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11. 发明授权

US06828403B2 Method of bonding a window to a substrate using a silane functional adhesive composition 失效
标题翻译：使用硅烷官能粘合剂组合物将窗口粘合到基底上的方法
公开(公告)号：US06828403B2
公开(公告)日：2004-12-07
申请号：US10035894
申请日：2001-11-09
申请人： Syed Z. Mahdi , Harry W. Hsieh
发明人： Syed Z. Mahdi , Harry W. Hsieh
IPC分类号： C08G1830
CPC分类号： C09J175/08 , C03C27/048 , C08G18/10 , C08G18/12 , C08G18/24 , C08G18/4808 , C08G18/4825 , C08G18/718 , C08G65/2642 , C08G65/2651 , C08G65/336 , C08G2190/00 , C08L71/00 , C08L75/04 , C09J5/06 , C09J171/02 , C09J2400/143 , C09J2471/00 , C09J2475/00 , C08G18/307 , C08G18/3893
摘要： The invention is an adhesive composition comprising a) i) a trialkoxysilane functional polyether or polyurethane wherein the polyether or polyurethane has a weight average molecular weight of 6000 or greater and a dialkyltin carboxylate or dialkyltin alcoholate; or ii) a dialkoxysilane functional polyether or polyurethane and a dialkyltin alcoholate; and b) a primary or secondary amino straight chain alkyl trialkoxysilane; wherein the dialkyltin carboxylate or dialkyltin alcoholate is present in an effective amount to facilitate bonding of the adhesive to a substrate of from about 0.1 to about 1.0 percent by weight based on the weight of the adhesive and the primary or secondary amino straight chained alkyl trialkoxysilane is present in an amount which is effective to facilitate bonding of the adhesive to a substrate wherein the amount is from about 0.5 to about 1.2 percent by weight.
摘要翻译：本发明是一种粘合剂组合物，其包含：i）三烷氧基硅烷官能的聚醚或聚氨酯，其中所述聚醚或聚氨酯具有6000或更大的重均分子量和二烷基锡羧酸酯或二烷基锡醇盐; orii）二烷氧基硅烷官能的聚醚或聚氨酯和二烷基锡醇盐; 和b）伯或仲氨基直链烷基三烷氧基硅烷;其中所述二烷基锡羧酸酯或二烷基锡醇化物以有效的量存在，以促进粘合剂与基材的粘合，其量为约0.1至约1.0重量％粘合剂和主要或仲氨基直链烷基三烷氧基硅烷以有效促进粘合剂粘合到基材上的量存在，其量为约0.5至约1.2重量％。

12. 发明授权

US6015475A Polyurethane sealant compositions 有权
标题翻译：聚氨酯密封剂组合物
公开(公告)号：US6015475A
公开(公告)日：2000-01-18
申请号：US129856
申请日：1998-08-06
申请人： Harry W. Hsieh , Syed Z. Mahdi
发明人： Harry W. Hsieh , Syed Z. Mahdi
IPC分类号： C03C27/04 , C08G18/10 , C08G18/12 , C08G18/16 , C08G18/18 , C08G18/24 , C08G18/28 , C08G18/48 , C08G18/73 , C09J175/04 , C09K3/10 , C09J4/00
CPC分类号： C08G18/73 , C08G18/10 , C08G18/12 , C08G18/16 , C08G18/161 , C08G18/163 , C08G18/18 , C08G18/1875 , C08G18/289 , C08G18/4812 , C08G2190/00
摘要： In one aspect, this invention is a polyurethane sealant composition comprising (1) a urethane prepolymer having an isocyanate functionality of at least about 2.0 and a weight average molecular weight of at least about 2,000; and (2) a catalytic amount of (a) a substantially active hydrogen free glycol acid salt of a tertiary amine and an organo metallic compound, (b) a mixture of a substantially active hydrogen free glycol acid salt of a tertiary amine and an organo metallic compound and a second organometallic compound, or (c) a mixture of an organometallic compound with dimorpholinodialkyl ether or an dialkylmorpholinodialkyl ether. In another embodiment, the polyurethane sealant composition further comprises (A) a silane, or (B) an adduct of an isocyanate reactive silane and a polyisocyanate, (C) the reaction product of an isocyanate reactive silane or an adduct of an isocyanate reactive silane and a polyisocyanate with a polyisocyanate and an active hydrogen containing compound or a polyurethane prepolymer which has free isocyanate moieties; which reaction product has an average of at least one silane group and at least one isocyanate group per molecule. In another embodiment the invention is a method for bonding glass to a substrate which comprises contacting a sealant according to the invention with glass and another substrate with the sealant disposed between the glass and substrate and thereafter allowing the sealant to cure so as to bind the glass to the substrate. The sealant composition of the invention is useful in bonding glass substrates to metal plastic, fiberglass or composite substrates, which may or may not be painted. It has been discovered to give unexpectedly high lap shear strength when no primer compositions have previously been applied to the painted plastic, metal, fiberglass or composite substrate.
摘要翻译：一方面，本发明是一种聚氨酯密封剂组合物，其包含（1）具有至少约2.0的异氰酸酯官能度和至少约2,000的重均分子量的氨基甲酸酯预聚物; 和（2）催化量的（a）叔胺和有机金属化合物的基本上活性的无氢二醇酸盐，（b）叔胺的基本上活性的无氢二醇酸盐和有机金属的混合物金属化合物和第二有机金属化合物，或（c）有机金属化合物与二吗啉代二烷基醚或二烷基吗啉代二烷基醚的混合物。在另一个实施方案中，聚氨酯密封剂组合物还包含（A）硅烷或（B）异氰酸酯反应性硅烷和多异氰酸酯的加合物，（C）异氰酸酯反应性硅烷或异氰酸酯反应性硅烷的加合物的反应产物和具有多异氰酸酯和含活性氢化合物或具有游离异氰酸酯部分的聚氨酯预聚物的多异氰酸酯; 该反应产物每分子具有至少一个硅烷基团和至少一个异氰酸酯基团的平均值。在另一个实施方案中，本发明是将玻璃粘合到基底上的方法，其包括使根据本发明的密封剂与玻璃和另一基底接触，所述密封剂设置在玻璃和基底之间，然后使密封剂固化以便将玻璃粘合到基底。本发明的密封剂组合物可用于将玻璃基材粘合到金属塑料，玻璃纤维或复合基材上，其可以涂漆或可以不被涂漆。已经发现当没有底漆组合物已经施加到涂漆的塑料，金属，玻璃纤维或复合基材上时，出现意想不到的高搭接剪切强度。

13. 发明授权

US09193880B2 Adhesion promotion additives and methods for improving coating compositions 有权
标题翻译：粘合促进添加剂和改善涂料组成的方法
公开(公告)号：US09193880B2
公开(公告)日：2015-11-24
申请号：US11959107
申请日：2007-12-18
申请人： Dominic J. Allam , Kiran K. Baikerikar , Syed Z. Mahdi
发明人： Dominic J. Allam , Kiran K. Baikerikar , Syed Z. Mahdi
IPC分类号： C08G77/20 , C09D7/12 , C09D11/03 , C08K5/544
CPC分类号： C09D7/1233 , C08K5/544 , C09D7/63 , C09D11/03 , Y02P20/582
摘要： An additive (and methods for a coating composition that includes at least one an agent for improving the performance of the coating composition, selected from a Michael addition product of siloxane further containing one or more active hydrogen containing functional moieties with two or more acrylate groups; a high molecular weight adduct having multiple alkoxysilane moieties; a compound including at least one terminal unsaturation and multiple alkoxysilyl groups; an organometallic compound that includes an element selected from silicon, titanium, zirconium, aluminum, or any combination thereof.
摘要翻译：添加剂（以及包含至少一种用于改善涂料组合物的性能的试剂的涂料组合物的方法，其选自硅氧烷的迈克尔加成产物，其进一步含有一个或多个含活性氢的官能部分与两个或多个丙烯酸酯基团; 具有多个烷氧基硅烷部分的高分子量加合物;包含至少一个末端不饱和键和多个烷氧基甲硅烷基的化合物;包括选自硅，钛，锆，铝或其任何组合的元素的有机金属化合物。

14. 发明授权

US09051499B2 Two-part polyurethane adhesive for bonding fiber-reinforced plastics 有权
标题翻译：用于粘合纤维增强塑料的两部分聚氨酯胶粘剂
公开(公告)号：US09051499B2
公开(公告)日：2015-06-09
申请号：US13990149
申请日：2011-11-17
申请人： Syed Z. Mahdi , Yee Y. Wang , Arthur F. Cawley
发明人： Syed Z. Mahdi , Yee Y. Wang , Arthur F. Cawley
IPC分类号： C09J175/04 , C09J5/06 , C08G18/08 , C08G18/10 , C08G18/16 , C08G18/32 , C08G18/40 , C08G18/48 , C08G18/63 , C08G18/76 , C08G18/79
CPC分类号： C09J175/04 , C08G18/089 , C08G18/10 , C08G18/168 , C08G18/3206 , C08G18/4072 , C08G18/4816 , C08G18/4841 , C08G18/4858 , C08G18/632 , C08G18/7664 , C08G18/797 , C09J5/06 , C08G18/6511 , C08G18/6674
摘要： A two-part polyurethane adhesive system includes a resin component A and a curative B. The resin component A includes a monomeric polyisocyanate and a prepolymer. The curative B includes a of ether polyol having a molecular weight of from 3000 to 20,000 and another polyol having 4-8 hydroxyl groups and a molecular weight of from 200 to 1000. The system includes a tin (IV) catalyst, which is contained in the resin component, and a blocked aza-type catalyst, which is contained in the curative. The system has excellent shelf stability, gives an excellent open time at ambient temperatures, and cures rapidly when heated to 65° C. or higher.
摘要翻译：双组分聚氨酯粘合剂体系包括树脂组分A和固化剂B.树脂组分A包括单体多异氰酸酯和预聚物。固化剂B包括分子量为3000至20,000的醚多元醇和具有4-8个羟基并且分子量为200至1000的另一种多元醇。该体系包括锡（IV）催化剂，其包含在树脂组分和封闭的氮杂型催化剂。该系统具有优异的储存稳定性，在环境温度下提供优异的开放时间，并且当加热至65℃或更高时可迅速固化。

15. 发明申请

US20130216840A1 POLYURETHANE BASED INSULATED GLASS SEALANT 有权
标题翻译：基于聚氨酯的绝缘玻璃密封剂
公开(公告)号：US20130216840A1
公开(公告)日：2013-08-22
申请号：US13878380
申请日：2011-11-10
申请人： Bindushree Radhakrishnan , Laura A. Grier , Syed Z. Mahdi
发明人： Bindushree Radhakrishnan , Laura A. Grier , Syed Z. Mahdi
IPC分类号： E04B1/66 , B32B37/12
CPC分类号： E04B1/66 , B32B37/12 , C03C27/10 , C08G18/289 , C08G18/36 , C08G18/778 , C08G18/7831 , C08G18/797 , C08G2190/00 , C09J175/04 , Y10T428/31551 , Y10T428/31601
摘要： Embodiments of the invention include insulated units and methods of producing the insulating units. The insulating units include a first surface, a structural seal disposed on at least portions of the first surface, and a second surface disposed on the structural seal. The structural seal includes the reaction product of at least one first isocyanate, at least one isocyanate reactive side, and at least one adhesion promoter including a reaction product of at least one secondary aminoalkoxy silane and at least one second isocyanate.
摘要翻译：本发明的实施例包括绝缘单元和绝缘单元的制造方法。绝缘单元包括第一表面，设置在第一表面的至少部分上的结构密封件和设置在结构密封件上的第二表面。结构密封包括至少一种第一异氰酸酯，至少一种异氰酸酯反应性侧和至少一种包含至少一种仲氨基烷氧基硅烷和至少一种第二异氰酸酯的反应产物的粘合促进剂的反应产物。

16. 发明授权

US07955696B2 Composites and methods for conductive transparent substrates 有权
标题翻译：导电透明基板的复合材料和方法
公开(公告)号：US07955696B2
公开(公告)日：2011-06-07
申请号：US11959208
申请日：2007-12-18
申请人： Kiran Baikerikar , Syed Z. Mahdi , Daniel L. Dermody , Didem Oner-Deliormanh
发明人： Kiran Baikerikar , Syed Z. Mahdi , Daniel L. Dermody , Didem Oner-Deliormanh
IPC分类号： B32B5/16
CPC分类号： H01B1/22 , C08L33/08 , C08L33/10 , C08L33/14 , C08L83/04 , C08L83/10 , H05B2203/013 , H05B2203/017 , Y02P20/582 , Y10T428/256 , Y10T428/31504 , Y10T428/31547 , Y10T428/31786 , C08L2666/52 , C08L83/00
摘要： The present invention is directed to a conductive article and method of making the same that includes a substrate; a conductive composite including a conductive material in a matrix that includes one or more film forming resins having at least one functional group capable of polymerization; one or more adhesion promoters; and one or more compounds, which are reactive with the film forming resin and which also contain at least one acidic moiety.
摘要翻译：本发明涉及一种导电制品及其制造方法，其包括基底; 导电性复合体，其包含基体中的导电性材料，所述基体包含一种或多种具有至少一个能够聚合的官能团的成膜树脂; 一种或多种粘合促进剂; 和一种或多种与成膜树脂反应并且还含有至少一个酸性部分的化合物。

17. 发明申请

US20100316828A1 PROTECTIVE COATING FOR WINDOW GLASS 有权
标题翻译：窗玻璃保护涂层
公开(公告)号：US20100316828A1
公开(公告)日：2010-12-16
申请号：US12859822
申请日：2010-08-20
申请人： Kiran Baikerikar , Syed Z. Mahdi
发明人： Kiran Baikerikar , Syed Z. Mahdi
IPC分类号： E06B3/00 , B32B17/10 , B32B27/08 , B05D5/06 , C09J143/04 , C09J157/12
CPC分类号： C03C17/007 , C03C2217/475 , C03C2217/485 , C03C2218/118 , C03C2218/31 , C08K3/04 , C09D4/00 , C09D5/00 , C09D7/61 , Y10S525/925 , Y10T428/31612 , Y10T428/31645 , Y10T428/31663 , Y10T428/31855
摘要： The invention is a composition comprising: a) one or more film forming resins having at least one functional group capable of polymerization; b) one or more reactive diluents capable of reacting with the film forming resin; c) one or more silicon, titanium, zirconium, aluminum or metal containing compounds capable of promoting adhesion of the composition to glass; d) one or more fillers capable of imparting abrasion resistance to the composition when cured; and e) one or more compounds which is reactive with the film forming resin which also contains at least one acidic moiety. The composition of the invention is useful as a frit on the window of a vehicle.
摘要翻译：本发明是一种组合物，其包含：a）一种或多种具有至少一个能够聚合的官能团的成膜树脂; b）能够与成膜树脂反应的一种或多种反应性稀释剂; c）一种或多种能促进组合物粘附到玻璃上的硅，钛，锆，铝或含金属的化合物; d）当固化时能赋予组合物耐磨性的一种或多种填料; 和e）一种或多种与还含有至少一个酸性部分的成膜树脂反应的化合物。本发明的组合物可用作车辆窗口上的玻璃料。

18. 发明授权

US07736692B2 Process for applying an adhesion primer to a window 有权
标题翻译：将粘合剂引入窗户的方法
公开(公告)号：US07736692B2
公开(公告)日：2010-06-15
申请号：US10458951
申请日：2003-06-11
申请人： Dominic J. Allam , Andrew R. Kneisel , Syed Z. Mahdi
发明人： Dominic J. Allam , Andrew R. Kneisel , Syed Z. Mahdi
IPC分类号： B05D5/06
CPC分类号： C09J5/02 , C03C17/001 , C03C17/002 , C03C17/32 , C03C27/048 , C09J2400/143
摘要： A process for applying an adhesion primer to a window. The process includes the steps of directing light (11) onto the window (10) to illuminate a portion (13) of the window and then applying an adhesion primer along the illuminated portion of the window. If the adhesion primer contains a component that evaporates, then the process can further include the step of forming an infrared image (19) of the window as the component evaporates to indicate the area of application (20) of the adhesion primer. If the adhesion primer contains a component that fluoresces when illuminated by ultraviolet light, then the process can further include the step of illuminating the window with ultraviolet light (22) to indicate the area of application (23) of the adhesion primer.
摘要翻译：将粘合剂引入窗户的方法。该方法包括以下步骤：将光（11）引导到窗口（10）上以照亮窗户的一部分（13），然后沿窗户的照明部分施加粘合底漆。如果粘合底漆含有蒸发的组分，则该方法还可以包括当组分蒸发以形成粘合底漆的涂布面积（20）时，形成窗口的红外图像（19）的步骤。如果粘合底漆含有当被紫外线照射时发荧光的成分，则该方法还可以包括用紫外线（22）照亮窗口以指示粘合底漆的施用面积（23）的步骤。

19. 发明申请

US20080152926A1 COMPOSITES AND METHODS FOR CONDUCTIVE TRANSPARENT SUBSTRATES 有权
标题翻译：导电透明基材的复合材料和方法
公开(公告)号：US20080152926A1
公开(公告)日：2008-06-26
申请号：US11959208
申请日：2007-12-18
申请人： Kiran Baikerikar , Syed Z. Mahdi , Daniel L. Dermody , Didem Oner-Deliormanh
发明人： Kiran Baikerikar , Syed Z. Mahdi , Daniel L. Dermody , Didem Oner-Deliormanh
IPC分类号： B32B27/06 , B05D5/12 , B05D7/04
CPC分类号： H01B1/22 , C08L33/08 , C08L33/10 , C08L33/14 , C08L83/04 , C08L83/10 , H05B2203/013 , H05B2203/017 , Y02P20/582 , Y10T428/256 , Y10T428/31504 , Y10T428/31547 , Y10T428/31786 , C08L2666/52 , C08L83/00
摘要： The present invention is directed to a conductive article and method of making the same that includes a substrate; a conductive composite including a conductive material in a matrix that includes one or more film forming resins having at least one functional group capable of polymerization; one or more adhesion promoters; and one or more compounds, which are reactive with the film forming resin and which also contain at least one acidic moiety.
摘要翻译：本发明涉及一种导电制品及其制造方法，其包括基底; 导电性复合体，其包含基体中的导电性材料，所述基体包含一种或多种具有至少一个能够聚合的官能团的成膜树脂; 一种或多种粘合促进剂; 和一种或多种与成膜树脂反应并且还含有至少一个酸性部分的化合物。

20. 发明授权

US06613816B2 Cure on demand adhesives and window module with cure on demand adhesive thereon 有权
标题翻译：固化按需粘合剂和窗口模块，在其上固化需要的粘合剂
公开(公告)号：US06613816B2
公开(公告)日：2003-09-02
申请号：US09875986
申请日：2001-06-07
申请人： Syed Z. Mahdi , Renhe R. Lin , Dwight K. Hoffman , Gordon M. Parker , Harry W. Hsieh
发明人： Syed Z. Mahdi , Renhe R. Lin , Dwight K. Hoffman , Gordon M. Parker , Harry W. Hsieh
IPC分类号： C08G7708
CPC分类号： C09J175/08 , C08G18/10 , C08G18/12 , C08G18/24 , C08G18/246 , C08G18/4808 , C08G18/4825 , C08G18/718 , C08G65/2642 , C08G65/2651 , C08G65/336 , C08G2190/00 , C09J171/02 , Y10T428/31601 , Y10T428/31612 , Y10T428/31645 , C08G18/307 , C08G18/3893
摘要： In one embodiment the invention is An adhesive composition comprising a) a polymer having a flexible backbone and a reactive moiety capable of cross-linking, b) a particle comprising an active agent encapsulated in an encapsulating agent wherein the active agent comprises a catalyst for cross-linking of the reactive moiety, a curing agent for the reactive moiety, an accelerator for the curing reaction or a mixture thereof; and the encapsulating agent comprises a side chain crystallizable polymer wherein the active agent is not substantially extractable from the particle at ambient conditions in a first extraction after particle formation.
摘要翻译：在一个实施方案中，本发明是一种粘合剂组合物，其包含a）具有柔性主链和能够交联的反应性部分的聚合物，b）包含包封在包封剂中的活性剂的颗粒，其中活性剂包含用于交联的催化剂，反应性部分的连接，反应性部分的固化剂，用于固化反应的促进剂或其混合物;并且所述包封剂包含侧链可结晶聚合物，其中活性剂在环境条件下基本上不可从颗粒中提取颗粒形成后的第一次提取。

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