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181. 发明授权

US5780580A Functionalized crystalline polyactones as toughners for thermosetting resins 失效
标题翻译：功能化结晶聚内酯作为热固性树脂的粘合剂
公开(公告)号：US5780580A
公开(公告)日：1998-07-14
申请号：US911450
申请日：1997-08-15
申请人： Shalaby W. Shalaby , Lance A. Monroe
发明人： Shalaby W. Shalaby , Lance A. Monroe
IPC分类号： C08G63/91 , C08L33/06 , C08L67/04 , C08L67/06 , C08G63/08
CPC分类号： C08L33/06 , C08G63/918 , C08L67/06 , C08L67/04
摘要： A crystalline polylactone is produced having reactive acrylate end groups. When incorporated into a thermosetting resin which includes reactive C.dbd.CH.sub.2 sites, the present functionalized polylactone acts as a toughener, greatly increasing the impact resistance of the final cured product. Also disclosed are carboxyl-bearing polylactones as tougheners for epoxy resin systems.
摘要翻译：生产具有反应性丙烯酸酯端基的结晶聚内酯。当结合到包含反应性C = CH 2位点的热固性树脂中时，本发明的官能化聚内酯作为增韧剂，大大增加了最终固化产物的耐冲击性。还公开了作为环氧树脂体系的增韧剂的含羧基的聚内酯。

182. 发明授权

US5773563A Absorbable .epsilon.-caprolactone polymers 失效
标题翻译：可吸收的ε-己内酯聚合物
公开(公告)号：US5773563A
公开(公告)日：1998-06-30
申请号：US660089
申请日：1996-06-03
申请人： Shalaby W. Shalaby
发明人： Shalaby W. Shalaby
IPC分类号： A61L17/12 , A61L17/14 , A61L24/04 , A61L27/18 , A61L27/34 , A61L27/50 , A61L29/08 , C08G63/91 , C08G63/08
CPC分类号： A61L27/34 , A61L17/12 , A61L17/145 , A61L24/046 , A61L27/18 , A61L27/50 , A61L29/085 , C08G63/912
摘要： Crystane, low melting .epsilon.-Caprolactone polymers which undergo accelerated hydrolysis, and their use as lubricant coatings and/or as coatings containing bioactive agents, as carriers of viable cells, and as coatings for open-cell microporous template or constucts for tissue regeneration; the polymers bearing basic functionalities can be linked ionically or covalently to the ester chain which induces autocatalyzed hydrolysis.
摘要翻译： Crystane，低熔点ε-经过加速水解的ε-己内酯聚合物，以及它们作为润滑剂涂层和/或作为包含生物活性剂的涂层作为活细胞载体的用途，以及用于开放细胞微孔模板或组织再生组织的涂层; 具有碱性官能团的聚合物可以与诱导自动催化水解的酯链离子或共价连接。

183. 发明授权

US5612052A Hydrogel-forming, self-solvating absorbable polyester copolymers, and methods for use thereof 失效
标题翻译：水凝胶形成，自溶溶性可吸收聚酯共聚物及其使用方法
公开(公告)号：US5612052A
公开(公告)日：1997-03-18
申请号：US421222
申请日：1995-04-13
申请人： Shalaby W. Shalaby
发明人： Shalaby W. Shalaby
IPC分类号： A61K47/48 , A61K9/00 , A61K47/34 , A61L31/06 , A61L31/14 , C08G63/66 , C08G63/664 , C08K5/00 , C08L67/00 , C08L67/02 , A61F2/00
CPC分类号： A61K9/0024 , A61K47/34 , A61L31/06 , A61L31/145 , C08G63/664
摘要： The present invention provides novel hydrogel-forming, self-solvating, absorbable polyester copolymers capable of selective, segmental association into compliant hydrogels upon contacting an aqueous environment. Methods of using the novel polyester copolymers of the invention in humans are also disclosed for providing a protective barrier to prevent post-surgical adhesion, treatment of defects in conduits such as blood vessels, and controlled release of a biologically active agent for modulating cellular events such as wound healing and tissue regeneration or therapeutic treatment of diseases such as infection of the periodontium, dry socket, bone, skin, vaginal, and nail infections.
摘要翻译：本发明提供了新颖的水凝胶形成，自溶性，可吸收的聚酯共聚物，其能够在与水性环境接触时能够选择性地，分段地缔合到顺应性水凝胶中。还公开了将本发明的新型聚酯共聚物用于人体的方法，用于提供保护屏障以防止手术后粘连，治疗管道如血管中的缺陷，以及控制释放用于调节细胞事件的生物活性剂作为伤口愈合和组织再生或治疗诸如牙周膜炎，干窝，骨骼，皮肤，阴道和指甲感染等疾病的治疗。

184. 发明授权

US5558517A Polymeric prosthesis having a phosphonylated surface 失效
标题翻译：具有膦酰化表面的聚合物假体
公开(公告)号：US5558517A
公开(公告)日：1996-09-24
申请号：US275634
申请日：1994-07-15
申请人： Shalaby W. Shalaby , Karen R. Rogers
发明人： Shalaby W. Shalaby , Karen R. Rogers
IPC分类号： C08F8/40 , C08J7/12 , A61C8/00
CPC分类号： C08J7/12 , C08F8/40
摘要： A process for phosphonylating the surface of an organic polymeric preform and the surface-phosphonylated preforms produced thereby are provided. Organic polymeric preforms made from various polymers including polyethylene, polyetheretherketone, polypropylene, polymethylmethacrylate, polyamides, and polyester, and formed into blocks, films, and fibers may have their surfaces phosphonylated according to the present inventive process. The process involves the use of a solvent that does not dissolve the organic polymeric preform but does dissolve a phosphorus halide such as phosphorus trichloride. The solvent chosen must also be nonreactive with the phosphorus halide. Such solvents available for use in the present process include the fully-halogenated liquid solvents such as carbon tetrachloride, carbon tetrabromide, and the like. The inventive process allows for surface phosphonylation of the organic polymeric preform such that up to about 30 percent, but preferably up to about 20 percent, of the reactive carbon sites in the polymer are phosphonylated. The inventive phosphonylated organic polymers are particularly useful as orthopedic implants because hydroxyapatite-like surfaces which can be subsequently created on the organic implants allow for co-crystallization of hydroxyapatite to form chemically-bound layers between prosthesis and bone tissue.
摘要翻译：提供了一种使有机聚合物预成型体的表面膦酰化和由其制备的表面膦酰化的预成型体的方法。由各种聚合物（包括聚乙烯，聚醚醚酮，聚丙烯，聚甲基丙烯酸甲酯，聚酰胺和聚酯）制成并且形成嵌段，膜和纤维的有机聚合物预成型件可以根据本发明的方法使其表面被膦酰化。该方法涉及使用不溶解有机聚合物预成型件但是溶解磷酰卤如三氯化磷的溶剂。所选择的溶剂也必须与卤化磷无反应。可用于本方法的这些溶剂包括全卤代液体溶剂如四氯化碳，四溴化碳等。本发明的方法允许有机聚合物预型体的表面膦酰化，使得高达约30％，但优选至多约20％的聚合物中的反应性碳位点被膦酰化。本发明的膦酰化有机聚合物特别可用作矫形植入物，因为随后可以在有机植入物上产生的羟基磷灰石样表面允许羟基磷灰石的共结晶以在假体和骨组织之间形成化学结合的层。

185. 发明授权

US5422068A Radiochemical sterilization 失效
标题翻译：放射化学灭菌
公开(公告)号：US5422068A
公开(公告)日：1995-06-06
申请号：US177872
申请日：1994-01-05
申请人： Shalaby W. Shalaby , Charles L. Linden, Jr.
发明人： Shalaby W. Shalaby , Charles L. Linden, Jr.
IPC分类号： A61L2/20 , A61L2/00 , A61L2/08
CPC分类号： A61L2/204 , A61L2/20
摘要： Radiochemical sterilization is accomplished by exposing a sterilant gas releasing substrate to an effective gas releasing amount of ionizing radiation and contacting an object to be sterilized with the released sterilant gas. Objects to be sterilized may be subjected to a combination of ionizing radiation and gas sterilant which is released by the ionizing radiation.
摘要翻译：通过将灭菌剂气体释放衬底暴露于有效气体释放量的电离辐射并使待消毒物体与释放的灭菌剂气体接触来实现放射化学灭菌。要灭菌的物体可以经受电离辐射和由电离辐射释放的气体灭菌剂的组合。

186. 发明授权

US5007923A Crystalline copolyesters of amorphous (lactide/glycolide) and p-dioxanone 失效
标题翻译：无定形（丙交酯/乙交酯）和对二恶烷酮的结晶共聚酯
公开(公告)号：US5007923A
公开(公告)日：1991-04-16
申请号：US472990
申请日：1990-01-31
申请人： Rao S. Bezwada , Hugh D. Newman, Jr. , Shalaby W. Shalaby
发明人： Rao S. Bezwada , Hugh D. Newman, Jr. , Shalaby W. Shalaby
IPC分类号： A61L17/00 , A61B17/06 , A61L17/10 , A61L17/12 , C08G63/08 , C08G63/664 , D01F6/84
CPC分类号： A61L17/105 , A61B17/06166 , A61L17/12 , C08G63/08 , C08G63/664
摘要： A crystalline copolyester of p-diaxanone and a prepolymer of lactide and glycolide, and absorbable surgical filaments derived therefrom.
摘要翻译：对二甲基酮的结晶共聚酯和丙交酯和乙交酯的预聚物，以及由其衍生的可吸收的外科细丝。

187. 发明授权

US4889119A Surgical fastener made from glycolide-rich polymer blends 失效
标题翻译：由富含乙交酯的聚合物混合物制成的外科紧固件
公开(公告)号：US4889119A
公开(公告)日：1989-12-26
申请号：US146014
申请日：1988-01-20
申请人： Dennis D. Jamiolkowski , Mark T. Gaterud , Hugh D. Newman, Jr. , Shalaby W. Shalaby
发明人： Dennis D. Jamiolkowski , Mark T. Gaterud , Hugh D. Newman, Jr. , Shalaby W. Shalaby
IPC分类号： A61L31/04
CPC分类号： A61L31/041 , A61B17/0643
摘要： There is described a surgical fastener comprising a glycolide-rich blend of two or more polymers, one polymer being a high lactide content polymer and another being a high glycolide content polymer. The blend as a whole contains from about 65 to 85 weight percent polymerized glycolide, with the high glycolide content polymer constituting at least 50 weight percent of the blend.
摘要翻译：描述了一种外科紧固件，其包含两种或更多种聚合物富含乙交酯的混合物，一种聚合物是高丙交酯含量聚合物，另一种是高乙交酯含量聚合物。共混物作为一个整体含有约65至85重量百分比的聚合乙交酯，高乙交酯含量聚合物占混合物的至少50重量％。

188. 发明授权

US4689424A Radiation sterilizable absorbable polymeric materials and methods for manufacturing the same 失效
标题翻译：辐射灭菌吸收性聚合材料及其制造方法
公开(公告)号：US4689424A
公开(公告)日：1987-08-25
申请号：US392331
申请日：1982-06-29
申请人： Shalaby W. Shalaby , Dennis D. Jamiolkowski
发明人： Shalaby W. Shalaby , Dennis D. Jamiolkowski
IPC分类号： A61L17/00 , A61L2/08 , A61L17/10 , A61L27/18 , C07C67/31 , C07C69/712 , C08G63/16 , C08G63/19 , C08G63/60 , C08G63/66 , C08G63/672 , C08G63/78 , C08G63/85 , C07C69/76
CPC分类号： C08G63/672 , A61L17/105 , A61L2/08 , A61L27/18
摘要： Radiation sterilizable polymeric materials, particularly radiation sterilizable absorbable, surgical products made from such polymeric materials.
摘要翻译：辐射灭菌聚合物材料，特别是由这种聚合材料制成的可辐射消毒的可吸收的外科手术产品。

189. 发明授权

US4653497A Crystalline p-dioxanone/glycolide copolymers and surgical devices made therefrom 失效
标题翻译：结晶对二恶烷酮/乙交酯共聚物和由其制成的手术装置
公开(公告)号：US4653497A
公开(公告)日：1987-03-31
申请号：US802547
申请日：1985-11-29
申请人： Rao S. Bezwada , Shalaby W. Shalaby , Hugh D. Newman, Jr.
发明人： Rao S. Bezwada , Shalaby W. Shalaby , Hugh D. Newman, Jr.
IPC分类号： A61L17/00 , A61F2/00 , A61L17/12 , A61L31/00 , C08G63/06 , C08G63/08 , C08G63/664 , C08G63/78 , C08G65/02 , C08G65/08 , D01F6/62 , D01F6/66
CPC分类号： C08G63/664 , A61L17/12 , Y10S525/937
摘要： Copolymers are made by reacting glycolide with a mixture of p-dioxanone monomer and homopolymer. The copolymers are useful in making surgical devices such as surgical sutures.
摘要翻译：共聚物通过使乙交酯与对二恶烷酮单体和均聚物的混合物反应制备。共聚物可用于制造外科手术装置如外科缝线。

190. 发明授权

US4643191A Crystalline copolymers of p-dioxanone and lactide and surgical devices made therefrom 失效
标题翻译：对二恶烷酮和丙交酯的结晶共聚物和由其制备的手术装置
公开(公告)号：US4643191A
公开(公告)日：1987-02-17
申请号：US802546
申请日：1985-11-29
申请人： Rao S. Bezwada , Shalaby W. Shalaby , Hugh Newman, Jr. , Adel Kafrawy
发明人： Rao S. Bezwada , Shalaby W. Shalaby , Hugh Newman, Jr. , Adel Kafrawy
IPC分类号： A61L17/00 , A61L17/12 , C08G63/06 , C08G63/08 , C08G63/664 , C08G63/78 , D01F6/84 , D01F6/86
CPC分类号： C08G63/664 , A61L17/12
摘要： A crystalline copolymer is produced by first polymerizing p-dioxanone to form a mixture of monomer and homopolymer, and then adding lactide to this mixture and polymerizing to form a copolymer.
摘要翻译：通过首先聚合对二恶烷酮以形成单体和均聚物的混合物，然后向该混合物中加入丙交酯并进行聚合以形成共聚物来制备结晶共聚物。

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