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    • 136. 发明专利
      CA2642787A1 CYCLOALKYLPHENYL SUBSTITUTED CYCLIC KETOENOLS 未知
    • CYCLOALKYLPHENYL SUBSTITUTED CYCLIC KETOENOLS
    • CA2642787A1
    • 2007-08-30
    • CA2642787
    • 2007-02-08
    • BAYER CROPSCIENCE AG
    • ANGERMANN ALFRED , FISCHER REINER , FRANKEN EVA-MARIA , ARNOLD CHRISTIAN , ROSINGER CHRISTOPHER HUGH , HILLS MARTIN JEFFREY , BRETSCHNEIDER THOMAS , LEHR STEFAN , FEUCHT DIETER , MALSAM OLGA , BOJACK GUIDO , KEHNE HEINZ
    • C07C49/225 , A01N43/08 , A01N43/36 , A01N43/56 , C07C57/46 , C07C233/00 , C07D207/36 , C07D231/54 , C07D307/60
    • Cyclic keto enol derivatives (I) are new. Cyclic keto enol derivatives of formula (I) are new. In (I): J = optionally substituted (OS) (hetero)cycloalkyl; X, Y' = H, alkyl, halo, haloalkyl, alkoxy or haloalkoxy; m = 1-3; CKE = a cyclic keto enol group of formula (1)-(10). A = e.g. H; alkyl, alkenyl or alkoxyalkyl; B' = e.g. H, alkyl or alkoxyalkyl; or D' = H or OS alkyl, alkenyl or alkynyl; Q 1> = e.g. H, alkyl or alkoxyalkyl; Q 2>, Q 4>, Q 5>, Q 6> = H or alkyl; Q 3> = e.g. H, alkyl, alkoxyalkyl, alkylthioalkyl, cycloalkyl or phenyl; G = e.g. H, COR 1> or E; E = a metal ion or ammonium; R 1> = e.g. alkyl, alkenyl, alkoxyalkyl or alkylthioalkyl. Provided that at least 1 of J, X or Y' = is in the 2-position of the phenyl moiety and is not H. Full definitions are given in the Definitions field. Independent claims are also included for: (1) a process for preparing (I); (2) composition comprising at least one compound (I) and at least one safener comprising a compound for formula (IIa-e), or one of 57 specific compounds listed in the specification; and (3) starting materials and intermediates of formulae (II), (III), (IV), (VI), (VIII), (IX), (XII), (XIII), (XIV), (XXVIII), (XXVII), (XXXII), (XXXIV), (XXXVI), (XI), (XXXVII), (XXXVIII), (XLI), (XLII) and (LXVI). In the safeners (IIa-e): m = 0-5; A 1> = a group of formula (a)-(d); n = 0-5; A 2> = OS 1-2C alkanediyl; R 14>, R 15> = e.g. OH or SH; R 16> = OS 1-4C alkyl; R 17>, R 18> = e.g. H or OS 1-6C alkyl, 2-6C alkenyl or 2-6C alkynyl; R 19> = e.g. H, CN or halo; R 20> = e.g. H or OS 1-6C alkyl; R 21> = e.g. H, CN or halo; X 1> = e.g. nitro, CN or halo; X 2>, X 3> = H or as for X 1>; t = 0-5; v = 0-5 (sic); R 22>, R 23> = H or 1-4C alkyl R 24> = e.g. H or OS 1-6C alkyl or 1-6C alkoxy; R 25> = e.g. H or OS 1-4C alkyl; R 26> = as for R 25>; or OS phenyl; and X 4>, X 5> = e.g. nitro, CN or COOH. Full definitions are included in the Definitions field. In the claimed starting materials and intermediates: Ar = phenyl substituted with X, Y' and (J) m; R 8> = alkyl; Ar' = phenyl optionally monosubstituted with halo, alkyl or alkoxy; Hal = halo; Z = a leaving group; U' = OR 8>, V'=H, halo, alkyl or alkoxy; and all other groups are as listed for (I). [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] ACTIVITY : Herbicide; Insecticide; Arachnicide; Molluscicide; Anthelmintic; Protozoacide; Nematocide. In a post-emergence test, 3-(4-cyclopropyl-2-ethyl-6-methyl-phenyl)-8-methoxy-2-oxo-1-aza-spiro[4.5]dec-3-en-4-yl carbonate ethyl ester gave at least 90% control of Lolium multiflorum and Setaria viridis at an application rate of 320 g/ha. MECHANISM OF ACTION : None given.
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Espacenet 法律信息 同族专利 专利引用
    • 137. 发明专利
      AU2007218300A1 Cycloalkylphenyl substituted cyclic ketoenols 未知
    • Cycloalkylphenyl substituted cyclic ketoenols
    • AU2007218300A1
    • 2007-08-30
    • AU2007218300
    • 2007-02-08
    • BAYER CROPSCIENCE AG
    • ANGERMANN ALFRED , ROSINGER CHRISTOPHER HUGH , KEHNE HEINZ , FISCHER REINER , ARNOLD CHRISTIAN , FEUCHT DIETER , HILLS MARTIN JEFFREY , LEHR STEFAN , BRETSCHNEIDER THOMAS , MALSAM OLGA , BOJACK GUIDO , FRANKEN EVA-MARIA
    • C07C49/225 , A01N43/08 , A01N43/36 , A01N43/56 , C07C57/46 , C07C233/00 , C07D207/36 , C07D231/54 , C07D307/60
    • Cyclic keto enol derivatives (I) are new. Cyclic keto enol derivatives of formula (I) are new. In (I): J = optionally substituted (OS) (hetero)cycloalkyl; X, Y' = H, alkyl, halo, haloalkyl, alkoxy or haloalkoxy; m = 1-3; CKE = a cyclic keto enol group of formula (1)-(10). A = e.g. H; alkyl, alkenyl or alkoxyalkyl; B' = e.g. H, alkyl or alkoxyalkyl; or D' = H or OS alkyl, alkenyl or alkynyl; Q 1> = e.g. H, alkyl or alkoxyalkyl; Q 2>, Q 4>, Q 5>, Q 6> = H or alkyl; Q 3> = e.g. H, alkyl, alkoxyalkyl, alkylthioalkyl, cycloalkyl or phenyl; G = e.g. H, COR 1> or E; E = a metal ion or ammonium; R 1> = e.g. alkyl, alkenyl, alkoxyalkyl or alkylthioalkyl. Provided that at least 1 of J, X or Y' = is in the 2-position of the phenyl moiety and is not H. Full definitions are given in the Definitions field. Independent claims are also included for: (1) a process for preparing (I); (2) composition comprising at least one compound (I) and at least one safener comprising a compound for formula (IIa-e), or one of 57 specific compounds listed in the specification; and (3) starting materials and intermediates of formulae (II), (III), (IV), (VI), (VIII), (IX), (XII), (XIII), (XIV), (XXVIII), (XXVII), (XXXII), (XXXIV), (XXXVI), (XI), (XXXVII), (XXXVIII), (XLI), (XLII) and (LXVI). In the safeners (IIa-e): m = 0-5; A 1> = a group of formula (a)-(d); n = 0-5; A 2> = OS 1-2C alkanediyl; R 14>, R 15> = e.g. OH or SH; R 16> = OS 1-4C alkyl; R 17>, R 18> = e.g. H or OS 1-6C alkyl, 2-6C alkenyl or 2-6C alkynyl; R 19> = e.g. H, CN or halo; R 20> = e.g. H or OS 1-6C alkyl; R 21> = e.g. H, CN or halo; X 1> = e.g. nitro, CN or halo; X 2>, X 3> = H or as for X 1>; t = 0-5; v = 0-5 (sic); R 22>, R 23> = H or 1-4C alkyl R 24> = e.g. H or OS 1-6C alkyl or 1-6C alkoxy; R 25> = e.g. H or OS 1-4C alkyl; R 26> = as for R 25>; or OS phenyl; and X 4>, X 5> = e.g. nitro, CN or COOH. Full definitions are included in the Definitions field. In the claimed starting materials and intermediates: Ar = phenyl substituted with X, Y' and (J) m; R 8> = alkyl; Ar' = phenyl optionally monosubstituted with halo, alkyl or alkoxy; Hal = halo; Z = a leaving group; U' = OR 8>, V'=H, halo, alkyl or alkoxy; and all other groups are as listed for (I). [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] ACTIVITY : Herbicide; Insecticide; Arachnicide; Molluscicide; Anthelmintic; Protozoacide; Nematocide. In a post-emergence test, 3-(4-cyclopropyl-2-ethyl-6-methyl-phenyl)-8-methoxy-2-oxo-1-aza-spiro[4.5]dec-3-en-4-yl carbonate ethyl ester gave at least 90% control of Lolium multiflorum and Setaria viridis at an application rate of 320 g/ha. MECHANISM OF ACTION : None given.
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Espacenet 法律信息 同族专利 专利引用
    • 140. 发明专利
      AU2006331050A1 3'-alkoxy-spirocyclopentyl-substituted tetramic and tetronic acids 未知
    • 3'-alkoxy-spirocyclopentyl-substituted tetramic and tetronic acids
    • AU2006331050A1
    • 2007-07-05
    • AU2006331050
    • 2006-12-11
    • BAYER CROPSCIENCE AG
    • DITTGEN JAN , LEHR STEFAN , ROSINGER CHRISTOPHER HUGH , ARNOLD CHRISTIAN , MALSAM OLGA , KEHNE HEINZ , HILLS MARTIN JEFFREY , FRANKEN EVA-MARIA , FISCHER REINER , FEUCHT DIETER , BOJACK GUIDO
    • C07D209/54 , A01N43/08 , A01N43/38 , C07C61/06 , C07C233/45 , C07D307/94
    • Spiro-cyclopentyl-pyrrole or -furan derivatives (I) are new. Spiro-cyclopentyl-pyrrole or -furan derivatives of formula (I) are new. W' : H, (halo)alkyl, alkenyl, alkynyl, halo, (halo)alkoxy or cyano; X' : halo, (halo)alkyl, alkenyl, alkynyl, (alkoxy)alkoxy, haloalkoxy or cyano; Y' : as W' or optionally substituted phenyl or heteroaryl; Z' : H, halo, (halo)alkyl, (halo)alkoxy or cyano; A : optionally substituted alkanediyl or cycloalkyl, optionally substituted and/or optionally interrupted by a heteroatom; B' : H, alkyl, alkenyl, (alkoxy)alkoxy, phenyl or heteroaryl (all optionally substituted) or cycloalkyl, optionally substituted and/or interrupted by heteroatoms and/or CO; or A = bond and B = H; D' : NH or O; Q 1>H, alkyl, alkoxy, alkoxyalkyl or alkylthioalkyl (all optionally substituted), cycloalkyl (optionally substituted and optionally having one CH 2 replaced by heteroatom), or phenyl, heteroaryl, phenalkyl or heteroarylalkyl (all optionally substituted); Q 2>H or alkyl, or Q 1> and Q 2> together form an optionally substituted 3-6C ring, optionally interrupted by a heteroatom; G : H, -COR 1>, -CL-MR 2>, -SO 2R 3>, -P(=L)R 4>R 5>, E or -C(=L)-NR 6>R 7>; E : metal or ammonium ion; L and M : O or S; R 1>(alkoxy)alkyl, alkenyl, alkylthioalkyl or polyalkoxyalkyl (all optionally substituted by halo or cyano), cycloalkyl or heterocyclyl (both optionally substituted by halo, alkyl or alkoxy) or phenyl, phenalkyl, heteroaryl, phenoxyalkyl or heteroaryloxyalkyl (all optionally substituted); R 2>alkyl, alkenyl or (poly)alkoxyalkyl (all optionally substituted by halo or cyano), or optionally substituted cycloalkyl, phenyl or benzyl; R 3>-R 5>alkyl, alkoxy, (di)alkylamino, alkylthio, alkenylthio or cycloalkylthio (all optionally halo substituted), or phenyl, benzyl, phenoxy or phenylthio (all optionally substituted); R 6> and R 7>H, (cyclo)alkyl, alkenyl, alkoxy or alkoxyalkyl (all optionally substituted by halo or cyano), phenyl or benzyl (both optionally substituted) or together complete an optionally substituted ring that may include O or S. Independent claims are included for the following: (1) Several methods for preparing (I); and (2) the new intermediates (II), (III), (XVI) and (XVIII). [Image] [Image] [Image] ACTIVITY : Herbicide; Selective Herbicide; Pre-emergence Herbicide; Post-emergence Herbicide; Plant Antifungal; Insecticide; Acaricide; Nematocide; Molluscicide; Protozoacide; Antifouling; Plant Growth Regulant. MECHANISM OF ACTION : None given.
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Espacenet 法律信息 同族专利 专利引用
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