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111. 发明申请

US20120161120A1 COMPOSITIONS OF ELECTRICALLY CONDUCTING POLYMERS MADE WITH ULTRA-PURE FULLY-FLUORINATED ACID POLYMERS 审中-公开
标题翻译：具有超纯全氟化聚合物的电导体聚合物组合物
公开(公告)号：US20120161120A1
公开(公告)日：2012-06-28
申请号：US13416316
申请日：2012-03-09
申请人： Che-Hsiung Hsu , Mark T. Martello , Hjalti Skulason
发明人： Che-Hsiung Hsu , Mark T. Martello , Hjalti Skulason
IPC分类号： H01L51/54 , H01B1/12
CPC分类号： H01B1/127 , C08L65/00 , H01L51/0036 , H01L51/5048 , H01L51/5088 , Y10T428/3154 , C08L2666/04 , C08L27/12
摘要： There is provided an electrically conductive polymer composition. The composition contains an electrically conductive polymer made with an ultra-pure fully-fluorinated acid polymer.
摘要翻译：提供导电聚合物组合物。该组合物含有由超纯全氟化酸聚合物制成的导电聚合物。

112. 发明授权

US08147719B2 Conductive polymer compositions 失效
标题翻译：导电聚合物组合物
公开(公告)号：US08147719B2
公开(公告)日：2012-04-03
申请号：US11756985
申请日：2007-06-01
申请人： Hjalti Skulason , Mark T. Martello , Che-Hsiung Hsu
发明人： Hjalti Skulason , Mark T. Martello , Che-Hsiung Hsu
IPC分类号： H01B1/00 , C08G73/06
CPC分类号： H01B1/127 , C08G61/123 , C08L33/16 , C08L65/00 , H01B1/122 , H01B1/124 , H01B1/128 , H01L51/0035 , C08L2666/04
摘要： Electrically conductive polymer compositions are provided. The compositions are dispersed in an aqueous liquid medium having an oxygen content less than 10% of the saturated level. The compositions can be an electrically conductive polymer doped with a fluorinated acid polymer, an electrically conductive polymer in admixture with a fluorinated acid polymer, or mixtures thereof. The conductive polymer composition has a conductivity that changes by less than 10% in 30 days.
摘要翻译：提供导电聚合物组合物。将组合物分散在氧含量低于饱和水平的10％的含水液体介质中。组合物可以是掺杂有氟化酸聚合物的导电聚合物，与氟化酸聚合物混合的导电聚合物，或其混合物。导电聚合物组合物的导电率在30天内变化小于10％。

113. 发明授权

US08142686B2 Electrically conductive polymer compositions 有权
标题翻译：导电聚合物组合物
公开(公告)号：US08142686B2
公开(公告)日：2012-03-27
申请号：US12633903
申请日：2009-12-09
申请人： Che-Hsiung Hsu , Hong Meng , Yulong Shen , Ming Zheng
发明人： Che-Hsiung Hsu , Hong Meng , Yulong Shen , Ming Zheng
IPC分类号： H01B1/00 , C08G75/00 , C08G73/06
CPC分类号： H01B1/122 , C08F234/00 , C09D139/00 , H01L51/004 , H01L51/5088
摘要： The present invention relates to electrically conductive polymer compositions, and their use in organic electronic devices. The electrically conductive polymer compositions include an intrinsically conductive polymer having at least one monomer unit derived from Formula I: where: Q=N, CR5 X=N, CR6 Z=NH, S, O, Se, Te R1 through R4 can be H, F, Cl, C1-C24 alkyl, C2-C24 alkenyl, aryl, C1-C10 alkoxy, C1-C10 alkylseleno, C1-C10 alkylthio, C1-C10 alkylsilyl, NH2, or C1-C10 dialkylamino, where adjacent R groups can join together to form a 5- or 6-membered aliphatic or aromatic rings, with the proviso that at least one of R1 through R4 is NH2, and at least one of R1 through R6 is H, and. R5 and R6 can be H, C1-C24 alkyl, C2-C24 alkenyl, and aryl. The electrically conducting polymer is doped with a non-fluorinated acid polymer.
摘要翻译：本发明涉及导电聚合物组合物及其在有机电子器件中的用途。导电聚合物组合物包括具有至少一种衍生自式I的单体单元的固有导电聚合物：其中：Q = N，CR5 X = N，CR 6 Z = NH，S，O，Se，Te R1至R4可以是H ，F，Cl，C 1 -C 24烷基，C 2 -C 24烯基，芳基，C 1 -C 10烷氧基，C 1 -C 10烷基硒，C 1 -C 10烷硫基，C 1 -C 10烷基甲硅烷基，NH 2或C 1 -C 10二烷基氨基，其中相邻的R基团连接在一起形成5或6元脂肪族或芳香环，条件是R 1至R 4中的至少一个为NH 2，并且R 1至R 6中的至少一个为H。 R 5和R 6可以是H，C 1 -C 24烷基，C 2 -C 24烯基和芳基。导电聚合物掺杂有非氟化酸聚合物。

114. 发明授权

US08062553B2 Compositions of polyaniline made with perfuoropolymeric acid which are heat-enhanced and electronic devices made therewith 失效
标题翻译：由加热增强的丙烯聚合物制成的聚苯胺的组合物和由其制成的电子器件
公开(公告)号：US08062553B2
公开(公告)日：2011-11-22
申请号：US11960790
申请日：2007-12-20
申请人： Che-Hsiung Hsu , Hjalti Skulason
发明人： Che-Hsiung Hsu , Hjalti Skulason
IPC分类号： H01B1/12
CPC分类号： H01L51/0035 , C08L79/02 , C08L81/00 , C08L81/10 , H01B1/128 , H01L51/5088
摘要： Electrically conductive dispersions of high pH polyaniline/perfluorosulfonic acid or perfluoroalkylene sulfonamide polymers are provided. Also provided are films made with such dispersions having enhanced electrical conductivity. Devices are provided with at least one layer comprised of a film that is baked at a temperature above 100° C. Further provided are processes for making films and layers for devices comprising such films.
摘要翻译：提供高pH聚苯胺/全氟磺酸或全氟亚烷基磺酰胺聚合物的导电分散体。还提供了由具有增强的导电性的这种分散体制成的膜。设备设置有至少一层，该层由在100℃以上的温度下烘烤的膜构成。进一步提供了用于制造包含这种膜的器件的膜和层的工艺。

115. 发明申请

US20110049431A1 ELECTRICALLY CONDUCTIVE POLYMER COMPOSITIONS 有权
标题翻译：电导电聚合物组合物
公开(公告)号：US20110049431A1
公开(公告)日：2011-03-03
申请号：US12633903
申请日：2009-12-09
申请人： Che-Hsiung Hsu , Hong Meng , Yulong Shen , Ming Zheng
发明人： Che-Hsiung Hsu , Hong Meng , Yulong Shen , Ming Zheng
IPC分类号： H01B1/12
CPC分类号： H01B1/122 , C08F234/00 , C09D139/00 , H01L51/004 , H01L51/5088
摘要： The present invention relates to electrically conductive polymer compositions, and their use in organic electronic devices. The electrically conductive polymer compositions include an intrinsically conductive polymer having at least one monomer unit derived from Formula I: where: Q=N, CR5 X=N, CR6 Z=NH, S, O, Se, Te R1 through R4 can be H, F, Cl, C1-C24 alkyl, C2-C24 alkenyl, aryl, C1-C10 alkoxy, C1-C10 alkylseleno, C1-C10 alkylthio, C1-C10 alkylsilyl, NH2, or C1-C10 dialkylamino, where adjacent R groups can join together to form a 5- or 6-membered aliphatic or aromatic rings, with the proviso that at least one of R1 through R4 is NH2, and at least one of R1 through R6 is H, and. R5 and R6 can be H, C1-C24 alkyl, C2-C24 alkenyl, and aryl. The electrically conducting polymer is doped with a non-fluorinated acid polymer.
摘要翻译：本发明涉及导电聚合物组合物及其在有机电子器件中的用途。导电聚合物组合物包括具有至少一种衍生自式I的单体单元的固有导电聚合物：其中：Q = N，CR5 X = N，CR 6 Z = NH，S，O，Se，Te R1至R4可以是H ，F，Cl，C 1 -C 24烷基，C 2 -C 24烯基，芳基，C 1 -C 10烷氧基，C 1 -C 10烷基硒，C 1 -C 10烷硫基，C 1 -C 10烷基甲硅烷基，NH 2或C 1 -C 10二烷基氨基，其中相邻的R基团连接在一起形成5或6元脂肪族或芳香环，条件是R 1至R 4中的至少一个为NH 2，并且R 1至R 6中的至少一个为H。 R 5和R 6可以是H，C 1 -C 24烷基，C 2 -C 24烯基和芳基。导电聚合物掺杂有非氟化酸聚合物。

116. 发明授权

US07837901B2 Electrically conductive polymer compositions 有权
标题翻译：导电聚合物组合物
公开(公告)号：US07837901B2
公开(公告)日：2010-11-23
申请号：US11475715
申请日：2006-06-27
申请人： Che-Hsiung Hsu , Christopher P. Junk , Frank P. Uckert , Mark F. Teasley , Andrew Edward Feiging , Charles J. Dubois , Natalie Daoud , Viascheslav A. Petrov , Zheng-Yu Yang , Amy Qi Han, legal representative
发明人： Che-Hsiung Hsu , Christopher P. Junk , Frank P. Uckert , Mark F. Teasley , Andrew Edward Feiging , Charles J. Dubois , Natalie Daoud , Viascheslav A. Petrov , Zheng-Yu Yang
IPC分类号： H01B1/00 , C08G75/00 , C08G75/32
CPC分类号： H01B1/127 , C08L23/26 , C08L65/00 , C08L73/02 , C09D165/00 , C09D179/02 , H01B1/128 , C08L2666/04 , C08L27/00
摘要： There are provided electrically conducting polymer compositions comprising an electrically conductive polymer or copolymer and an organic solvent wettable fluorinated acid polymer. Electrically conductive polymer materials are derived from thiophene, pyrrole, aniline and polycyclic heteroaromatic precursor monomers. Non-conductive polymers derived from alkenyl, alkynyl, arylene, and heteroarylene precursor monomers. The organic-solvent wettable fluorinated acid polymer is fluorinated or highly fluorinated and may be colloid-forming. Acidic groups include carboxylic acid groups, sulfonic acid groups, sulfonimide groups, phosphoric acid groups, phosphonic acid groups, and combinations thereof. The compositions can be used in organic electronic devices.
摘要翻译：提供了包含导电聚合物或共聚物和有机溶剂可湿性氟化酸聚合物的导电聚合物组合物。导电聚合物材料衍生自噻吩，吡咯，苯胺和多环杂芳族前体单体。衍生自烯基，炔基，亚芳基和亚杂芳基前体单体的非导电聚合物。有机溶剂可湿性氟化酸聚合物是氟化的或高度氟化的，可以是胶体形成。酸性基团包括羧酸基团，磺酸基团，磺酰亚胺基团，磷酸基团，膦酸基团及其组合。组合物可用于有机电子器件。

117. 发明申请

US20100187982A1 BUFFER BILAYERS FOR ELECTRONIC DEVICES 有权
标题翻译：电子设备缓冲器
公开(公告)号：US20100187982A1
公开(公告)日：2010-07-29
申请号：US12642093
申请日：2009-12-18
申请人： Che-Hsiung Hsu , Weiying Gao , Shiva Prakash
发明人： Che-Hsiung Hsu , Weiying Gao , Shiva Prakash
IPC分类号： H01L51/54 , B32B5/16
CPC分类号： H01L51/5088 , H01L51/0037 , H01L51/004 , H01L2251/5369 , Y10T428/24893
摘要： The present invention relates to buffer bilayers, and their use in electronic devices. The bilayer has a first layer including (a) at least one electrically conductive polymer doped with at least one non-highly-fluorinated acid polymer and (b) at least one highly-fluorinated acid polymer, and a second layer including inorganic nanoparticles which are oxides or sulfides.
摘要翻译：本发明涉及缓冲双层体及其在电子设备中的应用。双层具有第一层，其包括（a）至少一种掺杂有至少一种非高度氟化的酸聚合物的导电聚合物和（b）至少一种高度氟化的酸聚合物，以及包含无机纳米颗粒的第二层，氧化物或硫化物。

118. 发明授权

US07744777B2 Water dispersible polyanilines made with polymeric acid colloids for electronics applications 有权
标题翻译：用聚合酸胶体制成的水分散聚苯胺用于电子应用
公开(公告)号：US07744777B2
公开(公告)日：2010-06-29
申请号：US12062657
申请日：2008-04-04
申请人： Che-Hsiung Hsu , Frank P. Uckert
发明人： Che-Hsiung Hsu , Frank P. Uckert
IPC分类号： H05B1/00
CPC分类号： C08L79/02 , B82Y10/00 , B82Y30/00 , C08L33/02 , G11C13/0014 , G11C13/0016 , G11C17/16 , G11C17/165 , G11C2213/51 , H01B1/128 , H01G11/48 , H01G11/56 , H01L51/0003 , H01L51/0021 , H01L51/0035 , H01L51/0541 , H01L51/50 , H01L51/5048 , H01L51/52 , Y02E10/549 , Y02E60/13 , Y10S428/917 , C08L2666/20 , C08L2666/06 , C08L2666/02
摘要： An electronic device is provided which is a thin field effect transistor, a field effect resistance device, photosensor, photoswitch, light-emitting diode, light-emitting diode display, phototransistor, phototube, IR detector, diode laser, electrochemic displays, electromagnetic shielding device, solid electrolyte capacitors, energy storage device, memory storage device, biosensor, photoconductive cell, photovoltaic device, solar cell or diode, and comprises at least one layer comprising a composition comprising at least one polyaniline and at least one colloid-forming polymeric acid. Methods for making such devices are also provided.
摘要翻译：提供一种电子器件，它是一个薄场效应晶体管，一个场效应器件，光电传感器，光开关，发光二极管，发光二极管显示器，光电晶体管，光电管，红外探测器，二极管激光器，电化学显示器，电磁屏蔽装置固体电解质电容器，能量存储装置，存储器存储装置，生物传感器，光电导元件，光电器件，太阳能电池或二极管，并且包括至少一层包含至少一种聚苯胺和至少一种胶体形成聚合酸的组合物。还提供了制造这种装置的方法。

119. 发明授权

US07732062B1 Charge transport layers and organic electron devices comprising same 失效
标题翻译：电荷传输层和包含它们的有机电子器件
公开(公告)号：US07732062B1
公开(公告)日：2010-06-08
申请号：US11319940
申请日：2005-12-28
申请人： Che-Hsiung Hsu , Weiying Gao , Hong Meng
发明人： Che-Hsiung Hsu , Weiying Gao , Hong Meng
IPC分类号： A61K31/498
CPC分类号： H01L51/002 , B82Y10/00 , H01L51/0039 , H01L51/0046 , H01L51/0051 , H01L51/0054 , H01L51/0059 , H01L51/0071 , H01L51/0072 , H01L51/5052
摘要： Provided are organic n-doped electron transport layers comprising at least one electron transport material and at least one electron rich dopant material and organic p-doped hole injection layers comprising at least one hole transport material and at least one electron deficient dopant material.
摘要翻译：提供了包括至少一种电子传输材料和至少一种富电子掺杂剂材料的有机n掺杂电子传输层和包含至少一种空穴传输材料和至少一种电子缺陷掺杂剂材料的有机p掺杂空穴注入层。

120. 发明申请

US20100127222A1 HIGH WORK FUNCTION TRANSPARENT CONDUCTORS 有权
公开(公告)号：US20100127222A1
公开(公告)日：2010-05-27
申请号：US11476979
申请日：2006-06-28
申请人： Che-Hsiung Hsu , Hjalti Skulason
发明人： Che-Hsiung Hsu , Hjalti Skulason
IPC分类号： H01B1/04 , H01B1/12 , H01B1/22 , H01B1/24
CPC分类号： H01L51/0048 , B82Y10/00 , B82Y20/00 , B82Y30/00 , H01L51/5206 , H01L2251/5369 , Y10S977/783 , Y10S977/784 , Y10S977/788
摘要： There is provided a transparent conductor including conductive nanoparticles and at least one of (a) a fluorinated acid polymer and (b) a semiconductive polymer doped with a fluorinated acid polymer. The nanoparticles are carbon nanoparticles, metal nanoparticles, or combinations thereof. The carbon and metal nanoparticles are selected from nanotubes, fullerenes, and nanofibers. The acid polymers are fluorinated or highly fluorinated and have acidic groups including carboxylic acid groups, sulfonic acid groups, sulfonimide groups, phosphoric acid groups, phosphonic acid groups, and combinations thereof. The semiconductive polymers comprise homopolymers and copolymers derived from monomers selected from substituted and unsubstituted thiophenes, pyrroles, anilines, and cyclic heteroaromatics, and combinations of those. The compositions may be used in organic electronic devices (OLEDs).

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