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    • 147. 发明公开
    • Enhanced process for the production of synthesis gas starting from oxygenated compounds deriving from biomasses
    • 用于从生物质从的含氧化合物生产合成气的改进方法
    • EP2072459A1
    • 2009-06-24
    • EP08169549.6
    • 2008-11-20
    • ENI S.p.A.
    • Basini, LucaGuarinoni, Alessandra
    • C01B3/32
    • C01B3/323C01B2203/0261C01B2203/1211C01B2203/1229Y02P20/52
    • The present invention relates to a catalytic partial oxidation process for the production of synthesis gas starting from oxygenated compounds deriving from biomasses, comprising at least the following operative phase: reacting, in a suitable reactor, a reaction mixture comprising:
      a) one or more oxygenated compounds selected from glycerine, ethanol, triglycerides of fatty acids, carbohydrates having the general formula C n (H 2 O) n H 2 and/or mixtures thereof, preferably glycerine and/or ethylene glycol, even more preferably glycerine, b) an oxidant selected from oxygen, air or air enriched with oxygen, c) optionally a hydrocarbon propellant or vapour, wherein the ratio of moles of molecular oxygen/carbon moles of the oxygenated compound plus that of the possible propellant (O 2 /C) ranges from 0.20 to 0.60 mole/mole, said reaction being carried out at a temperature ranging from 450 to 1,100°C, at a pressure ranging from 1 to 50 ATM, with a GHSV (gas hourly space velocity) ranging from 10,000 to 1,000,000 Nl/(kg·h), in the presence of a catalyst comprising one or more transition metals on a solid carrier.
    • 本发明涉及一种用于生产由衍生自生物质的含氧化合物开始合成气的催化部分氧化方法,至少包括以下操作阶段:在合适的反应器中反应,反应混合物包含:a)一种或多种氧化 氧化剂的选自甘油,乙醇,脂肪酸甘油三酯,具有通式C n碳水化合物(H 2 O)N H 2和/或它们的混合物,优选甘油和/或乙二醇,甚至更优选甘油的化合物,b)中 从与富氧氧,空气或空气,c)任选的烃推进剂或蒸气,worin含氧化合物的分子氧/碳摩尔数的摩尔数之比选定加做可能的推进剂(O2 / C)从12时二十的范围内的 至0.60摩尔/摩尔,所述反应在范围从450至1100℃的温度下进行,在压力范围为1至50 ATM,用GHSV(气时空速)为FR OM 10,000至1,000,000 NL /(千克·h)中,在催化剂的存在下在固体载体上包括一种或多种过渡金属。