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    • 11. 发明申请
    • THERMOPLASTIC ELASTOMER POLYOLEFIN IN-REACTOR BLENDS AND MOLDED ARTICLES THEREFROM
    • 热塑性弹性体聚烯烃反应器共混物及其成型制品
    • WO2010075111A3
    • 2010-10-07
    • PCT/US2009068123
    • 2009-12-15
    • EXXONMOBIL CHEM PATENTS INCJIANG PEIJUNDEKMEZIAN ARMENAGSQUIRE KEVIN RGARCIA-FRANCO CESAR A
    • JIANG PEIJUNDEKMEZIAN ARMENAGSQUIRE KEVIN RGARCIA-FRANCO CESAR A
    • C08L23/04C08F10/02
    • C08L23/16C08F10/06C08F210/06C08L23/12C08L2205/02C08L2207/02C08L2207/07C08L2308/00C08L2314/06C08F2/001C08F210/16C08F2500/04C08F2500/11C08F2500/12C08F2500/17C08F2500/18C08F2500/20
    • This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene- containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3, wherein the polymer blend has a Tm of at least 90 0C (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%. Specifically this invention relates to an in-reactor polymer blend comprising: (a) a first ethylene polymer comprising 90 to 100 wt% ethylene and from 0 to less than 10 wt% comonomer, said first ethylene polymer component having density of greater than 0.920 g/cm3, an Mw of 20,000 g/mol or more; and (b) a second ethylene polymer comprising from 70 to 90 wt% ethylene and 30 to 10 wt% comonomer, said second ethylene polymer having a density of 0.910 g/cm3 or less, wherein the polymer blend has: (a) a Tm of at least 100 0C over a density ranging from 0.84 to 0.92 g/cm3; (b) a elongation at break of 300% or more; (c) a strain hardening index M300/M100 of at least 1.2; (d) a ratio of complex viscosity at 0.01 rad/s to the viscosity at 100 rad/s is of at least 30; and (e) a shear thinning slope of the plot of log(dynamic viscosity) versus log(frequency) less than -0.2.
    • 本发明涉及反应器内聚合物共混物,其包含:(a)密度大于0.90g / cm 3且Mw大于20,000g / mol的第一含乙烯聚合物和(b)第二含乙烯的聚合物 其密度小于0.90g / cm 3,其中聚合物共混物具有至少90℃的Tm(DSC第二熔体),密度小于0.92g / cm 3,并且第一和第二聚合物的密度不同 至少1%。 具体而言,本发明涉及一种反应器内聚合物共混物,其包含:(a)第一乙烯聚合物,其包含90至100wt%的乙烯和0至小于10wt%的共聚单体,所述第一乙烯聚合物组分的密度大于0.920g / cm 3,20,000g / mol或更高的Mw; 和(b)包含70-90重量%乙烯和30-10重量%共聚单体的第二乙烯聚合物,所述第二乙烯聚合物的密度为0.910g / cm 3或更小,其中所述聚合物共混物具有:(a)Tm 在0.84至0.92g / cm 3的密度范围内至少100℃; (b)300%或更多的断裂伸长率; (c)应变硬化指数M300 / M100至少为1.2; (d)0.01rad / s下的复数粘度与100rad / s下的粘度之比至少为30; 和(e)log(动态粘度)对log(频率)的曲线图的剪切稀化斜率小于-0.2。
    • 16. 发明申请
    • SYSTEM FOR COLLECTING SAMPLES FOR ANALYSIS
    • 收集分析样本的系统
    • WO1989012828A1
    • 1989-12-28
    • PCT/US1989002580
    • 1989-06-13
    • DEKMEZIAN, Armenag
    • MORIOKA, Tetsuya
    • G01N35/00
    • G01N1/18B01J20/291B01J2220/54G01N1/40G01N30/0005G01N30/02G01N30/44G01N30/80G01N30/84G01N35/00G01N2001/4027G01N2030/027G01N2030/3084G01N2030/743G01N2030/8417G01N2030/8804B01D15/34
    • An automated, on-line solvent elimination interface system is described for use in characterizing the Composition Distribution (CD) of unknown materials emerging from a fractionating unit (10) or a process stream. Fractionated samples to be analyzed, such as a polymer, in highly diluted form in one or more solvents, are provided by a fractionation unit (10) such as a gel permeation chromatograph (GPC), a high pressure liquid chromatograph (HPLC), or a field flow fractionator (FFF). A number of discharges of each particular fraction are supplied to individual collection units (20) within the interface system under controlled conditions of flow rate, temperature and pressure (vacuum) such that the solvents are flash-evaporated at the collection unit (20). A sufficient solid residue is built up on the collection unit (20) for analysis by, for example, a Fourier transform infrared (FTIR) analyzer.
    • 描述了一种自动化的在线溶剂消除界面系统,用于表征从分馏单元(10)或工艺流出现的未知材料的组成分布(CD)。 通过分离单元(10),例如凝胶渗透色谱仪(GPC),高压液相色谱仪(HPLC)或等离子体色谱仪(HPLC)提供分析样品,例如聚合物,以高度稀释的形式在一种或多种溶剂中 场流分馏器(FFF)。 在流量,温度和压力(真空)的受控条件下,在接收系统内的各个收集单元(20)中将各种特定馏分的排放量提供给吸收单元(20)的溶剂闪蒸。 在收集单元(20)上建立了足够的固体残留物,用于通过例如傅里叶变换红外(FTIR)分析仪进行分析。
    • 19. 发明申请
    • THERMOPLASTIC ELASTOMER POLYOLEFIN IN-REACTOR BLENDS AND MOLDED ARTICLES THEREFROM
    • 热塑性弹性体聚烯烃反应器混合物和其中的成型制品
    • WO2010075111A2
    • 2010-07-01
    • PCT/US2009/068123
    • 2009-12-15
    • EXXONMOBIL CHEMICAL PATENTS INC.JIANG, PeijunDEKMEZIAN, ArmenagSQUIRE, Kevin, R.GARCIA-FRANCO, Cesar, A.
    • JIANG, PeijunDEKMEZIAN, ArmenagSQUIRE, Kevin, R.GARCIA-FRANCO, Cesar, A.
    • C08L23/04C08F10/02
    • C08L23/16C08F10/06C08F210/06C08L23/12C08L2205/02C08L2207/02C08L2207/07C08L2308/00C08L2314/06C08F2/001C08F210/16C08F2500/04C08F2500/11C08F2500/12C08F2500/17C08F2500/18C08F2500/20
    • This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene- containing polymer having a density of greater than 0.90 g/cm 3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm 3 , wherein the polymer blend has a Tm of at least 90 0C (DSC second melt), a density of less than 0.92 g/cm 3 , and the densities of the first and second polymers differ by at least 1%. Specifically this invention relates to an in-reactor polymer blend comprising: (a) a first ethylene polymer comprising 90 to 100 wt% ethylene and from 0 to less than 10 wt% comonomer, said first ethylene polymer component having density of greater than 0.920 g/cm 3 , an Mw of 20,000 g/mol or more; and (b) a second ethylene polymer comprising from 70 to 90 wt% ethylene and 30 to 10 wt% comonomer, said second ethylene polymer having a density of 0.910 g/cm 3 or less, wherein the polymer blend has: (a) a Tm of at least 100 0C over a density ranging from 0.84 to 0.92 g/cm 3 ; (b) a elongation at break of 300% or more; (c) a strain hardening index M300/M100 of at least 1.2; (d) a ratio of complex viscosity at 0.01 rad/s to the viscosity at 100 rad/s is of at least 30; and (e) a shear thinning slope of the plot of log(dynamic viscosity) versus log(frequency) less than -0.2.
    • 本发明涉及一种反应器内聚合物共混物,其包含:(a)密度大于0.90g / cm 3,Mw大于20,000g / mol的第一含乙烯聚合物和(b)第二含乙烯的聚合物 聚合物的密度小于0.90g / cm 3,其中聚合物共混物具有至少90℃的Tm(DSC第二熔体),密度小于0.92g / cm 3,并且第一和第二聚合物的密度不同 至少1%。 具体而言,本发明涉及一种反应器内聚合物共混物,其包含:(a)包含90至100重量%乙烯和0至小于10重量%共聚单体的第一乙烯聚合物,所述第一乙烯聚合物组分的密度大于0.920g / cm3,Mw为20,000g / mol以上; 和(b)包含70-90wt%乙烯和30-10wt%共聚单体的第二乙烯聚合物,所述第二乙烯聚合物的密度为0.910g / cm 3或更低,其中所述聚合物共混物具有:(a)Tm 至少100℃,密度范围为0.84至0.92g / cm3; (b)断裂伸长率在300%以上; (c)至少为1.2的应变硬化指数M300 / M100; (d)0.01rad / s下的复数粘度与100rad / s下的粘度之比至少为30; 和(e)对数(动态粘度)对log(频率)小于-0.2的曲线的剪切变薄斜率。