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11. 发明申请

WO2009134534A2 TREATMENT OF SMALL PORE MOLECULAR SIEVES AND THEIR USE IN THE CONVERSION OF OXYGENATES TO OLEFINS 审中-公开
标题翻译：小孔分子筛的处理及其在氧气转化成烯烃中的用途
公开(公告)号：WO2009134534A2
公开(公告)日：2009-11-05
申请号：PCT/US2009/036520
申请日：2009-03-09
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , CAO, Guang , KENNEDY, Gordon, J. , SHAH, Matu, J.
发明人： CAO, Guang , KENNEDY, Gordon, J. , SHAH, Matu, J.
IPC分类号： C01B37/02 , C01B39/02 , C07C1/20
CPC分类号： B01J29/7015 , B01J29/035 , B01J29/06 , B01J2229/24 , B01J2229/37 , C01B37/02 , C01B39/026 , C07C1/20 , C07C2529/70 , C07C11/02
摘要： A method is disclosed of treating a porous crystalline molecular sieve having a pore size less than or equal to about 5 Angstroms to decrease its coke selectivity in oxygenate to olefin conversion reactions. The method comprises contacting the molecular sieve with an acid having a kinetic diameter greater than or equal to that of acetic acid.
摘要翻译：公开了一种处理孔径小于或等于约5埃的多孔结晶分子筛以降低其在含氧化合物与烯烃转化反应中的焦炭选择性的方法。该方法包括使分子筛与动力学直径大于或等于乙酸的酸的酸接触。

12. 发明申请

WO2009123782A3 SYNTHESIS OF ALUMINOPHOSPHATE AND METALLOALUMINOPHOSPHATE MOLECULAR SIEVES 审中-公开
公开(公告)号：WO2009123782A3
公开(公告)日：2009-10-08
申请号：PCT/US2009/032116
申请日：2009-01-27
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , CAO, Guang , AFEWORKI, Mobae , SHAH, Matu, J. , MERTENS, Machteld, M.
发明人： CAO, Guang , AFEWORKI, Mobae , SHAH, Matu, J. , MERTENS, Machteld, M.
IPC分类号： C01B37/08 , C01B39/54 , B01J29/85 , C10G3/00 , C07C1/20
摘要： In a method of synthesizing an aluminophosphate or metalloaluminophosphate molecular sieve, a synthesis mixture is provided comprising water, a source of aluminum, a source of phosphorus, optionally a source of a metal other than aluminum, a tertiary amine, and an alkylating agent capable of reacting with said tertiary amine to form a quaternary ammonium compound capable of directing the synthesis of said molecular sieve. The synthesis mixture is maintained under conditions sufficient to cause the alkylating agent to react with the tertiary amine to produce the quaternary ammonium compound and to induce crystallization of the molecular sieve.

13. 发明申请

WO2008085354A1 HIGH THROUGHPUT, MICROWAVE ENERGY HEATED CONTINUOUS HYDROTHERMAL SYNTHESIS APPARATUS 审中-公开
标题翻译：高速加热，微波加热连续水热合成设备
公开(公告)号：WO2008085354A1
公开(公告)日：2008-07-17
申请号：PCT/US2007/025908
申请日：2007-12-18
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , CAO, Guang , MISEO, Sabato , SOLED, Stuart, L. , FEELEY, Jennifer, S.
发明人： CAO, Guang , MISEO, Sabato , SOLED, Stuart, L. , FEELEY, Jennifer, S.
IPC分类号： B01J21/00
CPC分类号： B01J37/10 , B01J23/8885 , B01J37/0036
摘要： The present invention is a high throughput apparatus. The apparatus is an automated multi-channel preparation module that prepares a synthesis mixture, microwave heating zone, product collection vessels, and a means for continuously transferring the synthesis mixture through the apparatus.
摘要翻译：本发明是高通量装置。该装置是一种自动多通道制备模块，其制备合成混合物，微波加热区，产物收集容器以及用于将合成混合物连续转移通过该装置的装置。

14. 发明申请

WO2007053239A1 SYNTHESIS OF CHABAZITE-CONTAINING MOLECULAR SIEVES AND THEIR USE IN THE CONVERSION OF OXYGENATES TO OLEFINS 审中-公开
标题翻译：含氧化铵分子筛的合成及其在氧气转化为烯烃中的用途
公开(公告)号：WO2007053239A1
公开(公告)日：2007-05-10
申请号：PCT/US2006/035662
申请日：2006-09-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , CAO, Guang , MERTENS, Machteld, M. , SHAH, Matu, J. , ANTHONIS, Marc, H. , LI, Hailian , GURAM, Anil, S. , SAXTON, Robert, J. , MURAOKA, Mark, T. , YODER, Jeffrey, C. , VOLPE, Anthony, F.
发明人： CAO, Guang , MERTENS, Machteld, M. , SHAH, Matu, J. , ANTHONIS, Marc, H. , LI, Hailian , GURAM, Anil, S. , SAXTON, Robert, J. , MURAOKA, Mark, T. , YODER, Jeffrey, C. , VOLPE, Anthony, F.
IPC分类号： B01J29/70 , C01B39/48 , C10G3/00
CPC分类号： C01B39/48 , B01J29/70 , B01J29/7015 , B01J29/80 , C01B37/02 , C01B39/023 , C07C1/20 , C10G3/49 , C10G3/62 , C10G2300/1011 , C10G2400/20 , Y02P30/20 , C07C11/02
摘要： The synthesis of a crystalline material, in particular, a high silica zeolite, comprising a chabazite-type framework molecular sieve is conducted in the presence of an organic directing agent having the formula: [R 1 R 2 R 3 N-R 4 ]+ Q - wherein R 1 and R 2 are independently selected from hydrocarbyl groups and hydroxy-substituted hydrocarbyl groups having from 1 to 3 carbon atoms, provided that R 1 and R 2 may be joined to form a nitrogen-containing heterocyclic structure, R 3 is an alkyl group having 2 to 4 carbon atoms and R 4 is selected from a 4- to 8-membered cycloalkyl group, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms; and a 4- to 8-membered heterocyclic group having from 1 to 3 heteroatoms, said heterocyclic group being, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms and the or each heteroatom in said heterocyclic group being selected from the group consisting of O, N, and S, or R 3 and R 4 are hydrocarbyl groups having from 1 to 3 carbon atoms joined to form a nitrogen-containing heterocyclic structure; and Q - is a anion.
摘要翻译：包含菱沸石型骨架分子筛的结晶材料，特别是高二氧化硅沸石的合成在具有下式的有机导向剂的存在下进行：[R 1] 其中R 1和R 2各自独立地选自氢， 2个独立地选自具有1至3个碳原子的烃基和羟基取代的烃基，条件是R 1和R 2可以连接到形成含氮杂环结构，R 3是具有2至4个碳原子的烷基，R 4选自4-至8-元环烷基，任选被1至3个具有1至3个碳原子的烷基取代; 和具有1至3个杂原子的4至8元杂环基，所述杂环基任选被1至3个具有1至3个碳原子的烷基取代，并且所述杂环基中的每个杂原子被选定由O，N和S组成的组，或R 3和R 4是具有1至3个碳原子的烃基，连接形成含氮杂环结构体; 而Q ^{是阴离子。}

15. 发明申请

WO2006037436A3 ALUMINOPHOSPHATE MOLECULAR SIEVE, ITS SYNTHESIS AND USE 审中-公开
标题翻译：铝磷酸盐分子筛，其合成和用途
公开(公告)号：WO2006037436A3
公开(公告)日：2006-09-28
申请号：PCT/EP2005009878
申请日：2005-09-12
申请人： EXXONMOBIL CHEM PATENTS INC , EXXONMOBIL CHEMICAL LTD , CAO GUANG , SHAH MATU J , BRODY JOHN F , DORSET DOUGLAS L , STROHMAIER KARL G
发明人： CAO GUANG , SHAH MATU J , BRODY JOHN F , DORSET DOUGLAS L , STROHMAIER KARL G
IPC分类号： C01B39/00 , B01J27/182
CPC分类号： C07C1/20 , B01J29/83 , B01J29/85 , C01B37/04 , C01B37/08 , C01B39/54 , C10G3/00 , C10G3/49 , C10G2400/20 , C07C11/02
摘要： A large pore (metallo)aluminophosphate molecular sieve is disclosed The material has an X-ray diffraction pattern including the lines listed in Table 4 and is synthesized in the presence of 4-dimethylaminopyridine as structure directing agent.
摘要翻译：公开了一种大孔（金属）铝磷酸盐分子筛。该材料具有包括表4中列出的线的X射线衍射图，并在4-二甲基氨基吡啶作为结构导向剂存在下合成。

16. 发明申请

WO2005063622A2 CHABAZITE-TYPE MOLECULAR SIEVE, ITS SYNTHESIS AND ITS USE IN THE CONVERSION OF OXYGENATES TO OLEFINS 审中-公开
标题翻译： CHABAZITE型分子筛，其合成及其在氧气转化为烯烃中的用途
公开(公告)号：WO2005063622A2
公开(公告)日：2005-07-14
申请号：PCT/US2004042737
申请日：2004-12-20
申请人： EXXONMOBIL CHEM PATENTS INC , MERTENS MACHTELD M , CAO GUANG , LI HAILIAN , GURAM ANIL S , SAXTON ROBERT J , MURAOKA MARK T , YODER JEFFREY C
发明人： MERTENS MACHTELD M , CAO GUANG , LI HAILIAN , GURAM ANIL S , SAXTON ROBERT J , MURAOKA MARK T , YODER JEFFREY C
IPC分类号： B01J29/00 , B01J29/70 , C01B37/02 , C01B39/00 , C01B39/02 , C01B39/04 , C01B39/48 , C07C1/00 , C07C1/20
CPC分类号： B01J29/7015 , C01B37/02 , C01B39/48 , C07C1/20 , Y02P20/52 , Y02P30/42 , Y10S423/30 , C07C11/06 , C07C11/04 , C07C11/02
摘要： The synthesis of a crystalline material, in particular a high silica zeolite, having a chabazite-type framework is aided by the addition to the synthesis mixture of seeds of an AEI framework-type material. The chabazite-type product has a relatively small crystal size and exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.
摘要翻译：通过添加到AEI骨架型材料的种子的合成混合物来辅助具有菱沸石型骨架的结晶材料，特别是高二氧化硅沸石的合成。菱沸石型产品具有相对较小的晶体尺寸，并且在甲醇转化成低级烯烃，特别是乙烯和丙烯时具有活性和选择性。

17. 发明申请

WO2003106343A1 SYNTHESIS OF SILICOALUMINOPHOSPHATES 审中-公开
标题翻译：硅烷基磷酸酯的合成
公开(公告)号：WO2003106343A1
公开(公告)日：2003-12-24
申请号：PCT/US2003/012713
申请日：2003-04-24
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , CAO, Guang , SHAH, Matu, J.
发明人： CAO, Guang , SHAH, Matu, J.
IPC分类号： C01B37/08
CPC分类号： C01B37/08 , B01J29/85 , C01B39/54 , Y10S423/30
摘要： The invention is directed to a method of synthesising silicoaluminophosphate molecular sieves using synthesis templates that contain at least one dimethylamino moiety, selected from one or more of the following; N,N-dimethylethanolamine, N,N-dimethylpropanolamine, N,N-dimethylbutanolamine, N,N-dimethylheptanolamine, N,N-dimethylhexanolamine, N,N-dimethylethylenediamine, N,N-dimethylbutylenediamine, N,N-dimethylheptylenediamine, N,N-dimethylhexylenediamine 1-dimethylamino-2-propanol, N,N-dimethylethylamine, N,N-dimethylpropylamine, N,N-dimethylpentylamine, N,N-dimethylhexylamine or N,N-dimethylheptylamine. The use of dimethylamino moiety containing templates results in good quality SAPO molecular sieves of CHA framework type.
摘要翻译：本发明涉及使用含有至少一个选自以下一种或多种的二甲基氨基部分的合成模板合成硅铝磷酸盐分子筛的方法; N，N-二甲基乙醇胺，N，N-二甲基丙醇胺，N，N-二甲基丁醇胺，N，N-二甲基庚醇胺，N，N-二甲基己醇胺，N，N-二甲基乙二胺，N，N-二甲基丁二胺，N， N-二甲基己二胺1-二甲基氨基-2-丙醇，N，N-二甲基乙胺，N，N-二甲基丙胺，N，N-二甲基戊胺，N，N-二甲基己胺或N，N-二甲基庚胺。使用含二甲氨基部分的模板产生优质的CHA骨架类型的SAPO分子筛。

18. 发明申请

WO2003106340A1 SYNTHESIS OF MOLECULAR SIEVES HAVING THE CHA FRAMEWORK TYPE 审中-公开
标题翻译：具有CHA框架类型的分子筛的合成
公开(公告)号：WO2003106340A1
公开(公告)日：2003-12-24
申请号：PCT/US2003/012718
申请日：2003-04-24
申请人： EXXONMOBIL CHEMICAL PATENTS, INC. , CAO, Guang , SHAH, Matu , STROHAMAIER, Karl, G. , HALL, Richard, B.
发明人： CAO, Guang , SHAH, Matu , STROHAMAIER, Karl, G. , HALL, Richard, B.
IPC分类号： C01B37/04
CPC分类号： B01J29/85 , B01J29/83 , C10G3/49 , C10G3/62 , C10G2400/20 , Y02P30/20 , Y10S423/30
摘要： The invention is directed to a method for preparing microporous aluminophosphate or silicoaluminophosphate molecular sieves having the CHA framework type, the process comprising the steps of (a) forming a reaction mixture comprising a source of aluminum, a source of phosphorus, optionally a source of silicon, at least one source of fluoride ions and at least one template containing one or more N,N-dimethylamino moieties, (b), inducing crystallization of aluminophosphate and/or silicoaluminophosphate molecular sieve from the reaction mixture, and (c) recovering aluminophosphate and/or silicoaluminophosphate molecular sieve from the reaction mixture. The invention also relates to the molecular sieves obtained by this method and to molecular sieve catalyst compositions containing these molecular sieves.
摘要翻译：本发明涉及一种制备具有CHA骨架类型的微孔磷酸铝或硅铝磷酸盐分子筛的方法，该方法包括以下步骤：（a）形成包含铝源，磷源，任选的硅源的反应混合物，至少一种氟离子源和至少一个含有一个或多个N，N-二甲基氨基部分的模板，（b），从反应混合物中诱导磷酸铝和/或硅铝磷酸盐分子筛的结晶，和（c）回收磷酸铝和 /或硅铝磷酸盐分子筛。本发明还涉及通过该方法获得的分子筛和含有这些分子筛的分子筛催化剂组合物。

19. 发明申请

WO2010011423A3 SYNTHESIS OF CHABAZITE-CONTAINING MOLECULAR SIEVES AND THEIR USE IN THE CONVERSION OF OXYGENATES TO OLEFINS 审中-公开
标题翻译：含有柴胡的分子筛的合成及其在氧化物转化为烯烃中的应用
公开(公告)号：WO2010011423A3
公开(公告)日：2010-07-22
申请号：PCT/US2009046172
申请日：2009-06-03
申请人： EXXONMOBIL CHEM PATENTS INC , MERTENS MACHTELD M , CAO GUANG
发明人： MERTENS MACHTELD M , CAO GUANG
IPC分类号： B01J29/04 , C01B37/08 , C07C17/20
CPC分类号： B01J29/85 , B01J35/023 , B01J37/0009 , B01J2229/42 , C01B37/08 , C01B39/54 , C07C1/20 , C07C2529/70 , Y02P30/42 , C07C11/02
摘要： In a method of synthesizing a mostly CHA-type silicoaluminophosphate sieve, a reaction mixture comprises sources of water, silicon, aluminum, phosphorus, and a template. In one aspect, when the reaction mixture Si/Al2 ratio is less than 0.33, crystallization is induced at at least 165°C. Advantageously, the sieve so crystallized exhibits a Si/Al2 ratio less than 0.33 and/or at least 0.10 greater than the synthesis mixture SiMl2 ratio. In another aspect, the aluminum and phosphorus sources are first combined to form a primary mixture that is aged. The silicon source and template can then be added to form the synthesis mixture. After inducing crystallization, in this aspect, both the synthesis mixture and crystallized sieve exhibit a Si/Al2 ratio less than 0.33 and/or the crystallized sieve has an average crystal size not more than 3.0µm. The molecular sieve from both aspects can be used in a hydrocarbon (oxygenates-to-olefins) conversion process.
摘要翻译：在主要合成CHA型硅铝磷酸盐筛的方法中，反应混合物包含水，硅，铝，磷和模板的来源。在一个方面，当反应混合物Si / Al 2比率小于0.33时，在至少165℃下诱导结晶。有利的是，如此结晶的筛表现出比合成混合物SiMl 2比率小的0.34和/或至少0.10的Si / Al 2比率。另一方面，首先将铝和磷源合并以形成老化的主要混合物。然后可以加入硅源和模板以形成合成混合物。在引起结晶之后，在这方面，合成混合物和结晶筛均表现出小于0.33的Si / Al 2比和/或结晶筛的平均结晶尺寸不超过3.0μm。来自两个方面的分子筛可用于烃（含氧化合物转化为烯烃）转化过程。

20. 发明申请

WO2009123782A2 SYNTHESIS OF ALUMINOPHOSPHATE AND METALLOALUMINOPHOSPHATE MOLECULAR SIEVES 审中-公开
标题翻译：铝磷酸盐和金属磷酸盐分子筛的合成
公开(公告)号：WO2009123782A2
公开(公告)日：2009-10-08
申请号：PCT/US2009032116
申请日：2009-01-27
申请人： EXXONMOBIL CHEM PATENTS INC , CAO GUANG , AFEWORKI MOBAE , SHAH MATU J , MERTENS MACHTELD M
发明人： CAO GUANG , AFEWORKI MOBAE , SHAH MATU J , MERTENS MACHTELD M
IPC分类号： C01B37/08 , B01J29/85 , C01B39/54 , C07C1/20 , C10G3/00
CPC分类号： C01B37/08 , B01J29/83 , B01J29/85 , C01B37/04 , C01B39/54 , C07C1/20 , Y02P30/20 , Y02P30/42 , Y10S423/30 , C07C11/02
摘要： In a method of synthesizing an aluminophosphate or metalloaluminophosphate molecular sieve, a synthesis mixture is provided comprising water, a source of aluminum, a source of phosphorus, optionally a source of a metal other than aluminum, a tertiary amine, and an alkylating agent capable of reacting with said tertiary amine to form a quaternary ammonium compound capable of directing the synthesis of said molecular sieve. The synthesis mixture is maintained under conditions sufficient to cause the alkylating agent to react with the tertiary amine to produce the quaternary ammonium compound and to induce crystallization of the molecular sieve.
摘要翻译：在合成磷酸铝或金属铝磷酸盐分子筛的方法中，提供了合成混合物，其包含水，铝源，磷源，任选的除铝之外的金属源，叔胺和烷基化剂，其能够与所述叔胺反应形成能够引导所述分子筛合成的季铵化合物。将合成混合物保持在足以使烷基化剂与叔胺反应以产生季铵化合物并诱导分子筛结晶的条件下。

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