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101. 发明授权

US4322524A Cyanoethylpullulan 失效
标题翻译：氰基乙基
公开(公告)号：US4322524A
公开(公告)日：1982-03-30
申请号：US168269
申请日：1980-07-10
申请人： Yoshiro Onda , Hiroaki Muto , Hiroshi Suzuki
发明人： Yoshiro Onda , Hiroaki Muto , Hiroshi Suzuki
IPC分类号： C08B37/00
CPC分类号： C08B37/0018
摘要： The present invention provides a novel compound cyanoethylpullulan which is a cyanoethylation product of pullulan. Pullulan is readily cyanoethylated by the reaction with acrylonitrile in the presence of an alkali catalyst such as sodium hydroxide.The cyanoethylpullulan having a degree of cyanoethylation of at least 50% has various unique properties in the heat resistance, solubility in organic solvents, film-forming property, adhesive bonding to metals and the like in comparison with related cyanoethylated products such as cyanoethylcellulose and cyanoethylated polyvinyl alcohol.
摘要翻译：本发明提供了作为支链淀粉的氰乙基化产物的新型化合物氰乙基普兰兰。在碱性催化剂如氢氧化钠的存在下，通过与丙烯腈的反应，将支链淀粉容易地氰乙基化。具有至少50％氰基乙基化度的氰乙基普兰兰与相关的氰乙基纤维素和氰乙基化聚乙烯吡咯烷酮相关的氰乙基化产物相比具有各种独特的耐热性，在有机溶剂中的溶解性，成膜性，与金属的粘合性等醇。

102. 发明授权

US4167623A Pullulan aminoalkyl ether 失效
标题翻译：支链淀粉氨基烷基醚
公开(公告)号：US4167623A
公开(公告)日：1979-09-11
申请号：US848033
申请日：1977-11-03
申请人： Fumio Fujita , Kosuke Fukami , Masanori Fujimoto
发明人： Fumio Fujita , Kosuke Fukami , Masanori Fujimoto
IPC分类号： C08B37/00 , C07H15/04
CPC分类号： C08B37/0018
摘要： Pullulan aminoalkyl ether is obtained by reacting pullulan with an aminoalkylating agent in a solvent in the presence of an alkali. This ether may be used as a cationic polymer of considerable utility in industries. For instance, when used in a paper coating material, it gives desirable effects on gloss, RI dry pick, and RI wet pick and, furthermore, as compared with pullulan, markedly improves physical properties of the coated paper such as tearing strength, tensile strength and wrinkle recovery; it improves also retention of loading materials such as clay and calcium carbonate.
摘要翻译：支链淀粉氨基烷基醚通过在碱存在下在溶剂中将支链淀粉与氨基烷基化试剂反应得到。该醚可用作工业中相当实用的阳离子聚合物。例如，当在纸张涂布材料中使用时，其对光泽度，RI干性接枝和RI湿腻子具有期望的效果，此外，与支链淀粉相比，显着改善涂布纸的物理性能如撕裂强度，拉伸强度和皱纹恢复; 它还改善了载体材料如粘土和碳酸钙的保留。

103. 发明授权

US4090016A Carboxylated pullulan and method for producing same 失效
标题翻译：羧化支链淀粉及其制备方法
公开(公告)号：US4090016A
公开(公告)日：1978-05-16
申请号：US689064
申请日：1976-05-24
申请人： Kozo Tsuji , Masanori Fujimoto , Fujio Masuko , Tsuneyuki Nagase
发明人： Kozo Tsuji , Masanori Fujimoto , Fujio Masuko , Tsuneyuki Nagase
IPC分类号： D06M15/03 , C08B37/00
CPC分类号： C08B37/0018
摘要： Carboxylated pullulan obtained by oxidizing pullulan with an oxidizing agent is readily soluble in cold water and has favorable film-forming property, yielding a film having high mechanical strengths, high modulus of elasticity and good transparency.
摘要翻译：通过用氧化剂氧化支链淀粉获得的羧基化支链淀粉很容易溶于冷水，具有良好的成膜性，产生机械强度高，弹性模量高，透明性好的膜。

104. 发明授权

US4002173A Diester crosslinked polyglucan hydrogels and reticulated sponges thereof 失效
标题翻译：二酯交联聚葡聚糖水凝胶及其网状海绵
公开(公告)号：US4002173A
公开(公告)日：1977-01-11
申请号：US568030
申请日：1975-04-14
申请人： James H. Manning , John H. Stark
发明人： James H. Manning , John H. Stark
IPC分类号： A61L15/64 , A61K31/715 , A61L15/60 , A61P7/04 , B01J20/24 , C08B33/00 , C08B33/02 , C08B37/00 , C08B37/02 , F23L3/00
CPC分类号： C08B37/0021 , A61L15/425 , A61L15/60 , C08B33/02 , C08B37/0018 , A61L2400/04
摘要： Novel hydrogel compositions of diester crosslinked polyglucans and a process for their preparation are provided. Amylose, dextran, and pullulan succinates and glutarates when crosslinked as described were found to not only have use as general fluid sorbants but also to have exceptional hemostatic activity, adherence to a wound, and bioabsorption without causing undue irritation of the tissue or toxic effects. Reticulated hydrogel sponges made of the crosslinked diesters which are particularly useful as general fluid sorbants, and those of amylose succinate and amylose glutarate are most excellent bioabsorbable hemostatic agents. The sponges are made by lyophilizing water-soluble salts of the mono- or half-esters, such as water-soluble salts of amylose succinate or amylose glutarate, under process conditions of the invention in the presence of a reticulating agent which causes a controlled melting of the salt solution as it nears the dry state during the lyophilizing step. The resulting reticulated, porous, open-celled sponge is then crosslinked by heating the sponge under dehydrating conditions to form diester-crosslinks. The sponge is highly porous, is moderately strong, and has the ability to retain up to 40 times its weight of isotonic saline. When neutralized with physiologically acceptable salts, the sponge has exceptional hemostatic activity, adherence to bleeding tissue, and bioabsorption without causing substantial irritation of the tissue or toxic effects.The invention also comprises a process of providing hemostasis at the site of a wound, employing the diester cross-linked polyglucan hydrogels or reticulated sponges thereof.
摘要翻译：提供了二酯交联聚葡聚糖的新型水凝胶组合物及其制备方法。发现当如上所述交联时，直链淀粉，葡聚糖和支链淀粉琥珀酸酯和戊二酸酯不仅可以用作普通流体吸着剂，而且具有特殊的止血活性，对伤口的粘附和生物吸收，而不会对组织造成不适当的刺激或毒性作用。特别可用作一般液体吸附剂的交联二酯制成的网状水凝胶海绵，以及直链淀粉琥珀酸酯和直链淀粉戊二酸酯的网状水凝胶海绵是最优异的生物可吸收止血剂。海绵通过在本发明的工艺条件下，在引起受控熔化的网状剂的存在下，将单酯或半酯的水溶性盐如琥珀酸直链淀粉的水溶性盐或直链淀粉戊二酸盐的水溶性盐冻干，的盐溶液，因为其在冻干步骤期间接近干燥状态。然后通过在脱水条件下加热海绵将形成的网状多孔的开孔海绵交联，形成二酯交联。海绵是高度多孔的，中等强度，并且具有保留高达40倍重量的等渗盐水的能力。当用生理上可接受的盐中和时，海绵具有特殊的止血活性，对出血组织的粘附和生物吸收，而不会对组织产生显着的刺激或毒性作用。

105. 发明授权

US3912591A Process for the production of pullulan 失效
标题翻译：生产支链淀粉的方法
公开(公告)号：US3912591A
公开(公告)日：1975-10-14
申请号：US39262173
申请日：1973-08-29
申请人： HAYASHIBARA BIOCHEM LAB
发明人： KATO KOSO , SHIOSAKA MAKOTO
IPC分类号： C12P19/12 , C08B37/00 , C12N1/14 , C12P19/10 , C12D13/04
CPC分类号： C08B37/0018 , C12P19/10 , Y10S435/911
摘要： In the production of pullulan by aerobic, microbial fermentation of saccharides, the degree of polymerization, the yield and the culture period are controlled by adjusting the pH value and the concentration of phosphate ion in the culture medium.
摘要翻译：通过需氧生产支链淀粉，通过微生物发酵，通过调节培养基中磷酸根离子的pH值和浓度来控制聚合度，产量和培养时间。

106. 发明授权

US3827937A Method of producing pullulan 失效
标题翻译：生产PULLULAN的方法
公开(公告)号：US3827937A
公开(公告)日：1974-08-06
申请号：US29416772
申请日：1972-10-02
申请人： HAYASHIBARA BIOCHEM LAB
发明人： KATO K , SHIOSAKA M
IPC分类号： C12P19/12 , C08B37/00 , C12N1/14 , C12P19/10 , C12R1/645 , C12B1/00
CPC分类号： C12P19/10 , C08B37/0018 , Y10S435/911
摘要： PULLULAN IS PRODUCED BY AEROBIC, MICOBIAL FERMENTATION OF STARCH HYDROLYZATE HAVING A DEXTROSE EQUIVALENT (D.E.) OF 20-70 IN YIELDS SUPERIOR TO THOSE ACHIEVED HERETOFORE BY FERMENTATION OF SUCROSE OR GLUCOSE, WHICH ARE MORE COSTLY CARBON SOURCES.

107. 发明公开

US20240336706A1 SILICONE-MODIFIED PULLULAN, A COMPOSITION COMPRISING THE SAME, AND A COSMETIC 审中-公开
公开(公告)号：US20240336706A1
公开(公告)日：2024-10-10
申请号：US18700011
申请日：2022-10-12
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Hiroyuki Moriya
IPC分类号： C08B37/00 , A61K8/73 , A61Q19/00
CPC分类号： C08B37/0018 , A61K8/73 , A61Q19/00 , A61K2800/10
摘要： The present invention provides a silicone-modified pullulan, the silicone-modified pullulan being an addition reaction product of the following components (a) and (b): (a) pullulan having a water content of 1.0 mass % or less and a calcium content of less than 100 ppm; and (b) isocyanate group-containing silicone represented by the formula (1), wherein the silicone-modified pullulan has a calcium content of less than 100 ppm and a content of the urea group-containing silicone represented by the formula (2) of less than 2,000 ppm.

108. 发明公开

US20240262987A1 TERMINAL ALKENYL FUNCTIONAL SILYLATED POLYSACCHARIDES 审中-公开
公开(公告)号：US20240262987A1
公开(公告)日：2024-08-08
申请号：US18261177
申请日：2022-02-24
申请人： Dow Silicones Corporation , Rohm and Haas Company
发明人： Ryan Baumgartner , Shane Mangold , Zachary Wenzlick , Marc-Andre Courtemanche , Michael Ferritto , Gregoire Cardoen
IPC分类号： C08L1/08 , C07H1/00 , C07H23/00 , C08B15/05 , C08B30/18 , C08B31/00 , C08B37/00 , C08B37/02 , C08L3/02 , C08L3/04 , C08L5/02 , C08L5/08 , C08L5/12 , C08L5/16
CPC分类号： C08L1/08 , C07H1/00 , C07H23/00 , C08B15/05 , C08B30/18 , C08B31/00 , C08B37/0018 , C08B37/0021 , C08B37/0039 , C08B37/0054 , C08B37/0063 , C08B37/0087 , C08L3/02 , C08L3/04 , C08L5/02 , C08L5/08 , C08L5/12 , C08L5/16
摘要： A composition contains a silylated polysaccharide, where the silylated polysaccharide is characterized by: (a) having linked fructose, galactose, anhydrogalactose, or glucose saccharide units provided that glycosidic linkages of glucose are alpha linkages and that the silylated polysaccharide is other than a silylated starch; and (b) on average 1 to 100 mole-percent of the hydroxyl groups on the polysaccharide have been silylated with a silyl group having the structure —SiR3 linked to the polysaccharide through a C—O—Si bond where each R is independently selected from hydrocarbyl radicals having from one to 12 carbon atoms, provided that on average at least one R per polysaccharide has a terminally unsaturated carbon-carbon double bond.

109. 发明公开

US20240218347A1 Polymer of Protein-Conjugated Polysaccharide, Preparation Method Therefor, Enzyme-Stabilizing Composition Comprising Same, and Method for Detecting Target Nucleic Acid Molecule by Using Same 审中-公开
公开(公告)号：US20240218347A1
公开(公告)日：2024-07-04
申请号：US17924446
申请日：2022-10-07
申请人： SML GENETREE CO., LTD.
发明人： Yo Han Jeong , Jeong Ju Lee , So Hyeon Park , Kyung Ah Hwang , Ji Hoon Ahn
IPC分类号： C12N9/96 , C07K14/76 , C08B15/02 , C08B37/00 , C08B37/02 , C12Q1/6806 , C12Q1/6844
CPC分类号： C12N9/96 , C07K14/76 , C08B15/02 , C08B37/0018 , C08B37/0021 , C12Q1/6806 , C12Q1/6844
摘要： The present disclosure relates to a polymer in which bovine serum albumin (BSA) is conjugated to a polysaccharide, a method of preparing the same, an enzyme-stabilizing composition including the same, and a method of amplifying or detecting a target nucleic acid molecule in a biological sample by using the same. The polymer is used to prevent the hydrolysis, oxidation, or reduction of an enzyme, such as a nucleic acid polymerase, in a composition, thereby maintaining the stability of the composition. Even when stored at room temperature and high temperature, a composition including the polymer can stably maintain enzymatic activity equivalent to that of a composition kept frozen. Accordingly, the polymer of the present disclosure and a composition including the same efficiently detect a target nucleic acid molecule associated with the onset of infectious diseases and/or cancer, and thus can be usefully applied to the diagnosis of diseases.

110. 发明授权

US10081757B2 Shale swelling inhibitors 有权
公开(公告)号：US10081757B2
公开(公告)日：2018-09-25
申请号：US14648391
申请日：2013-11-22
申请人： ISP INVESTMENTS INC.
发明人： Cuiyue Lei , Osama M. Musa
IPC分类号： C09K8/528 , C09K8/68 , C09K8/52 , C08B11/20 , C08B15/00 , C08B31/12 , C08B37/00 , C08B37/02 , C08B37/08 , C09K8/035 , C08F299/00 , C08L29/04 , C08L33/06 , C08L33/26
CPC分类号： C09K8/52 , C08B11/20 , C08B15/00 , C08B31/12 , C08B37/0018 , C08B37/0021 , C08B37/003 , C08B37/0033 , C08B37/0042 , C08B37/0045 , C08B37/006 , C08B37/0069 , C08B37/0072 , C08B37/0075 , C08B37/0096 , C08F299/00 , C08L29/04 , C08L33/064 , C08L33/066 , C08L33/26 , C09K8/035 , C09K2208/12 , C08L39/06
摘要： The present invention provides amidic polymers, which exhibit shale swelling inhibitor activity having improved biodegradability. The amidic polymers of the invention may be employed in a wide variety of compositions, particularly in subterranean drilling operations. Non-limiting generic structures of the amidic polymers are set out below: formula (1) wherein R1-R3 and integers m and n are defined herein.

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