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    • 104. 发明申请
    • PROCESS FOR COMPLETE ANAEROBIC DIGESTION OF POLYMER MIXTURES
    • 聚合物混合物完全厌氧消解的方法
    • US20140017752A1
    • 2014-01-16
    • US13937753
    • 2013-07-09
    • BASF SE
    • Carsten SinkelRobert LoosKarlheinz JochemKai Oliver SiegenthalerXin YangUlf KüperMathias Zimmermann
    • C12P5/02
    • C12P5/023B09B3/00C08J11/105C08J2367/04C12P7/625Y02E50/343Y02W30/702
    • The present invention relates to a process for complete anaerobic digestion of polymer mixtures comprising: a) 25 to 95% by weight of a polyhydroxyalkanoate selected from the group consisting of poly-4-hydroxybutyrates, poly-3-hydroxybutyrates, poly(3-hydroxybutyrate-co-3-hydroxyvalerates), poly(3-hydroxybutyrate-co-3-hydroxyhexanoates) and poly(3-hydroxybutyrate-co-4-hydroxybutyrates), and b) 5 to 75% by weight of an aliphatic-aromatic polyester comprising: i) 65 to 95 mol %, based on components i to ii, of one or more C5-C36-dicarboxylic acid derivatives or C5-C36-dicarboxylic acids; ii) 35 to 5 mol %, based on components i to ii, of a terephthalic acid derivative or of a terephthalic acid; iii) 98 to 100 mol %, based on components i to ii, of an C2-C8-alkylenediol or C2-C6-oxyalkylenediol; iv) 0 to 2% by weight, based on components i to iii, of at least one polyfunctional compound comprising at least two isocyanate, isocyanurate, oxazoline or epoxide groups or at least three alcohol or carboxylic acid groups.
    • 本发明涉及聚合物混合物的完全厌氧消化的方法,其包括:a)25-95重量%的选自聚-4-羟基丁酸酯,聚-3-羟基丁酸酯,聚(3-羟基丁酸酯),聚羟基丁酸酯, - 3-羟基戊酸酯),聚(3-羟基丁酸酯 - 共-3-羟基己酸酯)和聚(3-羟基丁酸酯 - 共-4-羟基丁酸酯)和b)5至75重量%的脂族 - 芳族聚酯,其包含 :i)65至95摩尔%,基于组分i至ii,一种或多种C 5 -C 36二羧酸衍生物或C 5 -C 36二羧酸; ii)35至5摩尔%,基于组分i至ii,对苯二甲酸衍生物或对苯二甲酸; iii)基于组分i至ii的C 2 -C 8 - 亚烷基二醇或C 2 -C 6 - 氧化烯二醇的98至100摩尔% iv)基于组分i至iii的至少一种包含至少两种异氰酸酯,异氰脲酸酯,恶唑啉或环氧基团或至少三个醇或羧酸基团的多官能化合物为0至2重量%。
    • 108. 发明授权
    • Production of biodegradable thermoplastic materials from organic wastes
    • 从有机废物生产可生物降解的热塑性材料
    • US07141400B2
    • 2006-11-28
    • US10501052
    • 2003-01-15
    • Jian Yu
    • Jian Yu
    • C12P7/62C12P39/00
    • C08J11/105C08J2367/04C12M23/34C12M29/04C12P7/625Y02W30/702
    • A system and method for converting organic wastes to biodegradable thermoplastic materials including polyhydroxyalkanoates is disclosed, which method includes treating the organic wastes with an acidogenic microbial population to form fermentative organic acids, and polymerization of the organic acids by PHA-producing microbial species to form PHAs. The system includes a first compartment for acidogenesis of organic wastes without oxygen, and a second compartment, for polymer synthesis by enriched cultures of species with oxygen such as R. eutropha, P. oleovorans, or mixtures thereof. The compartments are integrated with barriers that permit mass transfer of organic acids while maintaining different culture conditions in the compartments.
    • 公开了一种将有机废物转化为可生物降解的热塑性材料(包括聚羟基链烷酸酯)的系统和方法,该方法包括用生酸微生物群体处理有机废物以形成发酵有机酸,并通过产生PHA的微生物物种聚合有机酸以形成PHAs 。 该系统包括用于无氧的有机废物的酸化的第一隔室,以及第二隔室,用于通过富氧物种富集的物种富集培养物进行聚合物合成,例如胡萝卜油,油菜素或其混合物。 隔室与允许有机酸传质的屏障整合,同时保持室内不同的培养条件。