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    • 102. 发明专利
    • POLYSULFONE SEMIPERMEABLE MEMBRANE AND MANUFACTURE THEREOF
    • JPH09122463A
    • 1997-05-13
    • JP30840495
    • 1995-10-31
    • NITTO DENKO CORP
    • HACHISUGA HISAOIKEDA KENICHI
    • B01D61/36B01D39/16B01D39/20B01D71/68
    • PROBLEM TO BE SOLVED: To provide a gas separation membrane with high permeation flux capable of meeting its practical applications from in view of the cost by forming the cross section of a porous layer of the same material as that of a homogeneous skin layer and thicker than the homogenous skin layer, out of a structure of voids, each of which has an average pore diameter of not more than 3μm, as a polysulfone resin semipermeable membrane consisting of the homogenous skin layer with an average thickness of 5-1000μm structurally continuous to the porous layer. SOLUTION: The 82 pts.wt. of diethyleneglycol dimethylether is added to 18 pts. by wt. of polysulfone, and this mixture is dissolved and defoamed to make a preparation. This solution for making a membrane is cast in a thickness of 200μm over a polyester unwoven cloth as a support layer, using an application, under a 25 deg.C temperature atmosphere. In addition, this coated polyester unwoven cloth is soaked in a 25 deg.C water as a coagulation liquid for 5min, and further, in a 25 deg.C water for one hour. Next, the cloth is dried at 100 deg.C to obtain a semipermeable membrane consisting of a homogeneous skin layer part 1 and a porous layer 2. Finally, a crosslinking silicone resin solution is applied to the surface of the semipermeable membrane to form a protecting film as an optional procedure.
    • 106. 发明专利
    • COMPOSITE REVERSE OSMOSIS MEMBRANE
    • JPH07171363A
    • 1995-07-11
    • JP32170893
    • 1993-12-21
    • NITTO DENKO CORP
    • HIROSE MASAHIKOIKEDA KENICHI
    • B01D71/56B01D71/82
    • PURPOSE:To obtain a composite reverse osmosis membrane which has a high salt blocking ratio and high water permeability even for mixed solutes by a method in which the precursor of a thin film composed of polyamide with a specified structure as a main component, after being formed on a support, is treated with a compound which can react with unreacted chlorosulfonyl groups in the precursor. CONSTITUTION:A composite membrane is composed of a thin membrane and a micro-porous support which supports the thin membrane. The thin membrane is obtained by a method in which the precursor of the thin membrane containing polyamide as a main component which is made from an amine component containing at least one kind of amine selected from the group consisting substantially of monomeric aime compounds having at least two primary and/or secondary amino groups and a halide component containing at least one kind of acid halide selected from the group consisting substantially of monomeric acid halide compounds having at least one chlorosulfonyl group is treated with an organic compound having an amino group or a hydroxyl group (e.g. alanine) which can react with unreacted chlorosulfonyl groups in the precursor.
    • 108. 发明专利
    • FILTRATION MEMBRANE FOR LIQUID ITS PRODUCTION AND FILTER USED THEREFOR
    • JPH06327950A
    • 1994-11-29
    • JP12372293
    • 1993-05-26
    • NITTO DENKO CORP
    • URAIRI MASAKATSUIKEDA KENICHI
    • B01D69/02B01D71/34B01D71/36
    • PURPOSE:To obtain a filtration membrane for liquid having high hydrophilic property and excelling in durability, chemical resistance, pressure resistance and heat resistance without necessitating air vent operation, and to obtain a filter using the membrane by intermingling a part which is continuously hydrophobic from the surface to the rear of a membrane and a part which is continuously hydrophilic from the surface to the rear of the membrane. CONSTITUTION:Narrow pores of a porous membrane are impregnated with a compound solution. During the impregnation, the membrane is shielded by using a shielding means which is preferably formed into a fixed pattern and irradiated with ultraviolet rays, so a part of F atoms of high molecular polymer porosity is replaced with hydrophilic radicals in an exposed part, and as a result, a filter membrane for liquid 1 having a hydrophilic part 2 and a hydrophobic part 3 is obtained. As an ultraviolet ray source, for example, a low voltage mercury lamp is used. The irradiation time is set in consideration of various factors, such as output, an irradiation distance, kinds and concentrations of compound water solutions and the form of a film, but it is normally about 20-30sec. The area ratio of the hydrophobic part 3 to the whole is preferably