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    • 16. 发明申请
    • METHODS OF MAKING AN ANTISTATIC AGENT
    • 制造抗静电剂的方法
    • US20080269526A1
    • 2008-10-30
    • US12170097
    • 2008-07-09
    • Theodorus Lambertus HoeksChiel Albertus LeendersRobert Dirk van de Grampel
    • Theodorus Lambertus HoeksChiel Albertus LeendersRobert Dirk van de Grampel
    • C07F9/54
    • C07C303/32C07F9/5407C07C309/06C07C309/10
    • Disclosed are methods for making the phosphonium sulfonate salt of generic formula (1): wherein each X is independently a halogen or hydrogen, provided that the molar ratio of halogen to hydrogen is greater than about 0.90; p is 0 or 1 and q and r are integers of 0 to about 7 provided that q+r is less than 8 and that if p is 1 then r is greater than zero; and each R is the same or different hydrocarbon radical containing 1 to about 18 carbon atoms, the method comprising the steps of combining in an aqueous medium, a compound of the generic formula (2): wherein M is K, and X, q, p, and r are as defined above, with a compound of the generic formula (3): (R)4P-Z   (3) wherein Z is a halogen and R is as defined above; and separating the phosphonium sulfonate of formula (1) from the aqueous medium. Also disclosed is an antistatic composition comprising phosphonium sulfonate (1), and articles prepared therefrom.
    • 公开了制备通式(1)的鏻磺酸盐的方法:其中每个X独立地是卤素或氢,条件是卤素与氢的摩尔比大于约0.90; p为0或1,q和r为0至约7的整数,条件是q + r小于8,如果p为1,则r大于零; 并且每个R是含有1至约18个碳原子的相同或不同的烃基,该方法包括以下步骤:在水性介质中混合通式(2)的化合物:其中M是K,X,q, p和r如上所定义,与通式(3)的化合物:<?in-line-formula description =“In-line Formulas”end =“lead”?(R) PZ(3)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中Z是卤素,R如上所定义; 并将式(1)的磺酸鏻与水性介质分离。 还公开了包含磺酸鏻(1)和由其制备的制品的抗静电组合物。