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    • 162. 发明授权
    • Cryogenic process for the separation of air to produce ultra high purity
nitrogen
    • 用于分离空气以产生超高纯氮的低温工艺
    • US5123947A
    • 1992-06-23
    • US638853
    • 1991-01-03
    • Rakesh Agrawal
    • Rakesh Agrawal
    • F25J3/04
    • F25J3/04872F25J3/044F25J3/0443F25J3/04448F25J3/04454F25J2200/30F25J2200/32F25J2200/50F25J2200/54F25J2200/74F25J2200/94F25J2205/02F25J2215/44F25J2220/42F25J2220/44F25J2250/20
    • This invention relates to a cryogenic process for the separation of air utilizing an integrated multi-column distillation system wherein an ultra high purity nitrogen product is generated. In the cryogenic distillation separation of air, air is initially compressed, pretreated and cooled for separation into its components. Ultra high purity, e.g., nitrogen typically having less than 0.1 ppm impurities is generated in a multi-column distillation system comprising a first column and an ultra high purity nitrogen column with enhanced nitrogen product recovery by withdrawing a gaseous nitrogen fraction from a first column and charging the fraction as a feed to the ultra high purity nitrogen column, withdrawing a nitrogen stream which is rich in volatile contaminants from the top of the ultra high purity nitrogen column and recovering a nitrogen product at a point below the removal point of the nitrogen rich stream containing volatile components. Removal of volatile components in the distillation process is effected by partially condensing a nitrogen vapor stream from either the first column or the ultra high purity column and removing at least one of the uncondensed portions of the nitrogen rich stream containing volatile components as a purge stream.
    • 本发明涉及一种使用集成的多塔蒸馏系统分离空气的低温方法,其中产生超高纯氮产物。 在空气的低温蒸馏分离中,空气最初被压缩,预处理并冷却以分离成其组分。 在包括第一塔和超高纯度氮塔的多塔蒸馏系统中产生超高纯度,例如通常具有小于0.1ppm杂质的氮,通过从第一塔中取出气态氮馏分而提高氮产物回收率, 将该馏分作为进料加入到超高纯氮塔中,从超高纯度氮塔的顶部排出富含挥发性污染物的氮气流,并在低于富氮的去除点的一个点回收氮产物 流含有挥发性成分。 通过将来自第一塔或超高纯度塔的氮蒸汽流部分冷凝并除去含有挥发性组分的富氮流的至少一个未冷凝部分作为吹扫流来实现蒸馏过程中挥发性组分的去除。
    • 163. 发明授权
    • Cryogenic gas purification process and apparatus
    • 低温气体净化工艺及装置
    • US4934147A
    • 1990-06-19
    • US407569
    • 1989-09-15
    • Douglas V. Eyre
    • Douglas V. Eyre
    • F25J3/04F25J3/08
    • F25J3/08F25J3/0426F25J3/04278F25J3/04351F25J3/04412F25J2200/02F25J2200/04F25J2200/30F25J2200/34F25J2205/40F25J2205/84F25J2210/42F25J2210/50F25J2215/44F25J2215/56F25J2215/58F25J2220/42F25J2220/44F25J2220/50F25J2220/52F25J2235/02F25J2270/42F25J2270/904F25J2280/02
    • A process and apparatus for the ultrapurification of cryogenic low boiling liquified gases such as oxygen and nitrogen which contain trace impurities. The impure gas is introduced into a first distillation column provided with a top column condenser and a bottom column reboiler. The impure gas is substantially at its liquid-gas equilibrium temperature at the pressures within the first distillation column. Here the gas is separated by distillation into a first vapor fraction containing low boiling point impurities and a first liquid fraction containing high boiling point impurities. The first vapor fraction is withdrawn and introduced into a second distillation column provided with a top column condenser and a bottom column reboiler. The first vapor fraction is substantially at the liquid-gas equilibrium temperature at the pressures within the second distillation column. Here the vapor fraction is separated by distillation into a second vapor fraction containing low boiling point impurities and a second liquid fraction free of trace impurities which is withdrawn as product. Cooling for the process is provided by indirect heat exchange with a cryogenic low boiling gas such as nitrogen, oxygen, or air. The gas to be purified as well as the heat exchange gas can be obtained from a standard air separation unit or the process can be conducted using gases and liquids obtained from storage.
    • 用于低温低沸点液化气体如氧气和氮气超纯化的方法和设备,其含有微量杂质。 将不纯气体引入设置有顶塔冷凝器和底塔再沸器的第一蒸馏塔中。 不纯气体在第一蒸馏塔内的压力下基本处于液 - 气平衡温度。 这里,通过蒸馏将气体分离成含有低沸点杂质的第一蒸气馏分和含有高沸点杂质的第一液体馏分。 取出第一蒸气馏分并将其引入设置有顶塔冷凝器和底塔再沸器的第二蒸馏塔中。 第一蒸气馏分在第二蒸馏塔内的压力下基本处于液 - 气平衡温度。 这里通过蒸馏将蒸气馏分分离成含有低沸点杂质的第二蒸气馏分和作为产物取出的无痕量杂质的第二液体部分。 通过与低温低沸点气体如氮气,氧气或空气的间接热交换来提供该方法的冷却。 待净化的气体以及热交换气体可以从标准空气分离单元获得,或者可以使用从储存器获得的气体和液体进行该过程。