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    • 11. 发明申请
    • Silicone Composition for Sealing Light Emitting Element, and Light Emitting Device
    • 用于密封发光元件的硅酮组合物和发光装置
    • US20080160322A1
    • 2008-07-03
    • US11795603
    • 2005-07-22
    • Kikuo MochizukiNobuo Hirai
    • Kikuo MochizukiNobuo Hirai
    • C08L83/07B32B27/00
    • H01L23/296C08G77/12C08G77/20C08L83/04H01L33/56H01L2224/45144H01L2224/48091H01L2224/48247H01L2924/1301Y10T428/31663C08L83/00H01L2924/00014H01L2924/00
    • A silicone composition for sealing a light emitting element includes: (A) a vinyl group-containing organopolysiloxane having a three-dimensional network structure represented by an average unit formula: (SiO4/2)a(ViR2SiO1/2)b(R3SiO1/2)c (where Vi represents a vinyl group, R's are identical or different substituted or unsubstituted monovalent hydrocarbon groups other than alkenyl groups, and a, b, and c are positive numbers satisfying that a/(a+b+c) is 0.2 to 0.6 and b/(a+b+c) is 0.001 to 0.2); (B) an organohydrogenpolysiloxane which has at least two hydrogen atoms, each hydrogen atom being bonded to a silicon atom per molecule, the organohydrogenpolysiloxane being contained in such an amount that an amount of a hydrogen atom bonded to a silicon atom is 0.3 to 3.0 mol per 1 mol of a vinyl group bonded to a silicon atom in the component (A); and (C) a hydrosilylation catalyst (catalytic amount), wherein a coefficient of linear expansion of the composition after curing is 10×10−6 to 290×10−6/° C. It is possible to obtain a cured product whose residual stress with a support substrate is reduced and which has long-term satisfactory and stable adhesiveness.
    • 用于密封发光元件的硅氧烷组合物包括:(A)具有由平均单元式表示的三维网状结构的含乙烯基的有机聚硅氧烷:(SiO 2/2/2) (R 3 SiO 2)2(R 3 SiO 2)2(R 3 SiO 2) (其中Vi表示乙烯基,R是与烯基不同的取代或未取代的一价烃基,并且a,b和c是满足的正数)的正数。 a /(a + b + c)为0.2〜0.6,b /(a + b + c)为0.001〜0.2)。 (B)具有至少两个氢原子的有机氢聚硅氧烷,每个分子中的每个氢原子与硅原子键合,所述有机氢聚硅氧烷的含量相当于与硅原子键合的氢原子的量为0.3〜3.0摩尔 每1mol与组分(A)中的硅原子键合的乙烯基; 和(C)氢化硅烷化催化剂(催化量),其中固化后组合物的线性膨胀系数为10×10 -6〜290×10 -6 -6℃。 可以获得与支撑基板的残留应力减小并且具有长期令人满意且稳定的粘合性的固化物。