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    • 104. 发明申请
    • MODIFICATION OF SOLID POLYSACCHARIDE WITH TRANSESTERIFICATION AGENT
    • 固体多糖与改性剂的改性
    • US20120090848A1
    • 2012-04-19
    • US13070671
    • 2011-03-24
    • B. Raghava Reddy
    • B. Raghava Reddy
    • E21B43/25C09K8/68E21B43/26
    • C09K8/08C09K8/40C09K8/514C09K8/68C09K8/685C09K8/90
    • Polysaccharides are reacted with transesterification agents forming modified products that: (1) have increased viscosifying efficiency, i.e., higher viscosities at reduced concentrations compared to the unmodified polysaccharide; or (2) are insolubilized at temperature ranges for which the unmodified polysaccharide would hydrate fully; or (3) both properties. In some cases, the insolubilized polysaccharides can be activated to dissolve and viscosify at specific temperature ranges by using pH modifiers. A method of treating a well is provided, including the steps of: (a) forming a treatment fluid comprising water and a modified polysaccharide, wherein the modified polysaccharide is characterized by having been made by the process of combining: (i) a water-soluble polysaccharide, wherein the polysaccharide is in a solid form during the combining step; and (ii) a transesterification agent, wherein the transesterification agent is in liquid form; wherein the step of combining is in the presence of less than 10% by weight water relative to the water-soluble polysaccharide and wherein any water present is at a pH of 8 or less; and (b) introducing the treatment fluid into the well.
    • 多糖与形成改性产物的酯交换剂反应,其中:(1)与未改性的多糖相比,具有增加的增粘效率,即降低浓度的较高粘度; 或(2)在未改性多糖将完全水合的温度范围内不溶; 或(3)两种性质。 在一些情况下,不溶性多糖可以通过使用pH调节剂被活化以在特定温度范围溶解和粘稠。 提供了一种处理井的方法,包括以下步骤:(a)形成包含水和改性多糖的处理流体,其中改性多糖的特征在于通过以下方法制备:(i) 可溶性多糖,其中所述多糖在组合步骤期间为固体形式; 和(ii)酯交换剂,其中所述酯交换剂为液体形式; 其中组合步骤相对于水溶性多糖存在小于10重量%的水,并且其中存在的任何水的pH为8以下; 和(b)将处理流体引入井中。
    • 105. 发明授权
    • Methods and compositions for treating subterranean formations with gelled hydrocarbon fluids
    • 用胶体烃流体处理地下地层的方法和组合物
    • US08119575B2
    • 2012-02-21
    • US12011263
    • 2008-01-25
    • Robert S. TaylorGary P. FunkhouserMichael A. McCabeB. Raghava Reddy
    • Robert S. TaylorGary P. FunkhouserMichael A. McCabeB. Raghava Reddy
    • C09K8/00
    • C09K8/64C09K8/82C09K2208/26
    • Among other things, methods of treating a subterranean formation with gelled hydrocarbon fluids are provided. In certain embodiments, these methods comprise the steps of providing a gelled liquid hydrocarbon treatment fluid comprising a liquid hydrocarbon and a gelling agent that comprises a polyvalent metal salt of an organophosphonic acid ester or a polyvalent metal salt of an organophosphinic acid, and treating the subterranean formation with the gelled liquid hydrocarbon treatment fluid. The gelled liquid hydrocarbon treatment fluids of the present invention are suitable for use in subterranean treatment operations, such as subterranean stimulation and sand control treatments like fracturing and gravel packing, that may be carried out in subterranean formations for the production of hydrocarbons. The compositions and methods of the present invention also may be suitable, for example, to be used as plugging agents, well bore cleanup fluids, viscous sweep fluids, or insulating fluids to be used in associated methods.
    • 其中,提供了用凝胶状烃流体处理地下地层的方法。 在某些实施方案中,这些方法包括以下步骤:提供包含液体烃和胶凝剂的胶凝液体烃处理流体,其包含有机膦酸酯的多价金属盐或有机亚膦酸的多价金属盐,并处理地下 用胶凝液化烃处理液形成。 本发明的胶凝液化烃处理流体适用于地下处理操作,例如地层刺激和砂控制处理,如压裂和砾石填充,其可以在用于生产烃的地下地层中进行。 本发明的组合物和方法也可适用于例如用作堵塞剂,井眼清洗液,粘性清洗流体或用于相关方法的绝缘流体。
    • 106. 发明申请
    • WELL TREATMENT FLUIDS CONTAINING A VISCOELASTIC SURFACTANT AND A CROSS-LINKING AGENT COMPRISING A WATER-SOLUBLE TRANSITION METAL COMPLEX
    • 含有粘弹性表面活性剂的水处理液和包含水溶性过渡金属络合物的交联剂
    • US20110105369A1
    • 2011-05-05
    • US12610083
    • 2009-10-30
    • B. Raghava Reddy
    • B. Raghava Reddy
    • C09K8/86
    • C09K8/602C09K8/685C09K2208/30
    • The invention is directed to methods for treating a portion of a well. The methods include the steps of: (A) forming a viscoelastic treatment fluid, wherein the treatment fluid comprises: (i) water; (ii) a viscoelastic surfactant (“VES”), wherein the VES is soluble in the water and wherein the VES is in the form of micelles; and (iii) a cross-linking agent for the VES molecules, wherein: (a) the cross-linking agent comprises cross-linking agent molecules having at least one complexed transition metal, wherein the transition metal has a valence state of at least three; and (b) the cross-linking agent is soluble in the water; and (B) introducing the treatment fluid into a portion of the well. According to a first aspect of the invention, (a) the VES comprises VES molecules having an alkyl group of greater than 14 carbon atoms and (b) the VES comprises VES molecules having at least one functional group selected from a carboxylate group, an amino group, an alcohol group, and an ether group. According to a second aspect of the invention, the VES comprises VES molecules having both an alkyl group of greater than 14 carbon atoms and at least one functional group selected from a carboxylate group, an amino group, an alcohol group, and an ether group.
    • 本发明涉及用于处理井的一部分的方法。 所述方法包括以下步骤:(A)形成粘弹性处理流体,其中所述处理流体包括:(i)水; (ii)粘弹性表面活性剂(“VES”),其中VES可溶于水,其中VES为胶束形式; 和(iii)用于VES分子的交联剂,其中:(a)所述交联剂包含具有至少一种络合的过渡金属的交联剂分子,其中所述过渡金属的价态至少为3 ; 和(b)交联剂可溶于水; 和(B)将处理流体引入井的一部分。 根据本发明的第一方面,(a)VES包括具有大于14个碳原子的烷基的VES分子和(b)VES包含具有至少一个选自羧酸酯基,氨基 组,醇基和醚基。 根据本发明的第二方面,VES包括具有大于14个碳原子的烷基和至少一个选自羧酸酯基,氨基,醇基和醚基的官能团的VES分子。
    • 107. 发明授权
    • Variable density fluids and methods of use in subterranean formations
    • 可变密度流体和地下地层中使用的方法
    • US07749942B2
    • 2010-07-06
    • US12165760
    • 2008-07-01
    • Krishna M. RaviDonald L. WhitfillB. Raghava ReddyMike Szymanski
    • Krishna M. RaviDonald L. WhitfillB. Raghava ReddyMike Szymanski
    • C09K8/24E21B21/00
    • C09K8/03C09K8/035C09K8/40C09K8/467C09K8/508C09K8/516C09K8/536C09K8/68C09K8/70C09K8/74C09K8/88C09K8/92
    • Herein provided are variable density fluid compositions and methods for using such compositions in a subterranean formation. One exemplary embodiment of the variable density fluid compositions of the present invention comprises a variable density fluid comprising: a base fluid; and a portion of elastic particles, the elastic particles having an isothermal compressibility factor in the range of from about 1.5×10−3 (1/psi) to about 1.5×10−9 (1/psi). Also provided are cement compositions comprising elastic particles, processes for preparing such cement compositions, and methods of cementing in subterranean formations using such cement compositions. One or more elastic particles are mixed with the cement before pumping the cement into a well bore. The elastic particles are preferably composed of an elastomeric material such as a copolymer of methylmethacrylate and acrylonitrile; a terpolymer of methylmethacrylate, acrylonitrile, and dichloroethane; a styrene-divinylbenzene copolymer; and polystyrene.
    • 本文提供的是可变密度流体组合物和在地下地层中使用这种组合物的方法。 本发明的可变密度流体组合物的一个示例性实施方案包括可变密度流体,其包含:基础流体; 和一部分弹性颗粒,弹性颗粒的等温压缩系数在约1.5×10-3(1 / psi)至约1.5×10-9(1 / psi)的范围内。 还提供了包含弹性颗粒的水泥组合物,用于制备这种水泥组合物的方法,以及使用这种水泥组合物在地下地层中固井的方法。 在将水泥泵入井眼之前,将一种或多种弹性颗粒与水泥混合。 弹性颗粒优选由弹性体材料构成,例如甲基丙烯酸甲酯和丙烯腈的共聚物; 甲基丙烯酸甲酯,丙烯腈和二氯乙烷的三元共聚物; 苯乙烯 - 二乙烯基苯共聚物; 和聚苯乙烯。