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121. 发明申请

US20120220792A1 PROCESS FOR PRODUCING ALDEHYDES OR KETONES BY OXIDIZING ALCOHOLS WITH OXYGEN 有权
标题翻译：通过用氧气氧化醇来生产醛酮或酮的方法
公开(公告)号：US20120220792A1
公开(公告)日：2012-08-30
申请号：US13497960
申请日：2010-07-30
申请人： Shengming Ma , Jinxian Liu , Jinqiang Kuang , Yu Liu , Yuli Wang , Qiong Yu , Weiming Yuan , Suhua Li , Bo Chen , Jiajia Cheng , Baoqiang Wan , Juntao Ye , Shichao Yu
发明人： Shengming Ma , Jinxian Liu , Jinqiang Kuang , Yu Liu , Yuli Wang , Qiong Yu , Weiming Yuan , Suhua Li , Bo Chen , Jiajia Cheng , Baoqiang Wan , Juntao Ye , Shichao Yu
IPC分类号： C07F7/18 , C07F7/08 , C07C201/12 , C07C45/38 , C07C45/39
CPC分类号： C07C45/38 , B01J31/006 , B01J31/28 , B01J2231/763 , B01J2531/842 , C07C45/39 , C07C201/12 , C07C2601/14 , C07C2601/16 , C07F7/1804 , C07C47/232 , C07C47/21 , C07C49/203 , C07C49/217 , C07C49/235 , C07C49/207 , C07C49/794 , C07C49/807 , C07C49/80 , C07C49/84 , C07C47/222 , C07C47/277 , C07C49/683 , C07C47/55 , C07C47/575 , C07C49/78 , C07C47/02 , C07C49/04 , C07C49/403 , C07C205/44
摘要： Provided is a process for producing aldehydes or ketones by oxidizing alcohols with oxygen, which comprises oxidizing alcohols to aldehydes or ketones in an organic solvent at room temperature with oxygen or air as an oxidant, wherein ferric nitrate (Fe(NO3)3.9H2O), 2,2,6,6-tetramethylpiperidine N-oxyl (TEMPO) and an inorganic chloride are used as catalysts, the reaction time is 1-24 hours, and the molar ratio of said alcohols, 2,2,6,6-tetramethylpiperidine N-oxyl and the inorganic chloride is 100:1˜10:1˜10:1˜10. The present process has the advantages of high yield, mild reaction conditions, simple operation, convenient separation and purification, recoverable solvents, substrates used therefor being various and no pollution, and therefore it is adaptable to industrialization.
摘要翻译：本发明提供一种通过用氧氧化醇来生产醛或酮的方法，该方法包括在室温下用氧气或空气作为氧化剂将醇氧化成有机溶剂中的醛或酮，其中硝酸铁（Fe（NO 3）3·4H 2 O）使用2,2,6,6-四甲基哌啶N-氧基（TEMPO）和无机氯化物作为催化剂，反应时间为1-24小时，所述醇，2,2,6,6-四甲基哌啶的摩尔比 N-氧基和无机氯化物为100:1〜10:1〜10:1〜10。本发明方法具有产量高，反应条件温和，操作简便，分离纯化方便，可回收溶剂，各种基材不污染，适用于工业化。

122. 发明授权

US07947622B2 Aerobic catalysts for alcohol oxidation in organic solvents and in supercritical carbon dioxide, process for the production thereof, and their use in oxidative conversions 失效
标题翻译：在有机溶剂和超临界二氧化碳中醇氧化的好氧催化剂，其生产方法及其在氧化转化中的应用
公开(公告)号：US07947622B2
公开(公告)日：2011-05-24
申请号：US10577367
申请日：2004-10-28
申请人： Mario Pagliaro , Rosaria Ciriminna
发明人： Mario Pagliaro , Rosaria Ciriminna
IPC分类号： B01J31/12
CPC分类号： B01J37/033 , B01J21/08 , B01J23/462 , B01J35/1023 , B01J35/1038 , B01J37/036 , C07C45/38 , C07C45/39 , Y02P20/544 , Y02P20/582 , C07C47/54 , C07C49/04 , C07C47/02 , C07C47/232 , C07C49/78 , C07C49/403
摘要： Nanohybrid sol-gel materials, based on silica organically modified (ormosil) and doped with the ruthenium species tetra-n-propylammonium perruthenate (TPAP) are highly efficient catalysts for the selective oxidation of alcohols to carbonyls with oxygen at low pressure, in organic solvents as well as in carbon dioxide in supercritical state. Novel, highly active and stable materials are the fluorinated ormosils. Optimal conditions for the preparation and use thereof in liquid-phase as well as in supercritical CO2 were set by studying the structure-activity relationships of the materials, with particular reference to the surface hydrophobic/hydrophilic properties and to the textural ones.
摘要翻译：纳米杂交溶胶 - 凝胶材料，基于二氧化硅有机改性（ormosil）并掺杂钌物质四正丙基铵过钌酸盐（TPAP）是用于在低压下在有机溶剂中将醇选择性氧化为羰基的高效催化剂以及超临界状态的二氧化碳。新型，高活性和稳定的材料是氟化乳胶。通过研究材料的结构 - 活性关系，特别是表面疏水/亲水性质和结构特性，确定了在液相和超临界CO2中制备和使用其最佳条件。

123. 发明授权

US07897817B2 Resin-platinum complex and resin-supported platinum cluster catalyst 有权
标题翻译：树脂 - 铂络合物和树脂负载的铂簇催化剂
公开(公告)号：US07897817B2
公开(公告)日：2011-03-01
申请号：US11885734
申请日：2005-12-01
申请人： Yasuhiro Uozumi , Yoichi Yamada , Takayasu Arakawa
发明人： Yasuhiro Uozumi , Yoichi Yamada , Takayasu Arakawa
IPC分类号： C07C49/00
CPC分类号： C07C45/39 , B01J23/42 , B01J31/068 , B01J31/1658 , B01J31/1805 , B01J31/2291 , B01J31/4038 , B01J31/4069 , B01J35/0013 , B01J35/006 , B01J2231/70 , B01J2531/828 , C07C51/235 , Y02P20/584 , C07C49/413 , C07C49/217 , C07C49/78 , C07C49/04 , C07C49/76 , C07C57/44
摘要： To provide a catalyst that has sufficient catalytic activity as a platinum catalyst and yet is readily separated from a target material and can be reused. A resin-supported platinum cluster catalyst containing a resin layer comprising a platinum particle core, the average diameter of which is from 1 nm to 10 nm, and a compound containing nitrogen (general formula R1NH2) surrounding the core. This catalyst can be obtained by forming a platinum complex from a compound containing nitrogen represented by the general formula R1NR22 (in the formula, R1 represents a carrier with a hydrophilic molecular chain and R2 represents a hydrogen atom, an alkyl group and the like) and a platinum compound represented by the general formula M(PtX4-nR3n)m (in the formula, M represents an alkali metal and the like, X represents a halogen atom and the like, R3 represents an unsaturated organic ligand, n represents an integer from zero to four and m represents an integer indicating the electrical charge of the metal, M) and allowing this platinum complex to react with a reducing agent in an aqueous solvent.
摘要翻译：提供具有作为铂催化剂的足够的催化活性并且容易与目标材料分离并且可以重复使用的催化剂。含有包含平均直径为1nm〜10nm的铂粒子核心的树脂层的树脂负载的铂簇催化剂和包含核的氮（通式R 1 NH 2）的化合物。该催化剂可以通过由通式R1NR22表示的含氮化合物形成铂络合物（式中，R1表示具有亲水性分子链的载体，R2表示氢原子，烷基等）和由通式M（PtX4-nR3n）m表示的铂化合物（式中，M表示碱金属等，X表示卤素原子等，R3表示不饱和有机配体，n表示来自 0至4，m表示金属的电荷的整数，M），并允许该铂络合物在水性溶剂中与还原剂反应。

124. 发明申请

US20080183020A1 Catalytic conversion of alcohols to aldehydes and ketones 审中-公开
标题翻译：醇转化为醛和酮的催化转化
公开(公告)号：US20080183020A1
公开(公告)日：2008-07-31
申请号：US11698089
申请日：2007-01-26
申请人： Melvin Keith Carter
发明人： Melvin Keith Carter
IPC分类号： C07C41/01 , C07C47/00 , C07C49/00
CPC分类号： C07C41/01 , C07C45/38 , C07C45/39 , C07C47/06 , C07C49/08 , C07C43/13
摘要： Catalytic reactions are taught for air or oxygen oxidative chemical conversion of primary alcohols to aldehydes, glycol ethers and related products and secondary alcohols to ketones and related products at ambient pressure. The catalytic process converts ethanol to acetaldehyde and 2-ethoxyethanol, n-propanol to propionaldehyde and its glycol ethers, 2-propanol to acetone, and other reactants to similar products. The catalysts are based on molecular strings of di-, tri- and/or poly- groups of transition metal complexes possessing a degree of symmetry. Laboratory results have demonstrated [manganese (II)]2, [cobalt (II)]2, [vanadium (II)]2 and similar families of catalysts to be effective for oxidative catalytic conversion of primary alcohols to products comprising related aldehydes and glycol ethers, and secondary alcohols to products comprising ketones and related products.
摘要翻译：催化反应被教导用于在环境压力下将伯醇与醛，二醇醚和相关产物以及仲醇在空气或氧气氧化化学转化成酮和相关产物。催化过程将乙醇转化为乙醛和2-乙氧基乙醇，正丙醇转化为丙醛及其二醇醚，2-丙醇至丙酮，以及其他类似产物的反应物。催化剂基于具有一定程度的对称性的过渡金属络合物的二，三和/或多基团的分子串。实验室结果已经证明[锰（II）] 2 ，[钴（II）] 2'，[钒（II）] 2和类似物对于将伯醇氧化催化转化成含有相关醛和乙二醇醚的产物的有效催化剂家族，以及仲醇转化为包含酮类和相关产品的产品。

125. 发明申请

US20080091044A1 Oxidation Catalyst And Oxidation Method 有权
标题翻译：氧化催化剂和氧化法
公开(公告)号：US20080091044A1
公开(公告)日：2008-04-17
申请号：US11666240
申请日：2005-11-17
申请人： Koshiro Yokota , Tatsuo Yamaguchi , Toru Watanabe
发明人： Koshiro Yokota , Tatsuo Yamaguchi , Toru Watanabe
IPC分类号： C07C27/10 , C07B41/00
CPC分类号： C07C67/40 , B01J21/08 , B01J21/18 , B01J23/44 , B01J23/628 , B01J31/121 , B01J2231/70 , C07B41/00 , C07C27/12 , C07C29/50 , C07C45/33 , C07C45/38 , C07C45/39 , C07C67/39 , C07C69/54 , C07C69/14 , C07C69/06
摘要： The present invention provides a method for oxidizing a hydrocarbon, an alcohol or an aldehyde, which comprises: oxidizing a hydrocarbon, an alcohol or an aldehyde to an alcohol, an aldehyde, a carboxylic acid or a carboxylate ester corresponding thereto, in a liquid phase having: a region in which oxygen is substantially present; and a region in which oxygen is substantially absent, in the presence of a catalyst containing a palladium, wherein the region in which oxygen is substantially absent is 0.1 to 10% by volume with respect to a total of the region in which oxygen is substantially present and the region in which oxygen is substantially absent.
摘要翻译：本发明提供了一种用于氧化烃，醇或醛的方法，其包括：将烃，醇或醛氧化成液相中的醇，醛，羧酸或与其对应的羧酸酯具有：基本上存在氧的区域; 以及在含有钯的催化剂的存在下，基本上不存在氧的区域，其中基本上不存在氧的区域相对于基本上存在氧的区域的总和为0.1-10体积％和氧基本上不存在的区域。

126. 发明授权

US07161000B2 Method for producing phenol condensate 有权
标题翻译：生产苯酚缩合物的方法
公开(公告)号：US07161000B2
公开(公告)日：2007-01-09
申请号：US10854334
申请日：2004-05-27
申请人： Hideyuki Higashimura , Eiichi Kotake , Masaaki Kubota , Shiro Kobayashi
发明人： Hideyuki Higashimura , Eiichi Kotake , Masaaki Kubota , Shiro Kobayashi
IPC分类号： C07D225/00 , C07C39/12
CPC分类号： C07C49/753 , C07C45/39
摘要： Provided is a method for producing a phenol condensate by oxidative condensation of a phenol compound not having a substituted group on at least one ortho-position, in the presence of a specific complex (II) and oxygen, wherein a condensate coupled at para-position of the phenol can be produced in an excellent yield, L-M (X)n (II) wherein L represents a ligand having 2 to 4 nitrogen atoms as donor atoms, M represents copper ion, nickel ion, cobalt ion, iron ion, manganese ion, chromium ion or vanadyl ion, X represents a counter ion, n is a number of Xs.
摘要翻译：本发明提供一种通过在特定络合物（II）和氧气存在下，在至少一个邻位的不具有取代基的酚化合物进行氧化缩合来制备苯酚缩合物的方法，其中在对位可以以优异的产率制备苯酚，<？在线公式描述=“在线公式”end =“lead”？> LM（X）n（II）其中L表示作为供体原子的具有2〜4个氮原子的配体，M表示铜离子，镍离子，钴离子，铁离子，锰离子，铬离子或氧离子离子，X表示抗衡离子，n是X的数量。

127. 发明授权

US07122663B2 Stable free nitroxyl radicals as oxidation catalysts and process for oxidation 失效
标题翻译：稳定的游离硝酰自由基作为氧化催化剂和氧化过程
公开(公告)号：US07122663B2
公开(公告)日：2006-10-17
申请号：US10466726
申请日：2002-01-15
申请人： Alessandro Zedda , Massimiliano Sala , Armin Schneider
发明人： Alessandro Zedda , Massimiliano Sala , Armin Schneider
IPC分类号： C07D245/00 , C07D487/00
CPC分类号： B01J31/40 , B01J31/006 , B01J31/0237 , B01J31/0244 , B01J2231/70 , C07C45/29 , C07C45/294 , C07C45/30 , C07C45/38 , C07C45/39 , C07C51/29 , C07D471/18 , C07D487/18 , C08K5/34926 , Y02P20/584 , C07C49/04 , C07C47/19 , C07C59/305
摘要： The instant invention relates to stable free nitroxyl radicals of formula (I) wherein at least one of the substituents R is —O. and the others are hydrogen or OH; X is —NR1R2, wherein R1 and R2 are independently hydrogen, C1–C18alkyl or together with the nitrogen atom to which they are bound form a 5 or 6 membered ring which may be further interrupted by an O atom. Further subjects of the invention are an oxidation process for alcohols to aldehydes or ketones or to carboxylic acids in the presence of a compound of formula (I) and the use of stable free nitroxyl radicals of formula (I) as oxidation catalysts.
摘要翻译：本发明涉及式（I）的稳定的游离硝酰基，其中至少一个取代基R为-O。其余为氢或OH; X是-NR 1 R 2 R 2，其中R 1和R 2分别独立地是氢，C 1 -C 4烷基，或者与它们所连接的氮原子一起形成可被O原子进一步中断的5或6元环。本发明的其它主题是在式（I）化合物和式（I）的稳定的游离硝酰基作为氧化催化剂的存在下，将醇与醛或酮或羧酸的氧化方法。

128. 发明申请

US20050203315A1 Process for converting alcohols to carbonyl compounds 审中-公开
标题翻译：将醇转化为羰基化合物的方法
公开(公告)号：US20050203315A1
公开(公告)日：2005-09-15
申请号：US10509779
申请日：2003-03-26
申请人： Hansjorg Grutzmacher , Hartmut Schonberg , Souad Boulmaaz
发明人： Hansjorg Grutzmacher , Hartmut Schonberg , Souad Boulmaaz
IPC分类号： C07D309/30 , B01J31/18 , B01J31/22 , B01J31/30 , C07B61/00 , C07C45/39 , C07C49/17 , C07C49/245 , C07C49/252 , C07D315/00 , C07F1/00 , C07C45/36 , C07F1/08
CPC分类号： C07D315/00 , B01J31/181 , B01J31/1815 , B01J31/183 , B01J2531/16 , C07C45/39 , C07C49/245 , C07C49/83 , C07C49/14 , C07C49/82
摘要： The present invention provides a process for selectively converting dihydroxy-or polyhydroxy alcohols into carbonyl compounds which process comprises the step of oxidizing the dihydroxy-or polyhydroxy alcohols with dioxygen (O2) as oxidant in the presence of a catalytic system comprising (1) a copper salt, a copper salt containing a heterocyclic ligand or a copper complex salt, and (2) a base.
摘要翻译：本发明提供了一种选择性地将二羟基或多羟基醇转化为羰基化合物的方法，该方法包括在二氧化或多羟基醇存在下，将二羟基或多羟基醇用二氧化钛（O 2 O 2）催化体系包括（1）铜盐，含有杂环配位体的铜盐或铜络合盐，和（2）碱。

129. 发明授权

US06828463B2 Process for the preparation of carbonyl compounds with a carbonyl group attached to the aromatic ring 失效
标题翻译：制备具有连接到芳环上的羰基的羰基化合物的方法
公开(公告)号：US06828463B2
公开(公告)日：2004-12-07
申请号：US10396358
申请日：2003-03-26
申请人： Vasant R. Choudhary , Vijay S. Narkhede , Jayant R. Indurkar
发明人： Vasant R. Choudhary , Vijay S. Narkhede , Jayant R. Indurkar
IPC分类号： C07C4527
CPC分类号： B01J23/24 , B01J23/007 , B01J23/34 , B01J27/0573 , C07C45/36 , C07C45/38 , C07C45/39
摘要： The present invention relates to a process for the preparation of aromatic carbonyl compound with carbonyl group attached to its aromatic ring, particularly relates to a process for the preparation of aromatic carbonyl compound with carbonyl group attached to its aromatic ring, by oxidizing with molecular oxygen the methylene or alcoholic group attached to aromatic ring of an aromatic compound, using a polyoxotnetallate(s) anion exchanged hydrotalcite catalyst.
摘要翻译：本发明涉及一种制备具有连接到其芳香环上的羰基的芳族羰基化合物的方法，特别涉及一种通过与其芳香环连接的羰基制备芳族羰基化合物的方法，通过用分子氧氧化用芳香族化合物的芳环连接的亚甲基或醇基，使用聚氧乙烯酸钠阴离子交换的水滑石催化剂。

130. 发明授权

US06812366B2 Catalyst useful for oxidation reactions 有权
标题翻译：催化剂用于氧化反应
公开(公告)号：US06812366B2
公开(公告)日：2004-11-02
申请号：US10653634
申请日：2003-09-02
申请人： Manhua Lin
发明人： Manhua Lin
IPC分类号： C07C4534
CPC分类号： C07C51/252 , B01J23/002 , B01J23/20 , B01J23/28 , B01J27/0576 , B01J35/0006 , B01J35/002 , B01J37/0236 , B01J2523/00 , C07C45/33 , C07C45/35 , C07C45/39 , C07C51/215 , C07C51/235 , C07C51/25 , C07C47/21 , C07C47/22 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68
摘要： A catalyst useful for oxidation reactions is disclosed. The catalyst is useful for the gas phase oxidation of alkanes, propylene, acrolein, or isopropanol to unsaturated aldehydes or carboxylic acids.
摘要翻译：公开了一种可用于氧化反应的催化剂。该催化剂可用于将烷烃，丙烯，丙烯醛或异丙醇气相氧化成不饱和醛或羧酸。

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