专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

11. 发明授权

US09169174B2 Methods for suppressing isomerization of olefin metathesis products 有权
标题翻译：烯烃复分解产物异构化抑制方法
公开(公告)号：US09169174B2
公开(公告)日：2015-10-27
申请号：US13335495
申请日：2011-12-22
申请人： Bruce E. Firth , Sharon E. Kirk
发明人： Bruce E. Firth , Sharon E. Kirk
IPC分类号： C07C7/20 , C11B5/00 , C11B1/10 , C11B3/00 , C11C3/10
CPC分类号： C07C7/20 , C11B1/10 , C11B3/006 , C11C3/10 , C07C11/02
摘要： A method for suppressing isomerization of an olefin metathesis product produced in a metathesis reaction includes adding an isomerization suppression agent that includes nitric acid to a mixture that includes the olefin metathesis product and residual metathesis catalyst from the metathesis reaction under conditions that are sufficient to passivate at least a portion of the residual metathesis catalyst. Methods of refining a natural oil are described.
摘要翻译：用于抑制在复分解反应中产生的烯烃易位产物的异构化的方法包括在易位反应条件下，在足够钝化的条件下，将包含硝酸的异构化抑制剂添加到包含烯烃复分解产物和残余复分解催化剂的混合物中至少一部分残余复分解催化剂。描述了天然油的精制方法。

12. 发明申请

US20130165708A1 METHODS FOR SUPPRESSING ISOMERIZATION OF OLEFIN METATHESIS PRODUCTS 有权
标题翻译：用于抑制烯醇衍生物异构化的方法
公开(公告)号：US20130165708A1
公开(公告)日：2013-06-27
申请号：US13335495
申请日：2011-12-22
申请人： Bruce E. Firth , Sharon E. Kirk
发明人： Bruce E. Firth , Sharon E. Kirk
IPC分类号： C07C7/20 , C11B5/00
CPC分类号： C07C7/20 , C11B1/10 , C11B3/006 , C11C3/10 , C07C11/02
摘要： A method for suppressing isomerization of an olefin metathesis product produced in a metathesis reaction includes adding an isomerization suppression agent that includes nitric acid to a mixture that includes the olefin metathesis product and residual metathesis catalyst from the metathesis reaction under conditions that are sufficient to passivate at least a portion of the residual metathesis catalyst. Methods of refining a natural oil are described.
摘要翻译：用于抑制在复分解反应中产生的烯烃易位产物的异构化的方法包括在易位反应条件下，在足够钝化的条件下，将包含硝酸的异构化抑制剂添加到包含烯烃复分解产物和残余复分解催化剂的混合物中至少一部分残余复分解催化剂。描述了天然油的精制方法。

13. 发明申请

US20120197032A1 METHODS OF REFINING NATURAL OILS, AND METHODS OF PRODUCING FUEL COMPOSITIONS 有权
标题翻译：炼制天然油的方法，以及生产燃料组合物的方法
公开(公告)号：US20120197032A1
公开(公告)日：2012-08-02
申请号：US13335584
申请日：2011-12-22
申请人： Bruce E. Firth , Sharon E. Kirk
发明人： Bruce E. Firth , Sharon E. Kirk
IPC分类号： C07C67/00 , C07C2/04 , C07C1/20 , C07C5/02
CPC分类号： C10G45/00 , C10G45/58 , C10G2300/1014 , C10G2300/304 , C10G2300/308 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/22 , C10L1/026 , C10L1/04 , C10L2200/0469 , C10L2200/0476 , C10L2270/026 , C10L2270/04 , C11B3/04 , Y02P30/20
摘要： A method of refining a natural oil includes: (a) providing a feedstock that includes a natural oil; (b) reacting the feedstock in the presence of a metathesis catalyst to form a metathesized product that includes olefins and esters; (c) passivating residual metathesis catalyst with an agent that comprises nitric acid; (d) separating the olefins in the metathesized product from the esters in the metathesized product; and (e) transesterifying the esters in the presence of an alcohol to form a transesterified product and/or hydrogenating the olefins to form a fully or partially saturated hydrogenated product. Methods for suppressing isomerization of olefin metathesis products produced in a metathesis reaction, and methods of producing fuel compositions are described.
摘要翻译：精制天然油的方法包括：（a）提供包含天然油的原料; （b）在复分解催化剂存在下使原料反应以形成包含烯烃和酯的复分解产物; （c）用包含硝酸的试剂钝化残留的复分解催化剂; （d）将复分解产物中的烯烃与复分解产物中的酯分离; 和（e）在醇存在下酯交酯化以形成酯交换产物和/或使烯烃氢化以形成完全或部分饱和的氢化产物。描述了在复分解反应中产生的烯烃复分解产物的异构化抑制方法和制备燃料组合物的方法。

14. 发明授权

US4538008A Preparation of ortho-alkylated phenols 失效
标题翻译：正烷基化酚的制备
公开(公告)号：US4538008A
公开(公告)日：1985-08-27
申请号：US602302
申请日：1984-04-20
申请人： Bruce E. Firth , Terry J. Rosen
发明人： Bruce E. Firth , Terry J. Rosen
IPC分类号： C07C37/055 , C07C37/48 , C07C43/205 , C07C37/00 , C07C39/06
CPC分类号： C07C37/055
摘要： Secondary or tertiary alkyl phenyl ethers may be induced to undergo thermal rearrangement on alumina, aluminum phosphate, or a silica-modified alumina as catalyst to afford the isomeric ortho-alkylphenol. Such rearrangement generally occurs under milder conditions than does the alkylation of a phenol with an olefin using the same alumina as an alkylating catalyst with high regioselectivity and good control over the extent of alkylation.
摘要翻译：可以诱导二级或叔烷基苯基醚在氧化铝，磷酸铝或二氧化硅改性的氧化铝上进行热重排作为催化剂，得到异构原烷基苯酚。这种重排通常在比使用与具有高区域选择性的烷基化催化剂相同的氧化铝与烯烃的烷基化的温和条件下进行，并且对烷基化程度的控制良好。

15. 发明授权

US4478605A Alkylated 5,6,7,8-tetrahydronaphthalenols as antioxidants 失效
标题翻译：烷基化5,6,7,8-四氢萘酚作为抗氧化剂
公开(公告)号：US4478605A
公开(公告)日：1984-10-23
申请号：US488227
申请日：1983-04-25
申请人： Bruce E. Firth
发明人： Bruce E. Firth
IPC分类号： C08K5/13 , C09K15/08 , C10L1/183 , C10M129/12 , C10L1/18
CPC分类号： C10L1/1837 , C08K5/13 , C09K15/08 , C10M129/12 , C10M2207/023 , C10M2207/025 , C10N2250/10
摘要： Alkylated 5,6,7,8-tetrahydronapthalenols are effective antioxidants for fuel oils. Di- and tri-alkylated tetrahydronaphthalenols are especially effective, with the di- and tri-isopropylated materials being preferred, at a concentration as low as about 5 ppm.
摘要翻译：烷基化的5,6,7,8-四氢萘酚是燃料油的有效抗氧化剂。二烷基化和三烷基化四氢萘烯醇是特别有效的，二异丙基化和三异丙基化的材料是优选的，浓度低至约5ppm。

16. 发明授权

US4447657A Preparation of ortho-alkylated phenols 失效
标题翻译：正烷基化酚的制备
公开(公告)号：US4447657A
公开(公告)日：1984-05-08
申请号：US440676
申请日：1982-11-10
申请人： Bruce E. Firth , Terry J. Rosen
发明人： Bruce E. Firth , Terry J. Rosen
IPC分类号： C07C37/055 , C07C37/48 , C07C43/205 , C07C37/05 , C07C39/06
CPC分类号： C07C43/205 , C07C37/055 , C07C37/48 , C07C41/16
摘要： Alkyl phenyl ethers may be induced to undergo thermal rearrangement on an alumina catalyst to afford the isomeric ortho-alkylphenol. Such rearrangement generally occurs under milder conditions than does the alkylation of a phenol with an olefin using the same alumina as an alkylating catalyst. Yields frequently are high with good selectivity.
摘要翻译：可以诱导烷基苯基醚在氧化铝催化剂上进行热重排，得到异构原烷基酚。这种重排通常在比使用与烷基化催化剂相同的氧化铝的烯烃与烯烃的烷基化的温和条件下进行。产率高，选择性好。

17. 发明申请

US20130165706A1 METHODS FOR SUPPRESSING ISOMERIZATION OF OLEFIN METATHESIS PRODUCTS 有权
标题翻译：用于抑制烯醇衍生物异构化的方法
公开(公告)号：US20130165706A1
公开(公告)日：2013-06-27
申请号：US13335466
申请日：2011-12-22
申请人： Bruce E. Firth , Sharon E. Kirk , Vasudeo S. Gavaskar
发明人： Bruce E. Firth , Sharon E. Kirk , Vasudeo S. Gavaskar
IPC分类号： C07C7/20 , C11B5/00
CPC分类号： C07C7/20 , C11B1/10 , C11B3/006 , C11C3/10 , C07C11/02
摘要： A method for suppressing isomerization of an olefin metathesis product produced in a metathesis reaction includes adding an isomerization suppression agent to a mixture that includes the olefin metathesis product and residual metathesis catalyst from the metathesis reaction under conditions that are sufficient to passivate at least a portion of the residual metathesis catalyst. The isomerization suppression agent is phosphorous acid, a phosphorous acid ester, phosphinic acid, a phosphinic acid ester or combinations thereof. Methods of refining natural oils are described.
摘要翻译：用于抑制在复分解反应中产生的烯烃复分解产物的异构化的方法包括在易位反应的条件下将异构化抑制剂添加到包含烯烃复分解产物和残余复分解催化剂的混合物中，所述条件足以钝化至少一部分残余复分解催化剂。异构化抑制剂是亚磷酸，亚磷酸酯，次膦酸，次膦酸酯或其组合。描述了炼制天然油的方法。

18. 发明授权

US06984749B2 Method for inhibiting polymerization during the recovery and purification of unsaturated mononitriles 失效
标题翻译：在不饱和单腈回收和纯化期间抑制聚合的方法
公开(公告)号：US06984749B2
公开(公告)日：2006-01-10
申请号：US10309962
申请日：2002-12-04
申请人： Bruce I. Rosen , Bruce E. Firth
发明人： Bruce I. Rosen , Bruce E. Firth
IPC分类号： C07C255/03
CPC分类号： C07C253/26 , C07C253/32 , C07C255/08
摘要： Economical processes are disclosed for recovery and refining of valuable nitrogen-containing organic compounds formed by catalytic oxidation of least one feed compound selected from the group consisting of propane, propylene, isobutane and isobutylene in the presence of ammonia to produce a gaseous. Processes of the invention include quenching the gaseous reactor effluent with an aqueous quench liquid; forming an aqueous solution comprising the corresponding unsaturated mononitrile, hydrogen cyanide and other organic co-products; and using an integrated sequence of distillations and phase separations to recover for recycle of a useful aqueous liquid, and obtain the desired nitrogen-containing products. According to the invention aqueous solutions are fractionated in an integrated system of multi-stage columns while an effective polymerization inhibiting amount of at least one member of a preselected class of p-phenylenediamine compounds is maintained therein.
摘要翻译：公开了经济方法用于在氨的存在下通过催化氧化选自丙烷，丙烯，异丁烷和异丁烯的至少一种进料化合物形成的有价值的含氮有机化合物来回收和精炼以产生气体。本发明的方法包括用水淬火液淬火气态反应器流出物; 形成包含相应的不饱和单腈，氰化氢和其它有机副产物的水溶液; 并使用一体化的蒸馏和相分离序列来回收有用的含水液体的再循环，并获得所需的含氮产物。根据本发明，水溶液在多级柱的一体化系统中分级，同时保持有效聚合抑制量的至少一种预选类对苯二胺化合物。

19. 发明授权

US4275249A Preparation of 2,4-Di-t-alkylphenol 失效
标题翻译： 2,4-二叔烷基酚的制备
公开(公告)号：US4275249A
公开(公告)日：1981-06-23
申请号：US99221
申请日：1979-11-30
申请人： Bruce E. Firth
发明人： Bruce E. Firth
IPC分类号： C07C37/14 , C07C37/11
CPC分类号： C07C37/14
摘要： A process for introducing a plurality of alkyl groups into the aromatic ring of a hydroxy-substituted aromatic compound comprises contacting said aromatic compound with an olefin in the presence of alumina or halided alumina as catalyst and recovering the product. When said aromatic compound is phenol, said olefin is isobutylene, and said catalyst is fluorided or chlorided alumina, 2,4-di-t-butylphenol is formed with superior selectivity.
摘要翻译：将多个烷基引入羟基取代的芳族化合物的芳环的方法包括在氧化铝或卤化氧化铝作为催化剂的存在下使所述芳族化合物与烯烃接触并回收产物。当所述芳族化合物为苯酚时，所述烯烃为异丁烯，所述催化剂为氟化或氯化氧化铝，形成2,4-二叔丁基苯酚，具有优异的选择性。

20. 发明授权

US09133416B2 Methods for suppressing isomerization of olefin metathesis products 有权
标题翻译：烯烃复分解产物异构化抑制方法
公开(公告)号：US09133416B2
公开(公告)日：2015-09-15
申请号：US13335517
申请日：2011-12-22
申请人： Bruce E. Firth , Sharon E. Kirk
发明人： Bruce E. Firth , Sharon E. Kirk
IPC分类号： C11B3/00 , C07C7/20 , C11B1/10 , C11C3/10 , C07C51/50 , C11B5/00
CPC分类号： C07C51/313 , B01J2231/54 , C07C7/20 , C07C51/50 , C11B1/10 , C11B3/006 , C11B5/00 , C11B5/0007 , C11B5/0014 , C11B5/0028 , C11C3/10 , Y10S502/52 , C07C11/02
摘要： A method for suppressing isomerization of an olefin metathesis product produced in a metathesis reaction includes adding an isomerization suppression agent to a mixture that includes the olefin metathesis product and residual metathesis catalyst from the metathesis reaction under conditions that are sufficient to passivate at least a portion of the residual metathesis catalyst. The isomerization suppression agent includes (i) a salt and/or an ester of a phosphorous oxo acid, and/or (ii) a derivative of the phosphorous oxo acid in which at least one P—H bond has been replaced by a P—C bond, and/or (iii) a salt and/or an ester of the derivative. Methods of refining natural oils are described.
摘要翻译：用于抑制在复分解反应中产生的烯烃复分解产物的异构化的方法包括在易位反应的条件下将异构化抑制剂添加到包含烯烃复分解产物和残余复分解催化剂的混合物中，所述条件足以钝化至少一部分残余复分解催化剂。异构化抑制剂包括（i）含磷酸的盐和/或酯，和/或（ii）其中至少一个P-H键被P-取代的磷酸的衍生物， C键，和/或（iii）衍生物的盐和/或酯。描述了炼制天然油的方法。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式