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111. 发明申请

US20150225879A1 Polymeric Structures Comprising a Dual Purpose and/or Component Thereof and Methods for Making Same 审中-公开
标题翻译：包含双重目的和/或成分的聚合物结构及其制备方法
公开(公告)号：US20150225879A1
公开(公告)日：2015-08-13
申请号：US14619137
申请日：2015-02-11
申请人： The Procter & Gamble Company
发明人： Stephen Wayne Heinzman , Jeffrey Allen Bowles
IPC分类号： D01F6/26 , B32B5/02
CPC分类号： B32B5/022 , B32B5/028 , B32B5/26 , B32B2262/04 , B32B2262/062 , B32B2432/00 , B32B2555/00 , D01F1/10 , D01F2/00 , D01F2/24 , D01F9/00 , D04H1/425 , D04H1/4258 , D04H1/4309 , D04H1/64 , D04H3/005 , D04H3/013 , Y10T442/10
摘要： Hydroxyl polymer polymeric structures, for example fibrous elements, such as filaments and/or fibers, and more particularly to hydroxyl polymer fibrous elements that contain a dual purpose material and/or dual purpose material component, fibrous structures made therefrom, and methods for making same are provided.
摘要翻译：羟基聚合物聚合物结构，例如纤维元素，例如长丝和/或纤维，更具体地说，涉及含有双重目的材料和/或双重目的的材料组分的羟基聚合物纤维元素，由其制备的纤维结构及其制备方法被提供。

112. 发明申请

US20050287366A1 Method for producing conducting polymer fibers with vinyl and conducting polymer fibers with vinyl produced thereby 有权
标题翻译：用乙烯基和导电聚合物纤维生产具有乙烯基的导电聚合物纤维的方法
公开(公告)号：US20050287366A1
公开(公告)日：2005-12-29
申请号：US11132231
申请日：2005-05-19
申请人： Hidenori Okuzaki , Takashi Aoyama , Tomiya Abe , Yuzo Ito
发明人： Hidenori Okuzaki , Takashi Aoyama , Tomiya Abe , Yuzo Ito
IPC分类号： D01F6/26 , D01D5/00 , D01D5/04 , D01F6/28 , D02J1/20
CPC分类号： D01F11/06 , D01D5/0038 , D01F6/26 , D01F6/28 , Y10T428/2913
摘要： The vinyl-type conducting polymer precursor is dissolved in solution containing volatile solvent such as methanol, and the precursor fibers are produced by electrospinning. The vinyl-type conducting polymer fibers are produced by heat treatment of the precursor fibers at certain temperature and time in a vacuum or in an inert gas atmosphere, or by zone reaction method, followed by doping with dopant.
摘要翻译：将乙烯基型导电性聚合物前体溶解在含有挥发性溶剂如甲醇的溶液中，并通过静电纺丝制备前体纤维。乙烯基型导电聚合物纤维是通过在真空或惰性气体气氛中的某些温度和时间，或通过区域反应方法热处理前体纤维，然后掺杂掺杂剂来制备的。

113. 发明授权

US06123883A Method for preparing polyaniline fibers 失效
标题翻译：聚苯胺纤维的制备方法
公开(公告)号：US06123883A
公开(公告)日：2000-09-26
申请号：US334719
申请日：1999-06-16
申请人： Benjamin R. Mattes , Hsing-Lin Wang
发明人： Benjamin R. Mattes , Hsing-Lin Wang
IPC分类号： C08J5/18 , C08G73/00 , C08G73/02 , D01F6/26 , D01F6/76 , H01B1/12 , D01D5/06 , D01F1/09 , D01F6/96
CPC分类号： C08G73/0266 , D01F6/76 , H01B1/128
摘要： Stable, concentrated solutions of high molecular weight polyaniline. In order to process high quality fibers and other articles possessing good mechanical properties, it is known that solution concentrations of the chosen polymer should be in the range from 15-30% (w/w). Moreover, it is desirable to use the highest molecular weight consistent with the solubility properties of the polymer. However, such solutions are inherently unstable, forming gels before processing can be achieved. The present invention describes the addition gel inhibitors (GIs) to the polymer solution, thereby permitting high concentrations (>15% (w/w)) of high molecular weight ((M.sub.w)>120,000, and (M.sub.n)>30,000) emeraldine base (EB) polyaniline to be dissolved. Secondary amines have been used for this purpose in concentrations which are small compared to those which might otherwise be used in a cosolvent role therefor. The resulting solutions are useful for generating excellent fibers, films, coatings and other objects, since the solutions are stable for significant time periods, and the GIs are present in too small concentrations to cause polymer deterioration. It is demonstrated that the GIs found to be useful do not act as cosolvents, and that gelation times of the solutions are directly proportional to the concentration of GI. In particular, there is a preferred concentration of GI, which if exceeded causes structural and electrical conductivity degradation of resulting articles. Heating of the solutions significantly improves solubility.
摘要翻译：稳定的高分子量聚苯胺浓缩溶液。为了处理具有良好机械性能的高品质纤维和其它制品，已知所选聚合物的溶液浓度应在15-30％（w / w）的范围内。此外，期望使用与聚合物的溶解性质一致的最高分子量。然而，这种溶液固有地不稳定，可以在加工前形成凝胶。本发明描述了对聚合物溶液的加成凝胶抑制剂（GI），从而允许高分子量（（Mw）> 120,000和（Mn）> 30,000）翠绿亚胺碱的高浓度（> 15％（w / w）（EB）聚苯胺溶解。为了这个目的已经使用了仲胺，其浓度与可能用于其共溶剂作用的那些相比，其用量较小。所得到的溶液可用于产生优异的纤维，膜，涂层和其它物体，因为溶液在相当长的时间内是稳定的，并且GI以太小的浓度存在以引起聚合物劣化。证明发现有用的GI不能作为共溶剂，溶液的凝胶化时间与GI的浓度成正比。特别地，存在优选的GI浓度，如果超过，则导致所得制品的结构和电导率降低。溶液的加热显着提高了溶解度。

114. 发明授权

US5981695A Stable, concentrated solutions of high molecular weight polyaniline and articles therefrom 失效
标题翻译：稳定的高分子量聚苯胺浓缩溶液及其制品
公开(公告)号：US5981695A
公开(公告)日：1999-11-09
申请号：US926338
申请日：1997-09-05
申请人： Benjamin R. Mattes , Hsing-Lin Wang
发明人： Benjamin R. Mattes , Hsing-Lin Wang
IPC分类号： C08J5/18 , C08G73/00 , C08G73/02 , D01F6/26 , D01F6/76 , H01B1/12 , C08J3/00
CPC分类号： C08G73/0266 , D01F6/76 , H01B1/128
摘要： Stable, concentrated solutions of high molecular weight polyaniline. In order to process high quality fibers and other articles possessing good mechanical properties, it is known that solution concentrations of the chosen polymer should be in the range from 15-30% (w/w). Moreover, it is desirable to use the highest molecular weight consistent with the solubility properties of the polymer. However, such solutions are inherently unstable, forming gels before processing can be achieved. The present invention describes the addition gel inhibitors (GIs) to the polymer solution, thereby permitting high concentrations (between 15% and 30% (w/w)) of high molecular weight ((M.sub.w)>120,000, and (M.sub.n)>30,000) emeraldine base (EB) polyaniline to be dissolved. Secondary amines have been used for this purpose in concentrations which are small compared to those which might otherwise be used in a cosolvent role therefor. The resulting solutions are useful for generating excellent fibers, films, coatings and other objects, since the solutions are stable for significant time periods, and the GIs are present in too small concentrations to cause polymer deterioration. It is demonstrated that the GIs found to be useful do not act as cosolvents, and that gelation times of the solutions are directly proportional to the concentration of GI. In particular, there is a preferred concentration of GI, which if exceeded causes structural and electrical conductivity degradation of resulting articles. Heating of the solutions significantly improves solubility.
摘要翻译：稳定的高分子量聚苯胺浓缩溶液。为了处理具有良好机械性能的高质量纤维和其它制品，已知所选聚合物的溶液浓度应在15-30％（w / w）的范围内。此外，期望使用与聚合物的溶解性质一致的最高分子量。然而，这种溶液固有地不稳定，可以在加工前形成凝胶。本发明描述了对聚合物溶液的添加凝胶抑制剂（GI），从而允许高分子量（（Mw）> 120,000和（Mn）> 30,000的高浓度（15％至30％（w / w））翠绿碱（EB）聚苯胺溶解。为了这个目的已经使用了仲胺，其浓度与可能用于其共溶剂作用的那些相比，其用量较小。所得到的溶液可用于产生优异的纤维，膜，涂层和其它物体，因为溶液在相当长的时间内是稳定的，并且GI以太小的浓度存在以引起聚合物劣化。证明发现有用的GI不能作为共溶剂，溶液的凝胶化时间与GI的浓度成正比。特别地，存在优选的GI浓度，如果超过，则导致所得制品的结构和电导率降低。溶液的加热显着提高了溶解度。

115. 发明授权

US5756031A Process for preparing polybenzazole filaments and fiber 失效
标题翻译：制备聚吲哚长丝和纤维的方法
公开(公告)号：US5756031A
公开(公告)日：1998-05-26
申请号：US793038
申请日：1997-01-30
申请人： Katsuya Tani , Ihachiro Iba , Timothy L. Faley , Michael E. Mills , Ira M. Thumma
发明人： Katsuya Tani , Ihachiro Iba , Timothy L. Faley , Michael E. Mills , Ira M. Thumma
IPC分类号： D01D5/26 , D01F6/74 , D01D5/04 , D01D5/06 , D01F6/26
CPC分类号： D01D5/26 , D01F6/74
摘要： A process for the preparation of polybenzazole filaments which comprises (a) extruding a solution of polybenzazole polymer in a mineral acid through a spinneret having at least 100 holes, which are arranged to form a annular pattern around the center of the spinneret, the center and at least two radial sections of the spinneret having no holes and an average width which is at least about 3 times the minimum pitch of the holes, thereby forming filaments of the polymer solution; (b) drawing the filaments of the polymer solution through a quench chamber while providing a substantially radial gas flow therein across the spinneret from at least two different directions; and (c) washing and drying the filaments of the polymer solution under conditions sufficient to form polybenzazole filaments.
摘要翻译： PCT No.PCT / US95 / 10271 Sec。 371日期1997年1月30日 102（e）日期1997年1月30日PCT提交1995年8月10日PCT公布。 WO96 / 05341 PCT出版物日期1996年2月22日一种制备聚吲唑长丝的方法，其包括（a）通过具有至少100个孔的喷丝头挤出无机酸中的聚苯并唑聚合物溶液，所述喷丝头被布置成围绕喷丝头，中心和喷丝头的至少两个径向部分没有孔，平均宽度为孔的最小间距的至少约3倍，从而形成聚合物溶液的长丝; （b）将聚合物溶液的长丝拉过淬火室，同时从至少两个不同的方向穿过喷丝头提供基本上径向的气流; 和（c）在足以形成聚吲哚长丝的条件下洗涤和干燥聚合物溶液的长丝。

116. 发明授权

US4728431A Pervaporation method for separating liquids in mixture 失效
标题翻译：用于分离混合物中液体的渗透蒸发法
公开(公告)号：US4728431A
公开(公告)日：1988-03-01
申请号：US771985
申请日：1985-09-03
申请人： Shigehiro Nagura , Minoru Takamizawa , Akira Yamamoto
发明人： Shigehiro Nagura , Minoru Takamizawa , Akira Yamamoto
IPC分类号： B01D61/36 , B01D71/44 , D01F6/00 , D01F6/26 , B01D13/00
CPC分类号： B01D61/362 , B01D63/02 , B01D71/44
摘要： The efficiency of the pervaporation method for the separation or enrichment of liquids in mixture, e.g. water and ethyl alcohol, can be greatly improved when the partitioning membrane is made of a polymeric composition comprising a specific organosilyl-substituted polyenic polymer composed of the monomeric moieties represented by the general formula ##STR1## in which R.sup.1 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms and the groups denoted by R are each independently a hydrogen atom, a monovalent hydrocarbon group having 1 to 8 carbon atoms or a silicon-containing organic group such as those represented by the general formula --CH.sub.2 --SiMe.sub.2 R.sup.2, Me being a methyl group and R.sup.2 being a lower alkyl group having 1 to 4 carbon atoms. The performance and durability of the membrane can be further improved when the polymeric composition is a polymer blend of the above described polyenic polymer and a poly(trimethyl vinyl silane).
摘要翻译：用于分离或富集混合物中的液体的渗透蒸发方法的效率，例如当分隔膜由包含由通式“IMAGE”表示的单体部分组成的特定有机甲硅烷基取代的多烯聚合物的聚合物组合物中可以大大改善，其中R 1是氢原子或烷基具有1至4个碳原子的基团和由R表示的基团各自独立地为氢原子，具有1至8个碳原子的一价烃基或含硅的有机基团，例如由通式-CH 2 -SiMe 2 R 2表示的基团， Me为甲基，R2为碳原子数1〜4的低级烷基。当聚合物组合物是上述多元聚合物与聚（三甲基乙烯基硅烷）的聚合物共混物时，可以进一步改善膜的性能和耐久性。

117. 发明专利

JP2014240529A 炭素繊維前駆体繊維およびその製造方法と、炭素繊維の製造方法有权
标题翻译：碳纤维前身纤维及其制造方法和碳纤维的制造方法
公开(公告)号：JP2014240529A
公开(公告)日：2014-12-25
申请号：JP2013122624
申请日：2013-06-11
申请人：国立大学法人東京大学 , Univ Of Tokyo , 国立大学法人東京大学
发明人： AOYANAGI SHU
IPC分类号： D01F6/26 , C08F8/00 , C08F238/00 , D01F9/20
摘要：【課題】耐炎化反応時の発熱量が少なく、耐炎化反応開始温度が低く、かつ炭素化収率が高い炭素繊維前駆体繊維、該炭素繊維前駆体繊維を連続的に安定して製造できる方法、および低コストで炭素繊維を製造できる方法の提供。【解決手段】本発明の炭素繊維前駆体繊維は、下記一般式(1)で表される構造単位(A)を1.0〜99.0モル%、および下記一般式(2)で表される構造単位(B)を1.0〜99.0モル%含むポリビニルアセチレン系重合体からなる。本発明の炭素繊維前駆体繊維の製造方法は、構造単位(A)を含むポリビニルアセチレン系重合体を用い、湿式紡糸法または乾湿式紡糸法で紡糸する。[化1]【選択図】なし
摘要翻译：要解决的问题：提供：在防火反应中具有低热值，低隔爆反应开始温度和高碳化收率的碳纤维前体纤维; 能够连续稳定地制造碳纤维前体纤维的方法; 以及能够以低成本制造碳纤维的方法。解决方案：碳纤维前体纤维由含有下述通式（1）所示的结构单元（A）的聚乙烯基乙炔系聚合物形成，其量为1.0 -99.0mol％和下述通式（2）表示的结构单元（B），为1.0-99.0mol％。碳纤维前体纤维的制造方法包括使用含有结构单元（A）的聚乙烯基乙炔系聚合物，通过湿式纺丝法或干式湿式纺丝法纺出聚合物。

118. 发明专利

JP2005330624A Method for producing vinyl-based conductive polymer fiber and vinyl-based conductive polymer fiber obtained by the method 有权
标题翻译：用于生产基于乙烯基的导电聚合物纤维和基于乙烯基的导电聚合物纤维的方法
公开(公告)号：JP2005330624A
公开(公告)日：2005-12-02
申请号：JP2004151021
申请日：2004-05-20
申请人： Hitachi Cable Ltd , Univ Of Yamanashi , 国立大学法人山梨大学 , 日立電線株式会社
发明人： OKUZAKI SHUSUKE , AOYAMA TAKASHI , ABE TOMIYA , ITO YUZO
IPC分类号： D01F6/26 , D01D5/00 , D01D5/04 , D01F6/28 , D02J1/20
CPC分类号： D01F11/06 , D01D5/0038 , D01F6/26 , D01F6/28 , Y10T428/2913
摘要： PROBLEM TO BE SOLVED: To provide a method for preparing a vinyl-based conductive polymer fiber, in which it has been considered to be impossible hitherto to fiberize the polymer material because of an insoluble and infusible polymer material, by electrospinning. SOLUTION: A precursor of a vinyl-based conductive polymer represented by general formula (1) (wherein R 1 is an aromatic hydrocarbon or a heterocyclic hydrocarbon; R 2 is a leaving group) is dissolved in a solution containing a volatile solvent and then, electrospinning of the solution is carried out to prepare a fiber of the precursor and the fiber of the precursor is heat-treated to produce the vinyl-based conductive polymer fiber represented by general formula (2) (R 1 and n are each the same as mentioned above). COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种用于制备乙烯基类导电聚合物纤维的方法，其中由于不溶性和不可渗透的聚合物材料而被认为是不可能将聚合物材料纤维化，通过静电纺丝。解决方案：由通式（1）表示的乙烯基类导电聚合物的前体（其中R 1 是芳族烃或杂环烃; R SB 2 是离去基团）溶解在含有挥发性溶剂的溶液中，然后进行静电纺丝以制备前体的纤维，并且将前体的纤维热处理以制备乙烯基类导电聚合物纤维由通式（2）表示（R 1 ，n分别与上述相同）。版权所有（C）2006，JPO＆NCIPI

119. 发明专利

JPH03206113A FIBER AND PRODUCT COMPRISING THE SAME 失效
公开(公告)号：JPH03206113A
公开(公告)日：1991-09-09
申请号：JP34087489
申请日：1989-12-29
申请人： KURARAY CO
发明人： MITA FUMIO , MATSUMOTO MITSUO , OKAZAKI MASAKI
IPC分类号： D01F6/26 , C08F34/02 , D01F6/44 , D04H1/4326 , D21H13/10 , D21H13/12
摘要： PURPOSE:To provid a fiber having excellent heat resistance, good mechanical physical properties and good decomposability and capable of being decomposed in the atmosphere, ground or water by employing a polymer having specific repeating structural unit as a main component. CONSTITUTION:The objective fiber comprises mainly a polymer having repeating structural units of formula I (R1-R6 are H or alkyl) (e.g. units of formula II-V) as the main chain thereof.

120. 发明专利

JPH0345707A POLYANILINE FIBER 失效
公开(公告)号：JPH0345707A
公开(公告)日：1991-02-27
申请号：JP18192289
申请日：1989-07-14
申请人： BRIDGESTONE CORP
发明人： NAKAJIMA TADASHI , KAWAGOE TAKAHIRO
IPC分类号： C08G73/00 , D01F6/26
摘要： PURPOSE:To obtain the title fiber having an excellent electroconductivity and orientation of crystal and suitable for reinforcing material, electroconductive material, antistatic material, electrode material, electrostatic and electromagnetic shield material, flame retardant material, etc., by spinning a high polymer substance consisting essentially of a specific polyaniline (derivative). CONSTITUTION:The aimed fiber obtained by spinning a high polymer substance consisting essentially of a polyaniline (derivative) being

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