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11. 发明公开

EP0158518A3 Process and accompanying catalysts for the hydroformylation of formaldehyde to glycol aldehyde 失效
标题翻译：甲醛对甘油醛的氢化过程及其辅助催化剂
公开(公告)号：EP0158518A3
公开(公告)日：1985-12-27
申请号：EP85302393
申请日：1985-04-04
申请人： THE HALCON SD GROUP, INC.
发明人： Jacobson, Stephen E.
IPC分类号： C07F15/00 , C07C45/68 , C07C47/19
CPC分类号： C07F15/065 , B01J31/189 , B01J31/20 , B01J31/2404 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/845 , C07C45/68 , C07F9/5004 , C07F9/5721 , C07F15/0053 , C07F15/008 , C07C47/19
摘要： A process and accompanying catalyst for the hydroformylation of formaldehyde to glycol aldehyde is disclosed. The process features the utilization of (1) a class of transition metal phosphine-amide complexes, (2) a class of transition metal phosphine-amine complexes, and (3) mixtures of 1 and 2 as particularly suitable for use.

12. 发明公开

EP0133763A3 Preparation of glycols from ethylene oxide 失效
标题翻译：从乙烯氧化物制备甘油
公开(公告)号：EP0133763A3
公开(公告)日：1985-11-27
申请号：EP84304912
申请日：1984-07-18
申请人： THE HALCON SD GROUP, INC.
发明人： Bhise, Vijay S. , Gilman, Harold
IPC分类号： C07C31/20 , C07C29/10
CPC分类号： C07C29/106 , C07D301/10 , Y02P20/52 , C07C31/202
摘要： A process for preparation of glycols in which the vapor remaining after the partial condensation of a conventional ethylene oxide stripper overhead vapor stream is contacted with an aqueous solution of ethylene carbonate to recover ethylene oxide. No water need be removed from the enriched ethylene carbonate stream. Carbon dioxide is added and ethylene carbonate is formed by reaction at about 50 to 200°C and 5 to 150 kg/cm 2 gauge in the presence of a suitable catalyst, preferably about 0.5-20 wt % of an organic phosphonium halide. After stripping off unreacted components, the ethylene carbonate is hydrolyzed to glycols in the presence of the same carbonation catalyst and at temperatures in the range of about 100 to 200°C and pressures of about 5 to 150 kg/cm 2 gauge. Optionally, ethylene oxide and ethylene carbonate may be co-produced.

13. 发明公开

EP0046680A1 Improved catalytic hydrogenation of glycolaldehyde to produce ethylene glycol 失效
标题翻译： Ä。ches ches on on。。。。。。。。。。。。。。
公开(公告)号：EP0046680A1
公开(公告)日：1982-03-03
申请号：EP81303852.8
申请日：1981-08-24
申请人： THE HALCON SD GROUP, INC.
发明人： Costa, Lawrence C.
IPC分类号： C07C31/20 , C07C29/14 , C07C69/003 , C07C67/08 , B01J31/16 , B01J31/26
CPC分类号： C07C45/68 , B01J31/1895 , B01J31/20 , B01J31/2404 , B01J2231/643 , B01J2531/821 , C07C29/141 , C07C67/08 , Y02P20/52 , C07C47/19 , C07C69/16 , C07C31/202
摘要： Ethylene glycol is produced in excellent yields and selectivities in a process which permits use of mild temperature and pressure conditions and comprises catalytically hydrogenating glycolaldehyde to form ethylene glycol in liquid phase employing a homogeneous ruthenium catalyst and a basic promoter.
摘要翻译：在允许使用温和的温度和压力条件并包括催化氢化乙二醇以在液相中使用均相钌催化剂和碱助催化剂形成乙二醇的方法中，以优异的产率和选择性生产乙二醇。

14. 发明公开

EP0014103A2 Improved process for the manufacture of carbamates 失效
标题翻译：一种用于生产氨基甲酸酯的方法。
公开(公告)号：EP0014103A2
公开(公告)日：1980-08-06
申请号：EP80300252.6
申请日：1980-01-28
申请人： THE HALCON SD GROUP, INC.
发明人： Moy, David
IPC分类号： C07C125/063
CPC分类号： C07C271/06
摘要： A process for the production of carbamates is provided in which an organic primary or secondary amine is contacted, in the substantial absence of reactive oxygen, with a source of carbon monoxide, an organic compound containing at least one hydroxyl group and a source of sulfur, selenium or tellerium, in the presence of an effective amount of a catalyst selected from nonhalide compounds and complexes of metals of groups IVB, VB, VIB, VIIB, VIII, IB and IIIA of the Periodic Table, and preferably also in the presence of at least one promoter selected from compounds of metals of Group IA and IIA of the Periodic Table.

15. 发明公开

EP0210017A1 Recovery of noble metal values from carbonylation residues 失效
标题翻译：从羰基化残余物回收贵金属的。
公开(公告)号：EP0210017A1
公开(公告)日：1987-01-28
申请号：EP86305239.5
申请日：1986-07-07
申请人： THE HALCON SD GROUP, INC.
发明人： Pugach, Joseph, Dr.
IPC分类号： B01J31/40
CPC分类号： B01J31/20 , B01J27/08 , B01J27/10 , B01J31/26 , B01J31/4046 , B01J2231/34 , B01J2531/822 , C07C51/56 , C22B3/16 , C22B3/165 , C22B11/044 , Y02P10/214 , Y02P10/234 , Y02P20/584
摘要： Heavy residues produced by noble metal catalysed carbonylation reactions and containing rhodium are treated with reagents to precipitate solids containing substantially all of the rhodium contained in the residues. The solids may be further treated to concentrate the rhodium or they may be returned directly for reuse in the carbonylation reaction. Suitable reagents include aliphatic alcohols, carboxylic acids, and carboxylic acid esters. Preferred are branched-chain alcohols, especially tertiary alcohols; of the acids, acetic acid is particularly preferred; and of the esters, n-butyl acetate and ethylidene diacetate are preferred. Subsequent treatments with other solvents, e.g. alkanes, cycloalkanes, ethers, and aromatic compounds, may be used to further concentrate the rhodium content of the precipitated solids.

16. 发明公开

EP0159175A3 Method for the production of variable amounts of power from syngas 失效
标题翻译：从SYNGAS生产可变电量的方法
公开(公告)号：EP0159175A3
公开(公告)日：1986-08-06
申请号：EP85302482
申请日：1985-04-09
申请人： THE HALCON SD GROUP, INC.
发明人： Cascone, Ronald F. , Solomon, C. Ashley
IPC分类号： F02C03/28 , F01K23/06
CPC分类号： F01K23/067 , F02C3/28 , F02C6/14 , Y02E20/16 , Y02E20/18 , Y02E50/12
摘要： A process for the production of variable amounts of electric power from a syngas feedstock is disclosed. The process captures, stores and releases carbon monoxide by forming and dissociating a suitable organic molecule, i.e., an alkyl formate, and thereby exploits the natural stoichiometry of the coal conversion to greatest advantage.
摘要翻译：公开了从合成气原料生产可变量的电力的方法。该方法通过形成和解离合适的有机分子，即甲酸烷基酯捕获，储存和释放一氧化碳，从而最大限度地利用煤转化的天然化学计量。

17. 发明公开

EP0127396A3 Process and catalyst for the production of aromatic amines 失效
标题翻译：用于生产芳族胺的方法和催化剂
公开(公告)号：EP0127396A3
公开(公告)日：1985-05-29
申请号：EP84303354
申请日：1984-05-17
申请人： THE HALCON SD GROUP, INC.
发明人： Becker, Mitchell , Sachs, Howard M.
IPC分类号： C07C85/06 , C07C87/64 , B01J21/04 , B01J27/06
CPC分类号： C07C209/18
摘要： A process for the amination of phenolic compounds, such as phenol, by contacting them with an aromatic amine, such as aniline, in the presence of a solid heterogeneous, low alkali, acidic alumina catalyst at elevated temperatures and superatmospheric pressures, to produce compounds such as diphenylamine. An improved process of catalyst preparation is also disclosed.
摘要翻译：在固体异质低碱性氧化铝催化剂存在下，在升高的温度和超大气压下，通过使酚类化合物如苯胺与芳族胺如苯胺的胺化来制备胺化合物的方法，以产生化合物作为二苯胺。还公开了一种改进的催化剂制备方法。

18. 发明公开

EP0130085A1 Process for the production of glycol aldehyde and catalyst therefor 失效
标题翻译： Verfahren zur Herstellung von Glykolaldehyd und Katalysatordafür。
公开(公告)号：EP0130085A1
公开(公告)日：1985-01-02
申请号：EP84304348.0
申请日：1984-06-27
申请人： THE HALCON SD GROUP, INC.
发明人： Jacobson, Stephen E.
IPC分类号： C07C47/19 , C07C45/75 , B01J31/24
CPC分类号： B01J31/2404 , B01J31/181 , B01J31/189 , B01J31/20 , B01J31/2208 , B01J31/24 , B01J31/2409 , B01J2231/34 , B01J2231/643 , B01J2531/821 , B01J2531/822 , B01J2531/845 , C07C45/68 , C07F15/008 , Y02P20/582 , C07C47/19
摘要： This invention discloses a process and accompanying catalyst for the preparation of glycol aldehyde from the reaction of formaldehyde, carbon monoxide and hydrogen in the presence of a rhodium phosphine amide catalyst having the formula:
wherein M is a metal selected from the group of rhodium, cobalt, ruthenium and mixtures thereof.

X is an anion selected from the class of halides, psuedohalides, hydrides, and deprotonated strong carboxylic acids;
P is phosphorous;
R 1 is an aliphatic or aromatic group containing from 1-20 carbon atoms;
R 2 is an aliphatic or aromatic group containing from 0-20, carbon atoms and may further comprise oxygen, nitrogen and/or sulfur atoms which may also be directly bonded to the amide C(O)N carbon or nitrogen;
R 3 and R. are aliphatic or aromatic groups containing from 1-50 carbon atoms;
x ranges from 0 to 3, y ranges from 1 to 5, and z from 1 to 4;
the resultant compound further characterized by the absence of hydrogen on the amide nitrogen atom and the additional limitationthat if R 2 is bonded to the amide nitrogen, then either R 3 or R. is bonded to the amide carbon.
摘要翻译：本发明公开了一种在具有下式的铑膦酰胺催化剂存在下由甲醛，一氧化碳和氢气反应制备二醇醛的方法和伴随催化剂：MXx（CO）y [P（R1）2R2（O ）C-NR 3 R 4] z，其中M是选自铑，钴，钌及其混合物的金属。 X是选自卤化物类，卤化物类，氢化物类和去质子化强羧酸类的阴离子; P是磷; R1是含有1-20个碳原子的脂族或芳族基团; R 2是含有0-20个碳原子的脂族或芳族基团，并且还可以包含氧原子，氮原子和/或硫原子，其也可以直接键合到酰胺C（O）N碳或氮; R3和R4是含有1-50个碳原子的脂族或芳族基团; x为0至3，y为1至5，z为1至4; 所得化合物的进一步特征在于酰胺氮原子上不存在氢，另外限制如果R 2与酰胺氮键合，则R3或R4与酰胺碳键合。

19. 发明公开

EP0127396A2 Process and catalyst for the production of aromatic amines 失效
标题翻译： Verfahren und Katalysator zur Herstellung von aromatischen Aminen。
公开(公告)号：EP0127396A2
公开(公告)日：1984-12-05
申请号：EP84303354.9
申请日：1984-05-17
申请人： THE HALCON SD GROUP, INC.
发明人： Becker, Mitchell , Sachs, Howard M.
IPC分类号： C07C85/06 , C07C87/64 , B01J21/04 , B01J27/06
CPC分类号： C07C209/18
摘要： A process for the amination of phenolic compounds, such as phenol, by contacting them with an aromatic amine, such as aniline, in the presence of a solid heterogeneous, low alkali, acidic alumina catalyst at elevated temperatures and superatmospheric pressures, to produce compounds such as diphenylamine. An improved process of catalyst preparation is also disclosed.
摘要翻译：在固体异质低碱性氧化铝催化剂存在下，在升高的温度和超大气压下，通过使酚类化合物如苯胺与芳族胺例如苯胺接触来胺化苯酚化合物的方法，以产生化合物作为二苯胺。还公开了一种改进的催化剂制备方法。

20. 发明公开

EP0127395A2 Production of diphenylamine and aniline from phenol and ammonia 失效
标题翻译： Herstellung von Diphenylaminen und Anilinen aus Phenolen und Ammoniaken。
公开(公告)号：EP0127395A2
公开(公告)日：1984-12-05
申请号：EP84303353.1
申请日：1984-05-17
申请人： THE HALCON SD GROUP, INC.
发明人： Becker, Mitchell , Sachs, Howard M.
IPC分类号： C07C85/06 , C07C87/52 , C07C87/64
CPC分类号： C07C209/18
摘要： A process for the production of predetermined variable amounts of diphenylamine and aniline from a feedstock consisting essentially of phenol and ammonia involves catalytically reacting phenol and ammonia to produce aniline in s i tu and then reacting part of the aniline with other phenol and aniline to produce DPA, with the remaining aniline being removed from the reaction media as product.
摘要翻译：公开了一种从基本上由苯酚和氨组成的原料生产预定的可变量的二苯胺和苯胺的方法。该方法涉及使苯酚和氨催化反应以原位产生苯胺，然后使部分苯胺与其它苯酚和苯胺反应以产生DPA，剩余的苯胺作为产物从反应介质中除去。

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