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111. 发明授权

US4346080A Cyclohexyl phenethylether used for combatting tobacco beetles 失效
标题翻译：用于打击烟草甲虫的环己基苯乙醚
公开(公告)号：US4346080A
公开(公告)日：1982-08-24
申请号：US267905
申请日：1981-05-28
申请人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
发明人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
IPC分类号： A01N31/06 , C07C43/168 , C11B9/00 , A01N25/00
CPC分类号： C11B9/0038 , A01N31/06 , C07C43/168 , C11B9/0061
摘要： Described is the compound cyclohexyl phenethylether having the structure: ##STR1## which has been found to be useful in augmenting or enhancing the aroma of perfumes and perfumed articles as well as colognes and, in addition, in combatting tobacco beetles of the species Lasioderma serricorne (F.).
摘要翻译：描述了具有以下结构的化合物环己基苯乙醚：已被发现可用于增强或增强香料和香料制品以及古龙水的芳香，并且另外还可用于对抗Lasioderma serricorne的烟草甲虫（ F。）。

112. 发明授权

US4337180A Use of cyclohexyl phenethylether in augmenting or enhancing the aroma of perfumes and colognes 失效
标题翻译：使用环己基苯乙醚增强或增强香水和古龙水的香气
公开(公告)号：US4337180A
公开(公告)日：1982-06-29
申请号：US267851
申请日：1981-05-28
申请人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
发明人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
IPC分类号： A01N31/06 , C07C43/168 , C11B9/00 , A61K7/46
CPC分类号： C11B9/0038 , A01N31/06 , C07C43/168 , C11B9/0061
摘要： Described is the compound cyclohexyl phenethylether having the structure: ##STR1## which has been found to be useful in augmenting or enhancing the aroma of perfumes and perfumed articles as well as colognes and, in addition, in combatting tobacco beetles of the species Lasioderma serricorne (F.).
摘要翻译：描述了具有以下结构的化合物环己基苯乙醚：已被发现可用于增强或增强香料和香料制品以及古龙水的芳香，并且另外还可用于对抗Lasioderma serricorne的烟草甲虫（ F。）。

113. 发明授权

US4324923A Cyclohexyl phenethylether derivative 失效
标题翻译：环己基苯乙醚衍生物
公开(公告)号：US4324923A
公开(公告)日：1982-04-13
申请号：US235844
申请日：1981-02-19
申请人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
发明人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
IPC分类号： A01N31/06 , C07C43/168 , C11B9/00 , C07C43/184
CPC分类号： C11B9/0038 , A01N31/06 , C07C43/168 , C11B9/0061
摘要： Described is the genus of compounds defined according to the structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each represents methyl or hydrogen with the proviso that one of R.sub.2, R.sub.3 and R.sub.4 is methyl and the other two of R.sub.2, R.sub.3 and R.sub.4 are hydrogen which have been found to be useful in augmenting or enhancing the aroma of perfumes and perfumed articles as well as colognes and, in addition, in combatting tobacco beetles of the species Lasioderma serricorne (F.). Also described are novel processes for preparing such cyclohexyl phenethylether derivatives by reacting cyclohexene having the structure: ##STR2## with a phenethyl alcohol derivative having the structure: ##STR3## in the presence of an acid catalyst.
摘要翻译：描述了根据以下结构定义的化合物属：其中R 1，R 2，R 3和R 4相同或不同，并且各自表示甲基或氢，条件是R 2，R 3和R 4中的一个为甲基，另一个为已经发现R2，R3和R4中的两个是氢，其可用于增强或增强香料和香料制品以及古龙水的香气，并且另外用于对抗Lasioderma serricorne（F.）的烟草甲虫。还描述了通过在酸催化剂存在下使具有以下结构的环己烯与具有以下结构的苯乙醇衍生物反应来制备这种环己基苯乙醚衍生物的新方法：

114. 发明授权

US4362657A Use of cyclohexyl phenethylether derivative in augmenting or enhancing the aromas of perfumes and colognes 失效
标题翻译：使用环己基苯乙醚衍生物来增强或增强香水和古龙水的香气
公开(公告)号：US4362657A
公开(公告)日：1982-12-07
申请号：US305538
申请日：1981-09-25
申请人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
发明人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
IPC分类号： A01N31/06 , C07C43/168 , C11B9/00 , A61K7/46
CPC分类号： A01N31/06 , C07C43/168 , C11B9/0038 , C11B9/0061
摘要： Described is the genus of compounds defined according to the structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each represents methyl or hydrogen with the proviso that one of R.sub.2, R.sub.3 and R.sub.4 is methyl and the other two of R.sub.2, R.sub.3 and R.sub.4 are hydrogen which have been found to be useful in augmenting or enhancing the aroma of perfumes and perfumed articles as well as colognes and, in addition, in combatting tobacco beetles of the species Lasioderma serricorne (F.). Also described are novel processes for preparing such cyclohexyl phenethylether derivatives by reacting cyclohexene having the structure: ##STR2## with a phenethyl alochol derivative having the structure: ##STR3## in the presence of an acid catalyst.
摘要翻译：描述了根据以下结构定义的化合物属：其中R 1，R 2，R 3和R 4相同或不同，并且各自表示甲基或氢，条件是R 2，R 3和R 4中的一个为甲基，另一个为已经发现R2，R3和R4中的两个是氢，其可用于增强或增强香料和香料制品以及古龙水的香气，并且另外用于对抗Lasioderma serricorne（F.）的烟草甲虫。还描述了通过在酸催化剂存在下使具有以下结构的环己烯与具有以下结构的苯乙基醇的衍生物反应制备这种环己基苯乙醚衍生物的新方法：

115. 发明授权

US4335008A Process for augmenting or enhancing the aroma of detergents using cyclohexyl phenethylether 失效
标题翻译：使用环己基苯乙醚增强或增强洗涤剂香气的方法
公开(公告)号：US4335008A
公开(公告)日：1982-06-15
申请号：US267900
申请日：1981-05-28
申请人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
发明人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
IPC分类号： A01N31/06 , C07C43/168 , C11B9/00 , C11D3/50
CPC分类号： A01N31/06 , C07C43/168 , C11B9/0038 , C11B9/0061 , C11D3/50
摘要： Described is the compound cyclohexyl phenethylether having the structure: ##STR1## which has been found to be useful in augmenting or enhancing the aroma of perfumes and perfumed articles as well as colognes and, in addition, in combatting tobacco beetles of the species Lasioderma serricorne (F.)
摘要翻译：描述了具有以下结构的化合物环己基苯乙醚：已被发现可用于增强或增强香料和香料制品以及古龙水的芳香，并且另外还可用于对抗Lasioderma serricorne的烟草甲虫（ F。

116. 发明授权

US4306096A Cyclohexyl phenethylether 失效
标题翻译：环己基苯乙醚
公开(公告)号：US4306096A
公开(公告)日：1981-12-15
申请号：US192238
申请日：1980-09-30
申请人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
发明人： Jacob Kiwala , Richard J. Tokarzewski , Frederick L. Schmitt , Mark A. Sprecker
IPC分类号： C07C43/164 , A01N31/06 , A23L27/20 , A24B3/12 , A61K8/33 , A61Q13/00 , C07C41/00 , C07C41/05 , C07C43/168 , C07C43/188 , C07C67/00 , C11B9/00
CPC分类号： A01N31/06 , C07C43/168 , C11B9/0038 , C11B9/0061
摘要： Described is the compound cyclohexyl phenethylether having the structure: ##STR1## which has been found to be useful in augmenting or enhancing the aroma of perfumes and perfumed articles as well as colognes and, in addition, in combatting tobacco beetles of the species Lasioderma serricorne (F.)
摘要翻译：描述了具有以下结构的化合物环己基苯乙醚：已被发现可用于增强或增强香料和香料制品以及古龙水的芳香，并且另外还可用于对抗Lasioderma serricorne的烟草甲虫（ F。

117. 发明授权

US5188129A Tricyclic ether-substituted acetic acid, tobacco flavoring use thereof and process for preparing same 失效
标题翻译：三环醚取代乙酸，烟草调味用途及其制备方法
公开(公告)号：US5188129A
公开(公告)日：1993-02-23
申请号：US759992
申请日：1991-09-13
申请人： Mohamad I. Farbood , James A. Morris , Arthur E. Downey , Jacob Kiwala
发明人： Mohamad I. Farbood , James A. Morris , Arthur E. Downey , Jacob Kiwala
IPC分类号： C12P7/02 , C12P17/04 , C12P17/06
CPC分类号： C12R1/645 , C12P17/04 , C12P17/06 , C12P7/02
摘要： Described are smoking tobacco compositions comprising smoking tobacco and intimately admixed therewith an aroma or taste augmenting, enhancing or imparting quantity of a tricyclic ether-substituted acetic acid having the structure: ##STR1##
摘要翻译：描述了吸烟烟草组合物，其包括吸烟烟草并且与其充分混合增加，增强或赋予量的具有以下结构的三环醚取代的乙酸的香味或味道：

118. 发明授权

US4485828A Use of substituted methyl isopropyl cyclohexenones in augmenting or enhancing the aroma or taste of smoking tobacco compositions and smoking tobacco article components 失效
标题翻译：取代的甲基异丙基环己烯酮在增加或增强吸烟烟草组合物和吸烟烟草制品组分的香气或味道中的用途
公开(公告)号：US4485828A
公开(公告)日：1984-12-04
申请号：US492013
申请日：1983-05-05
申请人： Philip T. Klemarczyk , Lambert Dekker , Jacob Kiwala
发明人： Philip T. Klemarczyk , Lambert Dekker , Jacob Kiwala
IPC分类号： A24B15/34 , C07C45/72 , C07C45/74 , C11B9/00 , C11D3/50 , A24B3/12 , A24B15/30 , A24D1/00
CPC分类号： C11D3/50 , A24B15/34 , C07C45/72 , C07C45/74 , C11B9/0034
摘要： Described is a process for augmenting or enhancing the aroma or taste of smoking tobacco compositions and/or smoking tobacco article components comprising the step of adding to a smoking tobacco composition and/or smoking tobacco article component, an aroma or taste augmenting or enhancing quantity of at least one compound defined according to the structure: ##STR1## wherein one of the dashed lines represents a carbon-carbon double bond and the other of the dashed lines represents a carbon-carbon single bond; wherein R.sub.4 represents methyl or ethyl; wherein one of R.sub.1, R.sub.2 and R.sub.3 represents 2-methyl-1-propenyl or 2-methyl-1-propylidenyl; and the other of R.sub.1, R.sub.2 and R.sub.3 represent hydrogen; with the provisos that:(i) when the dashed line at the 3-4 position is a double bond, then R.sub.3 is hydrogen or 2-methyl-1-propenyl;(ii) when the dashed line at the 2-3 position is a double bond, then R.sub.2 is hydrogen or 2-methyl-1-propenyl;(iii) when R.sub.4 is ethyl, then R.sub.2 is methyl and the double bond is at the 2-3 position; and(iv) when R.sub.4 is methyl, then R.sub.2 is hydrogen; 2-methyl-1-propenyl or 2-methyl-1-propylidenyl;with the members of said genus being novel compounds when R.sub.4 is ethyl or when R.sub.4 is methyl and the double bond is at the 3-4 position or when R.sub.4 is methyl and the double bond is at the 2-3 position with R.sub.3 being hydrogen.
摘要翻译：描述了用于增强或增强吸烟烟草组合物和/或烟草制品组分的香味或味道的方法，其包括将吸烟烟草组合物和/或烟草制品组分添加到香烟或味道增强或增加量的步骤至少一种根据以下结构定义的化合物：其中虚线中的一条代表碳 - 碳双键，另一条虚线代表碳 - 碳单键; 其中R 4表示甲基或乙基; 其中R 1，R 2和R 3中的一个表示2-甲基-1-丙烯基或2-甲基-1-丙基; R1，R2和R3中的另一个表示氢; 条件是：（i）当3-4位的虚线是双键时，则R3是氢或2-甲基-1-丙烯基; （ii）当2-3位的虚线为双键时，则R2为氢或2-甲基-1-丙烯基; （iii）当R 4为乙基时，R 2为甲基，双键为2-3位; 和（iv）当R 4为甲基时，则R 2为氢; 2-甲基-1-丙烯基或2-甲基-1-亚丙基; 当R 4是乙基时，或当R 4是甲基时，所述属的成员是新化合物，并且双键在3-4位，或者当R4是甲基时，并且双键在R3是氢的2-3位。

119. 发明授权

US4084009A Flavoring with a hydroxy cyclohexenone derivative 失效
标题翻译：用羟基环己烯酮衍生物调味
公开(公告)号：US4084009A
公开(公告)日：1978-04-11
申请号：US774059
申请日：1977-03-03
申请人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred Hugo Vock , Edward J. Shuster
发明人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred Hugo Vock , Edward J. Shuster
IPC分类号： A23G4/00 , A23G4/06 , A23L27/20 , A24B15/34 , C07C13/23 , C07C29/40 , C07C29/50 , C07C45/59 , C07D317/72 , C11B9/00 , A23L1/226
CPC分类号： A23G4/06 , A23L27/203 , A24B15/34 , C07C13/23 , C07C29/40 , C07C45/34 , C07C45/59 , C07D317/72 , C11B9/0034 , C07C2101/16
摘要： Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, tobacco flavor and aroma, perfume and perfumed article aroma augmenting, enhancing and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product, tobacco, perfume and perfumed article aroma imparting materials of hydroxy cyclohexenone derivatives having the generic formula: ##STR1## wherein one of X and Y is a keto moiety having the structure: ##STR2## and the other of X and Y is a carbinol moiety having the structure: ##STR3## and wherein R is C.sub.1 -C.sub.5 alkyl.
摘要翻译：描述了用于食品，口香糖，牙膏和药用产品风味和香气，烟草香料和香气，香料和香料制品香气增强，增强和赋予组合物以及作为食品，口香糖，牙膏，药用产品的方法和组合物，烟草，香料和香料赋予的具有以下通式的羟基环己烯酮衍生物的芳香赋予材料：其中X和Y之一是具有以下结构的酮部分：X和Y是具有结构：，其中R是C 1 -C 5烷基。

120. 发明授权

US4449008A Substituted methyl isopropyl cyclohexenones, organoleptic uses thereof and process for preparing same 失效
标题翻译：取代的甲基异丙基环己烯酮，其感官用途及其制备方法
公开(公告)号：US4449008A
公开(公告)日：1984-05-15
申请号：US492010
申请日：1983-05-05
申请人： Philip T. Klemarczyk , Lambert Dekker , Jacob Kiwala
发明人： Philip T. Klemarczyk , Lambert Dekker , Jacob Kiwala
IPC分类号： A24B15/34 , C07C45/72 , C07C45/74 , C11B9/00 , C11D3/50 , C07C49/603 , C07C45/45
CPC分类号： C11D3/50 , A24B15/34 , C07C45/72 , C07C45/74 , C11B9/0034
摘要： Described is the genus of compounds defined according to the structure: ##STR1## wherein one of the dashed lines represents a carbon-carbon double bond and the other of the dashed lines represents a carbon-carbon single bond; wherein R.sub.4 represents methyl or ethyl; wherein one of R.sub.1, R.sub.2 and R.sub.3 represents 2-methyl-1-propenyl or 2-methyl-1-propylidenyl; and the other of R.sub.1, R.sub.2 and R.sub.3 represent hydrogen; with the provisos that:(i) when the dashed line at the 3-4 position is a double bond, then R.sub.3 is hydrogen or 2-methyl-1-propenyl;(ii) when the dashed line at the 2-3 position is a double bond, then R.sub.2 is hydrogen or 2-methyl-1-propenyl;(iii) when R.sub.4 is ethyl, then R.sub.2 is methyl and the double bond is at the 2-3 position; and(iv) when R.sub.4 is methyl, then R.sub.2 is hydrogen; 2-methyl-1-propenyl or 2-methyl-1-propylidenyl;with the members of said genus being novel compounds when R.sub.4 is ethyl or when R.sub.4 is methyl and the double bond is at the 3-4 position or when R.sub.4 is methyl and the double bond is at the 2-3 position with R.sub.3 being hydrogen, which compounds are useful in augmenting or enhancing the aroma or taste of consumable materials including smoking tobacco compositions, smoking tobacco articles, perfume compositions, colognes and perfumed articles (e.g. solid or liquid anionic, cationic, nonionic or zwitterionic detergents, cosmetic powder compositions, fabric softener compositions and fabric softener articles). Also described is the process for preparing the compound.
摘要翻译：描述根据以下结构定义的化合物属：其中虚线中的一条代表碳 - 碳双键，另一条虚线代表碳 - 碳单键; 其中R 4表示甲基或乙基; 其中R 1，R 2和R 3中的一个表示2-甲基-1-丙烯基或2-甲基-1-丙基; R1，R2和R3中的另一个表示氢; 条件是：（i）当3-4位的虚线是双键时，则R3是氢或2-甲基-1-丙烯基; （ii）当2-3位的虚线为双键时，则R2为氢或2-甲基-1-丙烯基; （iii）当R 4为乙基时，R 2为甲基，双键为2-3位; 和（iv）当R 4为甲基时，则R 2为氢; 2-甲基-1-丙烯基或2-甲基-1-亚丙基; 当R4是乙基时或当R4是甲基，双键在3-4位时，或当R4是甲基，双键在R3位置是R3是氢时，所述属的成员是新的化合物，这些化合物可用于增强或增强消费材料的香气或味道，包括吸烟烟草组合物，烟草制品，香水组合物，古龙水和香料制品（例如固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，化妆品粉末组合物，织物软化剂组合物和织物柔软剂制品）。还描述了制备化合物的方法。

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