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101. 发明申请

WO2008038173A2 POLYMERISATION (INCLUDING OLIGOMERISATION) OF OLEFINIC COMPOUNDS IN THE PRESENCE OF CATALYST, AND A CATALYST ACTIVATOR INCLUDING A HALOGENATED ORGANIC GROUP 审中-公开
标题翻译：在催化剂存在下烯烃化合物的聚合（包括低聚），以及包括卤化有机基团的催化剂活化剂
公开(公告)号：WO2008038173A2
公开(公告)日：2008-04-03
申请号：PCT/IB2007/053590
申请日：2007-09-06
申请人： SASOL TECHNOLOGY (PTY) LIMITED , TOOZE, Robert Paul , HANTON, Martin John , TENZA, Kenny
发明人： TOOZE, Robert Paul , HANTON, Martin John , TENZA, Kenny
IPC分类号： B01J31/22 , B01J31/18 , B01J31/14 , C08F4/70 , C08F10/00
CPC分类号： B01J31/1815 , B01J31/143 , B01J2231/122 , B01J2531/56 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C08F10/00 , C08F110/02 , C08F110/14 , C08F2500/02 , C08F4/69224 , C08F4/68224 , C08F4/60089 , C08F4/7042 , C08F4/7047
摘要： According to the present invention there is provided a process for producing a polymenc (including oligomenc) product by the polymerisation (including oligomeπsation) of at least one olefinic compound, by contacting the at least one olefinic compound with the combination of a polymerisation (including ohgomensation) catalyst and a catalyst activator The catalyst activator is a compound which includes at least one halogenated organic group which is bound to one or more binding atoms selected from the group consisting of a group 5A atom and a group 6A atom, which one or more binding atoms are in turn bound to a central atom in the form of aluminium The polymeπsation (including ohgomensation) catalyst includes the combination of ι) a source of a transition metal, and n) a ligating compound of the formula (I). The invention also relates to a combination of a polymerisation (including ohgomensation) catalyst and a catalyst activator and to the use of such a combination in a polymerisation (including ohgomensation) process.
摘要翻译：根据本发明，提供了通过至少一种烯属化合物的聚合（包括低聚）生产多聚（包括低聚）产物的方法，通过使至少一种烯属化合物与聚合（包括ohgomensation）催化剂和催化剂活化剂的组合。催化剂活化剂是包括至少一个卤代有机基团的化合物，所述卤代有机基团与选自5A族原子和基团中的一个或多个结合原子结合 6A原子，其中一个或多个结合原子又以铝的形式结合到中心原子上。聚合（包括ohgomensation）催化剂包括以下组合：1）过渡金属源，和n）公式（I）。本发明还涉及聚合（包括ohgomensation）催化剂和催化剂活化剂的组合以及这种组合在聚合（包括ohgomensation）工艺中的用途。

102. 发明申请

WO2007006740A1 SINGLE SITE CATALYST SYSTEMS HAVING A SCORPION-LIKE STRUCTURE 审中-公开
标题翻译：具有类似结构的单站催化剂体系
公开(公告)号：WO2007006740A1
公开(公告)日：2007-01-18
申请号：PCT/EP2006/063994
申请日：2006-07-06
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , HILLAIRET, Caroline , MICHAUD, Guillaume , SIROL, Sabine
发明人： HILLAIRET, Caroline , MICHAUD, Guillaume , SIROL, Sabine
IPC分类号： C08F4/622 , C08F10/00 , C08F4/70 , C07C2/32
CPC分类号： C08F10/00 , C07C2/32 , C07C2531/22 , C07D213/53 , C08F110/02 , C08F4/69224 , C08F2500/04 , C08F2500/02 , C08F2500/20 , C08F4/7042
摘要： The present invention discloses single site catalyst systems having scorpion-like three dimensional structure that are suitable for oligomerising or polymerising ethylene and alpha-olefins.
摘要翻译：本发明公开了具有适用于低聚或聚合乙烯和α-烯烃的蝎状三维结构的单中心催化剂体系。

103. 发明申请

WO2005082815A1 HETEROGENEOUS CHROMIUM CATALYSTS 审中-公开
标题翻译：异构铬催化剂
公开(公告)号：WO2005082815A1
公开(公告)日：2005-09-09
申请号：PCT/EP2005/050565
申请日：2005-02-09
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , BODART, Philippe , NENU, Cristina , WECKHUYSEN, Bert
发明人： BODART, Philippe , NENU, Cristina , WECKHUYSEN, Bert
IPC分类号： C07C2/32
CPC分类号： C07F11/005 , C08F110/02 , C08F4/22 , C08F4/025 , C08F4/69224
摘要： The present invention relates to a heterogeneous chromium catalyst system for the polymerisation of ethylene and/or alpha olefins prepared by the steps of: (a) providing a silica-containing support, (b) treating the silica-containing support with a chromium compound to form a chromium-based silica-containing support, (c) activating the chromium-based silica-containing support, (d) chemically reducing the activated chromium-based silica-containing support to produce a precursor catalyst, (e) reacting the reduced precursor catalyst with a tridentate ligand compound to obtain a catalyst and (f) optionally activating the catalyst issued from step (e) with a cocatalyst.
摘要翻译：本发明涉及通过以下步骤制备的用于聚合乙烯和/或α-烯烃的非均相铬催化剂体系：（a）提供含二氧化硅的载体，（b）用铬化合物处理含二氧化硅的载体，形成含铬基二氧化硅的载体，（c）活化含铬基二氧化硅的载体，（d）化学还原活性铬基二氧化硅载体以制备前体催化剂，（e）使还原前体具有三齿配体化合物的催化剂以获得催化剂和（f）任选地使用助催化剂活化由步骤（e）发出的催化剂。

104. 发明申请

WO2005063829A1 CATALYST SYSTEM FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：WO2005063829A1
公开(公告)日：2005-07-14
申请号：PCT/EP2004/014609
申请日：2004-12-22
申请人： BASELL POLYOLEFINE GMBH , MIHAN, Shahram
发明人： MIHAN, Shahram
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F4/6392 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F110/02 , C08F2420/02 , C08F4/025 , C08F4/69224 , C08F2500/17 , C08F2500/10 , C08F4/7042
摘要： The present invention relates to a catalyst system for olefin polymerization comprising an organic transition metal compound and, as cocatalyst, an ionic compound made up of anions of the formula (la), Where the radicals R 1 are identical or different and are each, independently of one another, a radical R 2 R 3 (CF 3 ) 2 , R 2 is a carbon or silicon atom and R 3 is hydrogen, C 1 -C 20 -alkyl, C 1 -C 20 -fluoroalkyl, C 6 -C 20 -aryl, C 6 -C 20 -fluoroaryl, C 7 -C 40 -arylalkyl, C 7 -C 40 -fluoroarylalkyl, C 7 -C 40 -alkylaryl, C 7 -C 40 -fluoroalkylaryl or an SiR 4 3 group, where R 4 may be identical or different and is each C 1 -C 20 -alkyl, C 1 -C 20 -fluoroalkyl, C 6 -C 20 -aryl, C 6 -C 20 fluoroaryl, C 7 -C 40 -arylalkyl, C 7 -C 40 -fluoroarylalkyl, C 7 -C 40 -alkylaryl or C 7 -C 40 -fluoroalkylaryl, and Lewis-acid cations or Brönsted acids as cations. In addition, the invention relates to the process for preparing such a catalyst system and to a process for the polymerization of olefins in which this catalyst system is used.
摘要翻译：本发明涉及一种用于烯烃聚合的催化剂体系，其包括有机过渡金属化合物和作为助催化剂的由式（Ia）的阴离子组成的离子化合物，其中基团R 1相同或不同，各自独立地为相互独立地是基团R 2 R 3（CF 3）2，R 2是碳或硅原子，R 3是氢，C 1 -C 20 - 烷基，C 1 -C 20 - 氟代烷基，C 6 -C 20 - 芳基，C 6 -C 20 - 氟代芳基，C 7 -C 40 - 芳烷基，C 7 -C 40 - 氟芳基烷基，C 7 -C 40 - 烷基芳基，C 7 -C 40 - 氟烷基芳基或SiR 4 3基团，其中R 4，可以相同或不同，为C 1 -C 20 - 烷基，C 1 -C 20 - 氟代烷基，C 6 -C 20 - 芳基，C 6 -C 20氟芳基，C 7 -C 40 - 芳基烷基，C 7 -C 40 - 氟芳基烷基，C 7 -C 40 - 烷基芳基或C 7 - C 40 - 氟烷基芳基和路易斯酸阳离子或布朗斯台德酸作为阳离子。此外，本发明涉及制备这种催化剂体系的方法以及使用该催化剂体系的烯烃聚合方法。

105. 发明申请

WO00059914A1 METAL COMPOUNDS CONTAINING NEUTRAL, MULTIDENTATE AZACYCLIC LIGANDS, CATALYSTS USING THEM, OLEFIN POLYMERIZATION METHODS USING THEM 审中-公开
标题翻译：含有中性，多种亚型配体的金属化合物，使用它们的催化剂，使用它们的烯烃聚合方法
公开(公告)号：WO00059914A1
公开(公告)日：2000-10-12
申请号：PCT/US2000/004757
申请日：2000-02-25
IPC分类号： C07F7/10 , B01J31/14 , B01J31/16 , B01J31/18 , C07F7/08 , C08F4/02 , C08F4/44 , C08F4/60 , C08F4/645 , C08F10/00 , C08F110/02 , C07F5/00 , B01J31/00 , B01J37/00 , C07D231/00 , C07D293/00
CPC分类号： C08F10/00 , B01J31/14 , B01J31/1608 , B01J31/1815 , B01J2531/46 , B01J2531/56 , B01J2531/62 , B01J2531/845 , B01J2531/847 , C07F7/0814 , C08F110/02 , C08F4/64089 , C08F4/69224 , C08F4/68224 , C08F4/7006
摘要： Neutral, multidentate azacyclic ligands and their complexes with group 3-10 and lanthanide metals are disclosed. The ligands are of the general formula Ra-A-(L)b where R is hydrogen or hydrocarbyl, A is silicon, germanium, tin or lead, each L is pyrazolyl, triazolyl or tetraazolyl, a = 0-2, b = 2-4, a + b = 4. When activated with common activators, the metal complexes polymerize olefins.
摘要翻译：公开了中性，多齿氮杂环配体及其与3-10族和镧系元素金属的络合物。配体具有通式Ra-A-（L）b，其中R是氢或烃基，A是硅，锗，锡或铅，每个L是吡唑基，三唑基或四唑基，a = 0-2，b = 2 -4，a + b = 4。当用普通活化剂活化时，金属络合物使烯烃聚合。

106. 发明申请

WO00050170A2 A NEW TRANSITION METAL COMPLEX, ITS PREPARATION AS WELL AS A CATALYST SYSTEM COMPRISING BASED THEREUPON AND ITS USE FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：一种全新的过渡金属络合物，它作为一种催化剂体系的制备，包括基于该催化剂的催化剂及其用于烯烃聚合的催化剂
公开(公告)号：WO00050170A2
公开(公告)日：2000-08-31
申请号：PCT/FI2000/000136
申请日：2000-02-22
IPC分类号： B01J31/18 , C07F7/00 , C07F11/00 , C08F10/00 , B01J31/00
CPC分类号： B01J31/182 , B01J31/1805 , B01J2531/46 , B01J2531/48 , B01J2531/62 , B01J2531/842 , C07F7/006 , C07F11/005 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/64089 , C08F4/69224
摘要： The invention relates to new triaza transition metal complexes and their use as polymerization catalysts. They have the formula (1): LnMXm-n, wherein each L is independently a ligand which is multidentate by adjacent cooordinating atoms, M is the central atom which is a metal selected from Groups 4-8 of the Periodic Table of the Elements (IUPAC 1990), each X is independently a unidentate organic or halogen ligand, m is the coordination number or number of coordination sites on the central atom M, and n is the number of the ligands L which is an integer from 1 to m. At least one of the ligands L has formula (2), wherein each of R1-R6 is independently selected from hydrogen and organic groups having from 1 to 10 carbon atoms and the ligand L is coordinated to the central atom M by one to four of the three nitrogen atoms and/or the carbon atom of the ligand L according to formula (2).
摘要翻译：本发明涉及新的三氮杂过渡金属络合物及其作为聚合催化剂的用途。它们具有式（1）：LnMXm-n，其中每个L独立地是由相邻共配原子多齿的配体，M是选自元素周期表第4-8族的金属的中心原子（ IUPAC 1990），每个X独立地是单齿有机或卤素配体，m是中心原子M上的配位点的配位数或数目，n是1至m的整数的配体L的数目。配体L中的至少一个具有式（2），其中R 1 -R 6各自独立地选自氢和具有1至10个碳原子的有机基团，并且配体L与中心原子M配位1至4个根据式（2）的配体L的三个氮原子和/或碳原子。

107. 发明申请

WO2008038173A3 POLYMERISATION (INCLUDING OLIGOMERISATION) OF OLEFINIC COMPOUNDS IN THE PRESENCE OF CATALYST, AND A CATALYST ACTIVATOR INCLUDING A HALOGENATED ORGANIC GROUP 审中-公开
标题翻译：在催化剂存在下的烯烃化合物的聚合（包括低级化）和包含有机有机组的催化剂活化剂
公开(公告)号：WO2008038173A3
公开(公告)日：2008-09-18
申请号：PCT/IB2007053590
申请日：2007-09-06
申请人： SASOL TECH PTY LTD , TOOZE ROBERT PAUL , HANTON MARTIN JOHN , TENZA KENNY
发明人： TOOZE ROBERT PAUL , HANTON MARTIN JOHN , TENZA KENNY
IPC分类号： B01J31/22 , B01J31/14 , B01J31/18 , C08F4/70 , C08F10/00
CPC分类号： B01J31/1815 , B01J31/143 , B01J2231/122 , B01J2531/56 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C08F10/00 , C08F110/02 , C08F110/14 , C08F2500/02 , C08F4/69224 , C08F4/68224 , C08F4/60089 , C08F4/7042 , C08F4/7047
摘要： According to the present invention there is provided a process for producing a polymenc (including oligomenc) product by the polymerisation (including oligomepsation) of at least one olefinic compound, by contacting the at least one olefinic compound with the combination of a polymerisation (including ohgomensation) catalyst and a catalyst activator The catalyst activator is a compound which includes at least one halogenated organic group which is bound to one or more binding atoms selected from the group consisting of a group 5A atom and a group 6A atom, which one or more binding atoms are in turn bound to a central atom in the form of aluminium The polymepsation (including ohgomensation) catalyst includes the combination of ?) a source of a transition metal, and n) a ligating compound of the formula (I). The invention also relates to a combination of a polymerisation (including ohgomensation) catalyst and a catalyst activator and to the use of such a combination in a polymerisation (including ohgomensation) process.
摘要翻译：根据本发明，提供了通过使至少一种烯烃化合物与聚合（包括偶联）的组合接触，通过使至少一种烯属化合物进行聚合（包括少量吞吐）来生产多聚（包括寡聚）产物的方法）催化剂和催化剂活化剂催化剂活化剂是一种化合物，其包括至少一个与一个或多个选自5A族原子和6A族原子的结合原子结合的卤代有机基团，其中一个或多个结合原子又以铝的形式结合到中心原子。聚醚（包括偶联）催化剂包括α）过渡金属源和n）式（I）的连接化合物的组合。本发明还涉及聚合（包括偶联）催化剂和催化剂活化剂的组合以及在聚合（包括偶联）方法中使用这种组合。

108. 发明申请

WO2006030193A1 POLYOLEFINS 审中-公开
标题翻译：的聚烯烃
公开(公告)号：WO2006030193A1
公开(公告)日：2006-03-23
申请号：PCT/GB2005/003522
申请日：2005-09-13
申请人： INNOVENE EUROPE LIMITED , GIBSON, Vernon, Charles , JACOBSEN, Grant, Berent , JONES, David, John , LONG, Richard, James
发明人： GIBSON, Vernon, Charles , JACOBSEN, Grant, Berent , JONES, David, John , LONG, Richard, James
IPC分类号： C08F210/18 , C08F4/622
CPC分类号： C08F210/18 , C08F10/00 , C08F4/69224 , C08F4/68224 , C08F210/06 , C08F232/00 , C08F2500/25 , C08F4/6925 , C08F4/69275 , C08F4/6825 , C08F4/68215 , C08F4/69215 , C08F4/69146 , C08F4/69034 , C08F4/64013
摘要： Process for making copolymer (eg elastomeric copolymer) by copolymerising (1) ethylene with (2) at least one comonomer aliphatic C 3 -C 20 alpha-olefins and (3) at least one C 4 to C 30 conjugated or non-conjugated dienes. The monomers are contacted with (a) a transition metal catalyst of Formula A, and (b) an activating quantity of a suitable activator, Z is five-membered heterocyclic group having at least one carbon atom, at least one nitrogen atom and at least one other hetero atom selected from nitrogen, sulphur and oxygen, the remaining atoms being nitrogen or carbon; M is a metal from Group 3 to 11 or lanthanide; E 1 and E 2 are divalent (i) aliphatic hydrocarbon, (ii) alicyclic hydrocarbon, (iii) aromatic hydrocarbon, (iv) alkyl substituted aromatic hydrocarbon (v) heterocyclic groups and (vi) heterosubstituted derivatives of said groups (i) to (v); D 1 and D 2 are donor atoms or groups; X is an anionic group, L is a neutral donor group; n = m = zero or 1; y and z are independently zero or integers such that the number of X and L groups satisfy the valency and oxidation state of the metal M.
摘要翻译：通过共聚合（1）乙烯与（2）至少一种共聚单体脂族C

109. 发明申请

WO2006009980A2 POLYMERIZATION PROCESS 审中-公开
标题翻译：聚合工艺
公开(公告)号：WO2006009980A2
公开(公告)日：2006-01-26
申请号：PCT/US2005021721
申请日：2005-06-20
申请人： EXXONMOBIL CHEM PATENTS INC , LIN ZERONG , SHIRODKAR PRADEEP P
发明人： LIN ZERONG , SHIRODKAR PRADEEP P
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F2/14 , C08F2/06 , C08F2500/07 , C08F2500/04 , C08F210/14 , C08F210/08 , C08F4/69224 , C08F4/7042
摘要： This invention relates to a process to polymerize olefins comprising contacting, in a reactor, a pyridyl-di-imine compound and an activator with one or more olefin monomer(s) in the presence of a fluorinated hydrocarbon.
摘要翻译：本发明涉及聚合烯烃的方法，包括在反应器中使吡啶基二亚胺化合物和活化剂与一种或多种烯烃单体在氟化烃存在下接触。

110. 发明申请

WO2005103099A1 CATALYST SYSTEM FOR OLEFIN POLYMERIZATION, ITS PRODUCTION AND USE 审中-公开
标题翻译：用于烯烃聚合的催化剂体系，其生产和使用
公开(公告)号：WO2005103099A1
公开(公告)日：2005-11-03
申请号：PCT/EP2005/004255
申请日：2005-04-21
申请人： BASELL POLYOLEFINE GMBH , MIHAN, Shahram , SCHMITZ, Harald
发明人： MIHAN, Shahram , SCHMITZ, Harald
IPC分类号： C08F110/02
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F110/02 , Y10S526/943 , C08F2/34 , C08F4/61904 , C08F4/65916 , C08F4/025 , C08F4/60089 , C08F4/69224 , C08F4/7042
摘要： Process for producing a catalyst system, which comprises the following steps: A) provision of a mixture of at least two different organic transition metal compounds, at least one hydrolyzed organoaluminum compound and a solvent and impregnation of a dry porous support component with the mixture from step A), with the total volume of the mixture being from 0.6 to 1.5 times the total pore volume of the support component, and also catalyst systems obtainable in this way and their use for olefin polymerization.
摘要翻译：制备催化剂体系的方法，其包括以下步骤：A）提供至少两种不同的有机过渡金属化合物，至少一种水解的有机铝化合物和溶剂的混合物，并将干燥多孔载体组分浸渍在混合物中步骤A），混合物的总体积为载体组分的总孔体积的0.6-1.5倍，以及可以以这种方式获得的催化剂体系及其在烯烃聚合中的用途。

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