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161. 发明授权

US08129052B2 Polymer adhesive seals for protected anode architectures 有权
标题翻译：用于保护阳极结构的聚合物粘合剂密封件
公开(公告)号：US08129052B2
公开(公告)日：2012-03-06
申请号：US11514678
申请日：2006-09-01
申请人： Steven J. Visco , Yevgeniy S. Nimon , Lutgard C. De Jonghe , Bruce D. Katz , Alexei Petrov
发明人： Steven J. Visco , Yevgeniy S. Nimon , Lutgard C. De Jonghe , Bruce D. Katz , Alexei Petrov
IPC分类号： H01M4/40 , H01M4/76 , H01M2/08
CPC分类号： H01M4/76 , H01M4/02 , H01M4/13 , H01M4/134 , H01M4/366 , H01M6/34 , H01M10/052 , H01M12/02 , H01M12/06
摘要： Protected anode architectures for active metal anodes have a polymer adhesive seal that provides an hermetic enclosure for the active metal of the protected anode inside an anode compartment. The compartment is substantially impervious to ambient moisture and battery components such as catholyte (electrolyte about the cathode), and prevents volatile components of the protected anode, such as anolyte (electrolyte about the anode), from escaping. The architecture is formed by joining the protected anode to an anode container. The polymer adhesive seals provide an hermetic seal at the joint between a surface of the protected anode and the container.
摘要翻译：用于活性金属阳极的受保护阳极结构具有聚合物粘合剂密封件，其为阳极室内的受保护阳极的活性金属提供密封外壳。隔室基本上不受环境湿度的影响，电池组件如阴极电解液（电解液围绕阴极），并防止受保护阳极的挥发性成分，如阳极电解液（阳极电解液）逸出。该结构通过将受保护的阳极接合到阳极容器而形成。聚合物粘合剂密封件在受保护阳极的表面和容器之间的接合处提供气密密封。

162. 发明授权

US08048570B2 Compliant seal structures for protected active metal anodes 有权
标题翻译：用于受保护的活性金属阳极的符合密封结构
公开(公告)号：US08048570B2
公开(公告)日：2011-11-01
申请号：US12032564
申请日：2008-02-15
申请人： Steven J. Visco , Yevgeniy S. Nimon , Lutgard De Jonghe , Bruce D. Katz , Alexei Petrov
发明人： Steven J. Visco , Yevgeniy S. Nimon , Lutgard De Jonghe , Bruce D. Katz , Alexei Petrov
IPC分类号： H01M4/40 , H01M4/76 , H01M2/08
CPC分类号： H01B1/122 , H01M2/08 , H01M2/16 , H01M2/1686 , H01M2/18 , H01M4/13 , H01M4/131 , H01M4/133 , H01M6/30 , H01M6/42 , H01M10/052 , H01M10/34 , H01M12/08 , H01M2004/021 , H01M2004/027 , Y02E60/128 , Y10T29/4911
摘要： Protected anode architectures have ionically conductive protective membrane architectures that, in conjunction with compliant seal structures and anode backplanes, effectively enclose an active metal anode inside the interior of an anode compartment. This enclosure prevents the active metal from deleterious reaction with the environment external to the anode compartment, which may include aqueous, ambient moisture, and/or other materials corrosive to the active metal. The compliant seal structures are substantially impervious to anolytes, catholytes, dissolved species in electrolytes, and moisture and compliant to changes in anode volume such that physical continuity between the anode protective architecture and backplane are maintained. The protected anode architectures can be used in arrays of protected anode architectures and battery cells of various configurations incorporating the protected anode architectures or arrays.
摘要翻译：受保护的阳极结构具有离子导电保护膜结构，其结合顺应性密封结构和阳极背板，有效地将活性金属阳极包围在阳极室的内部。该外壳防止活性金属与阳极室外部的环境有害的反应，阳极室可包括水性环境湿气和/或对活性金属具有腐蚀性的其它材料。顺应性密封结构基本上不透过阳极电解液，阴极电解液，电解质中溶解的物质和水分，并且符合阳极体积的变化，从而保持阳极保护结构和背板之间的物理连续性。受保护的阳极结构可用于保护阳极结构的阵列和包含受保护的阳极结构或阵列的各种配置的电池单元。

163. 发明授权

US07858223B2 Electrochemical device component with protected alkali metal electrode 有权
标题翻译：电化学元器件与受保护的碱金属电极
公开(公告)号：US07858223B2
公开(公告)日：2010-12-28
申请号：US11824579
申请日：2007-06-28
申请人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz
发明人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz
IPC分类号： H01M2/16 , H01M10/05
CPC分类号： C03C4/18 , C03C10/00 , H01M2/16 , H01M2/1673 , H01M4/134 , H01M4/366 , H01M4/38 , H01M6/18 , H01M6/181 , H01M6/182 , H01M6/185 , H01M6/187 , H01M6/188 , H01M10/052 , H01M10/0525 , H01M10/056 , H01M10/0562 , H01M10/0565 , H01M10/0583 , H01M2004/021 , H01M2300/0065 , H01M2300/0094
摘要： Disclosed are ionically conductive composites for protection of active metal anodes and methods for their fabrication. The composites may be incorporated in active metal negative electrode (anode) structures and battery cells. In accordance with the invention, the properties of different ionic conductors are combined in a composite material that has the desired properties of high overall ionic conductivity and chemical stability towards the anode, the cathode and ambient conditions encountered in battery manufacturing. The composite is capable of protecting an active metal anode from deleterious reaction with other battery components or ambient conditions while providing a high level of ionic conductivity to facilitate manufacture and/or enhance performance of a battery cell in which the composite is incorporated.
摘要翻译：公开了用于保护活性金属阳极的离子导电复合材料及其制造方法。复合材料可以结合在活性金属负极（阳极）结构和电池单元中。根据本发明，将不同离子导体的性质组合成复合材料，其具有对电池制造中遇到的对阳极，阴极和环境条件的高总离子导电性和化学稳定性的期望性质。该复合材料能够保护活性金属阳极免受与其它电池组分或环境条件的有害反应，同时提供高水平的离子导电性以促进其中掺入复合材料的电池单元的制造和/或增强性能。

164. 发明授权

US07829212B2 Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture 有权
标题翻译：受保护的活性金属电极和具有非水层间结构的电池单元结构
公开(公告)号：US07829212B2
公开(公告)日：2010-11-09
申请号：US11824597
申请日：2007-06-28
申请人： Steven J. Visco , Bruce D. Katz , Yevgeniy S. Nimon , Lutgard C. De Jonghe
发明人： Steven J. Visco , Bruce D. Katz , Yevgeniy S. Nimon , Lutgard C. De Jonghe
IPC分类号： H01M6/14 , H01M6/16 , H01M2/16
CPC分类号： H01M2/1673 , H01G11/06 , H01G11/52 , H01G11/58 , H01M2/1686 , H01M4/13 , H01M4/366 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/0562 , H01M10/0565 , H01M2300/0002 , H01M2300/0085 , Y02E60/122 , Y02E60/13 , Y02P70/54 , Y10T29/49108
摘要： Active metal and active metal intercalation electrode structures and battery cells having ionically conductive protective architecture including an active metal (e.g., lithium) conductive impervious layer separated from the electrode (anode) by a porous separator impregnated with a non-aqueous electrolyte (anolyte). This protective architecture prevents the active metal from deleterious reaction with the environment on the other (cathode) side of the impervious layer, which may include aqueous or non-aqueous liquid electrolytes (catholytes) and/or a variety electrochemically active materials, including liquid, solid and gaseous oxidizers. Safety additives and designs that facilitate manufacture are also provided.
摘要翻译：活性金属和活性金属插入电极结构以及具有离子导电保护结构的电池单元，其包括通过浸渍有非水电解质（阳极电解液）的多孔隔离物与电极（阳极）分离的活性金属（例如锂）导电不渗透层。这种保护结构防止活性金属与不透水层的另一（阴极）侧的环境有害的反应，其可以包括水性或非水性液体电解质（阴极电解液）和/或各种电化学活性材料，包括液体，固体和气体氧化剂。还提供了便于制造的安全性添加剂和设计。

165. 发明授权

US07674558B2 Alleviation of voltage delay in lithium-liquid depolarizer/electrolyte solvent battery cells 失效
标题翻译：缓解锂 - 液体去极化器/电解质溶剂电池中的电压延迟
公开(公告)号：US07674558B2
公开(公告)日：2010-03-09
申请号：US12273119
申请日：2008-11-18
申请人： Lutgard De Jonghe , Yevgeniy S. Nimon , Steven J. Visco
发明人： Lutgard De Jonghe , Yevgeniy S. Nimon , Steven J. Visco
IPC分类号： H01M4/58
CPC分类号： H01M4/38 , H01M4/0402 , H01M4/368 , H01M4/405 , H01M6/14 , H01M10/0563 , H01M10/4235
摘要： Voltage delay in an active metal anode/liquid cathode battery cell can be significantly reduced or completely alleviated by coating the active metal anode (e.g., Li) surface with a thin layer of an inorganic compound with Li-ion conductivity using chemical treatment of Li surface. Particularly, preferred examples of such compounds include lithium phosphate, lithium metaphosphate, and/or their mixtures or solid solutions with lithium sulphate. These compounds can be formed on the Li surface by treatment with diluted solutions of the following individual acids: H3PO4, HPO3 and H2SO4, their acidic salts, or their binary or ternary mixtures in a dry organic solvent compatible with Li, for instance in 1,2-DME; by various deposition techniques. Such chemical protection of the Li or other active metal electrode significantly reduces the voltage delay due to protected anode's improved stability toward the electrolyte.
摘要翻译：通过使用Li表面的化学处理，用具有Li离子传导性的无机化合物的薄层涂覆活性金属阳极（例如Li）表面，可以显着降低或完全减轻活性金属阳极/液体阴极电池单元中的电压延迟。特别地，这些化合物的优选实例包括磷酸锂，偏磷酸锂和/或其与硫酸锂的混合物或固溶体。这些化合物可以在Li表面上通过用与Li相容的干燥有机溶剂中的以下各种酸：H 3 PO 4，HPO 3和H 2 SO 4，它们的酸性盐或其二元或三元混合物的稀释溶液，例如1， 2-DME; 通过各种沉积技术。 Li或其他活性金属电极的这种化学保护显着地降低了由于被保护的阳极提高了对电解质的稳定性的电压延迟。

166. 发明申请

US20090286114A1 ACTIVE METAL FUEL CELLS 有权
标题翻译：活性金属燃料电池
公开(公告)号：US20090286114A1
公开(公告)日：2009-11-19
申请号：US12334116
申请日：2008-12-12
申请人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz , Lutgard C. De Jonghe
发明人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz , Lutgard C. De Jonghe
IPC分类号： H01M8/04 , H01M4/02
CPC分类号： H01M12/04 , H01M2/1646 , H01M4/40 , H01M12/08 , H01M16/003 , Y02E60/128 , Y02P90/40
摘要： Active metal fuel cells are provided. An active metal fuel cell has a renewable active metal (e.g., lithium) anode and a cathode structure that includes an electronically conductive component (e.g., a porous metal or alloy), an ionically conductive component (e.g., an electrolyte), and a fluid oxidant (e.g., air, water or a peroxide or other aqueous solution). The pairing of an active metal anode with a cathode oxidant in a fuel cell is enabled by an ionically conductive protective membrane on the surface of the anode facing the cathode.
摘要翻译：提供了活性金属燃料电池。活性金属燃料电池具有可再生活性金属（例如锂）阳极和阴极结构，其包括电子导电组分（例如，多孔金属或合金），离子导电组分（例如电解质）和流体氧化剂（例如空气，水或过氧化物或其它水溶液）。活性金属阳极与燃料电池中的阴极氧化剂的配对通过面向阴极的阳极表面上的离子导电保护膜来实现。

167. 发明授权

US07608178B2 Active metal electrolyzer 失效
标题翻译：活性金属电解槽
公开(公告)号：US07608178B2
公开(公告)日：2009-10-27
申请号：US10986441
申请日：2004-11-10
申请人： Lutgard De Jonghe , Steven J. Visco , Yevgeniy S. Nimon
发明人： Lutgard De Jonghe , Steven J. Visco , Yevgeniy S. Nimon
IPC分类号： H01M4/04
CPC分类号： C25C1/02 , H01M10/52 , H01M10/54 , Y02P10/212 , Y02W30/84
摘要： Electro-winning of active metal (e.g., lithium) ions from a variety of sources including industrial waste, and recycled lithium and lithium-ion batteries is accomplished with an electrolyzer having a protected cathode that is stable against aggressive solvents, including water, aqueous electrolytes, acid, base, and a broad range of protic and aprotic solvents. The electrolyzer has a highly ionically conductive protective membrane adjacent to the alkali metal cathode that effectively isolates (de-couples) the alkali metal electrode from solvent, electrolyte processing and/or cathode environments, and at the same time allows ion transport in and out of these environments. Isolation of the cathode from other components of a battery cell or other electrochemical cell in this way allows the use of virtually any solvent, electrolyte and/or anode material in conjunction with the cathode. The electrolyzer can be configured and operated to claim or reclaim lithium or other active metals from such sources.
摘要翻译：从包括工业废弃物和再循环的锂离子和锂离子电池在内的各种来源的活性金属（例如锂）离子的电击可以用电解槽来实现，该电解槽具有对侵蚀性溶剂稳定的电解槽，包括水，电解质水溶液，酸，碱和广泛的质子和非质子溶剂。电解槽具有与碱金属阴极相邻的高度离子导电的保护膜，其有效地将碱金属电极与溶剂，电解质处理和/或阴极环境隔离（去耦合），并且同时允许离子传输进出这些环境。以这种方式将阴极与电池单元或其它电化学电池的其它部件隔离使得能够与阴极结合使用实际上任何溶剂，电解质和/或阳极材料。可以配置和操作电解器以从这些来源中提取或回收锂或其它活性金属。

168. 发明授权

US07491458B2 Active metal fuel cells 失效
标题翻译：活性金属燃料电池
公开(公告)号：US07491458B2
公开(公告)日：2009-02-17
申请号：US10825587
申请日：2004-04-14
申请人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz , Lutgard C. De Jonghe
发明人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz , Lutgard C. De Jonghe
IPC分类号： H01M4/40 , H01M12/06 , H01M2/16
CPC分类号： H01M12/04 , H01M2/1646 , H01M4/40 , H01M12/08 , H01M16/003 , Y02E60/128 , Y02P90/40
摘要： Active metal fuel cells are provided. An active metal fuel cell has a renewable active metal (e.g., lithium) anode and a cathode structure that includes an electronically conductive component (e.g., a porous metal or alloy), an ionically conductive component (e.g., an electrolyte), and a fluid oxidant (e.g., air, water or a peroxide or other aqueous solution). The pairing of an active metal anode with a cathode oxidant in a fuel cell is enabled by an ionically conductive protective membrane on the surface of the anode facing the cathode.
摘要翻译：提供了活性金属燃料电池。活性金属燃料电池具有可再生活性金属（例如锂）阳极和阴极结构，其包括电子导电组分（例如，多孔金属或合金），离子导电组分（例如电解质）和流体氧化剂（例如空气，水或过氧化物或其它水溶液）。活性金属阳极与燃料电池中的阴极氧化剂的配对通过面向阴极的阳极表面上的离子导电保护膜来实现。

169. 发明申请

US20080161746A1 PROTECTED LITHIUM ELECTRODES FOR ELECTRO-TRANSPORT DRUG DELIVERY 失效
标题翻译：用于电子输送药物递送的保护的锂电极
公开(公告)号：US20080161746A1
公开(公告)日：2008-07-03
申请号：US11946791
申请日：2007-11-28
申请人： Steven J. Visco , Yevgeniy S. Nimon
发明人： Steven J. Visco , Yevgeniy S. Nimon
IPC分类号： A61N1/30 , A61K33/00
CPC分类号： A61K33/00 , A61K33/24 , A61N1/0436 , A61N1/044 , A61N1/0448 , A61N1/306
摘要： This invention provides new and novel devices and methods for administering lithium (Li) ions to a mammalian subject, especially the delivery of lithium (Li) ions to a body component for example across a body or tissue surface such as skin or a mucosal membrane, or for delivery of lithium ions directly to bodily fluids in a controllable and reproducible manner. In certain embodiments the device comprises a donor electrode that is a donor of a lithium ion; a protective architecture that is ionically conductive to the lithium ion, configured for application to a skin surface and positioned to isolate said donor electrode from the skin surface; and a counter electrode assembly configured for application to a skin surface, where said counter electrode assembly comprises a counter electrode operably coupled to said donor electrode.
摘要翻译：本发明提供了用于向哺乳动物受试者施用锂（Li）离子的新的和新颖的装置和方法，特别是将锂（Li）离子递送到身体组分，例如穿过身体或组织表面如皮肤或粘膜，或以可控和可重复的方式将锂离子直接递送到体液。在某些实施方案中，该装置包括作为锂离子的供体的供体电极; 对锂离子进行离子导电的保护结构，被配置为施加到皮肤表面并定位成将所述供体电极与皮肤表面隔离; 以及配置用于施加到皮肤表面的对电极组件，其中所述对电极组件包括可操作地耦合到所述施主电极的对电极。

170. 发明申请

US20080057399A1 Ionically conductive composites for protection of active metal anodes 审中-公开
公开(公告)号：US20080057399A1
公开(公告)日：2008-03-06
申请号：US11823847
申请日：2007-06-27
申请人： Steven Visco , Yevgeniy Nimon , Bruce Katz
发明人： Steven Visco , Yevgeniy Nimon , Bruce Katz
IPC分类号： H01M2/16
CPC分类号： H01M4/134 , C03C4/18 , C03C10/00 , H01M4/366 , H01M4/381 , H01M4/382 , H01M4/40 , H01M4/405 , H01M10/052 , H01M10/0562 , H01M10/0583 , H01M2004/021 , H01M2300/0094 , Y10T29/49112 , Y10T29/49115
摘要： Disclosed are ionically conductive composites for protection of active metal anodes and methods for their fabrication. The composites may be incorporated in active metal negative electrode (anode) structures and battery cells. In accordance with the invention, the properties of different ionic conductors are combined in a composite material that has the desired properties of high overall ionic conductivity and chemical stability towards the anode, the cathode and ambient conditions encountered in battery manufacturing. The composite is capable of protecting an active metal anode from deleterious reaction with other battery components or ambient conditions while providing a high level of ionic conductivity to facilitate manufacture and/or enhance performance of a battery cell in which the composite is incorporated.

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