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    • 131. 发明专利
    • DE3886881D1
    • 1994-02-17
    • DE3886881
    • 1988-10-14
    • MATSUSHITA ELECTRIC IND CO LTD
    • OGAWA KAZUFUMI
    • C08F38/00
    • The gist of the process for producing a polyacetylene of the present invention is a process by which a polyacetylene which is stable even in an atmosphere containing oxygen can be produced by spreading on water surface a solution of a fatty acid series substance containing an acetylene or diacetylene group dissolved in an organic solvent, evaporating the organic solvent, gathering up molecules of the substance containing an acetylene or diacetylene group which remain on the water surface, in the water surface direction on the water surface by means of a barrier, and polymerizing the molecules in a state of monomolecular film on the water surface, i.e., Langmuir (L) film by the use of radiation such as X-rays, electron beams, gamma -rays, etc. While applying a predetermined surface pressure, or by building up Langmuir-Blodgett (LB) films of an acetylene derivative into a film on a predetermined substrate under a definite surface pressure, and subjecting the LB films to polymerization by the use of such radiation as described above. That is, the present inventors have found that a straight-chain, ultra-high-molecular-weight (ultra-conjugated, high-molecular-weight) polyacetylene having a continuous conjugated system can be produced by subjecting molecules of an acetylene derivative to radiation polymeriztation while compressing the same under a definite surface pressure. Furthermore, the present inventors have found that when a DC bias is applied in the surface direction during the radiation polymerization of the L film or the building-up of the LB films into a film, a polyacetylene having a longer continuous conjugated system can be obtained.
    • 139. 发明专利
    • DE60223435D1
    • 2007-12-27
    • DE60223435
    • 2002-02-27
    • MATSUSHITA ELECTRIC IND CO LTD
    • OGAWA KAZUFUMI
    • G11B7/24G11B7/244G11B7/245G11B7/25G11B7/254G11B7/2542G11B7/257G11B7/258G11B7/259
    • An optical recording film (5,5',5") includes a chemisorptive thin film (7) with orienting properties fixed directly or through a primer layer (2) to a substrate (1) surface, and a coating formed on a surface of the chemisorptive thin film (7). The coating has an initial molecule orientation attained by aligning a group of polymerizable molecules in a predetermined direction on the surface of the chemisorptive thin film (7), and polymerizing the polymerizable molecules to one another. Regions with changed initial molecule orientation and regions with unchanged initial molecule orientation of the coating are formed when selectively irradiating the coating with light (6) that changes the initial molecule orientation, thus making optical information recording possible. It is also possible to introduce photodegrading functional groups into the coating. By introducing functional groups whose orientation is changed by light or functional group that are degraded by light, an optical recording film allowing optical recording and an optical recording medium using the same are provided.