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    • 119. 发明授权
    • Composition and process for production of copper circuitry in microelectronic device structures
    • 在微电子器件结构中生产铜电路的组成和工艺
    • US06589329B1
    • 2003-07-08
    • US09522102
    • 2000-03-09
    • Thomas H. BaumChongying Xu
    • Thomas H. BaumChongying Xu
    • C23C1616
    • C23C16/18C07F1/08C07F7/0803
    • Compositions useful for chemical vapor delivery (CVD) formation of copper layers in semiconductor integrated circuits, e.g., interconnect metallization in semiconductor device structures, as an adhesive seed layer for plating, for the deposition of a thin-film recording head or for circuitization of packaging components. The copper precursor formulation may include one or more copper precursors, e.g., a precursor of the formula hfac(Cu)L where L is a low-cost ligand such as an alkene and/or alkyne such as [(hfac)Cu]2 (DMDVS). The formulation may include in addition to the copper precursor(s) one or more low-cost ligand species such as alkenes, alkynes, dienes and combinations thereof, to increase thermal stability of the formulation and provide enhanced vaporization properties for CVD.
    • 可用于半导体集成电路中铜层的化学气相传输(CVD)形成的组合物,例如半导体器件结构中的互连金属化,用于电镀的粘合种子层,用于沉积薄膜记录头或用于封装的电路化 组件。 铜前体制剂可以包括一种或多种铜前体,例如式hfac(Cu)L的前体,其中L是低成本配体如烯烃和/或炔烃,例如[(hfac)Cu] 2( DMDVS)。 除了铜前体之外,配方可以包括一种或多种低成本配体物质,例如烯烃,炔,二烯及其组合,以增加制剂的热稳定性并提供CVD的增强的气化性质。