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11. 发明申请

WO2016026887A1 PROCESS FOR THE PREPARATION OF DIENE POLYMERS OR RANDOM VINYL ARENE-DIENE COPOLYMERS 审中-公开
标题翻译：制备二烯聚合物或随机乙烯基二烯共聚物的方法
公开(公告)号：WO2016026887A1
公开(公告)日：2016-02-25
申请号：PCT/EP2015/069025
申请日：2015-08-19
申请人： VERSALIS S.P.A.
发明人： SODDU, Luca , VALLIERI, Andrea , SOLITO, Antonio
IPC分类号： C08F293/00
CPC分类号： C08F36/06 , C08F112/08 , C08F212/08 , C08F236/06 , C08F236/10 , C08F2438/02 , C08F2/38
摘要： Process for the preparation of a diene polymer or a random vinyl arene-diene copolymer comprising anionically (co)polymerising at least one conjugated diene monomer, optionally in the presence of at least one vinyl arene, in the presence of at least one hydrocarbon solvent, at least one lithium-based initiator and at least one organic compound containing at least one nitroxide group having general formula (I) or (II): wherein: R 1 , R 2 , R 3 and R 4 , mutually identical or different, represent a hydrogen atom; or are selected from C 1 -C 20 , preferably C 1 -C 8 , linear or branched alkyl groups optionally containing heteroatoms such as, for example, oxygen, nitrogen,sulphur,optionally substituted cycloalkyl groups, optionally substituted C 1 -C 20 , preferably C 1 -C 8 , linear or branched alkoxy groups, optionally substituted aryl groups; -x is an integer ranging from 0 to 7, preferably ranging from 4 to 5; -y is an integer ranging from 1 to 3, preferably ranging from 1 to 2.
摘要翻译：制备二烯聚合物或无规乙烯基芳烃 - 二烯共聚物的方法，其包括任选在至少一种乙烯基芳烃存在下，在至少一种烃溶剂存在下阴离子（共）聚合至少一种共轭二烯单体，至少一种锂基引发剂和至少一种含有至少一个具有通式（I）或（II）的氮氧根基团的有机化合物：其中：R 1，R 2，R 3和R 4相互相同或不同，表示氢原子; 或选自C1-C20，优选C1-C8，任选含有杂原子的直链或支链烷基，例如氧，氮，硫，任选取代的环烷基，任选取代的C 1 -C 20，优选C 1 -C 8直链或支链烷氧基，任选取代的芳基; -x为0〜7的整数，优选为4〜5; -y为1〜3的整数，优选为1〜2。

12. 发明申请

WO2016024198A3 COAXIALLY ARRANGED MODE CONVERTERS 审中-公开
公开(公告)号：WO2016024198A3
公开(公告)日：2016-02-18
申请号：PCT/IB2015/056067
申请日：2015-08-10
申请人： ENI S.P.A.
发明人： DI RENZO, Domenico , MALIARDI, Alberto , GALGANI, Giovanni
IPC分类号： E21B43/24 , H01Q1/04
摘要： The present invention relates to a device for generating a disturbance in the differential mode of propagation of an RF signal transmitted along a coaxial transmission line.

13. 发明申请

WO2009095377A1 SPIRO COMPOUNDS AS NPY Y5 RECEPTOR ANTAGONISTS 审中-公开
标题翻译： SPIRO化合物作为NPY Y5受体拮抗剂
公开(公告)号：WO2009095377A1
公开(公告)日：2009-08-06
申请号：PCT/EP2009/050867
申请日：2009-01-27
申请人： GLAXO GROUP LIMITED , BIAGETTI, Matteo , CONTINI, Stefania Anne , GENSKI, Thorsten , GUERY, Sebastien , LESLIE, Colin Philip , MAZZALI, Angelica , PIZZI, Domenica Antonia , SABBATINI, Fabio Maria , SERI, Catia
发明人： BIAGETTI, Matteo , CONTINI, Stefania Anne , GENSKI, Thorsten , GUERY, Sebastien , LESLIE, Colin Philip , MAZZALI, Angelica , PIZZI, Domenica Antonia , SABBATINI, Fabio Maria , SERI, Catia
IPC分类号： C07D413/12 , C07D413/14 , C07D417/14 , A61K31/423 , A61P3/00
CPC分类号： C07D413/12 , C07D413/14 , C07D417/14
摘要： The present invention relates to novel compounds of formula (I), or a pharmaceutically acceptable salt thereof, (I) wherein R is an aryl or heteroaryl, which may be substituted by one or more: halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkyl, C 1 -C 4 haloalkoxy, cyano; Z 1 is H, C 1 -C 4 alkyl or F; Z is CH 2 , CH(C 1 -C 4 alkyl), C(C 1 -C 4 alkyl)2 or a bond; A is a 6-10 membered aryl or heteroaryl, which may be substituted by one or more: halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkyl, C 1 -C 4 haloalkoxy, cyano; or -C(=O)-X; or O(CH 2 ) 0-1 R 1 ; B is hydrogen or is a 5-6 membered heteroaryl, or a 4-6 membered heterocycle, or phenyl, which may be substituted by one or more: halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkyl, C 1 -C 4 haloalkoxy, hydroxyl, cyano; A and B being linked via any atom; R 1 is -(C 1 -C 4 )alkyl(C 1 -C 4 )alkoxy; or C 3 -C 8 cycloalkyl; or R 1 is an aryl or heteroaryl, which may be substituted by one or more: halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkyl, C 1 -C 4 haloalkoxy, cyano; or R 1 is a 4-6 membered heterocycle, which may be substituted by one or more: halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkyl, C 1 -C 4 haloalkoxy, cyano; X is OR 2 or NR 3 R 4 ; R 2 is C 1 -C 4 alkyl; R 3 is hydrogen or together with R 4 and the nitrogen form a 5-6 saturated membered ring; R 4 is C 3 -C 8 cycloalkyl; processes for their preparation, intermediates used in these processes, pharmaceutical compositions containing them and their use in therapy, as NPY Y5 receptor antagonists and as agents for the treatment and/or prophylaxis of eating disorders such as a binge eating disorder.
摘要翻译：本发明涉及新的式（I）化合物或其药学上可接受的盐，其中R是芳基或杂芳基，其可被一个或多个取代：卤素，C 1 -C 4烷基，C 1 -C 4 烷氧基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，氰基; Z 1是H，C 1 -C 4烷基或F; Z是CH 2，CH（C 1 -C 4烷基），C（C 1 -C 4烷基）2或键; A是6-10元芳基或杂芳基，其可以被一个或多个取代：卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，氰基; 或-C（= O）-X; 或O（CH 2）0-1R1; B是氢或是5-6元杂芳基或4-6元杂环，或苯基，其可被一个或多个取代：卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷基，C 1 -C4卤代烷氧基，羟基，氰基; A和B通过任何原子相连; R1是 - （C1-C4）烷基（C1-C4）烷氧基; 或C 3 -C 8环烷基; 或者R 1是可被一个或多个卤素取代的芳基或杂芳基：卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，氰基; 或R 1是4-6元杂环，其可以被一个或多个取代：卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，氰基; X为OR2或NR3R4; R2是C1-C4烷基; R3是氢或与R4一起形成5-6饱和的元环; R4是C3-C8环烷基; 它们的制备方法，这些方法中使用的中间体，含有它们的药物组合物及其在治疗中的用途，作为NPY Y5受体拮抗剂以及用于治疗和/或预防进食障碍如狂饮病症的药剂。

14. 发明申请

WO2019215684A1 THERMOPLASTIC COPOLYMERS WITH A HIGH SULPHUR CONTENT AND PROCESS FOR THEIR PREPARATION 审中-公开
公开(公告)号：WO2019215684A1
公开(公告)日：2019-11-14
申请号：PCT/IB2019/053858
申请日：2019-05-10
申请人： ENI S.P.A.
发明人： DE ANGELIS, Alberto Renato , GUIDOLIN, Marco
IPC分类号： C08G75/00 , C08G75/14 , C08L81/04
摘要： Thermoplastic copolymer with a high sulphur content comprising sulphur in a quantity higher than or equal to 40% by weight, preferably ranging from 45% by weight to 90% by weight, with respect to the total weight of said thermoplastic copolymer, and at least one monomer having general formula (I) wherein: R 1 and R 2 , equal to or different from each other, represent a hydrogen atom; or they are selected from C 1 -C 20 , preferably C 1 -C 15 , linear or branched alkyl groups, C 2 -C 20 , preferably C 2 -C 15 , linear or branched alkenyl groups, C 2 -C 20 , preferably C 2 -C 15 , linear or branched alkylidene groups; or R 1 and R 2 , may optionally be bound to one another so as to form, together with the other atoms to which they are bound, a cycloalkene containing from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with C 1 -C 20 , preferably C 1 -C 15 , linear or branched alkyl groups, said cycle optionally containing heteroatoms such as, for example, oxygen, sulphur, nitrogen, silicon, phosphorus, selenium; said monomer having the general formula (I) being present in a quantity lower than or equal to 60% by weight, preferably ranging from 10% by weight to 55% by weight, with respect to the total weight of said thermoplastic copolymer. Said thermoplastic copolymer with a high sulphur content exhibits a high glass transition temperature (T g ) [i.e. glass transition temperature (T g ) higher than or equal to 80°C] and good mechanical properties and can be advantageously used, as such or in admixture with other (co)polymers (for example, styrene, divinylbenzene), in a great many applications such as, for example, packaging, electronics, household appliances, computer cases, CD cases, kitchens, laboratories, office and medical items, in buildings and in construction.

15. 发明申请

WO2019215626A1 POLYMERIZATION PROCESS FOR THE SYNTHESIS OF VINYL AROMATIC POLYMERS WITH A CONTROLLED STRUCTURE 审中-公开
公开(公告)号：WO2019215626A1
公开(公告)日：2019-11-14
申请号：PCT/IB2019/053763
申请日：2019-05-08
申请人： VERSALIS SPA
发明人： GHELFI, Franco , FERRANDO, Angelo , LONGO, Aldo , BUFFAGNI, Mirko
IPC分类号： C08F12/08 , C08F2/06 , C08F2/38
摘要： The present invention relates to a polymerization process for the synthesis of vinyl aromatic polymers, in which the sequence of monomers in the chain and the linear, branched soluble, or crosslinked insoluble structure, with reactive or different polarity functions, are controlled. Said process comprises the step of polymerizing vinyl aromatic monomers by means of an Atom Transfer Radical Polymerization (ATRP) reaction with an Activator ReGenerated by Electron Transfer (ARGET), the reaction being carried out at a temperature comprised between 25°C and 110°C in an inert gas atmosphere in the presence of a complex catalyst containing a cupric halide and a multidentate amine ligand, feeding to the reaction an organic initiator having two geminal halogens, an alkali metal (bi)carbonate, a solvent pair of an aliphatic alcohol and an acetic ester of the same aliphatic alcohol and possibly ascorbic acid, provided that no initiator is used with three or more active halogens, or polyvinyl monomers or inimers.

16. 发明申请

WO2019215319A1 ELASTOMERIC TERPOLYMERS WITH A HIGH SULFUR CONTENT AND PROCESS FOR THEIR PREPARATION 审中-公开
公开(公告)号：WO2019215319A1
公开(公告)日：2019-11-14
申请号：PCT/EP2019/062025
申请日：2019-05-10
申请人： ENI S.P.A. , CNR
发明人： DE ANGELIS, Alberto Renato , REGATTIERI, Giovanni , CARROZZA, Chiara Francesca
IPC分类号： C08G75/00 , C08G75/14 , C08L81/04
摘要： Elastomeric terpolymer with a high sulfur content comprising: - sulfur in a quantity higher than or equal to 40% by weight, preferably ranging from 55% by weight to 90% by weight, with respect to the total weight of said elastomeric terpolymer; - a first monomer selected from aromatic vinyl compounds, preferably from styrene, divinylbenzene, vinyl toluene, tert -butylstyrene, ρ -methylstyrene, γ-methylstyrene, α-methylstyrene, vinylnaphthalene; - a second monomer selected from: - aromatic vinyl compounds, preferably from styrene, divinylbenzene, vinyl toluene, tert -butylstyrene, ρ -methylstyrene, γ-methylstyrene, α-methylstyrene, vinylnaphthalene; - monomers having general formula (I): CH 2 =CH-(CH 2 ) y -(X) n -(X) m -(CH 2 ) x -CH=CH 2 , wherein: - X represents a sulfur atom, a selenium atom, a tellurium atom, preferably a sulfur atom, a selenium atom; - y and x, equal to or different from one another, are a whole number ranging from 0 to 4; - n and m, equal to or different from one another, are a whole number ranging from 0 to 3, at least one of n and m being equal to 1; said first monomer and said second monomer being present in a quantity lower than or equal to 60% by weight, preferably ranging from 10% by weight to 45% by weight, with respect to the total weight of said elastomeric terpolymer; said first monomer and said second monomer being different from one another. Said elastomeric terpolymer with a high sulfur content may be advantageously used in various applications such as, for example, thermal insulation, conveyor belts, transmission belts, flexible hoses and, in particular, in elastomeric compositions for tyres.

17. 发明申请

WO2019201887A1 ENERGY STORAGE DEVICE FOR HIGH TEMPERATURE APPLICATIONS 审中-公开
公开(公告)号：WO2019201887A1
公开(公告)日：2019-10-24
申请号：PCT/EP2019/059738
申请日：2019-04-16
申请人： ENI S.P.A.
发明人： LAMBERTI, Andrea , ZAMPATO, Massimo , CARMINATI, Stefano , SERRAPEDE, Mara , GIGOT, Arnaud Nicolas
IPC分类号： H01G11/32 , H01G11/36 , H01G11/46 , H01G11/60 , H01G11/70
摘要： An energy storage device,especially a super capacitor, useful for high temperature application has current collector elements supporting a carbonaceous matrix modified or doped with pseudo-capacitive materials, including one or more transition metal dichalcogenides, transition metal oxides and mixtures thereof,in contact with a non-aqueous electrolyte composition whereby it is possible to exploit the faradic mechanism in addition to the electric double layer mechanism as an energy storage principle.

18. 发明申请

WO2019008499A1 PROCESS FOR PRODUCING OLEFINS FROM ALCOHOLS 审中-公开
公开(公告)号：WO2019008499A1
公开(公告)日：2019-01-10
申请号：PCT/IB2018/054900
申请日：2018-07-02
申请人： VERSALIS S.P.A.
发明人： FOIS, Giovanni Antonio , BUZZONI, Roberto
IPC分类号： C07C1/24 , C07C11/04
摘要： The invention relates to a process for producing olefins from alcohols by means of catalytic dehydration. More in particular, the present invention relates to a process for producing at least one olefin by dehydrating at least one alcohol having a number of carbon atoms comprised between 2 and 6, preferably comprised between 2 and 4, more preferably at least one alcohol having a number of carbon atoms of 3, even more preferably 2-propanol, in the presence of a catalytic material comprising at least one large pore zeolite in acid form, or predominantly acid form, preferably selected from the group consisting of zeolites having BEA structure, MTW structure and mixtures thereof, and preferably at least one inorganic binder, more preferably alumina. Preferably, the olefin has the same number of carbon atoms as the starting alcohol. Furthermore, preferably the olefin does not contain conjugated double bonds and more preferably the olefin is a mono-olefin. Subject matter of the present invention is also the use of the aforementioned olefin in an alkylation process of aromatic hydrocarbons, in particular the use of propylene for alkylating benzene to provide cumene. The aforementioned cumene can be used in an integrated process for preparing phenol and acetone, in accordance with the Hock method, wherein acetone can be reduced to 2- propanol, to be recycled to the process of the invention to obtain propylene again.

19. 发明申请

WO2018154444A1 POLYMER PHOTOVOLTAIC CELL WITH AN INVERTED STRUCTURE AND PROCESS FOR ITS PREPARATION 审中-公开
公开(公告)号：WO2018154444A1
公开(公告)日：2018-08-30
申请号：PCT/IB2018/051045
申请日：2018-02-21
申请人： ENI S.P.A.
发明人： COMINETTI, Alessandra , PO, Riccardo
IPC分类号： H01L51/42
摘要： Polymeric photovoltaic cell (or solar cell) with an inverted structure comprising: an anode; a first anode buffer layer; an active layer comprising at least one photoactive organic polymer as the electron donor and at least one organic electron acceptor compound; a cathode buffer layer; a cathode; wherein between said first anode buffer layer and said active layer a second anode buffer layer is placed comprising a hole transporting material, said hole transporting material being obtained through a process comprising: reacting at least one heteropoly acid containing at least one transition metal belonging to group 5 or 6 of the Periodic Table of the Elements; with at least an equivalent amount of a salt or a complex of a transition metal belonging to group 5 or 6 of the Periodic Table of the Elements with an organic anion, or with an organic ligand; in the presence of at least one organic solvent selected from alcohols, ketones, esters, preferably alcohols. Said polymer photovoltaic cell (or solar cell) with an inverted structure displays high photoelectric conversion efficiency values (η), i.e. a photoelectric conversion efficiency (η) greater than or equal to 4.5%, and good open circuit voltage (Voc), short-circuit current density (Jsc) and fill factor (FF) values. Furthermore, said polymer photovoltaic cell (or solar cell) with an inverted structure is able to maintain said values over time, in particular, in terms of photoelectric conversion efficiency (η).

20. 发明申请

WO2018134757A1 OXO-NITROGENATED IRON COMPLEX, CATALYTIC SYSTEM COMPRISING SAID OXO-NITROGENATED IRON COMPLEX AND PROCESS FOR THE (CO)POLYMERIZATION OF CONJUGATED DIENES 审中-公开
公开(公告)号：WO2018134757A1
公开(公告)日：2018-07-26
申请号：PCT/IB2018/050308
申请日：2018-01-18
申请人： VERSALIS S.P.A.
发明人： SOMMAZZI, Anna , GUIDO, Pampaloni , RICCI, Giovanni , MASI, Francesco , RENILI, Filippo
IPC分类号： C07F15/02 , C07C251/08 , C08F36/00 , C08F36/08 , C08F136/06 , C08F4/70
摘要： Oxo-nitrogenated iron complex having general formula (I): in which: R 1 and R 2 , identical or different, represent a hydrogen atom; or they are selected from linear or branched, optionally halogenated C 1 - C 20 , preferably C 1 -C 15 , alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R 3 represents a hydrogen atom, or it is selected from linear or branched, optionally halogenated C 1 - C 20 , preferably C 1 - C 15 alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; X, identical or different, represent a halogen atom such as, for example, chlorine, bromine, iodine, preferably chlorine; or they are selected from. linear or branched C 1 -C 20 , preferably C 1 - C 15 , alkyl groups, -OCOR 4 groups or -OR 4 groups in which R 4 is selected from linear or branched C 1 - C 20 , preferably C 1 - C 15 , alkyl groups; n is 2 or 3. Said oxo-nitrogenated iron complex having general formula (I) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.

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