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    • 115. 再颁专利
    • Process for removing oxygen and nitrogen from crude argon
    • 从粗氩中除去氧和氮的方法
    • USRE34595E
    • 1994-05-03
    • US847968
    • 1992-03-06
    • Michael S. K. ChenPhilip J. Cook
    • Michael S. K. ChenPhilip J. Cook
    • B01D53/22B01D53/32C01B13/02C01B23/00F25J3/04F25J3/08B01D71/02
    • B01D53/22B01D53/326C01B13/0251C01B23/00F25J3/04739F25J3/04969F25J3/08C01B2210/0078F25J2205/80F25J2205/82F25J2215/58F25J2230/58F25J2245/02
    • .[.A process is provided for purifying argon gas, especially an argon gas stream obtained by cryogenically separating air, wherein the argon gas is heated and compressed, and then permeated through a solid electrolyte membrane selective to the permeation of oxygen over other components of the gas, and removing oxygen from the argon by selective permeation of oxygen through the membrane. The purified argon can then be distilled to remove other components such as nitrogen..]..Iadd.A process is provided for producing a purified argon stream wherein oxygen and nitrogen are removed from crude bulk argon streams, particularly those produced by cryogenic, adsorptive or membrane separation of air. The process comprises separating a heated, compressed crude argon stream containing nitrogen and oxygen into an oxygen permeate stream and an oxygen-depleted argon stream by passing the compressed heated argon stream through a solid electrolyte membrane selective to the permeation of oxygen. The oxygen-depleted argon stream is then fed to a distillation column to separate nitrogen from the oxygen-depleted argon stream to form the purified argon stream and a nitrogen waste stream. .Iaddend.
    • [提供一种用于纯化氩气,特别是通过低温分离空气获得的氩气流的方法,其中氩气被加热和压缩,然后渗透通过氧气渗透到气体的其它组分上的固体电解质膜 ,并通过选择性渗透氧气从氩气中除去氧气。 然后可以纯化纯化的氩气以除去其它组分如氮气。]提供了一种生产纯化氩气流的方法,其中从原始粗氩气流中除去氧和氮,特别是通过低温,吸附或膜分离空气产生的那些 。 该方法包括通过将压缩的加热氩气流通过固体电解质膜,以选择性地渗透氧气,将含有氮气和氧气的加热的压缩粗氩气流分离成氧气渗透物流和贫氧氩气流。 然后将贫氧氩气流送入蒸馏塔以将氮气与贫氧氩气流分离以形成纯化的氩气流和氮气流。
    • 119. 发明授权
    • Cryogenic gas purification process and apparatus
    • 低温气体净化工艺及装置
    • US4934147A
    • 1990-06-19
    • US407569
    • 1989-09-15
    • Douglas V. Eyre
    • Douglas V. Eyre
    • F25J3/04F25J3/08
    • F25J3/08F25J3/0426F25J3/04278F25J3/04351F25J3/04412F25J2200/02F25J2200/04F25J2200/30F25J2200/34F25J2205/40F25J2205/84F25J2210/42F25J2210/50F25J2215/44F25J2215/56F25J2215/58F25J2220/42F25J2220/44F25J2220/50F25J2220/52F25J2235/02F25J2270/42F25J2270/904F25J2280/02
    • A process and apparatus for the ultrapurification of cryogenic low boiling liquified gases such as oxygen and nitrogen which contain trace impurities. The impure gas is introduced into a first distillation column provided with a top column condenser and a bottom column reboiler. The impure gas is substantially at its liquid-gas equilibrium temperature at the pressures within the first distillation column. Here the gas is separated by distillation into a first vapor fraction containing low boiling point impurities and a first liquid fraction containing high boiling point impurities. The first vapor fraction is withdrawn and introduced into a second distillation column provided with a top column condenser and a bottom column reboiler. The first vapor fraction is substantially at the liquid-gas equilibrium temperature at the pressures within the second distillation column. Here the vapor fraction is separated by distillation into a second vapor fraction containing low boiling point impurities and a second liquid fraction free of trace impurities which is withdrawn as product. Cooling for the process is provided by indirect heat exchange with a cryogenic low boiling gas such as nitrogen, oxygen, or air. The gas to be purified as well as the heat exchange gas can be obtained from a standard air separation unit or the process can be conducted using gases and liquids obtained from storage.
    • 用于低温低沸点液化气体如氧气和氮气超纯化的方法和设备,其含有微量杂质。 将不纯气体引入设置有顶塔冷凝器和底塔再沸器的第一蒸馏塔中。 不纯气体在第一蒸馏塔内的压力下基本处于液 - 气平衡温度。 这里,通过蒸馏将气体分离成含有低沸点杂质的第一蒸气馏分和含有高沸点杂质的第一液体馏分。 取出第一蒸气馏分并将其引入设置有顶塔冷凝器和底塔再沸器的第二蒸馏塔中。 第一蒸气馏分在第二蒸馏塔内的压力下基本处于液 - 气平衡温度。 这里通过蒸馏将蒸气馏分分离成含有低沸点杂质的第二蒸气馏分和作为产物取出的无痕量杂质的第二液体部分。 通过与低温低沸点气体如氮气,氧气或空气的间接热交换来提供该方法的冷却。 待净化的气体以及热交换气体可以从标准空气分离单元获得,或者可以使用从储存器获得的气体和液体进行该过程。