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131. 发明申请

WO1996034662A1 CATALYTIC-HYDROTHERMAL DISPOSAL PROCESS OF CHEMICAL MILITARY MATERIALS 审中-公开
标题翻译：用于催化水处置武器的化学物质
公开(公告)号：WO1996034662A1
公开(公告)日：1996-11-07
申请号：PCT/EP1995001710
申请日：1995-05-05
申请人： UHDE GMBH , HEDERER, Hartmut , THIAGARAJAN, Natarajan , ANDERSEN, Kjeld
发明人： UHDE GMBH
IPC分类号： A62D03/00
CPC分类号： A62D3/20 , A62D3/35 , A62D2101/02 , A62D2101/22 , A62D2101/24 , A62D2101/26
摘要： The chemical military materials include both the group of chemical agents used in chemical weapons and the group of fuels used in military aircraft. Chemical military materials must be disposed of at the end of their storage life. A continuous process is disclosed for that purpose. The chemical military materials are first suspended and/or dissolved in water and an alkaline catalyst is added to the aqueous mixture. A reaction mixture is thus obtained. The reaction mixture is brought to the reaction pressure by liquid feeding means, for example a high pressure pump. The reaction pressure lies between 100 bars and 1000 bars. The reaction mixture is heated up to a reaction temperature lower than the critical temperature of pure water. The usual reaction temperature is 350 DEG C. The reaction mixture heated up to the reaction temperature then flows over a catalyst bed that contains a catalytic zirconium dioxide. The catalysed reactions produce a hot mixture of converted materials that is substantially free of chemical military materials. The hot mixture of converted materials is cooled down and expanded in a separator, producing a gaseous phase with CO2, CH4 and H2, an oily phase and an aqueous phase with dissolved salts that may all be dumped.
摘要翻译：武器的化学物质包括该组的可作为化学武器的化学战剂，以及在军用飞机使用的组的燃料。武器的化学物质必须在其保质期后丢弃。这是在一个连续的过程中完成的。在此，化学武器材料首先悬浮在水和/或溶解的和水的混合物中加入碱性催化活性添加剂。使得进料混合物生产的。然后，与这样的液体资金进料混合物。带来作为高压泵向反应压力。反应压力为100巴和1000巴之间。将进料混合物被加热到低于纯水的临界温度的反应温度。典型的反应温度为350℃。加热到反应温度进料混合物通过催化剂床有催化作用的二氧化锆，其中所述热产生Konvertgemisch在催化的反应，这是无化学物质臂基本上通过。热Konvertgemisch被冷却并在分离器放松。被填埋在此，气相与CO 2，CH 4和H 2，油相和水相含有溶解的盐出现。

132. 发明申请

WO1996030084A1 PROCESS FOR THE DESTRUCTION OF HALOCARBONS 审中-公开
标题翻译：破坏哈尔金的过程
公开(公告)号：WO1996030084A1
公开(公告)日：1996-10-03
申请号：PCT/GB1996000684
申请日：1996-03-22
申请人： EA TECHNOLOGY LIMITED , HILLIS, Maurice, Raymond , GARDNER, David, Alan , AMBROSE, David, James
发明人： EA TECHNOLOGY LIMITED
IPC分类号： A62D03/00
CPC分类号： A62D3/32 , A62D3/36 , A62D2101/22 , B01D53/70
摘要： A process for the destruction of halocarbons comprises supporting metallic sodium at a temperature above its melting point on a solid particulate carrier material and contacting the halocarbon or halocarbons in a gaseous state with the supported sodium to react the halocarbon or halocarbons with the sodium to form elemental carbon and sodium halide or halides.
摘要翻译：用于破坏卤代烃的方法包括将金属钠在高于其熔点的温度下固定在固体颗粒载体材料上，并将气态的卤化碳或卤代烃与负载的钠接触以使卤代烃或卤代烃与钠反应形成元素碳和卤化钠或卤化物。

133. 发明申请

WO1996027412A1 FEED PROCESSING EMPLOYING DISPERSED MOLTEN DROPLETS 审中-公开
标题翻译：进料加工使用分散的润滑剂
公开(公告)号：WO1996027412A1
公开(公告)日：1996-09-12
申请号：PCT/US1996001954
申请日：1996-02-15
申请人： MOLTEN METAL TECHNOLOGY, INC. , WILKINSON, Mark, A. , NAGEL, Christopher, J.
发明人： MOLTEN METAL TECHNOLOGY, INC.
IPC分类号： A62D03/00
CPC分类号： A62D3/32 , A62D2101/20 , A62D2203/10 , B01J4/002 , B01J10/005 , B01J2219/0004 , B01J2219/0009 , B01J2219/00155 , C07C1/00 , C10B49/14 , C10B53/00 , C10J3/57 , C10J2200/152 , C10J2300/1238 , C10K1/002 , C10K1/007 , C10K1/02 , C10K1/024 , C10K1/026 , C10K1/08 , C10K1/20 , F27B3/04 , F27B3/08 , F27D3/1518 , F27D3/16 , F27D3/18 , F27D2003/162 , F27D2003/164 , F27M2001/05 , F27M2003/11 , Y10S423/12
摘要： A method and an apparatus produce a product in at least one phase from an organic component in a feed gas stream. The method includes forming a process zone including a process molten bath and a process gas space disposed over the process molten bath. Molten droplets of said molten bath are then dispersed across the process gas space. The feed gas stream is then directed into the process gas zone, wherein the organic component is exposed to said molten droplets, thereby converting at least a portion of the organic component to a product in at least one phase. The apparatus of the invention comprises a reactor which includes a gas formation section, having a feed inlet, and means for retaining a solid feed component within the gas formation section. The apparatus also includes a process section, disposed in the reactor, having a process gas space, a gas outlet and a process molten bath disposed therein. Further, means are provided for dispersing molten droplets of said molten bath across the process gas space to expose an organic component in the feed gas stream to molten droplets.
摘要翻译：方法和装置在进料气流中的有机组分的至少一个相中产生产物。该方法包括形成包括处理熔融浴的处理区和设置在处理熔融浴上的处理气体空间。然后将所述熔融浴的熔融液滴分散在工艺气体空间中。然后将进料气流导入工艺气体区，其中有机组分暴露于所述熔融液滴，从而将至少一部分有机组分转化成至少一个相中的产物。本发明的装置包括一个反应器，该反应器包括一个具有进料口的气体形成部分，以及用于将固体进料组分保持在气体形成部分内的装置。该设备还包括设置在反应器中的处理部分，其具有工艺气体空间，气体出口和设置在其中的工艺熔融浴。此外，提供了用于将熔融液滴的熔融液滴分散在工艺气体空间上以将进料气流中的有机组分暴露于熔融液滴的装置。

134. 发明申请

WO1996014901A1 TREATMENT PROCESS FOR CONTAMINATED WASTE 审中-公开
标题翻译：污染废物处理工艺
公开(公告)号：WO1996014901A1
公开(公告)日：1996-05-23
申请号：PCT/CA1995000527
申请日：1995-09-15
申请人： SOLUCORP INDUSTRIES LTD.
发明人： SOLUCORP INDUSTRIES LTD. , VOS, Rikkert, J.
IPC分类号： A62D03/00
CPC分类号： A62D3/33 , A62D2101/24 , A62D2101/43
摘要： A process for treating contaminated waste to stabilize environmentally harmful heavy metal. The contaminated waste is contacted with a mixture of (i) inorganic sulfide, (ii) calcium phosphate to prevent oxidation of the sulfide and (iii) calcium carbonate, the last acting as a base. Water is added to enhance mass transfer during the mixing. The calcium carbonate may be mixed with calcium oxide, to provide an additional base.
摘要翻译：处理受污染废物以稳定环境有害的重金属的过程。受污染的废物与（i）无机硫化物，（ii）磷酸钙的混合物接触以防止硫化物的氧化和（iii）最后作为碱的碳酸钙。加入水以增强混合期间的质量传递。碳酸钙可以与氧化钙混合，以提供额外的碱。

135. 发明申请

WO1995024945A1 TREATMENT OF UNDESIRABLE HALOGENATED ORGANIC COMPOUNDS 审中-公开
标题翻译：不可接受的有机化合物的处理
公开(公告)号：WO1995024945A1
公开(公告)日：1995-09-21
申请号：PCT/GB1995000552
申请日：1995-03-15
申请人： ESKOM , SEPPA, Raikko, Urmas, Ilari , ENGELBRECHT, Willem, Johannes , HEARN, Ian, Russell , VAN STADEN, Gideon, François , SCHNEIDER, David, François
发明人： ESKOM
IPC分类号： A62D03/00
CPC分类号： A62D3/40 , A62D2101/04 , A62D2101/22 , A62D2203/10
摘要： A process for treating an undesirable halogenated organic compound comprises heating a reactor wall by means of electrical induction or resistance heating; maintaining the reactor wall at a predetermined reaction temperature of at least 1500 DEG C; and allowing heat to radiate from the reactor wall into a reaction zone adjacent to, and in contact with, the reactor wall. A substantially solids-free gaseous feedstock comprising an undesirable halogenated organic compound is fed into the reaction zone. A non-oxidizing substantially solids-free gaseous atmosphere is maintained in the reaction zone. The compound is heated up sufficiently by means of the heat radiated by the reactor wall in order for it to pyrolyse and thus be transformed into more desirable components. A gaseous product comprising the more desirable components is withdrawn from the reaction zone.
摘要翻译：用于处理不期望的卤化有机化合物的方法包括通过电感应或电阻加热来加热反应器壁; 将反应器壁保持在至少1500℃的预定反应温度; 并且允许热量从反应器壁辐射到与反应器壁相邻并且与反应器壁接触的反应区中。将包含不期望的卤代有机化合物的基本不含固体的气态原料进料到反应区中。在反应区中保持非氧化性基本上不含固体的气体气氛。通过由反应器壁辐射的热量将化合物充分加热，以使其热解，从而转化为更理想的组分。包含更理想的组分的气态产物从反应区中排出。

136. 发明申请

WO1995023631A1 METHOD AND APPARATUS FOR REMEDIATING SOIL 审中-公开
标题翻译：补救土壤的方法和装置
公开(公告)号：WO1995023631A1
公开(公告)日：1995-09-08
申请号：PCT/US1995002695
申请日：1995-03-01
申请人： SERL HIGH INTENSITY SOIL WASHING, LTD. , SHORTHOUSE, Barry, Owen
发明人： SERL HIGH INTENSITY SOIL WASHING, LTD.
IPC分类号： A62D03/00
CPC分类号： B09C1/02 , Y10S588/90
摘要： A method and apparatus (10) for treating contaminated soil by breaking up the contaminated soil and separating the soil by particle size (14) and passing the smaller sized soil particles through a series of soil (20, 30) washes in a first direction while directing the washing water in a second direction which is opposite to the first. The apparatus is preferably portable and provides for a continuous cleaning of the soil and recycling of the water in order to allow the decontaminated soil to be immediately returned to the ground.
摘要翻译：一种用于通过分解污染土壤并通过粒径分离土壤（14）并使较小尺寸的土壤颗粒通过一系列土壤（20,30）沿第一方向洗涤来处理污染的土壤的方法和装置（10），同时在与第一方向相反的第二方向上引导洗涤水。该装置优选是便携式的，并且提供对土壤的连续清洁和水的再循环，以便使净化的土壤立即返回到地面。

137. 发明申请

WO1995022375A1 PROCESS FOR THE TREATMENT OF CONTAMINATED MATERIAL 审中-公开
标题翻译：污染物处理工艺
公开(公告)号：WO1995022375A1
公开(公告)日：1995-08-24
申请号：PCT/GB1995000287
申请日：1995-02-13
申请人： BRITISH NUCLEAR FUELS PLC , ECCLES, Harry
发明人： BRITISH NUCLEAR FUELS PLC
IPC分类号： A62D03/00
CPC分类号： C22B3/18 , B09C1/02 , B09C1/10 , C02F3/345 , C02F11/004 , Y02P10/234
摘要： A process for the decontamination of a medium comprising a material contaminated with one or more organic species and one or more metal species comprises the steps of treating a body of the said medium by a process which breaks down the organic contaminant(s) by or through the action of microbial agents followed by treating the same body with microbially produced sulphuric acid so as to solubilise and leach the metal species as a metal sulphate and treating the leached metal sulphate by a bioprecipitation process which converts the said sulphate to one or more insoluble metal sulphides.
摘要翻译：一种用于对包含被一种或多种有机物质和一种或多种金属物质污染的材料进行净化的介质的去污的方法包括以下步骤：通过或通过分解有机污染物的方法处理所述介质的主体微生物剂的作用，随后用微生物产生的硫酸处理相同的体系，以便以金属硫酸盐溶解和浸出金属物质，并通过生物沉淀法处理浸出的金属硫酸盐，所述生物沉淀法将所述硫酸盐转化为一种或多种不溶性金属硫化物。

138. 发明申请

WO1995018652A1 SODIUM DISPERSION AND ORGANOHALIDE REACTION PROCESSES 审中-公开
标题翻译：钠溶液和有机金属反应过程
公开(公告)号：WO1995018652A1
公开(公告)日：1995-07-13
申请号：PCT/CA1994000001
申请日：1994-01-04
申请人： NEOS TECHNOLOGY INC. , MACAS, Tadas, S.
发明人： NEOS TECHNOLOGY INC.
IPC分类号： A62D03/00
CPC分类号： A62D3/34 , A62D2101/22
摘要： A process for the production of an alkali dispersion includes charging a mixing vessel with a solid alkali metal, a liquid which is inert to the alkali metal and a grinding media. The vessel is connected to a vibrating driver which is vibrated until the alkali metal is ground by the media finely enough to form a dispersion in the liquid. Preferably the driver is a resonant driver which is vibrated at the resonant frequency of the driver. Mineral oils or other liquids containing organohalides such as PCBs can be used as a liquid which is treated during the grinding by the organohalide reacting with the alkali metal.
摘要翻译：制备碱性分散体的方法包括：将固体碱金属，对碱金属呈惰性的液体和研磨介质填充混合容器。该容器连接到振动驱动器，该振动驱动器振动直到碱金属被介质研磨成足以在液体中形成分散体。优选地，驱动器是以驱动器的谐振频率振动的谐振驱动器。含有有机卤化物（如PCB）的矿物油或其它液体可用作在研磨期间通过与碱金属反应的有机卤化物处理的液体。

139. 发明申请

WO1995017927A1 COMPOSITION AND PROCESS FOR REDUCING OR PREVENTING METAL AND ACID CONTAMINATION IN ROCK DRAINAGE 审中-公开
标题翻译：用于减少或防止岩石渗漏中的金属和酸污染的组合物和方法
公开(公告)号：WO1995017927A1
公开(公告)日：1995-07-06
申请号：PCT/US1994014565
申请日：1994-12-16
申请人： BUCKMAN LABORATORIES INTERNATIONAL, INC.
发明人： BUCKMAN LABORATORIES INTERNATIONAL, INC. , KRAVETZ, Mark, E. , McNEEL, Thomas, E.
IPC分类号： A62D03/00
CPC分类号： A62D3/33 , A62D2101/43 , B09C1/08 , C02F2103/06
摘要： The formation of contaminants in drainage from waste rock or tailings is reduced or prevented by contacting the waste rock or tailings with an organic or inorganic sulfur compound in combination with a neutralizing agent, a fixating agent or a neutralizing agent and a fixating agent. When an organic or inorganic sulfur compound is used with the neutralizing agent or fixating agent, the amount of neutralizing agent and/or the amount of fixating agent required to reduce or prevent the formation of contaminants in drainage from waste rock or tailings is substantially reduced. The amount of sulfur compound applied to the waste rock or tailings can be about 1 % to 5 % by weight and the amount of neutralizing agent and/or fixating agent applied to the waste rock or tailings can be about 1 % to about 15 % by weight, based on the weight of the waste rock or tailings. The organic or inorganic sulfur compounds are those having a sulfhydryl group or an ionized sulfhydryl group or a sulfur compound which is capable of producing a sulfhydryl group or an ionized sulfhydryl group.
摘要翻译：通过将废石或尾矿与有机或无机硫化合物与中和剂，固定剂或中和剂和固定剂组合使其接触，减少或防止从废石或尾矿排出的污染物的形成。当有机或无机硫化合物与中和剂或固定剂一起使用时，中和剂的量和/或减少或防止从废石或尾矿排水中形成污染物所需的固着剂的量大大减少。施加到废石或尾矿的硫化合物的量可以为约1重量％至5重量％，并且施用于废石或尾矿的中和剂和/或固化剂的量可以为约1％至约15％，通过重量，基于废石或尾矿的重量。有机或无机硫化合物是具有巯基或离子化巯基的化合物或能够产生巯基或电离巯基的硫化合物。

140. 发明申请

WO1995011726A1 SELECTIVE OXIDATION CATALYSTS FOR HALOGENATED ORGANICS 审中-公开
标题翻译：选择性氧化催化剂用于氢化有机物
公开(公告)号：WO1995011726A1
公开(公告)日：1995-05-04
申请号：PCT/US1994012244
申请日：1994-10-26
申请人： THE UNIVERSITY OF AKRON
发明人： THE UNIVERSITY OF AKRON , GREENE, Howard, L. , RAMACHANDRAN, Balachandran , CHATTERJEE, Sougato
IPC分类号： A62D03/00
CPC分类号： A62D3/38 , A62D2101/22 , A62D2101/28 , B01D53/8662 , B01J29/061
摘要： The invention relates to a process and a catalyst composition for the destruction of volatile organic compounds (VOCs). The process includes the step of contacting the VOCs with an oxygen-containing gas in the presence of a catalyst which is a metal-exchanged, metal-impregnated aluminosilicate zeolite with at least one exchanged metal in the zeolite being selected from the group consisting of Ti, V, Cr, Co, Ni, Cu, Fe, Mo, Mn, Pd, and Pt, and at least one impregnated metal in the zeolite being selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Mo, Pd and Pt, and wherein the difference between the exchanged metal and the impregnated metal varies the temperature necessary to promote oxidation of the compounds and for a contact time sufficient to oxidize the compounds. The process reaction temperature can vary from about 100 DEG C to about 650 DEG C and the contact time can vary from about 0.01 to 20 seconds. Preferably, the reaction temperature is from about 150 DEG C to about 450 DEG C and the contact time is from about 0.1 to 1.0 seconds. The CO/CO2 ratio and the Cl2/HCl ratio in the gaseous effluent can be varied through selection of at least two impregnating metals with at least one exchanged metal in the aluminosilicate zeolite or by the use of at least one impregnating metal with at least two exchanged metals in the aluminosilicate zeolite.
摘要翻译：本发明涉及用于破坏挥发性有机化合物（VOC）的方法和催化剂组合物。该方法包括在催化剂存在下使VOC与含氧气体接触的步骤，催化剂是金属交换的金属浸渍的硅铝酸盐沸石，沸石中的至少一种交换金属选自Ti ，V，Cr，Co，Ni，Cu，Fe，Mo，Mn，Pd和Pt，沸石中的至少一种浸渍金属选自Ti，V，Cr，Mn，Fe，Co， Ni，Cu，Mo，Pd和Pt，并且其中交换的金属和浸渍金属之间的差异改变促进化合物氧化所需的温度和足以氧化化合物的接触时间。工艺反应温度可以在约100℃至约650℃之间变化，接触时间可以在约0.01至20秒之间变化。优选地，反应温度为约150℃至约450℃，接触时间为约0.1至1.0秒。气态流出物中的CO / CO 2比和Cl 2 / HCl比可以通过在铝硅酸盐沸石中选择至少两种浸渍金属与至少一种交换的金属或通过使用至少一种浸渍金属至少两种来改变在铝硅酸盐沸石中交换金属。

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