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11. 发明授权

US4510091A Continuous reduction of edible oils 失效
标题翻译：持续减少食用油
公开(公告)号：US4510091A
公开(公告)日：1985-04-09
申请号：US360071
申请日：1982-03-19
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C11C3/12
CPC分类号： C11C3/123
摘要： Selective continuous hydrogenations of fatty materials are possible over a fixed bed of zerovalent nickel on an alpha-alumina support. The selectivity of such continuous hydrogenations is further enhanced by performing such hydrogenations in an upflow mode. When soybean oil is used and hydrogenation is continued to an IV of about 110, the resulting partially hydrogenated soybean oil is comparable in its solids content to that obtained in a batch hydrogenation using presently conventional commercial catalysts.
摘要翻译：脂肪材料的选择性连续加氢可能在α-氧化铝载体上的零价镍固定床上。通过在向上流动模式中进行这种氢化，这种连续氢化的选择性进一步增强。当使用大豆油并且氢化持续至约110的IV时，所得部分氢化的大豆油的固体含量与使用目前常规的商业催化剂的间歇氢化获得的固含量相当。

12. 发明授权

US4424162A Selective hydrogenation of fatty materials 失效
标题翻译：脂肪物质的选择性加氢
公开(公告)号：US4424162A
公开(公告)日：1984-01-03
申请号：US297883
申请日：1981-08-31
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C11C3/12
CPC分类号： C11C3/126
摘要： Hydrogenation of fatty materials using zerovalent platinum group metals supported on alpha-alumina are substantially more selective than those where the metal is supported on a porous alumina. An alpha-alumina with surface area less than about 5 m.sup.2 /g, a micropore volume under about 0.05 ml/g, and a macropore volume less than about 0.25 ml/g is particularly desirable. Using these methods, continuous hydrogenations based on a fixed bed process are sufficiently selective to be commercially practicable.
摘要翻译：使用负载在α-氧化铝上的零价铂族金属的脂肪材料的氢化比其中金属负载在多孔氧化铝上的那些基本上更具选择性。表面积小于约5m 2 / g，微孔体积在约0.05ml / g，大孔体积小于约0.25ml / g的α-氧化铝是特别需要的。使用这些方法，基于固定床方法的连续氢化具有足够的选择性以在商业上可行。

13. 发明授权

US07727928B2 Catalyst composition and use thereof in ethane oxidation 失效
标题翻译：催化剂组成及其在乙烷氧化中的应用
公开(公告)号：US07727928B2
公开(公告)日：2010-06-01
申请号：US12461050
申请日：2009-07-30
申请人： James Frank Brazdil , Richard J George , Bruce I Rosen
发明人： James Frank Brazdil , Richard J George , Bruce I Rosen
IPC分类号： B01J23/20 , C07C27/14 , C07C51/215 , C07C51/25 , B01J23/24 , B01J23/14
CPC分类号： B01J23/002 , B01J23/14 , B01J23/20 , B01J23/28 , B01J23/30 , B01J37/0045 , B01J37/0236 , B01J2523/00 , C07C5/48 , C07C51/215 , C07C51/25 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2523/14 , C07C2523/20 , C07C2523/22 , C07C2523/28 , C07C2523/30 , Y02P20/52 , C07C11/04 , C07C53/08 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/43 , B01J2523/41 , B01J2523/47
摘要： A catalyst composition and its use for the oxidation of ethane to ethylene and acetic acid which comprises (i) a support, and (ii) in combination with oxygen, the elements molybdenum, vanadium and niobium, optionally tungsten and a component Z, which is one or more metals of Group 14 of the Periodic Table of Elements; a, b, c, d and e represent the gram atom ratios of the elements Mo, W, Z, V and Nb respectively, such that 0
摘要翻译：催化剂组合物及其用于将乙烷氧化成乙烯和乙酸的用途，其包括（i）载体，和（ii）与氧组合，元素钼，钒和铌，任选的钨和组分Z，其是元素周期表第14族的一种或多种金属; a，b，c，d和e分别表示元素Mo，W，Z，V和Nb的克原子比，使得0

14. 发明授权

US06747171B2 Low temperature purification of naphthalene dicarboxylic acids 有权
标题翻译：萘二羧酸的低温纯化
公开(公告)号：US06747171B2
公开(公告)日：2004-06-08
申请号：US09775025
申请日：2001-02-01
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C07C5142
CPC分类号： C07C51/487 , C07C63/38
摘要： A process for purifying a naphthalenic carboxylic acid comprising contacting at a temperature below about 575° F. a mixture comprising an impure naphthalenic carboxylic acid and a solvent in the presence of hydrogen gas with a noble metal on carbon catalyst. The process results in reduced amounts of organic impurities in the purified acid when compared to other purification processes.
摘要翻译：一种纯化萘羧酸的方法，包括在低于约575°F的温度下将含有不纯的萘甲酸和溶剂的混合物在氢气存在下与贵金属在碳催化剂上接触。与其他纯化方法相比，该方法导致纯化酸中有机杂质的量减少。

15. 发明授权

US5453538A Process for the manufacture of aromatic dicarboxylic acids utilizing cerium to facilitate a low bromine to metals catalyst ratio 失效
标题翻译：利用铈制造芳族二羧酸的方法，以促进低溴与金属的催化比
公开(公告)号：US5453538A
公开(公告)日：1995-09-26
申请号：US195274
申请日：1994-02-14
申请人： Jeffrey L. Broeker , Walter Partenheimer , Bruce I. Rosen
发明人： Jeffrey L. Broeker , Walter Partenheimer , Bruce I. Rosen
IPC分类号： B01J31/04 , C07C51/265 , B01J31/00
CPC分类号： B01J31/0231 , B01J31/04 , C07C51/265 , B01J2231/70 , B01J2531/38 , B01J2531/72 , B01J2531/845
摘要： A process for the manufacture of aromatic dicarboxylic acids is disclosed using a low bromine to metals ratio facilitated by the use of cerium along with the cobalt and manganese catalyst. Aromatic dicarboxylic acids such as terephthalic acid are useful in the manufacture of fiber, films, bottles and molded products.
摘要翻译：公开了一种制备芳族二羧酸的方法，其中通过使用铈以及钴和锰催化剂促进了低溴与金属的比例。芳族二羧酸如对苯二甲酸可用于制造纤维，薄膜，瓶子和模制产品。

16. 发明授权

US5095145A Preparation of purified terephthalic acid from waste polyethylene terephthalate 失效
标题翻译：从废聚对苯二甲酸乙二醇酯制备纯化的对苯二甲酸
公开(公告)号：US5095145A
公开(公告)日：1992-03-10
申请号：US609202
申请日：1990-11-05
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C07C51/09
CPC分类号： C07C51/09 , C08J11/14 , C08J2367/02 , Y02W30/704
摘要： A process is disclosed for producing fiber-grade terephthalic acid from waste polyethylene terephthalate film, fiber, bottles, manufacturing residues, and other manufactured articles. The process comprises depolymerizing waste polyethylene terephthalate in an aqueous mixture to obtain crude terephthalic acid having a b*-value less than 10.00 and an RFCVIS value of about 5000, or greater, which is thereupon hydrogenated in aqueous solution for a period of up to 8 hours. Organic and inorganic impurities are retained in the aqueous components. The purified terephthalic acid has a b*-value less than 2.00, a relative fluorescence concentration in visible light (RFCVIS) of less than 2500, metals content less than 100 ppmw and total organic impurities of less than 1000 ppmw.
摘要翻译：公开了一种从废聚对苯二甲酸乙二醇酯膜，纤维，瓶，制造残余物和其它制品制造纤维级对苯二甲酸的方法。该方法包括将废聚对苯二甲酸乙二醇酯解聚在水性混合物中以获得具有小于10.00的ab *值的粗对苯二甲酸和约5000或更大的RFCVIS值，然后在水溶液中氢化至多8小时。有机和无机杂质保留在水性组分中。纯化的对苯二甲酸具有小于2.00的b *值，可见光（RFCVIS）中的相对荧光浓度小于2500，金属含量小于100ppmw，总有机杂质小于1000ppmw。

17. 发明授权

US4510092A Continuous reduction of edible oils 失效
标题翻译：持续减少食用油
公开(公告)号：US4510092A
公开(公告)日：1985-04-09
申请号：US360114
申请日：1982-03-19
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： B01J21/04 , B01J23/755 , C11C3/12
CPC分类号： C11C3/123 , B01J21/04 , B01J23/755 , B01J35/1009 , B01J35/108
摘要： A method of continuously hydrogenating fatty materials over a fixed catalyst bed utilizes zerovalent nickel on alpha-alumina. Partial hydrogenation of soybean oil to an IV of about 110 can be successfully performed using alpha-alumina of surface area less than about 5 m.sup.2 /g to afford a product whose SFI is acceptable for end product use.
摘要翻译：在固定催化剂床上连续氢化脂肪材料的方法在α-氧化铝上使用零价镍。可以使用表面积小于约5m 2 / g的α-氧化铝成功地进行大豆油部分氢化至约110的IV，以得到SFI对于最终产品使用是可接受的产品。

18. 发明授权

US4401639A Preparation of carbonyl cyanide 失效
标题翻译：羰基氰的制备
公开(公告)号：US4401639A
公开(公告)日：1983-08-30
申请号：US391752
申请日：1982-06-24
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C01C3/14
CPC分类号： C01C3/14
摘要： Carbonyl cyanide may be prepared by reacting a solution of a trihalomethyl haloformate in an organic solvent with a cyanide salt in the presence of a phase transfer catalyst. Carbonyl cyanide may be prepared by this method in good yield and with great convenience.
摘要翻译：羰基氰化物可以通过在相转移催化剂存在下使卤代甲酸三卤甲酯在有机溶剂中与氰化物盐的溶液反应来制备。羰基氰可以通过该方法以良好的产率和极大的方便性制备。

19. 发明授权

US4385001A Selective reduction of edible oils 失效
标题翻译：食用油的选择性还原
公开(公告)号：US4385001A
公开(公告)日：1983-05-24
申请号：US274913
申请日：1981-06-18
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C11C3/12
CPC分类号： C11C3/126
摘要： Edible oils may be selectively hydrogenated using a zerovalent, supported, catalytically active cobalt catalyst. Where the cobalt is supported on alumina, the selectivity of hydrogenation is virtually independent of the nature of the alumina. The process is sufficiently selective that continuous hydrogenation may be performed with about the same selectivity as that presently obtained in batch processes using presently conventional catalysts.
摘要翻译：食用油可以使用零价，负载的，催化活性的钴催化剂选择性氢化。当钴负载在氧化铝上时，氢化的选择性实际上与氧化铝的性质无关。该方法具有足够的选择性，可以以与目前常规催化剂的分批方法中获得的当量相同的选择性进行连续氢化。

20. 发明申请

US20110009666A1 Oxidation catalyst and its preparation 有权
标题翻译：氧化催化剂及其制备方法
公开(公告)号：US20110009666A1
公开(公告)日：2011-01-13
申请号：US12585984
申请日：2009-09-30
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C07C51/25 , C07C51/215 , C07C5/00
CPC分类号： C07C51/25 , B01J21/04 , B01J23/002 , B01J23/56 , B01J23/6525 , B01J23/686 , B01J35/0026 , B01J35/10 , B01J35/1009 , B01J37/0045 , B01J2523/00 , C07C5/3332 , C07C51/215 , C07C2521/04 , C07C2523/68 , Y02P20/52 , C07C53/08 , B01J2523/19 , B01J2523/55 , B01J2523/56 , B01J2523/68 , C07C11/04
摘要： Process for the selective oxidation of ethane to ethylene and/or acetic acid, and/or the selective oxidation of ethylene to acetic acid, by contacting ethane and/or ethylene with a molecular oxygen-containing gas at elevated temperature in the presence of a spray-dried supported catalyst composition. The supported catalyst composition includes molybdenum, vanadium and niobium metal components, supported on a support comprising alpha-alumina. The supported catalyst is prepared by forming a slurry of the metal components and alpha-alumina support particles or an alpha-alumina support precursor, and spray-drying the slurry.
摘要翻译：通过使乙烷和/或乙烯与含分子氧的气体在升高的温度下在喷雾存在下接触将乙烷选择性氧化成乙烯和/或乙酸，和/或将乙烯选择性氧化成乙酸的方法 - 负载型催化剂组合物。负载的催化剂组合物包括负载在包含α-氧化铝的载体上的钼，钒和铌金属组分。通过形成金属组分和α-氧化铝载体颗粒或α-氧化铝载体前体的浆料并喷雾干燥浆料来制备负载型催化剂。

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