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    • 11. 发明专利
    • DE1169467B
    • 1964-05-06
    • DEL0031619
    • 1958-10-31
    • LITHOPLATE INC
    • DEAL ELMER FRANKRICHLIN ISADOR M
    • B41N3/03C09D161/20
    • 907,289. Photo-lithographic printing-plate. LITHOPLATE Inc. Oct. 14, 1958 [Nov. 1, 1957], No. 32782/58. Class 98 (2). A support is treated with a modified melamine-aldehyde resin in aqueous dispersion or solution to result in a hydrophilic layer, and then with a light-sensitive diazo compound which becomes hydrophobic and insoluble on exposure. The support may be of paper, resin impregnated paper or, particularly, of metal, the resin therefor of alkylated methylol melamine-formaldehyde wherein methyl or ethyl alcohol is used for etherification, or polyalkylenepolyamine - melamine - formaldehyde for which modification a number of short and long chain polyamines and polyimines are quoted. Descriptions of producing the resins are provided and amplified by references to foreign Specifications concerning such, and the diazo sensitizers are mainly disclosed by similar references. Eight examples describe production of the resin layers and treatment thereof with the condensation product of paraformaldehyde and p-diezo-diphenylamine sulphate as sensitizer.
    • 14. 发明专利
    • LACQUER EMULSION FOR LITHOGRAPHIC PLATES AND METHOD FOR THEIR MANUFACTURE
    • GB1215437A
    • 1970-12-09
    • GB1318869
    • 1969-03-13
    • LITHOPLATE INC
    • THOMAS DANIEL CHARLESHATHAWAY CHARLES THOMAS
    • B41N3/08
    • 1,215,437. Preparing lithographic plates. LITHOPLATE, Inc. March 13, 1969, No.13188/69. Heading G2M. [Also in Division C3] A lacquer emulsion for treating exposed lithographic plates, comprising a two-phase liquid emulsion including in combination (1) an aqueous phase containing a densensitizer for removing unexposed areas from said plate, and (2) a non-aqueous phase comprising as the major ingredients (a) an essentially water-insoluble solvent having a solubility of no more than 2À4 grams per 100 ml of water at room temperature and (b) a water-insoluble oleophilic resin dissolved in said solvent, said resin being of the type resistant to lithographic fountain solutions. lithographic inks, weak acids, alcohols, aliphatic hydrocarbons, and drying oils and having water absorption less than 5%, said resin having when dry, a Rockwell hardness of M-50 to M-100, an impact strength of one to twenty foot pounds per inch of notch, flexural strength between 1000 and 23,000 p.s.i., and tensile strength of 1000 to 13,000 p.s.i., Said non-aqueous phase being dispersed in said aqueous phase with the particle size of the resin particles being between one and five hundred microns. The densensitizer is a hydrophilic colloid e.g. gum arabic and/or carboxymethyl cellulose and an acid desensitizing agent. The aqueous phase preferably contains a solid thickener, e.g. silica. Specified resins are acrylic ester copolymers, polyvinyl formal, vinyl chlorideacetate, vinylidene chloride-acylonitrile, polycarbonates, polystyrene, polyester, polyurethane, silicones, cellulose acetate and bisphenol A- epichlorhydrin condensates, commercial products being employed in the Examples. There are dissolved preferably in cyclohexanone. Optional additives are colourants, non-ionic surfactant and a water-miseible solvent which slows down evaporation of the organic resin solvent, particularly carbitol acetate and isophorone. The lacquers can be used on plates using diazo or cinnamate light-sensitive materials.
    • 16. 发明专利
    • Lithographic plate-base
    • GB920268A
    • 1963-03-06
    • GB3345859
    • 1959-10-02
    • LITHOPLATE INC
    • B41N3/03
    • 920,268. Lithographic plate base. LITHOPLATE Inc. Oct. 2, 1959 [Oct. 3, 1958], No. 33458/59. Class 98 (2). A base member is provided with a coating formed by applying successively (1) a waterdispersible amine modified urea-formaldehyde resin, alkali metal sulphurous acid salt modified urea-formaldehyde resin, alkylated methylol melamine resin or melamine-formaldehyde- -polyalkylene-polyamine resin, said resin being uncured on the base member, (2) a water dispersible polyhydroxy organic compounder or polycarboxy compound; and (3) a watersoluble salt or zirconium, hafnium, titanium or thorium. These metal salts appear to act as curing agents for the previously applied materials and the resulting coating adheres firmly to the base member, has an hydrophilic surface and is substantially free of unreacted salts of the metals. In Example 1 a cleaned and desmutted aluminium sheet is immersed successively in a dispersion of polyalkylenepolyaminemelamine - formaldehyde resin, a solution of carboxymethyl cellulose containing gluconic acid and then one of zirconium acetate with a water rinse after each immersion and dried, when it is ready for application of a casein bichromate sensitizer. Seven other examples repeat the procedure with the variations of using (2) carboxymethyl-hydroxy ethyl cellulose and titanium lactate; (3) titanium lactate as the only change; (4) gluconic acid for the second immersion; (5) steel base plates instead of aluminium; (6) a sulphite modified ureaformaldehyde resin; (7) amine modified ureaformaldehyde resin; and (8) alkylated methylol melamine resin. Numerous other base members including glass, plastic, wood, paper as well as other metals, and other resins, dispersions and salts for the immersions or corresponding coating procedures are listed, and references are provided for further sensitizers.