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121. 发明申请

US20100112454A1 COMPLIANT SEAL STRUCTURES FOR PROTECTED ACTIVE METAL ANODES 有权
标题翻译：用于保护活性金属阳极的合适密封结构
公开(公告)号：US20100112454A1
公开(公告)日：2010-05-06
申请号：US12607360
申请日：2009-10-28
申请人： Steven J. Visco , Yevgeniy S. Nimon , Lutgard De Jonghe , Bruce D. Katz , Alexei Petrov
发明人： Steven J. Visco , Yevgeniy S. Nimon , Lutgard De Jonghe , Bruce D. Katz , Alexei Petrov
IPC分类号： H01M2/00
CPC分类号： H01M2/08 , H01B1/122 , H01M2/16 , H01M2/1686 , H01M2/18 , H01M4/00 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/366 , H01M4/667 , H01M4/668 , H01M4/70 , H01M6/30 , H01M6/34 , H01M6/42 , H01M10/052 , H01M10/34 , H01M12/06 , H01M12/08 , H01M2004/021 , H01M2004/027 , Y02E60/122 , Y02E60/128 , Y02P70/54
摘要： Protected anode architectures have ionically conductive protective membrane architectures that, in conjunction with compliant seal structures and anode backplanes, effectively enclose an active metal anode inside the interior of an anode compartment. This enclosure prevents the active metal from deleterious reaction with the environment external to the anode compartment, which may include aqueous, ambient moisture, and/or other materials corrosive to the active metal. The compliant seal structures are substantially impervious to anolytes, catholyes, dissolved species in electrolytes, and moisture and compliant to changes in anode volume such that physical continuity between the anode protective architecture and backplane are maintained. The protected anode architectures can be used in arrays of protected anode architectures and battery cells of various configurations incorporating the protected anode architectures or arrays.
摘要翻译：受保护的阳极结构具有离子导电保护膜结构，其结合顺应性密封结构和阳极背板，有效地将活性金属阳极包围在阳极室的内部。该外壳防止活性金属与阳极室外部的环境有害的反应，阳极室可包括水性环境水分和/或对活性金属具有腐蚀性的其它材料。顺应性密封结构基本上不透过阳极电解液，阴极电解质，电解质中的溶解物质和水分，并且符合阳极体积的变化，从而维持阳极保护结构和背板之间的物理连续性。受保护的阳极结构可用于保护阳极结构的阵列和包含受保护的阳极结构或阵列的各种配置的电池单元。

122. 发明申请

US20090311605A1 CATHODES AND RESERVOIRS FOR AQUEOUS LITHIUM/AIR BATTERY CELLS 有权
标题翻译：空气电池电池阴极和储存
公开(公告)号：US20090311605A1
公开(公告)日：2009-12-17
申请号：US12484079
申请日：2009-06-12
申请人： Steven J. Visco , Lutgard C. De Jonghe , Yevgeniy S. Nimon , Alexei Petrov , Kirill Pridatko
发明人： Steven J. Visco , Lutgard C. De Jonghe , Yevgeniy S. Nimon , Alexei Petrov , Kirill Pridatko
IPC分类号： H01M4/58
CPC分类号： H01M2/1673 , H01M4/382 , H01M6/04 , H01M6/045 , H01M8/08 , H01M12/02 , H01M12/04 , H01M12/06 , Y10T29/49108
摘要： Li/air battery cells are configurable to achieve very high energy density. The cells include a protected a lithium metal or alloy anode and an aqueous catholyte in a cathode compartment. In addition to the aqueous catholyte, components of the cathode compartment include an air cathode (e.g., oxygen electrode) and a variety of other possible elements.
摘要翻译： Li /空气电池单元可配置为实现非常高的能量密度。电池包括在阴极室中的受保护的锂金属或合金阳极和含水阴极电解液。除了水性阴极电解液之外，阴极室的部件还包括空气阴极（例如氧气电极）和各种其它可能的元件。

123. 发明授权

US07482096B2 Alleviation of voltage delay in lithium-liquid depolarizer/electrolyte solvent battery cells 失效
标题翻译：缓解锂 - 液体去极化器/电解质溶剂电池中的电压延迟
公开(公告)号：US07482096B2
公开(公告)日：2009-01-27
申请号：US10455259
申请日：2003-06-04
申请人： Lutgard De Jonghe , Yevgeniy S. Nimon , Steven J. Visco
发明人： Lutgard De Jonghe , Yevgeniy S. Nimon , Steven J. Visco
IPC分类号： H01M4/58
CPC分类号： H01M4/38 , H01M4/0402 , H01M4/368 , H01M4/405 , H01M6/14 , H01M10/0563 , H01M10/4235
摘要： Voltage delay in an active metal anode/liquid cathode battery cell can be significantly reduced or completely alleviated by coating the active metal anode (e.g., Li) surface with a thin layer of an inorganic compound with Li-ion conductivity using chemical treatment of Li surface. Particularly, preferred examples of such compounds include lithium phosphate, lithium metaphosphate, and/or their mixtures or solid solutions with lithium sulphate. These compounds can be formed on the Li surface by treatment with diluted solutions of the following individual acids: H3PO4, HPO3 and H2SO4, their acidic salts, or their binary or ternary mixtures in a dry organic solvent compatible with Li, for instance in 1,2-DME; by various deposition techniques. Such chemical protection of the Li or other active metal electrode significantly reduces the voltage delay due to protected anode's improved stability toward the electrolyte.
摘要翻译：通过使用Li表面的化学处理，用具有Li离子传导性的无机化合物的薄层涂覆活性金属阳极（例如Li）表面，可以显着降低或完全减轻活性金属阳极/液体阴极电池单元中的电压延迟。特别地，这些化合物的优选实例包括磷酸锂，偏磷酸锂和/或其与硫酸锂的混合物或固溶体。这些化合物可以在Li表面上通过用与Li相容的干燥有机溶剂中的以下各种酸：H 3 PO 4，HPO 3和H 2 SO 4，它们的酸性盐或其二元或三元混合物的稀释溶液，例如1， 2-DME; 通过各种沉积技术。 Li或其他活性金属电极的这种化学保护显着地降低了由于被保护的阳极提高了对电解质的稳定性的电压延迟。

124. 发明申请

US20090005824A1 ELECTROTRANSPORT DEVICES, METHODS AND DRUG ELECTRODE ASSEMBLIES 审中-公开
标题翻译：电子输送装置，方法和药物电极组件
公开(公告)号：US20090005824A1
公开(公告)日：2009-01-01
申请号：US12163821
申请日：2008-06-27
申请人： Steven J. Visco , Yevgeniy S. Nimon , Bruce Katz
发明人： Steven J. Visco , Yevgeniy S. Nimon , Bruce Katz
IPC分类号： A61N1/18
CPC分类号： A61N1/0448 , A61N1/0436 , A61N1/0444
摘要： A drug electrode assembly usefully employed in an electrotransport device for the delivery of drugs across a tissue surface includes an electrode, a drug reservoir which stores the drug (including an ionized (e.g., anionic) or neutrally charged drug species), and a liquid impermeable solid-state assist ion conducting barrier layer interposed between the electrode and the drug reservoir. The barrier layer can be a single-ion conductor of a specific (unique) species of ion called the assist ion. During drug delivery, the assist ion moves across the barrier layer into or out of the drug reservoir, and as the assist ion crosses the barrier layer/drug reservoir interphase, the drug species moves to the tissue surface. The assist ion can be, for example, sodium ions (Na+), and the electrode can be an electrode of the assist ion (i.e., a sodium electrode).
摘要翻译：有效地用于电传输装置中用于在组织表面递送药物的药物电极组件包括电极，储存药物的药物储存器（包括电离（例如阴离子）或中性带电药物））和不透液体固态辅助离子传导阻挡层介于电极和药物储存器之间。阻挡层可以是称为辅助离子的特定（独特）离子种类的单离子导体。在药物递送期间，辅助离子穿过阻隔层进入或流出药物储存器，并且当辅助离子穿过阻挡层/药物储存器相间时，药物物质移动到组织表面。辅助离子可以是例如钠离子（Na +），电极可以是辅助离子的电极（即钠电极）。

125. 发明授权

US07390591B2 Ionically conductive membranes for protection of active metal anodes and battery cells 有权
公开(公告)号：US07390591B2
公开(公告)日：2008-06-24
申请号：US10772228
申请日：2004-02-03
申请人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz
发明人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz
IPC分类号： H01M2/16 , H01M6/14
CPC分类号： H01M4/13 , H01M2/1673 , H01M4/366 , H01M10/0525 , H01M10/0562 , H01M2300/0065 , H01M2300/0094
摘要： Disclosed are ionically conductive membranes for protection of active metal anodes and methods for their fabrication. The membranes may be incorporated in active metal negative electrode (anode) structures and battery cells. In accordance with the invention, the membrane has the desired properties of high overall ionic conductivity and chemical stability towards the anode, the cathode and ambient conditions encountered in battery manufacturing. The membrane is capable of protecting an active metal anode from deleterious reaction with other battery components or ambient conditions while providing a high level of ionic conductivity to facilitate manufacture and/or enhance performance of a battery cell in which the membrane is incorporated.

126. 发明申请

US20080038641A1 Protected active metal electrode and battery cell structures with non-aqueous interplayer architecture 有权
标题翻译：受保护的活性金属电极和具有非水相互作用体系结构的电池单元结构
公开(公告)号：US20080038641A1
公开(公告)日：2008-02-14
申请号：US11824597
申请日：2007-06-28
申请人： Steven Visco , Bruce Katz , Yevgeniy Nimon , Lutgard De Jonghe
发明人： Steven Visco , Bruce Katz , Yevgeniy Nimon , Lutgard De Jonghe
IPC分类号： H01M6/14 , H01M4/42 , H01M4/44 , H01M6/16 , H01M4/46
CPC分类号： H01M2/1673 , H01G11/06 , H01G11/52 , H01G11/58 , H01M2/1686 , H01M4/13 , H01M4/366 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/0562 , H01M10/0565 , H01M2300/0002 , H01M2300/0085 , Y02E60/122 , Y02E60/13 , Y02P70/54 , Y10T29/49108
摘要： Active metal and active metal intercalation electrode structures and battery cells having ionically conductive protective architecture including an active metal (e.g., lithium) conductive impervious layer separated from the electrode (anode) by a porous separator impregnated with a non-aqueous electrolyte (anolyte). This protective architecture prevents the active metal from deleterious reaction with the environment on the other (cathode) side of the impervious layer, which may include aqueous or non-aqueous liquid electrolytes (catholytes) and/or a variety electrochemically active materials, including liquid, solid and gaseous oxidizers. Safety additives and designs that facilitate manufacture are also provided.
摘要翻译：活性金属和活性金属插入电极结构以及具有离子导电保护结构的电池单元，其包括通过浸渍有非水电解质（阳极电解液）的多孔隔离物与电极（阳极）分离的活性金属（例如锂）导电不渗透层。这种保护结构防止活性金属与不透水层的另一（阴极）侧的环境有害的反应，其可以包括水性或非水性液体电解质（阴极电解液）和/或各种电化学活性材料，包括液体，固体和气体氧化剂。还提供了便于制造的安全性添加剂和设计。

127. 发明授权

US07282302B2 Ionically conductive composites for protection of active metal anodes 有权
标题翻译：用于保护活性金属阳极的离子导电复合材料
公开(公告)号：US07282302B2
公开(公告)日：2007-10-16
申请号：US10731771
申请日：2003-12-05
申请人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz
发明人： Steven J. Visco , Yevgeniy S. Nimon , Bruce D. Katz
IPC分类号： H01M2/16 , H01M6/14 , H01M6/22
CPC分类号： C03C4/18 , C03C10/00 , H01M2/16 , H01M2/1673 , H01M4/134 , H01M4/366 , H01M4/38 , H01M6/18 , H01M6/181 , H01M6/182 , H01M6/185 , H01M6/187 , H01M6/188 , H01M10/052 , H01M10/0525 , H01M10/056 , H01M10/0562 , H01M10/0565 , H01M10/0583 , H01M2004/021 , H01M2300/0065 , H01M2300/0094
摘要： Disclosed are ionically conductive composites for protection of active metal anodes and methods for their fabrication. The composites may be incorporated in active metal negative electrode (anode) structures and battery cells. In accordance with the invention, the properties of different ionic conductors are combined in a composite material that has the desired properties of high overall ionic conductivity and chemical stability towards the anode, the cathode and ambient conditions encountered in battery manufacturing. The composite is capable of protecting an active metal anode from deleterious reaction with other battery components or ambient conditions while providing a high level of ionic conductivity to facilitate manufacture and/or enhance performance of a battery cell in which the composite is incorporated.
摘要翻译：公开了用于保护活性金属阳极的离子导电复合材料及其制造方法。复合材料可以结合在活性金属负极（阳极）结构和电池单元中。根据本发明，将不同离子导体的性质组合成复合材料，其具有对电池制造中遇到的对阳极，阴极和环境条件的高总离子导电性和化学稳定性的期望性质。该复合材料能够保护活性金属阳极免受与其它电池组分或环境条件的有害反应，同时提供高水平的离子导电性以促进其中掺入复合材料的电池单元的制造和/或增强其性能。

128. 发明申请

US20070172739A1 COMPOSITE SOLID ELECTROLYTE FOR PROTECTION OF ACTIVE METAL ANODES 有权
标题翻译：用于保护活性金属阳极的复合固体电解质
公开(公告)号：US20070172739A1
公开(公告)日：2007-07-26
申请号：US11612741
申请日：2006-12-19
申请人： Steven Visco , Lutgard DeJonghe , Yevgeniy Nimon
发明人： Steven Visco , Lutgard DeJonghe , Yevgeniy Nimon
IPC分类号： H01M10/36 , H01M10/40 , H01M2/16 , H01M4/56 , H01M4/54 , H01M4/50 , H01M4/34 , H01M4/52
CPC分类号： H01M10/056 , H01B1/122 , H01M2/1673 , H01M4/04 , H01M4/0416 , H01M4/08 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/139 , H01M4/242 , H01M4/32 , H01M4/38 , H01M4/383 , H01M4/385 , H01M4/387 , H01M4/62 , H01M4/86 , H01M6/04 , H01M6/16 , H01M6/181 , H01M6/185 , H01M6/188 , H01M6/24 , H01M6/34 , H01M8/08 , H01M10/052 , H01M10/0561 , H01M10/0566 , H01M12/04 , H01M12/06 , H01M12/08 , H01M2004/027 , H01M2300/0005 , H01M2300/0017 , H01M2300/0065 , H01M2300/0068 , H01M2300/0071 , H01M2300/0082 , H01M2300/0085 , H01M2300/0091 , Y02E60/128
摘要： A composite solid electrolyte include a monolithic solid electrolyte base component that is a continuous matrix of an inorganic active metal ion conductor and a filler component used to eliminate through porosity in the solid electrolyte. In this way a solid electrolyte produced by any process that yields residual through porosity can be modified by the incorporation of a filler to form a substantially impervious composite solid electrolyte and eliminate through porosity in the base component. Methods of making the composites is also disclosed. The composites are generally useful in electrochemical cell structures such as battery cells and in particular protected active metal anodes, particularly lithium anodes, that are protected with a protective membrane architecture incorporating the composite solid electrolyte. The protective architecture prevents the active metal of the anode from deleterious reaction with the environment on the other (cathode) side of the architecture, which may include aqueous, air and organic liquid electrolytes and/or electrochemically active materials.
摘要翻译：复合固体电解质包括作为无机活性金属离子导体的连续基体和用于消除固体电解质中的孔隙率的填充剂组分的单片固体电解质基底组分。以这种方式，可以通过引入填料以形成基本上不可渗透的复合固体电解质并通过基础组分中的孔隙度来消除通过产生残余孔隙率的任何方法产生的固体电解质。还公开了制备复合材料的方法。复合材料通常可用于电化学电池结构，例如电池单元，特别是保护性活性金属阳极，特别是锂阳极，其被保护膜结构保护，并结合复合固体电解质。保护结构防止阳极的活性金属与结构的另一（阴极）侧的环境有害的反应，其可以包括水性，空气和有机液体电解质和/或电化学活性材料。

129. 发明申请

US20070117007A1 LI/AIR NON-AQUEOUS BATTERIES 有权
标题翻译： LI / AIR非水性电池
公开(公告)号：US20070117007A1
公开(公告)日：2007-05-24
申请号：US11562883
申请日：2006-11-22
申请人： Steven Visco , Yevgeniy Nimon
发明人： Steven Visco , Yevgeniy Nimon
IPC分类号： H01M2/16 , H01M2/18 , H01M12/06
CPC分类号： H01M12/06 , H01M2/1646 , H01M2/1673 , H01M4/134 , H01M4/381 , H01M4/382 , H01M6/16 , H01M6/164 , H01M6/185 , H01M6/187 , H01M6/22 , H01M10/052 , H01M10/0562 , H01M10/0565 , H01M12/08 , H01M2300/0025 , H01M2300/0068 , H01M2300/0071 , H01M2300/0085 , H01M2300/0094 , Y02E60/128
摘要： Non-aqueous alkali metal (e.g., Li)/oxygen battery cells constructed with a protected anode that minimizes anode degradation and maximizes cathode performance by enabling the use of cathode performance enhancing solvents in the catholyte have negligible self-discharge and high deliverable capacity. In particular, protected lithium-oxygen batteries with non-aqueous catholytes have this improved performance.
摘要翻译：通过使阴极电解液中阴极性能增强溶剂的使用最小化而使阳极劣化最小化并使阴极性能最大化的被保护阳极构成的非水碱金属（例如Li）/氧电池单元具有可忽略的自放电和高可输送能力。特别地，具有非水性阴极电解液的受保护的锂 - 氧电池具有这种改进的性能。

130. 发明申请

US20070051620A1 Polymer adhesive seals for protected anode architectures 有权
标题翻译：用于保护阳极结构的聚合物粘合剂密封件
公开(公告)号：US20070051620A1
公开(公告)日：2007-03-08
申请号：US11514678
申请日：2006-09-01
申请人： Steven Visco , Yevgeniy Nimon , Lutgard De Jonghe , Bruce Katz , Alexei Petrov
发明人： Steven Visco , Yevgeniy Nimon , Lutgard De Jonghe , Bruce Katz , Alexei Petrov
IPC分类号： C25C7/02 , C25B11/04
CPC分类号： H01M4/76 , H01M4/02 , H01M4/13 , H01M4/134 , H01M4/366 , H01M6/34 , H01M10/052 , H01M12/02 , H01M12/06
摘要： Protected anode architectures for active metal anodes have a polymer adhesive seal that provides an hermetic enclosure for the active metal of the protected anode inside an anode compartment. The compartment is substantially impervious to ambient moisture and battery components such as catholyte (electrolyte about the cathode), and prevents volatile components of the protected anode, such as anolyte (electrolyte about the anode), from escaping. The architecture is formed by joining the protected anode to an anode container. The polymer adhesive seals provide an hermetic seal at the joint between a surface of the protected anode and the container.
摘要翻译：用于活性金属阳极的受保护阳极结构具有聚合物粘合剂密封件，其为阳极室内的受保护阳极的活性金属提供密封外壳。隔室基本上不受环境湿度的影响，电池组件如阴极电解液（电解液围绕阴极），并防止受保护阳极的挥发性成分，如阳极电解液（阳极电解液）逸出。该结构通过将受保护的阳极接合到阳极容器而形成。聚合物粘合剂密封件在受保护阳极的表面和容器之间的接合处提供气密密封。

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