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11. 发明申请

WO2009016153A3 PHOSPHORUS MODIFIED MOLECULAR SIEVES, THEIR USE IN CONVERSION OF ORGANICS TO OLEFINS 审中-公开
标题翻译：磷酸改性分子筛，它们在有机物转化成烯烃中的用途
公开(公告)号：WO2009016153A3
公开(公告)日：2010-04-29
申请号：PCT/EP2008059883
申请日：2008-07-28
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , MINOUX DELPHINE , VAN DONK SANDER
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , MINOUX DELPHINE , VAN DONK SANDER
IPC分类号： B01J29/85 , C01B39/02 , C07C1/20 , C07C2/08 , C07C11/02
CPC分类号： C07C1/322 , B01J29/40 , B01J29/85 , B01J2229/36 , B01J2229/37 , C01B39/026 , C07C1/20 , C07C1/22 , C07C1/26 , C07C2/06 , C07C4/06 , C07C7/04 , C07C2529/85 , C10G3/00 , C10G2300/202 , C10G2300/4081 , C10G2400/20 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C11/06
摘要： The present invention is a phosphorous modified zeolite (A) made by a process comprising in that order: selecting a zeolite with low Si/AI ratio (advantageously lower than 30) among H+ or NH4 +-form of MFI, MEL, FER, MOR, clinoptilolite, said zeolite having been made preferably without direct addition of organic template; steaming at a temperature ranging from 400 to 870°C for 0.01-200h; leaching with an aqueous acid solution containing the source of P at conditions effective to remove a substantial part of Al from the zeolite and to introduce at least 0.3 wt% of P; separation of the solid from the liquid; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step. The present invention also relates to a process (hereunder referred as 'XTO process') for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted with the above catalyst (in the XTO reactor) under conditions effective to convert at least a portion of the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to olefin products (the XTO reactor effluent). The present invention also relates to a process (hereunder referred as 'combined XTO and OCP process') to make light olefins from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the above catalyst at conditions effective to convert at least a portion of the feedstock to form an XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in the OCP reactor at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译：本发明是通过以下方法制备的磷改性沸石（A）：在MFI，MEL，FER，MOR的H +或NH4 +形式中选择具有低Si / Al比（有利地低于30）的沸石，斜发沸石，所述沸石优选不直接添加有机模板; 在400〜870℃的温度范围内蒸煮0.01〜200h; 在有效从沸石中除去大部分Al并引入至少0.3wt％P的条件下，用含有P源的酸性水溶液浸出; 从液体中分离固体; 任选的洗涤步骤或任选的干燥步骤或任选的干燥步骤，随后进行洗涤步骤; 煅烧步骤。本发明还涉及从含氧，含卤素或含硫有机原料制备烯烃产物的方法（以下称为“XTO法”），其中所述含氧卤化物或含硫的在有效将至少一部分含氧，含卤素或含硫有机原料转化为烯烃产物（XTO反应器流出物）的条件下，有机原料与上述催化剂（在XTO反应器中）接触。本发明还涉及从含氧的含卤化物或含硫有机原料制备轻质烯烃的方法（以下称为“组合的XTO和OCP方法”），包括：使含有氧的含卤素的或含硫有机原料在具有上述催化剂的XTO反应器中，在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃馏分的XTO反应器流出物的条件下; 将所述轻质烯烃与所述重质烃馏分分离; 在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下使OCP反应器中的所述重质烃馏分接触。

12. 发明申请

WO2009156433A3 PROCESS TO MAKE OLEFINS FROM OXYGENATES 审中-公开
标题翻译：从氧化剂制备油脂的方法
公开(公告)号：WO2009156433A3
公开(公告)日：2010-02-18
申请号：PCT/EP2009057887
申请日：2009-06-24
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
IPC分类号： C07C1/20 , B01J29/40 , B01J37/28
CPC分类号： C07C1/22 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J37/10 , B01J38/12 , B01J2229/16 , B01J2229/186 , B01J2229/36 , C07C1/20 , C07C1/26 , C07C1/322 , C07C4/06 , C07C2529/40 , C10G3/44 , C10G3/49 , C10G3/62 , C10G9/00 , C10G55/04 , C10G2400/20 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a) providing a catalyst comprising zeolitic molecular sieves containing 10 member and larger channels in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting said oxygen-containing, halogenide-containing or sulphur- containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译：本发明涉及一种在组合的XTO-OC方法中由含氧的含卤素或含硫有机原料制备轻质烯烃的方法，包括：a）提供包含含有10个成员的沸石分子筛和在其微孔结构中较大的通道，b）提供XTO反应区，OC反应区和催化剂再生区，所述催化剂在三个区中循环，使得至少一部分再生催化剂通过OC反应区，将OC反应区中的至少一部分催化剂通入XTO反应区，并将XTO反应区中的至少一部分催化剂通入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃部分的XTO反应器流出物的条件下，将XTO反应器中的含氧，含卤素或含硫有机原料与催化剂接触 ; d）从所述重质烃馏分中分离出所述轻质烯烃; e）使OC反应器中的所述重质烃馏分与催化剂在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下接触。

13. 发明申请

WO2009156433A2 PROCESS TO MAKE OLEFINS FROM ORGANICS 审中-公开
标题翻译：从有机物制备烯烃的方法
公开(公告)号：WO2009156433A2
公开(公告)日：2009-12-30
申请号：PCT/EP2009/057887
申请日：2009-06-24
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , NESTERENKO, Nikolai , VERMEIREN, Walter , GRASSO, Giacomo , VAN DONK, Sander , GARCIA, Wolfgang
发明人： NESTERENKO, Nikolai , VERMEIREN, Walter , GRASSO, Giacomo , VAN DONK, Sander , GARCIA, Wolfgang
IPC分类号： C07C1/20 , C07C4/06 , B01J37/28 , B01J29/40
CPC分类号： C07C1/22 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J37/10 , B01J38/12 , B01J2229/16 , B01J2229/186 , B01J2229/36 , C07C1/20 , C07C1/26 , C07C1/322 , C07C4/06 , C07C2529/40 , C10G3/44 , C10G3/49 , C10G3/62 , C10G9/00 , C10G55/04 , C10G2400/20 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a) providing a catalyst comprising zeolitic molecular sieves containing 10 member and larger channels in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting said oxygen-containing, halogenide-containing or sulphur- containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译：本发明涉及一种在组合的XTO-OC方法中由含氧的含卤化物或含硫有机原料制备轻质烯烃的方法，包括：a）提供包含含有10个成员的沸石分子筛和在其微孔结构中较大的通道，b）提供XTO反应区，OC反应区和催化剂再生区，所述催化剂在三个区中循环，使得至少一部分再生催化剂通过OC反应区，将OC反应区中的至少一部分催化剂通入XTO反应区，并将XTO反应区中的至少一部分催化剂通入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃部分的XTO反应器流出物的条件下，将XTO反应器中的含氧，含卤素或含硫有机原料与催化剂接触 ; d）从所述重质烃馏分中分离出所述轻质烯烃; e）使OC反应器中的所述重质烃馏分与催化剂在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下接触。

14. 发明申请

WO2009098269A1 PROCESS TO MAKE OLEFINS FROM ETHANOL 审中-公开
标题翻译：从乙醇制备油脂的方法
公开(公告)号：WO2009098269A1
公开(公告)日：2009-08-13
申请号：PCT/EP2009/051342
申请日：2009-02-05
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , MINOUX, Delphine , NESTERENKO, Nikolai , VERMEIREN, Walter , VAN DONK, Sander , GRASSO, Giacomo
发明人： MINOUX, Delphine , NESTERENKO, Nikolai , VERMEIREN, Walter , VAN DONK, Sander , GRASSO, Giacomo
IPC分类号： C07C11/06 , C07C11/04 , C07C1/24 , C07C4/06
CPC分类号： C07C11/04 , C07C1/24 , C07C4/06 , C07C11/06
摘要： The present invention relates to a process for the conversion of ethanol to make essentially ethylene and propylene, comprising : a) introducing in a reactor (A) (also called the first low temperature reaction zone) a stream comprising ethanol, optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1) in said reactor (A) at conditions effective to dehydrate at least a portion of the ethanol to essentially ethylene, c) recovering from said reactor an effluent comprising : essentially ethylene, minor amounts of various hydrocarbons, water, optionally unconverted ethanol and the optional inert component of step a), d) fractionating said effluent of step c) to remove water, unconverted ethanol, optionally the inert component, and optionally the whole or a part of the various hydrocarbons to get a stream (D) comprising essentially ethylene and optionally the inert component, e) introducing at least a part of said stream (D) mixed with a stream (D1 ) comprising olefins having 4 carbon atoms or more (C4+ olefins) in a OCP reactor (also called the second high temperature reaction zone) under the condition that the mixture (D)+(D1) comprises at least 10wt% of C4+ olefins, f) contacting said stream comprising at least a part of (D) and the stream (D1 ) in said OCP reactor with a catalyst which is selective towards light olefins in the effluent, to produce an effluent with an olefin content of lower molecular weight than that of the feedstock, g) fractionating said effluent of step f) to produce at least an ethylene stream, a propylene stream and a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, optionally recycling ethylene in whole or in part at the inlet of the OCP reactor of step f), or at the inlet of the reactor (A) or in part at the inlet of the OCP reactor of step f) and in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the OCP reactor.
摘要翻译：本发明涉及一种将乙醇转化成基本上乙烯和丙烯的方法，其包括：a）在反应器（A）（也称为第一低温反应区）中引入包含乙醇，任选的水，任选地，惰性组分，b）在有效将至少一部分乙醇脱水至基本上乙烯的条件下，使所述料流与所述反应器（A）中的催化剂（A1）接触; c）从所述反应器回收包含：基本上乙烯，次要的流出物各种烃，水，任选未转化的乙醇和步骤a）的任选的惰性组分的量，d）将步骤c）的所述流出物分馏以除去水，未转化的乙醇，任选的惰性组分，以及任选的全部或部分各种烃以得到基本上包含乙烯和任选的惰性组分的物流（D），e）将至少一部分与流（D1）com混合的所述物流（D）在混合物（D）+（D1）包含至少10重量％的C 4 +烯烃的条件下，在OCP反应器（也称为第二高温反应区）中具有4个碳原子或更多个（C 4 +烯烃）使所述OCP反应器中包含至少一部分（D）和物流（D1）的物流与流出物中的轻质烯烃选择性的催化剂接触，以产生具有低于原料，g）对步骤f）的所述流出物进行分馏以产生至少一种乙烯流，丙烯料流和基本上由具有4个碳原子或更多碳原子的烃组成的馏分，任选地在乙烯流入口处全部或部分回收乙烯 OCP反应器，或在反应器（A）的入口或部分在步骤f）的OCP反应器的入口处，部分地在反应器（A）的入口处，可任选地再循环基本上组分的馏分的碳氢化合物 OCP或更多在OCP反应器的入口处。

15. 发明申请

WO2009098267A1 PROCESS TO MAKE OLEFINS FROM ETHANOL 审中-公开
标题翻译：从乙醇制备油脂的方法
公开(公告)号：WO2009098267A1
公开(公告)日：2009-08-13
申请号：PCT/EP2009/051340
申请日：2009-02-05
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , MINOUX, Delphine , NESTERENKO, Nikolai , VERMEIREN, Walter , VAN DONK, Sander , GRASSO, Giacomo
发明人： MINOUX, Delphine , NESTERENKO, Nikolai , VERMEIREN, Walter , VAN DONK, Sander , GRASSO, Giacomo
IPC分类号： C07C1/24 , C07C11/02
CPC分类号： C10G11/05 , C07C1/20 , C07C1/24 , C07C4/06 , C07C11/06 , C07C2529/035 , C07C2529/70 , C07C2529/85 , Y02P30/42 , C07C11/04
摘要： The present invention relates to a process for the conversion of ethanol to make essentially ethylene and propylene, comprising : a) introducing in a reactor (A) (also called the first low temperature reaction zone) a stream comprising ethanol under a partial pressure at least about 0.2 MPa, optionally water, optionally an inert component; b) contacting said stream with a catalyst (A1) in said reactor (A) at conditions effective to convert at least a portion of the ethanol to essentially ethylene, propylene and olefins having 4 carbon atoms or more (C4+ olefins); c) recovering from said reactor an effluent comprising : ethylene and C4+ fraction containng mainly olefins having 4 carbon atoms or more (C4+ olefins), propylene and various hydrocarbons, water, optionally unconverted ethanol and the optional inert component of step a); d) fractionating said effluent of step c) to remove water, unconverted ethanol, optionally the inert component, optionally the propylene and optionally the whole or a part of the various hydrocarbons to get a stream (D) comprising essentially ethylene, olefins having 4 carbon atoms or more (C4+ olefins) and optionally the inert component; e) introducing at least a part of said stream (D) optionally mixed with a stream (D1) comprising olefins having 4 carbon atoms or more (C4+ olefins) in a OCP reactor (also called the second high temperature reaction zone) under the condition that said mixture (D)+(D1) comprises at least 10wt% of C4+ olefins; f) contacting said stream comprising at least a part of (D) and the optional (D1) in said OCP reactor with a catalyst which is selective towards light olefins in the effluent, to produce an effluent with an olefin content of lower molecular weight than that of the feedstock; g) fractionating said effluent of step f) to produce at least an ethylene stream, a propylene stream and a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, optionally recycling ethylene in whole or in part at the inlet of the OCP reactor of step f), or at the inlet of the reactor (A) or in part at the inlet of the OCP reactor of step f) and in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the OCP reactor.
摘要翻译：本发明涉及一种将乙醇转化成基本上乙烯和丙烯的方法，包括：a）至少在部分压力下将反应器（A）（也称为第一低温反应区）引入包含乙醇的料流约0.2MPa，任选的水，任选的惰性组分; b）在有效将至少一部分乙醇转化成基本上为具有4个碳原子或更多个（C 4 +烯烃）的乙烯，丙烯和烯烃的条件下，使所述料流与所述反应器（A）中的催化剂（A1）接触; c）从所述反应器回收流出物，其包含：乙烯和C4 +馏分主要含有具有4个碳原子或更多个（C 4 +烯烃）的烯烃，丙烯和各种烃，水，任选未转化的乙醇和步骤a）的任选的惰性组分; d）将步骤c）的所述流出物分馏以除去水，未转化的乙醇，任选的惰性组分，任选的丙烯和任选的各种烃的全部或部分，以获得基本上包含乙烯，含有4个碳的烯烃原子或更多（C4 +烯烃）和任选的惰性组分; e）在OCP反应器（也称为第二高温反应区）中将至少一部分所述物流（D）任选与包含具有4个碳原子或更多个（C 4 +烯烃）的烯烃的物流（D1）所述混合物（D）+（D1）包含至少10重量％的C 4 +烯烃; f）使所述OCP反应器中包含至少一部分（D）和任选的（D1）的物流与在流出物中对轻质烯烃有选择性的催化剂接触，以产生具有低于原料的; g）将步骤f）的所述流出物分馏以产生至少一种乙烯流，丙烯料流和基本上由具有4个碳原子或更多碳原子的烃组成的馏分，任选地将乙烯全部或部分在OCP反应器的入口步骤f），或在反应器（A）的入口处或部分在步骤f）的OCP反应器的入口处，部分地在反应器（A）的入口处，可任选地再循环基本上由以下物质组成的馏分：具有在OCP反应器的入口处具有4个或更多个碳原子。

16. 发明申请

WO2009092781A2 PROCESS FOR OBTAINING MODIFIED MOLECULAR SIEVES 审中-公开
标题翻译：获得修饰分子筛的方法
公开(公告)号：WO2009092781A2
公开(公告)日：2009-07-30
申请号：PCT/EP2009050758
申请日：2009-01-23
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , VAN DONK SANDER , MINOUX DELPHINE
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , VAN DONK SANDER , MINOUX DELPHINE
IPC分类号： B01J27/16 , B01J29/06 , B01J29/40 , C07C1/20 , C07C4/06
CPC分类号： C07C1/20 , B01J27/16 , B01J29/06 , B01J29/061 , B01J29/40 , B01J29/405 , B01J37/0201 , B01J37/0207 , B01J37/024 , B01J37/28 , B01J2229/16 , B01J2229/186 , B01J2229/36 , B01J2229/37 , C07C4/06 , C07C2523/02 , C07C2527/14 , C07C2529/06 , C07C2529/40 , C07C2529/82 , C07C2529/85 , C08F110/02 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： The invention covers a process for obtaining an alkaline earth or rare earth metal-P-modified molecular sieve (M-P-modified molecular sieve) comprising the following steps: a), selecting at least one molecular sieve selected from one of: - a P-modified molecular sieve which contains at least 0.3 wt% of P obtained by dealuminating a molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P - a molecular sieve which is modified with P during step b) by dealuminating the molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P thereby introducing at least 0.3 wt % of P b). contacting said molecular sieve with an alkaline earth or rare earth metal-containing compound (M-containing compound) to introduce at least 0.05 wt% of the alkaline earth or rare earth metal to the molecular sieve. The invention also covers a catalyst composite comprising: a), at least 10 wt % of a M-P-modified molecular sieve comprising at least 0.05 % by weight of an alkaline earth or rare earth metal (M) and at least 0.3 wt% of P, b). optionally metal phosphate, c). optionally matrix material, and d). optionally binder. The catalyst of the invention can also be used in a process for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted in the XTO reactor with the catalyst composite according to the invention under conditions effective to convert the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to olefin products (the XTO reactor effluent). The catalyst composite of the invention can also be used in addition or alternatively in an OCP process.
摘要翻译：本发明包括获得碱土或稀土金属-P-改性分子筛（MP-改性分子筛）的方法，其包括以下步骤：a）选择至少一种选自以下物质之一的分子筛：-P- 其包含至少0.3重量％的通过在汽蒸步骤中将分子筛脱铝而获得的P，然后使用含有P的分子筛的酸溶液进行浸提步骤，所述分子筛在步骤b）期间用P改性，通过在汽蒸步骤中使分子筛脱铝，接着使用含有P源的酸溶液进行浸出步骤，由此引入至少0.3重量％的P b）。使所述分子筛与含碱土金属或稀土金属的化合物（含M化合物）接触以将至少0.05重量％的碱土金属或稀土金属引入分子筛中。本发明还包括催化剂复合物，其包含：a）至少10wt％的包含至少0.05重量％的碱土金属或稀土金属（M）和至少0.3重量％的P ，b）。任选地金属磷酸盐，c）。任选的基质材料，和d）。可选的粘合剂本发明的催化剂也可用于由含氧，含卤化物或含硫有机原料制备烯烃产物的方法，其中所述含氧，含卤化物或含硫有机原料与具有根据本发明的催化剂复合物的XTO反应器在有效将含氧，含卤化物或含硫有机原料转化成烯烃产物（XTO反应器流出物）的条件下进行。本发明的催化剂复合材料还可以另外或可选地用于OCP工艺中。

17. 发明申请

WO2009016155A2 USE OF PHOSPHORUS MODIFIED MOLECULAR SIEVES IN CONVERSION OF ORGANICS TO OLEFINS 审中-公开
标题翻译：磷酸改性分子筛在有机物转化成烯烃中的应用
公开(公告)号：WO2009016155A2
公开(公告)日：2009-02-05
申请号：PCT/EP2008/059885
申请日：2008-07-28
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , NESTERENKO, Nikolai , VERMEIREN, Walter , MINOUX, Delphine , VAN DONK, Sander
发明人： NESTERENKO, Nikolai , VERMEIREN, Walter , MINOUX, Delphine , VAN DONK, Sander
IPC分类号： C07C1/20 , C07C11/02 , B01J29/00 , B01J29/85 , C01B39/02 , C07C2/08
CPC分类号： C07C1/20 , B01J29/40 , B01J37/28 , B01J2229/18 , B01J2229/37 , C07C1/322 , C07C4/06 , C07C2529/85 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OCP process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with a catalyst made of a P-modified zeolite (A) at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in the OCP reactor with a catalyst made of a P-modified zeolite (A) at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins; wherein said P-modified zeolite (A) is made by a process comprising in that order: selecting a zeolite (advantageously with Si/AI ratio between 4 and 500) among H + or NH 4 + -form of MFI, MEL, FER, MOR, clinoptilolite; introducing P at conditions effective to introduce advantageously at least 0.05 wt% of P; separation of the solid from the liquid if any; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step.
摘要翻译：本发明涉及一种在组合的XTO-OCP方法中由含氧，含卤素或含硫有机原料制备轻质烯烃的方法，包括：将含氧的含卤素或含硫的在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃馏分的XTO反应器流出物的条件下，在XTO反应器中的有机原料具有由P改性沸石（A）制成的催化剂; 将所述轻质烯烃与所述重质烃馏分分离; 在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下，使所述OCP反应器中的所述重质烃馏分与由P-改性沸石（A）制成的催化剂接触; 其中所述P型改性沸石（A）通过以下方法制备：在MFI，MEL，FER，MOR，HNO 3的H +或NH 4 +形式中选择沸石（有利地具有4至500的Si / Al比）斜发沸石; 在有效引入至少0.05重量％的P的条件下引入P; 从液体中分离出固体物质; 任选的洗涤步骤或任选的干燥步骤或任选的干燥步骤，随后进行洗涤步骤; 煅烧步骤。

18. 发明申请

WO2008110530A1 MTO PROCESS BASED ON MEAPO MOLECULAR SIEVES COMBINED WITH AN OCP PROCESS TO MAKE OLEFINS 审中-公开
标题翻译：基于与OCP方法组合的MEAPO分子筛的MTO方法制备OLEFINS
公开(公告)号：WO2008110530A1
公开(公告)日：2008-09-18
申请号：PCT/EP2008/052816
申请日：2008-03-10
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , VERMEIREN, Walter , NESTERENKO, Nikolai
发明人： VERMEIREN, Walter , NESTERENKO, Nikolai
IPC分类号： C07C1/20 , C07C4/06 , C07C11/04 , C07C11/06 , C08F10/02 , C08F10/06
CPC分类号： C07C11/04 , C01B3/44 , C07C1/20 , C07C1/26 , C07C4/06 , C07C11/06 , C07C17/10 , C07C2529/035 , C07C2529/40 , C07C2529/85 , C10G3/45 , C10G3/49 , C10G2300/202 , C10G2300/4081 , C10G2300/802 , C10G2400/20 , Y02P20/52 , Y02P30/42 , C07C9/00 , C07C19/075
摘要： The present invention relates to a process to make light olefins from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in a primary reactor with a catalyst made of a metalloaluminophosphate (MeAPO) molecular sieve with lamellar crystal morphology at conditions effective to convert at least a portion of the feedstock to form a first reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in a second reactor at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins; wherein said MeAPO has an empirical chemical composition on an anhydrous basis, after synthesis and calcination, expressed by the formula H x Me y Al z P k O 2 in which, y+z+k=1 x = 10 and advantageously ranges from 10 to 100.
摘要翻译：本发明涉及从含氧，含卤素或含硫有机原料制备轻质烯烃的方法，包括：将初级反应器中的含氧，含卤化物或含硫有机原料与催化剂接触在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃部分的第一反应器流出物的条件下，由具有层状晶体形态的金属铝磷酸盐（MeAPO）分子筛制成; 将所述轻质烯烃与所述重质烃馏分分离; 在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下使所述重质烃馏分在第二反应器中接触; 其中所述MeAPO具有在无水基础上的经验化学组成，在合成和煅烧之后，由下式表示：其中R 1，R 2，R 3，其中，y + z + k = 1 x <= yy具有范围从0.0008至0.4，有利地为0.005至0.18 z的值具有范围 0.25至0.67和有利地从0.38至0.55k的值具有0.2至0.67的值，有利地为0.36至0.54，所述分子筛主要具有平板晶体形态，其中宽度（W）和厚度（T）：W / T> 10，有利地在10-100范围内。

19. 发明申请

WO2013017498A1 CATALYST COMPRISING A PHOSPHORUS MODIFIED ZEOLITE AND HAVING PARTLY AN ALPO STRUCTURE 审中-公开
标题翻译：包含磷改性沸石的催化剂，具有ALPO结构
公开(公告)号：WO2013017498A1
公开(公告)日：2013-02-07
申请号：PCT/EP2012/064581
申请日：2012-07-25
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY , NESTERENKO, Nikolai , MINOUX, Delphine , ADAM, Cindy , DATH, Jean-Pierre
发明人： NESTERENKO, Nikolai , MINOUX, Delphine , ADAM, Cindy , DATH, Jean-Pierre
IPC分类号： B01J29/40 , B01J29/85 , B01J37/10 , B01J37/28 , C07C1/20
CPC分类号： C07C2/66 , B01J29/40 , B01J29/405 , B01J29/7049 , B01J29/85 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J37/0009 , B01J37/10 , B01J37/28 , B01J2229/16 , B01J2229/183 , B01J2229/186 , B01J2229/36 , B01J2229/37 , B01J2229/40 , B01J2229/42 , C07C1/24 , C07C2/864 , C07C4/06 , C07C2529/40 , C07C2529/70 , C07C2529/80 , C07C2529/83 , C07C2529/85 , Y02P20/52 , Y02P30/42 , C07C11/04
摘要： The present invention relates to a catalyst comprising a phosphorus modified zeolite, said phosphorus modified zeolite having partly an ALPOstructure, wherein, the catalyst comprises a P-modified zeolite and a binder, the zeolite comprises at least one ten members ring in the structure, optionally the catalyst comprises one or more metal oxides, the ALPO structure is determined by a signal between 35-45 ppm in 27 Al MAS NMR spectrum. The present invention also relates to the use of the above catalyst wherein said catalyst is operated in presence of steam at high temperature. "high temperature" means above 300°C and up to 800°C. By way of example one can cite, the alcohol dehydration to convert at least an alcohol into the corresponding olefin, the olefin cracking to make lighter olefins, the MTO and the alkylation of aromatic compounds with olefins and/or alcohols to produce, by way of example, paraxylene, ethylbenzene, cumene etc.
摘要翻译：本发明涉及包含磷改性沸石的催化剂，所述磷改性沸石部分具有ALPO结构，其中催化剂包含P-改性沸石和粘合剂，所述沸石包含至少一个结构中的十元环，任选地催化剂包含一种或多种金属氧化物，ALPO结构由27 Al MAS NMR光谱中的35-45ppm之间的信号确定。本发明还涉及上述催化剂的用途，其中所述催化剂在高温蒸汽存在下操作。 “高温”是指高于300℃和高达800℃。举例来说，可以列举醇脱水以将至少一种醇转化为相应的烯烃，烯烃裂解以制备较轻烯烃，MTO和芳族化合物与烯烃和/或醇的烷基化反应以通过例如对二甲苯，乙苯，枯烯等

20. 发明申请

WO2013017497A1 METHOD FOR MAKING A CATALYST COMPRISING A PHOSPHORUS MODIFIED ZEOLITE AND USE OF SAID ZEOLITE 审中-公开
标题翻译：制备包含磷改性沸石的催化剂的方法和使用ZEOLITE
公开(公告)号：WO2013017497A1
公开(公告)日：2013-02-07
申请号：PCT/EP2012/064580
申请日：2012-07-25
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY , NESTERENKO, Nikolai , MINOUX, Delphine , ADAM, Cindy , DATH, Jean-Pierre
发明人： NESTERENKO, Nikolai , MINOUX, Delphine , ADAM, Cindy , DATH, Jean-Pierre
IPC分类号： B01J29/40 , B01J29/85 , B01J37/10 , B01J37/28 , C07C1/20
CPC分类号： B01J29/85 , B01J29/40 , B01J29/65 , B01J29/7023 , B01J29/7026 , B01J29/7038 , B01J29/7042 , B01J29/7046 , B01J37/0009 , B01J37/10 , B01J37/28 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C1/24 , C07C2/08 , C07C2/66 , C07C2/864 , C07C4/06 , C07C2521/08 , C07C2527/14 , C07C2529/40 , C07C2529/65 , C10G3/49 , C10G29/205 , C10G29/22 , Y02P20/52 , Y02P30/42 , C07C11/04 , C07C11/06 , C07C11/08 , C07C15/46 , C07C15/08
摘要： The present invention relates, in a first embodiment, to a method to make a phosphorus modified zeolite comprising the following steps in this order, a) providing a zeolite comprising at least one ten members ring in the structure, optionally steaming said zeolite, b) mixing said zeolite of step a) with at least a component selected among one or more binders and shaping additives, then shaping said mixture, c) optionally making a ion-exchange, d) optionally steaming the shaped catalyst, optionally before step c), at least among said steaming of step d) and the steaming of step a) one is mandatory, e) introducing phosphorus on the catalyst to introduce at least 0.1 wt% of phosphorus, said introduction being made by dry impregnation or chemical vapor deposition, f) introducing a metal, optionally simultaneously with step e), g) optionally washing the catalyst, h) optionally calcinating the catalyst, i) steaming the catalyst, also referred to as the equilibration step. In a second embodiment phosphorus can be introduced by any means and at step i) the steaming severity (X) is at least about 2. In said second embodiment the catalyst is advantageously steamed at a temperature above 625°C, preferably in the range 700 to 800°C. The metal of step f) is advantageously Calcium. The present invention also relates to the use said catalyst in the alcohol dehydration, the olefin cracking to make lighter olefins, the MTO and the alkylation of aromatics by alcohols with olefins and/or alcohols.
摘要翻译：在第一个实施方案中，本发明涉及一种制备磷改性沸石的方法，该方法包括以下步骤：a）提供在该结构中包含至少一个十元环的沸石，任选地蒸煮所述沸石，b）将步骤a）的所述沸石与至少一种选自一种或多种粘合剂和成型添加剂的组分混合，然后将所述混合物成形，c）任选地进行离子交换，d）任选地在步骤c）之前蒸汽成型催化剂，至少在步骤d）的蒸汽和步骤a）的蒸汽中，一个是强制性的，e）在催化剂上引入磷以引入至少0.1重量％的磷，所述引入通过干浸渍或化学气相沉积，f ）任选地与步骤e）同时引入金属，g）任选地洗涤催化剂，h）任选地煅烧催化剂，i）蒸煮催化剂，也称为平衡步骤。在第二个实施方案中，磷可以通过任何方式引入，并且步骤i）蒸汽的苛刻度（X）至少约为2.在所述第二实施方案中，有利地，催化剂在高于625℃，优选在700℃ 至800°C。步骤f）的金属有利地是钙。本发明还涉及在醇脱水中使用所述催化剂，烯烃裂解以制备较轻烯烃，通过醇与烯烃和/或醇烷基化MTO和芳族化合物的烷基化。

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