tris(cyclopentadienyl)trinickel dicarbonyl.
摘要翻译：通过使乙烯与金属改性的催化剂紧密接触来使乙烯低聚。催化剂通过使（a）难熔金属氧化物/二氧化硅载体如氧化铝/二氧化硅接触来制备，其中载体的二氧化硅含量为约2至约95重量％，并且载体的金属氧化物含量为约5 （b）碱性金属溶液，然后（c）使得到的金属改性载体与三（环戊二烯基）三联苯二酰胺接触。

19. 发明授权

US4272407A Metal modified refractory metal oxide/silica supported nickel cluster catalyst 失效
$Metal modified refractory metal oxide/silica supported nickel cluster catalyst$
标题翻译：金属改性难熔金属氧化物/二氧化硅负载镍簇催化剂
公开(公告)号：US4272407A
公开(公告)日：1981-06-09
申请号：US151951
申请日：1980-05-21
申请人： David L. Beach , Thaddeus P. Kobylinski
发明人： David L. Beach , Thaddeus P. Kobylinski
IPC分类号： B01J31/20 , B01J31/22 , B01J31/26 , C07B61/00 , C07C1/00 , C07C2/34 , C07C11/02 , C07C67/00 , B01J31/12
CPC分类号： B01J31/2295 , B01J31/04 , B01J31/1616 , B01J31/20 , B01J31/26 , C07C2/34 , B01J21/12 , B01J2231/20 , B01J2531/0211 , B01J2531/847 , C07C2521/08 , C07C2521/12 , C07C2531/22 , Y02P20/52
摘要： A catalyst that is highly active in the oligomerization of lower olefins such as ethylene is produced by contacting (a) a refractory metal oxide/silica support, such as alumina/silica wherein the silica content of the support is from about 2 to about 95 weight percent and the metal oxide content of the support is from about 5 to about 98 percent with (b) a solution of a basic metal and then (c) contacting the resulting metal modified support with a tris(cyclopentadienyl)trinickel dicarbonyl.
摘要翻译：通过使（a）难熔金属氧化物/二氧化硅载体如氧化铝/二氧化硅接触，其中低级烯烃如乙烯的低聚反应具有高活性的催化剂，其中载体的二氧化硅含量为约2至约95重量％并且（b）碱性金属溶液，然后（c）使得到的金属改性载体与三（环戊二烯基）三联铁二羰基接触，载体的金属氧化物含量为约5至约98％。

20. 发明授权

US4272406A Refractory metal oxide/silica supported nickel cluster catalyst 失效
$Refractory metal oxide/silica supported nickel cluster catalyst$
标题翻译：耐火金属氧化物/二氧化硅负载镍簇催化剂
公开(公告)号：US4272406A
公开(公告)日：1981-06-09
申请号：US151948
申请日：1980-05-21
申请人： David L. Beach , Thaddeus P. Kobylinski
发明人： David L. Beach , Thaddeus P. Kobylinski
IPC分类号： B01J31/20 , B01J31/22 , B01J31/26 , C07B61/00 , C07C1/00 , C07C2/34 , C07C5/25 , C07C11/02 , C07C67/00 , C08F4/42 , C08F4/60 , B01J31/12
CPC分类号： B01J31/1616 , B01J31/20 , B01J31/2295 , C07C2/34 , C07C5/2587 , B01J21/12 , B01J2231/20 , B01J2531/0211 , B01J2531/847 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2531/22 , Y02P20/52 , Y02P20/588
摘要： A catalyst that is highly active at low operating temperatures and pressures in the oligomerization of lower olefins such as ethylene is produced by contacting (a) a refractory metal oxide/silica support such as alumina/silica wherein the silica content of the support is from about 2 to about 95 weight percent and the metal oxide content of the support is from about 5 to about 98 percent with (b) a tris(cyclopentadienyl)trinickel dicarbonyl. When used to oligomerize ethylene, these catalysts are characterized by a relatively high reaction rate at moderate temperatures and pressures. Their use permits the production of relatively high proportions of desirable trimer, tetramer, pentamer, and higher olefinic products.
摘要翻译：通过使（a）难熔金属氧化物/二氧化硅载体如氧化铝/二氧化硅接触，其中低级烯烃如乙烯的低聚反应在低操作温度和低压下具有高活性的催化剂，其中载体的二氧化硅含量为约 2重量％至约95重量％，并且载体的金属氧化物含量为约5至约98％，（b）三（环戊二烯基）三联铁二羰基。当用于低聚乙烯时，这些催化剂的特征在于在适度的温度和压力下具有较高的反应速率。它们的使用允许生产相对高比例的所需三聚体，四聚体，五聚体和更高级的烯烃产物。

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