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11. 发明申请

US20050096215A1 Process for producing synthesis gas using stabilized composite catalyst 审中-公开
标题翻译：使用稳定复合催化剂生产合成气的方法
公开(公告)号：US20050096215A1
公开(公告)日：2005-05-05
申请号：US10699018
申请日：2003-10-31
申请人： Rafael Espinoza , Harold Wright , Tianyan Niu , Kandaswamy Jothimurugesan
发明人： Rafael Espinoza , Harold Wright , Tianyan Niu , Kandaswamy Jothimurugesan
IPC分类号： B01J23/10 , B01J23/46 , B01J23/63 , B01J35/00 , C01B3/38 , C01B3/40 , B01J21/18 , B01J21/08 , B01J21/12 , C01B3/32
CPC分类号： C01B3/40 , B01J23/10 , B01J23/464 , B01J23/63 , B01J35/0006 , C01B3/386 , C01B2203/0261 , C01B2203/1041 , C01B2203/1047 , C01B2203/1082 , C01B2203/1094 , C01B2203/1241 , Y02P20/52
摘要： A catalytic partial oxidation process for producing synthesis gas is disclosed which comprises passing a light hydrocarbon and oxygen mixture over a composite catalyst to produce a mixture of carbon monoxide and hydrogen. Preferred composite catalysts are prepared by mixing together discrete particles of catalytic metal and of promoter. The resulting catalyst resists deactivation due to reaction between the active metal and the promoter. A catalyst and method for making a catalyst and a method for making middle distillates from light hydrocarbons are also disclosed.
摘要翻译：公开了用于生产合成气的催化部分氧化方法，其包括使轻烃和氧混合物在复合催化剂上通过以产生一氧化碳和氢气的混合物。优选的复合催化剂通过将催化金属和促进剂的离散颗粒混合在一起来制备。所得催化剂由于活性金属和助催化剂之间的反应而抵抗失活。还公开了催化剂和制备催化剂的方法以及从轻质烃制备中间馏分的方法。

12. 发明授权

US06564157B2 On-line device for predicting at least one fluid flow parameter in a process 有权
标题翻译：用于在过程中预测至少一个流体流参数的在线设备
公开(公告)号：US06564157B2
公开(公告)日：2003-05-13
申请号：US09729921
申请日：2000-12-06
申请人： David A. Olson , Yuri Lawryshyn , Harold Wright
发明人： David A. Olson , Yuri Lawryshyn , Harold Wright
IPC分类号： G01F100
CPC分类号： C02F1/325 , C02F1/008 , C02F1/32 , C02F2201/326 , G01F1/00
摘要： An on-line device for predicting at least one fluid flow parameter in a process includes structure and/or function whereby a flow domain has disposed therein a pre-determined portion in which a fluid flows. Preferably, the device includes a computer having: (i) a memory for receiving a database, the database including relative information in respect of a plurality of nodes or a plurality of particle pathways in the pre-determined portion; (ii) structure to receive input data from the process, and (iii) structure to calculate the at least one fluid flow parameter from the database and the input data. The device is particularly advantageously employed as a UV dosimeter.
摘要翻译：用于在过程中预测至少一个流体流动参数的在线装置包括结构和/或功能，其中流动域在其中设置流体流动的预定部分。优选地，该设备包括具有以下功能的计算机：（i）用于接收数据库的存储器，所述数据库包括关于预定部分中的多个节点或多个粒子路径的相关信息; （ii）从过程接收输入数据的结构，以及（iii）从数据库和输入数据计算至少一个流体流量参数的结构。该装置特别有利地用作UV剂量计。

13. 发明申请

US20050265920A1 Supports and catalysts comprising rare earth aluminates, and their use in partial oxidation 审中-公开
标题翻译：含有稀土铝酸盐的载体和催化剂，以及它们在部分氧化中的应用
公开(公告)号：US20050265920A1
公开(公告)日：2005-12-01
申请号：US11139233
申请日：2005-05-27
申请人： Cemal Ercan , Shuibo Xie , Harold Wright , Yaming Jin , Daxiang Wang , Kristi Fjare , David Minahan , Beatrice Ortego , David Simon
发明人： Cemal Ercan , Shuibo Xie , Harold Wright , Yaming Jin , Daxiang Wang , Kristi Fjare , David Minahan , Beatrice Ortego , David Simon
IPC分类号： B01J21/04 , B01J21/10 , B01J21/12 , B01J23/00 , B01J23/63 , B01J23/75 , B01J23/89 , B01J37/06 , B01J37/08 , C01B3/38 , C01B3/40 , C01B3/26
CPC分类号： C01B3/386 , B01J21/04 , B01J21/10 , B01J21/12 , B01J23/002 , B01J23/10 , B01J23/40 , B01J23/464 , B01J23/63 , B01J23/75 , B01J23/8913 , B01J35/002 , B01J35/0053 , B01J35/0066 , B01J35/08 , B01J35/1009 , B01J35/1038 , B01J35/1061 , B01J37/0207 , B01J37/0244 , B01J37/06 , B01J37/08 , B01J37/18 , B01J2523/00 , C01B3/40 , C01B2203/0261 , C01B2203/062 , C01B2203/1011 , C01B2203/1041 , C01B2203/1047 , C01B2203/1064 , C01B2203/1082 , C01B2203/1094 , C01B2203/1241 , C01B2203/1247 , Y02P20/52 , B01J2523/31 , B01J2523/3706 , B01J2523/3737 , B01J2523/822
摘要： The present invention relates to thermally stable supports and catalysts for use in high temperature operation, and methods of preparing such supports and catalysts, which includes adding a rare earth metal to an aluminum-containing precursor prior to calcining. The present invention can be more specifically seen as a support, process and catalyst wherein the thermally stable support comprises two rare earth aluminates of different molar ratios of aluminum to rare earth metal, and optionally, alumina and/or a rare earth oxide. More particularly, the invention relates to the use of noble metal catalysts comprising the thermally stable support for synthesis gas production via partial oxidation of light hydrocarbon (e.g., methane) with minimal deactivation over long-term operations and further relates to gas-to-liquids conversion processes.
摘要翻译：本发明涉及用于高温操作的热稳定性载体和催化剂，以及制备这种载体和催化剂的方法，其包括在煅烧之前向含铝前体中加入稀土金属。本发明可以更具体地看作是一种载体，方法和催化剂，其中热稳定载体包含两种不同摩尔比的铝与稀土金属的稀土铝酸盐，以及任选的氧化铝和/或稀土氧化物。更具体地说，本发明涉及贵金属催化剂的用途，所述催化剂包括热稳定性载体，用于通过在长期操作下具有最小失活的轻质烃（例如甲烷）的部分氧化产生合成气，并且还涉及气体 - 液体转换过程。

14. 发明申请

US20050261383A1 Novel syngas catalysts and their method of use 有权
标题翻译：新型合成气催化剂及其使用方法
公开(公告)号：US20050261383A1
公开(公告)日：2005-11-24
申请号：US10706644
申请日：2003-11-12
申请人： Shuibo Xie , Chad Ricketson , David Minahan , Yaming Jin , Harold Wright
发明人： Shuibo Xie , Chad Ricketson , David Minahan , Yaming Jin , Harold Wright
IPC分类号： B01J21/04 , B01J21/10 , B01J21/12 , B01J23/00 , B01J23/10 , B01J23/40 , B01J23/46 , B01J23/56 , B01J23/63 , B01J23/656 , B01J23/75 , B01J23/89 , B01J35/00 , B01J35/10 , B01J37/02 , B01J37/06 , B01J37/08 , C01B3/26 , C01B3/38 , C01B3/40 , C07C27/06 , C10G2/00
CPC分类号： C01B3/40 , B01J21/04 , B01J21/10 , B01J21/12 , B01J23/002 , B01J23/10 , B01J23/40 , B01J23/464 , B01J23/468 , B01J23/56 , B01J23/63 , B01J23/6567 , B01J23/75 , B01J23/8913 , B01J35/002 , B01J35/0026 , B01J35/0053 , B01J35/1014 , B01J35/1019 , B01J37/0201 , B01J37/06 , B01J37/08 , B01J2523/00 , C01B3/386 , C01B2203/0261 , C01B2203/062 , C01B2203/1011 , C01B2203/1017 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , C01B2203/1094 , C01B2203/1241 , C01B2203/1633 , C10G2/30 , Y02P20/52 , B01J2523/31 , B01J2523/3706 , B01J2523/22 , B01J2523/3737 , B01J2523/822 , B01J2523/821 , B01J2523/845 , B01J2523/41
摘要： The present invention relates to improved catalyst compositions, as well as methods of making and using such compositions. Preferred embodiments of the present invention comprise catalyst compositions having high melting point metallic alloys, and methods of preparing and using the catalysts. In particular, the metallic alloys are preferably rhodium alloys. Accordingly, the present invention also encompasses an improved method for converting a hydrocarbon containing gas and an atomic oxygen-containing gas to a gas mixture comprising hydrogen and carbon monoxide, i.e., syngas, using the catalyst compositions in accordance with the present invention. In addition, the present invention contemplates an improved method for converting hydrocarbon gas to liquid hydrocarbons using the novel syngas catalyst compositions described herein.
摘要翻译：本发明涉及改进的催化剂组合物，以及制备和使用这些组合物的方法。本发明的优选实施方案包括具有高熔点金属合金的催化剂组合物，以及制备和使用催化剂的方法。特别地，金属合金优选为铑合金。因此，本发明还包括使用根据本发明的催化剂组合物将含烃气体和含原子氧的气体转化为包含氢气和一氧化碳即合成气的气体混合物的改进方法。此外，本发明考虑了使用本文所述的新型合成气催化剂组合物将烃气体转化为液体烃的改进方法。

15. 发明申请

US20050124706A1 Pressure swing catalyst regeneration procedure for Fischer-Tropsh catalyst 失效
标题翻译： Fischer-Tropsh催化剂的变压催化剂再生方法
公开(公告)号：US20050124706A1
公开(公告)日：2005-06-09
申请号：US11035093
申请日：2005-01-13
申请人： Harold Wright , Ajoy Raje , Rafael Espinoza
发明人： Harold Wright , Ajoy Raje , Rafael Espinoza
IPC分类号： B01J23/889 , B01J23/89 , B01J23/94 , B01J38/02 , B01J38/06 , B01J38/10 , C07C1/04 , C10G2/00 , C07C27/06
CPC分类号： C10G2/32 , B01J23/8896 , B01J23/8913 , B01J23/94 , B01J38/02 , B01J38/06 , B01J38/10 , C07C1/045 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/89 , C07C2527/125 , Y02P20/584
摘要： A process is disclosed for regenerating a catalyst used in a process for synthesizing hydrocarbons. The synthesis process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. The regeneration process involves contacting a deactivated Fischer-Tropsch catalyst with a regeneration gas under regeneration-promoting conditions that include a pressure lower than the mean Fischer-Tropsch reaction pressure, for a period of time sufficient to reactivate the Fischer-Tropsch catalyst.
摘要翻译：公开了用于再生用于合成烃的方法中的催化剂的方法。合成方法包括使包含氢气和一氧化碳的进料流与催化剂接触，所述反应区保持在有效产生包含烃的流出物流的转化促进条件下。再生方法包括在再生促进条件下将失活的费 - 托催化剂与再生气体接触，所述再生促进条件包括低于平均费 - 托反应压力的压力一段足以重新活化费 - 托催化剂的时间。

16. 发明授权

US07947116B2 Hydrogen separation process 有权
标题翻译：氢分离过程
公开(公告)号：US07947116B2
公开(公告)日：2011-05-24
申请号：US11671344
申请日：2007-02-05
申请人： Michael Mundschau , Xiaobing Xie , Carl Evenson, IV , Paul Grimmer , Harold Wright
发明人： Michael Mundschau , Xiaobing Xie , Carl Evenson, IV , Paul Grimmer , Harold Wright
IPC分类号： B01D53/22
CPC分类号： B01D53/226 , B01D53/229 , B01D2257/108 , C01B3/503 , C01B3/505 , C01B2203/0405 , C01B2203/041 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , C01B2203/86 , Y02P20/142 , Y02P30/30
摘要： A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200° C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200° C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.
摘要翻译：一种从含有氢气和至少一种含碳气体的进料流中分离富氢产物流的方法，包括在大于大气压和大于200℃的入口压力下将进料流进料至大于200℃的温度，氢分离膜系统，其包括选择性地可渗透氢的膜，并且在膜的渗透侧产生富氢渗透物产物流和在膜的萃余液侧上的富含二氧化碳的产物萃余液流。一种从含有氢气和至少一种含碳气体的进料流中分离富氢产物流的方法，包括在大于大气压和大于200℃的入口压力下将进料流进料至大于200℃的温度，一种集成的水煤气变换/氢分离膜系统，其中氢分离膜系统包括选择性渗透氢的膜，并且在膜的渗透侧产生富氢渗透物产物流和富含二氧化碳的产物残液在膜的萃余液侧流。一种用于预处理膜的方法，包括：将所述膜在惰性气体流中加热到所需的操作温度和所需的进料压力足够的时间以使膜机械地变形; 将进料压力降至约环境压力; 并且任选地，在膜的变形之前，期间或之后使氧化剂流过膜。一种支撑氢分离膜系统的方法，包括选择氢分离膜系统，其包括沉积在氢输送膜层上的一个或多个催化剂外层，并将氢分离膜系统密封到多孔载体上。

17. 发明授权

US07031849B2 On-line device for predicting at least one fluid flow parameter in a process 失效
标题翻译：用于在过程中预测至少一个流体流参数的在线设备
公开(公告)号：US07031849B2
公开(公告)日：2006-04-18
申请号：US10384782
申请日：2003-03-11
申请人： Yuri Lawryshyn , David A. Olson , Harold Wright
发明人： Yuri Lawryshyn , David A. Olson , Harold Wright
IPC分类号： G06F19/00
CPC分类号： C02F1/325 , C02F1/008 , C02F1/32 , C02F2201/326 , G01F1/00
摘要： An online device and method for predicting at least one fluid flow parameter in a process (which comprises a bounded flow domain having disposed therein a pre-determined matrix) includes a computer and/or process steps whereby: (i) a memory receives a database, the database comprising location information for a plurality of nodes or particle pathways in the matrix; (ii) input data is received from the process, and (iii) the at least one fluid flow parameter is calculated from the database and the input data. Preferably, structure and/or process steps are provided to adjust the database in the event that the input data does not correspond with at least one pre-determined flow state.
摘要翻译：一种用于在过程（其包括其中设置有预定矩阵的有界流域）中预测至少一个流体流参数的在线设备和方法包括计算机和/或处理步骤，其中：（i）存储器接收数据库所述数据库包括所述矩阵中多个节点或粒子通路的位置信息; （ii）从该过程接收输入数据，以及（iii）从数据库和输入数据计算至少一个流体流量参数。优选地，提供结构和/或处理步骤以在输入数据与至少一个预定流量状态不对应的情况下调整数据库。

18. 发明申请

US20060029539A1 Synthesis gas process comprising partial oxidation using controlled and optimized temperature profile 有权
标题翻译：使用受控和优化的温度分布进行部分氧化的合成气工艺
公开(公告)号：US20060029539A1
公开(公告)日：2006-02-09
申请号：US10912787
申请日：2004-08-06
申请人： Subhash Dutta , Harold Wright
发明人： Subhash Dutta , Harold Wright
IPC分类号： C01B3/26 , B01J8/00
CPC分类号： B01J23/63 , B01J8/009 , B01J8/0411 , B01J8/0438 , B01J8/0453 , B01J8/048 , B01J8/0492 , B01J8/0496 , B01J2208/0015 , B01J2208/00203 , B01J2208/00309 , B01J2208/00548 , B01J2208/00628 , C01B3/386 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/1047 , C01B2203/1241 , C01B2203/141 , C01B2203/143 , C01B2203/1614 , Y02P20/52
摘要： This invention relates to methods for reacting a hydrocarbon, molecular oxygen, and optionally water and/or carbon dioxide, to form synthesis gas. The preferred embodiments are characterized by delivering a substochiometric amount of oxygen to each of a multitude of reaction zones, which allows for optimum design of the catalytic packed bed and the gas distribution system, and for the optimization and control of the temperature profile of the reaction zones. The multitude of reaction zones may include a series of successive fixed beds, or a continuous zone housed within an internal structure having porous, or perforated, walls, through which an oxygen-containing stream can permeate. By controlling the oxygen supply, the temperatures, conversion, and product selectivity of the reaction can be in turn controlled and optimized. Furthermore the potential risks of explosion associated with mixing hydrocarbon and molecular oxygen is minimized with increased feed carbon-to-oxygen molar ratios.
摘要翻译：本发明涉及使烃，分子氧和任选的水和/或二氧化碳反应形成合成气的方法。优选的实施方案的特征在于将几何量的氧气输送到多个反应区域中的每一个，这允许催化填充床和气体分配系统的最佳设计，以及优化和控制反应温度曲线区域。多个反应区可以包括一系列连续的固定床，或者容纳在具有多孔或穿孔壁的内部结构内的连续区域，含氧流可穿过该壁。通过控制供氧，可以控制和优化反应的温度，转化率和产物选择性。此外，与碳氢化合物和分子氧混合相关的爆炸的潜在风险可以通过增加进料碳 - 氧摩尔比来最小化。

19. 发明申请

US20050209349A1 Regeneration of synthesis gas catalysts 有权
标题翻译：合成气催化剂再生
公开(公告)号：US20050209349A1
公开(公告)日：2005-09-22
申请号：US11113756
申请日：2005-04-25
申请人： Daxiang Wang , Baili Hu , Yaming Jin , Harold Wright
发明人： Daxiang Wang , Baili Hu , Yaming Jin , Harold Wright
IPC分类号： B01J23/46 , B01J23/94 , B01J23/96 , B01J35/00 , B01J38/04 , B01J38/10 , B01J38/12 , C01B3/38 , C01B3/40 , C07C27/06 , B01J20/34
CPC分类号： B01J38/04 , B01J23/464 , B01J23/94 , B01J23/96 , B01J35/002 , B01J38/10 , B01J38/12 , C01B3/386 , C01B3/40 , C01B2203/0261 , C01B2203/06 , C01B2203/062 , C01B2203/1047 , C01B2203/1082 , C01B2203/1241 , Y02P20/52 , Y02P20/584
摘要： The present invention relates to a process for the preparation of synthesis gas (i.e., a mixture of carbon monoxide and hydrogen), typically labeled syngas. More particularly, the present invention relates to a regeneration method for a syngas catalyst. Still more particularly, the present invention relates to the regeneration of syngas catalysts using a re-dispersion technique. One embodiment of the re-dispersion technique involves the treatment of a deactivated syngas catalyst with a re-dispersing gas, preferably a carbon monoxide-containing gas such as syngas. If necessary, the catalyst is then exposed to hydrogen for reduction and further re-dispersion.
摘要翻译：本发明涉及通常标记为合成气的合成气（即，一氧化碳和氢气的混合物）的制备方法。更具体地说，本发明涉及合成气催化剂的再生方法。更具体地说，本发明涉及使用再分散技术再生合成气催化剂。再分散技术的一个实施方案涉及用再分散气体，优选含有一氧化碳的气体如合成气处理失活的合成气催化剂。如果需要，然后将催化剂暴露于氢气中进行还原和再分散。

20. 发明授权

US6033656A Method of preventing or alleviating mammalian obesity 失效
标题翻译：预防或缓解哺乳动物肥胖的方法
公开(公告)号：US6033656A
公开(公告)日：2000-03-07
申请号：US304641
申请日：1999-05-04
申请人： Toshiyuki Mikami , Bruce Spiegelman , Harold Wright
发明人： Toshiyuki Mikami , Bruce Spiegelman , Harold Wright
IPC分类号： A61K31/336 , A61K31/74 , C08G63/00 , C08K3/00 , C08K3/20
CPC分类号： A61K31/336
摘要： The present invention provides methods of suppressing the activation of Peroxisome Proliferator-Activated Receptor gamma in a mammalian body by administering an effective amount of bisphenol A diglycidyl ether to a mammal, methods of suppressing the accumulation of fat in the mammalian fat cell or adipose tissue by administering an effective amount of bisphenol A diglycidyl ether to a mammal, methods of preventing or alleviating mammalian obesity by administering an effective amount of bisphenol A diglycidyl ether to a mammal, bisphenol A diglycidyl ether for use as an active pharmaceutical substance or composition for the treatment of obesity, and uses of bisphenol A diglycidyl either for the preparation of a pharmaceutical composition for the treatment of obesity.
摘要翻译：本发明提供了通过向哺乳动物施用有效量的双酚A二缩水甘油醚来抑制哺乳动物体内过氧化物酶体增殖物激活受体γ的活化的方法，通过以下方法抑制哺乳动物脂肪细胞或脂肪组织中脂肪的积累：向哺乳动物施用有效量的双酚A二缩水甘油醚，通过向哺乳动物施用有效量的双酚A二缩水甘油醚来预防或减轻哺乳动物肥胖的方法，用作活性药物的双酚A二缩水甘油醚或用于治疗的组合物的肥胖，以及双酚A二缩水甘油酯的用途，用于制备用于治疗肥胖症的药物组合物。

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