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101. 发明授权

US4495184A Morpholino propanol derivatives, fungicidal compositions and use 失效
标题翻译：吗啉代醇衍生物，杀真菌剂及用途
公开(公告)号：US4495184A
公开(公告)日：1985-01-22
申请号：US496673
申请日：1983-05-23
申请人： Hans-Joachim Knops , Wolfgang Kramer , Paul-Ernst Frohberger
发明人： Hans-Joachim Knops , Wolfgang Kramer , Paul-Ernst Frohberger
IPC分类号： C07D295/08 , A01N33/04 , A01N33/08 , A01N37/12 , A01N37/34 , A01N43/84 , A01N47/12 , A01N47/20 , A01N55/00 , A01N55/10 , C07C67/00 , C07C213/00 , C07C215/30 , C07C217/70 , C07C217/72 , C07C219/22 , C07C239/00 , C07C253/00 , C07C255/58 , C07C255/59 , C07C271/08 , C07C313/00 , C07C323/32 , C07D209/08 , C07D295/067 , C07D295/084 , C07F7/18
CPC分类号： C07D295/067 , A01N33/04 , A01N33/08 , A01N37/12 , A01N47/12 , A01N47/20 , A01N55/00 , C07D209/08 , C07D295/092 , C07F7/1856
摘要： A 1-phenyl-3-amino-propane derivative of the formula ##STR1## in which R.sup.1 and R.sup.2 independently represent alkyl radicals or R.sup.1 and R.sup.2 together with the nitrogen atom to which they are bonded complete an optionally substituted heterocyclic radical of the formula ##STR2## and or additionally, if R.sup.4 represents the radical --O--CO--R.sup.5, --O--CO--NHR.sup.6 or --O--SiR.sub.3.sup.7, complete an optionally substituted heterocyclic radical of the formula ##STR3## R.sup.3 represents a hydrogen atom or an alkyl radical, R.sup.4 represents a hydroxyl group, halogen or the radical --O--CO--R.sup.5, --O--CO--NHR.sup.6 or --O--SiR.sub.3.sup.7,R.sup.5 represents an alkyl, alkenyl or halogenoalkyl radical or an optionally substituted aryl or aralkyl radical,R.sup.6 represents an alkyl or alkenyl radical or an optionally substituted aryl radical,R.sup.7 represents an alkyl radical each Y independently represents an alkyl radical, a halogen atom or a halogenoalkyl, alkoxy, alkylthio, halogenoalkoxy, halogenoalkylthio, cycloalkyl or cyano radical andn is 0, 1, 2 or 3,or a physiologically acceptable acid addition salt thereof which possesses fungicidal activity.
摘要翻译：其中R 1和R 2独立地表示烷基或R 1和R 2与它们所键合的氮原子一起形成的式“IMAGE”的1-苯基-3-氨基 - 丙烷衍生物与式或者另外，如果R 4代表基团-O-CO-R 5，-O-CO-NHR 6或-O-SiR 37，则完成式R 3的任选取代的杂环基代表氢原子或烷基基团，R 4表示羟基，卤素或-O-CO-R 5，-O-CO-NHR 6或-O-SiR 37基团，R 5表示烷基，烯基或卤代烷基或任选取代的芳基或芳烷基，R 6 表示烷基或烯基或任选取代的芳基，R 7表示烷基，每个Y独立地表示烷基，卤素原子或卤代烷基，烷氧基，烷硫基，卤代烷氧基，卤代烷硫基，环烷基或氰基，n为0， 1,2或3，或者一个生理学家其具有杀真菌活性的其可接受的酸加成盐。

102. 发明授权

US3974174A 1-(1,2,4-Triazolyl-1')-2-phenoxy-4,4-dimethyl-pentan-3-ones 失效
标题翻译： 1-（1,2,4-三唑基-1（40）-2-苯氧基-4,4-二甲基 - 戊-3-酮
公开(公告)号：US3974174A
公开(公告)日：1976-08-10
申请号：US483758
申请日：1974-06-27
申请人： Karl Heinz Buchel , Wolfgang Kramer , Paul-Ernst Frohberger
发明人： Karl Heinz Buchel , Wolfgang Kramer , Paul-Ernst Frohberger
IPC分类号： A01N43/653 , A01P3/00 , C07C45/63 , C07C45/75 , C07C49/255 , C07D233/60 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , C07C45/63 , C07C45/75 , C07C49/255 , C07D233/56 , C07D249/08
摘要： 1-(1,2,4-TRIAZOLYL-1')-2-PHENOXY-4,4-DIMETHYL-PENTAN-3-ONES OF THE FORMULA ##SPC1##In whichn is an integer from 0 to 5,X is halogen, halogenoalkyl, alkyl, alkoxy, alkylthio, alkylsulfonyl, nitro, nitrile, carbalkoxy or phenyl, andY is a keto group or a functional derivative of a keto group,Or a salt thereof,Which possess fungicidal properties.
摘要翻译：其中N为0至5的整数的式（I-1,2,4-三唑基-1'） - 2-苯氧基-4,4-二甲基-3-戊烷，X为卤素，卤代烷基，烷基，烷氧基，烷硫基，烷基磺酰基，硝基，腈，烷氧基或苯基，Y是酮基的酮基或官能衍生物，或其任何杀真菌性质的盐或其盐。

103. 发明授权

US4465678A Aminopropiophenone derivatives and fungicidal use 失效
标题翻译：氨基苯丙酮衍生物和杀真菌用途
公开(公告)号：US4465678A
公开(公告)日：1984-08-14
申请号：US444419
申请日：1982-11-24
申请人： Hans-Joachim Knops , Wolfgang Kramer , Paul-Ernst Frohberger
发明人： Hans-Joachim Knops , Wolfgang Kramer , Paul-Ernst Frohberger
IPC分类号： A01N33/16 , A01N33/24 , A01N37/34 , C07C67/00 , C07C225/16 , C07C225/18 , C07C239/00 , C07C251/48 , C07C253/00 , C07C255/58 , C07C313/00 , C07C323/32 , C07C323/47 , C07D209/08 , C07D215/06 , C07D265/30 , C07D295/108 , C07D295/13 , A01N43/34 , C07C131/00
CPC分类号： C07D295/108 , C07D209/08 , C07D215/06 , C07D295/13
摘要： Aminopropiophenone derivatives of the formula ##STR1## in which X is a keto group or an oxime radical of the formula>C.dbd.N--O--R.sup.4,Y each independently is an alkyl radical, a halogen atom, or a halogenoalkyl, alkoxy, alkythio, halogenoalkoxy, halogenoalkylthio, cycloalkyl or cyano radical,n is 0, 1, 2, or 3,R.sup.1 and R.sup.2 each independently is an alkyl radical, or,R.sup.1 and R.sup.2, together with the nitrogen atom to which they are bonded, complete an optionally substituted heterocyclic radical of the formula ##STR2## or in addition, if X is >C.dbd.N--O--R.sup.4, also may complete an optionally substituted heterocyclic radical of the formula ##STR3## R.sup.3 is a hydrogen atom or an alkyl radical, and R.sup.4 is a hydrogen atom or an alkyl, alkenyl, alkinyl or aralkyl radical,or physiologically acceptable acid addition salts thereof, which possess fungicidal activity.
摘要翻译：其中X为酮基或式C = NO-R 4的肟基的式“IMAGE”的氨基苯丙酮衍生物各自独立地为烷基，卤素原子或卤代烷基，烷氧基，烷基，卤代烷氧基，卤代烷硫基，环烷基或氰基，n为0,1,2或3，R 1和R 2各自独立地为烷基，或者R 1和R 2与它们所键合的氮原子一起完成任选取代的另外，如果X是> C = NO-R 4，也可以完成下式的任选取代的杂环基：R 3是氢原子或烷基，R 4是氢原子或具有杀真菌活性的烷基，链烯基，炔基或芳烷基或其生理上可接受的酸加成盐。

104. 发明授权

US3952002A Triazolyl-O,N-acetals 失效
标题翻译：三唑基-O，N-缩醛
公开(公告)号：US3952002A
公开(公告)日：1976-04-20
申请号：US465713
申请日：1974-04-30
申请人： Wolfgang Kramer , Karl Heinz Buchel , Werner Meiser , Helmut Kaspers , Paul-Ernst Frohberger
发明人： Wolfgang Kramer , Karl Heinz Buchel , Werner Meiser , Helmut Kaspers , Paul-Ernst Frohberger
IPC分类号： A01N43/647 , A01N43/653 , A01P3/00 , C07D233/60 , C07D249/04 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , C07D233/56 , C07D249/04 , C07D249/08
摘要： Triazolyl-O,N-acetals of the formula ##EQU1## in which R.sup.1 and R.sup.4 each independently is alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, aryl, or aralkyl,R.sup.2 and R.sup.3 each independently is hydrogen or one of the radicals mentioned under R.sup.1, andA is a 1,2,4-triazolyl-(1), 1,2,4-triazolyl-(4) or 1,2,3-triazolyl-(1)-radical,Which possess fungicidal and microbiostatic properties.
摘要翻译：式R 2 OH的三唑基-O，N-缩醛| R1-O-C--C-R（I）|| AzR3，其中R 1和R 4各自独立地是烷基，烯基，炔基，环烷基，环烯基，芳基或芳烷基，R 2和R 3各自独立地是氢或R 1下提及的基团之一，A是1,2,4-三唑基 - （1），1,2,4-三唑基 - （4）或1,2， 3-三唑基 - （1） - 自由基，具有正确的杀真菌和微生物特性。

105. 发明授权

US3940414A 1-Phenoxy-[imidazolyl-(1)]-2-hydroxy-alkanes 失效
标题翻译： 1-苯氧基 - {8咪唑基 - （1）{9 -2-羟基 - 烷烃
公开(公告)号：US3940414A
公开(公告)日：1976-02-24
申请号：US480433
申请日：1974-06-17
申请人： Wolfgang Kramer , Karl Heinz Buchel , Paul-Ernst Frohberger , Hans Scheinpflug
发明人： Wolfgang Kramer , Karl Heinz Buchel , Paul-Ernst Frohberger , Hans Scheinpflug
IPC分类号： A01N43/50 , A01P3/00 , C07D233/60 , C07D521/00
CPC分类号： C07D231/12 , C07D233/56 , C07D249/08
摘要： Imidazolyls of the formula ##EQU1## in which R.sup.1 is optionally substituted aryl,R.sup.2 is hydrogen, alkyl or optionally substituted aryl,R.sup.3 is hydrogen, alkyl, alkenyl, cycloalkyl, optionally substituted aryl or optionally substituted aralkyl, andR.sup.4 is alkyl, alkenyl, cycloalkyl, optionally substituted aryl or optionally substituted aralkyl,And their salts, which possess fungicidal and plant growth regulating properties.
摘要翻译：式R 2 OH || R1O-CC-R4（I）| R3的咪唑啉，其中R 1为任选取代的芳基，R 2为氢，烷基或任选取代的芳基，R 3为氢，烷基，烯基，环烷基，任选取代的芳基或任选地取代的芳烷基，R4是烷基，烯基，环烷基，任选取代的芳基或任选取代的芳烷基，以及它们的真菌和植物生长调节性质。

106. 发明授权

US4515617A Benzyl-pyrimidinylalkyl-ethers as plant growth regulators and fungicides, and corresponding pyrimidinylcarbinols 失效
标题翻译：苄基 - 嘧啶基烷基醚作为植物生长调节剂和杀真菌剂，以及相应的嘧啶基甲醇
公开(公告)号：US4515617A
公开(公告)日：1985-05-07
申请号：US519609
申请日：1983-08-02
申请人： Graham Holmwood , Klaus Lurssen , Paul-Ernst Frohberger
发明人： Graham Holmwood , Klaus Lurssen , Paul-Ernst Frohberger
IPC分类号： A01N43/54 , C07D239/26
CPC分类号： C07D239/26 , A01N43/54
摘要： A benzyl-pyrimidinylalkyl-ether of the formula ##STR1## in which R is alkyl, optionally substituted cycloalkyl or optionally substituted phenyl, andX.sup.1, X.sup.2 and X.sup.3 each independently is hydrogen, halogen, alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, cyano, optionally substituted phenoxy, optionally substituted phenylalkyl or optionally substituted phenylalkoxy,or an acid addition salt or metal salt complex thereof, which possesses fungicidal and plant growth-regulating properties. The corresponding pyrimidinyl-carbinols are also new.
摘要翻译：其中R为烷基，任选取代的环烷基或任选取代的苯基，且X 1，X 2和X 3各自独立地为氢，卤素，烷基，环烷基，烷氧基，烷硫基，卤代烷基，卤代烷氧基的苄基 - 嘧啶基烷基 - 醚，卤代烷硫基，氰基，任选取代的苯氧基，任选取代的苯基烷基或任选取代的苯基烷氧基，或其酸加成盐或金属盐络合物，其具有杀真菌剂和植物生长调节性质。相应的嘧啶基 - 甲醇也是新的。

107. 发明授权

US4189498A Combating pests with 2-carboxymethyl-3-carboxy-chromones and esters 失效
标题翻译：防治害虫与2-羧甲基-3-羧基 - 色酮和酯类
公开(公告)号：US4189498A
公开(公告)日：1980-02-19
申请号：US918129
申请日：1978-06-22
申请人： Hans-Joachim Kabbe , Paul-Ernst Frohberger , Peter Roessler
发明人： Hans-Joachim Kabbe , Paul-Ernst Frohberger , Peter Roessler
IPC分类号： A01N43/14 , C07D311/24 , A61K31/35 , C07D311/04
CPC分类号： C07D311/24
摘要： 2-Carboxymethyl-3-carboxy-chromones and esters of the formula ##STR1## in which R, R.sup.1 and R.sup.2 each independently is hydrogen, an optionally substituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, aralkyl or aryl group, halogen, hydroxyl, cyano or an optionally substituted alkoxy, aryloxy, aralkoxy, alkoxy-carbonyl or dialkylamino group, orR and R.sup.1, together with two carbon atoms of the benzene ring system, form a carbocyclic or heterocyclic 5-membered or 6-membered ring, andR.sup.3 is hydrogen, optionally substituted alkyl, alkenyl, cycloalkyl, cycloalkenyl or aralkyl,are characterized by fungicidal and arthropodicidal activities. The novel compounds are produced by reacting an o-hydroxyacetophenone of the formula ##STR2## with a glyoxylic acid derivative of the formulaOCH--COOZin whichZ is a cation,in the presence of a basic compound, followed by acidification to form the dicarboxylic acid and, optionally, the ester.
摘要翻译： 2-羧甲基-3-羧基 - 色酮和式“IMAGE”的酯，其中R，R 1和R 2各自独立地为氢，任选取代的烷基，烯基，环烷基，环烯基，芳烷基或芳基，卤素，羟基，氰基或任选取代的烷氧基，芳氧基，芳烷氧基，烷氧基 - 羰基或二烷基氨基，或R和R 1与苯环体系的两个碳原子一起形成碳环或杂环的5元或6元环，并且R 3为氢，任选取代的烷基，烯基，环烷基，环烯基或芳烷基，其特征在于杀真菌和节肢动物杀虫活性。通过在碱性化合物的存在下，使式“IMAGE”的邻羟基苯乙酮与其中Z为阳离子的式OCH-COOZ的乙醛酸衍生物反应，然后酸化形成二羧酸酸和任选的酯。

108. 发明授权

US4053620A Combating fungi with 1-aryl-5-alkylidene-2,4-dioxo-imidazolidines 失效
标题翻译：与1-亚苄基-5-烷基-2,4-二氧基咪唑啉酮组合真菌
公开(公告)号：US4053620A
公开(公告)日：1977-10-11
申请号：US668547
申请日：1976-03-19
申请人： Edgar Enders , Paul-Ernst Frohberger
发明人： Edgar Enders , Paul-Ernst Frohberger
IPC分类号： A01N43/50 , C07D233/96 , A01N9/22
CPC分类号： C07D233/96
摘要： Fungicidal compositions containing, and methods of combating fungi, using 1-aryl-5-alkylidene-2,4-dioxo-imidazolidines of the formula ##STR1## in which R is aryl optionally substituted by nitro; by halogen; by alkyl, alkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl each with up to 6 carbon atoms; by haloalkyl with up to 5 halogen atoms and 1 or 2 carbon atoms; by cycloalkyl with 5 or 6 carbon atoms; by hydroxyl; by cyano; by thiocyanato; by acetyl; by formyl; by phenyl or phenoxy each optionally carrying halogen or nitro as substituents; by phenylthio; by phenylsulfonyl; by halosulfonyl; by benzyl; by anilino; by monoalkylamino or dialkylamino, each with up to 4 carbon atoms in each alkyl moiety; or by a cyclic amine radical in which the amine nitrogen is a constituent of a 5-membered or 6-membered heterocyclic structure which can in addition contain at least one further hetero-atom selected from the group consisting of nitrogen, oxygen and sulfur ring members; it being possible for an aryl radical to be substituted by the group ##STR2## R' is hydrogen or alkyl with up to 6 carbon atoms, EXHIBIT STRONG FUNGICIDAL PROPERTIES.

109. 发明授权

US4053598A Preparation of 2,4-dioxo-1,2,3,4-tetrahydro-s-triazino-[1,2-a]-benzimidazoles 失效
标题翻译： 2,4-二氧代-1,2,3,4-四氢-S-三唑并（1,2-A） - 苯并咪唑的制备
公开(公告)号：US4053598A
公开(公告)日：1977-10-11
申请号：US694418
申请日：1976-06-09
申请人： Werner Daum , Paul-Ernst Frohberger
发明人： Werner Daum , Paul-Ernst Frohberger
IPC分类号： A01N43/90 , C07D235/30 , C07D487/04 , C07D413/14 , A61K31/53 , A61K31/535
CPC分类号： C07D235/30 , C07D487/04
摘要： 2,4-Dioxo-1,2,3,4-tetrahydro-s-triazino-[1,2-a]-benzimidazoles of the formula ##STR1## are produced by reacting a benzimidazole compound of the formula ##STR2## with a diphenyl carbonate of the formula ##STR3## wherein R.sup.1 is optionally substituted alkyl or aryl, alkenyl or dialkylamino,R.sup.2 is hydrogen, alkyl or trifluoromethyl,R.sup.3 is any of the R.sup.1 radicals or hydroxycarbonylalkyl, andR.sup.4 is hydrogen, alkyl or halogen.The reaction can be effected employing the benzimidazole in impure form, without isolation, in the vessel in which it is formed. Those compounds wherein R.sup.1 is a variously .omega.-substituted alkyl radical and R.sup.2 is hydrogen or methyl are new and all the compounds exhibit fungicidal activity.

110. 发明授权

US4010174A Thiazolinone-(2)-carboxylic acid esters and process therefor 失效
标题翻译：噻唑啉酮 - （2） - 羧酸酯及其工艺
公开(公告)号：US4010174A
公开(公告)日：1977-03-01
申请号：US610818
申请日：1975-09-05
申请人： Klaus Grohe , Paul-Ernst Frohberger
发明人： Klaus Grohe , Paul-Ernst Frohberger
IPC分类号： C07D277/56 , C07D277/14
CPC分类号： C07D277/56
摘要： Thiazolinone-(2)-carboxylic acid esters having the formula: ##STR1## ARE PREPARED BY REACTING A .beta.-AMINO ACRYLIC ACID ESTER WITH CHLOROCARBOXYL SULPHENYL CHLORIDE (COCl-SCl) at a temperature of from 0.degree. to 200.degree. C. The esters are useful as plant protecting agents such as a fungicide.
摘要翻译：具有下式的噻唑啉酮 - （2） - 羧酸酯：通过在0℃至200℃的温度下通过用氯化硼酰氯化物（COCl-SCl）反应β-氨基丙酸酸酯来制备。可用作植物保护剂如杀真菌剂。

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