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    • 102. 发明授权
    • Mixture containing dicyanate or polycyanate compound, substituted
bicyclo[2.]hept-5-ene-2,3-dicarboximide and thermoplastic
    • 含有二氰酸酯或聚氰酸酯化合物的混合物,取代的双环[2.2.1]庚-5-烯-2,3-二甲酰亚胺和热塑性
    • US4885346A
    • 1989-12-05
    • US279883
    • 1988-12-05
    • Andreas KramerFrancis Perritaz
    • Andreas KramerFrancis Perritaz
    • C08G18/67C08F212/32C08G73/12
    • C08G73/12C08F212/32
    • Heat curable mixtures comprising(a) 5 to 95% by weight of at least one aromatic dicyanate or polycyanate compound or a prepolymer thereof,(b) 95 to 5% by weight of at least one compound of formula I or II ##STR1## or of a prepolymer of a compound of formula I or II, (c) 0 to 50% by weight, based on the sum of (a)+(b), of at least one compound of formula III ##STR2## (d) 0.1 to 50% by weight, based on the sum of (a)+(b), of at least one thermoplastic having a glass transition temperature of at least 120.degree. C., in which formulae aboveR.sub.1, R.sub.2 and R.sub.3 are each independently of one another a hydrogen atom or methyl,n is 1 or 2 and m is 2 or 3,R is hydrogen or an aliphatic, cycloaliphatic or aromatic radical, R' is an aliphatic radical, m- or p-phenylene or m- or p-phenyleneoxy, and R" is an organic radical or valency m containing 2 to 30 carbon atoms, are suitable for the production of mouldings such as prepregs or composites, coatings and bonds.
    • 包含(a)5至95重量%的至少一种芳族二氰酸酯或聚氰酸酯化合物或其预聚物,(b)95至5重量%的至少一种式I或II化合物(IMAGE) (II)或式I或II化合物的预聚物,(c)0至50重量%,基于(a)+(b)的总和,至少一种化合物 式(III)(d)(d)0.1至50重量%,基于(a)+(b)的总和,至少一种玻璃化转变温度为至少120℃的热塑性塑料, R 1,R 2和R 3各自独立地为氢原子或甲基,n为1或2,m为2或3,R为氢或脂族,脂环族或芳族基团,R'为脂族基团 对 - 亚苯基或对 - 亚苯基氧基,R“是含有2-30个碳原子的有机基团或价态m,适用于制备诸如预浸料或复合材料,涂层和粘结的模制品。
    • 103. 发明授权
    • Thermally hardenable epoxy resin composition having an improved impact resistance at low temperatures
    • 在低温下具有改善的耐冲击性的热固化性环氧树脂组合物
    • US09221969B2
    • 2015-12-29
    • US10538877
    • 2003-12-17
    • Andreas KramerJurgen Finter
    • Andreas KramerJurgen Finter
    • C08L63/00C08G59/28C09J163/00
    • C08L63/00C08G59/28C08L2666/22C09J163/00
    • The invention relates to compositions containing at least one epoxide adduct A that comprises an average of more than one epoxide group per molecule, at least one polymer B of formula (I), at least one thixotropic agent C based on a urea derivative in a non-diffusing carrier material, and at least one hardener D for epoxy resins, which is activated at an increased temperature. Said composition is used especially as an adhesive and is provided with an extraordinarily high impact peel working value, especially at low temperatures. The invention further relates to epoxide group-terminal impact strength modifiers of formula (I), which significantly increase the impact resistance in epoxy resin compositions, particularly two-component epoxy resin compositions.
    • 本发明涉及至少一种包含至少一种环氧化物加合物A的组合物,其每分子平均含有多于一个环氧基团,至少一种式(I)的聚合物B,至少一种基于非衍生物的脲衍生物的触变剂C, 以及至少一种用于环氧树脂的硬化剂D,其在升高的温度下被活化。 所述组合物特别用作粘合剂,并且具有特别高的冲击剥离工作值,特别是在低温下。 本发明还涉及式(I)的环氧基团 - 末端冲击强度改性剂,其显着提高了环氧树脂组合物,特别是双组分环氧树脂组合物的耐冲击性。
    • 106. 发明授权
    • Process for removing carbonaceous deposits on surfaces of catalysts and plant parts
    • 用于去除催化剂和植物部件表面上的碳质沉积物的方法
    • US08349090B2
    • 2013-01-08
    • US13124281
    • 2009-10-09
    • Manfred WinterHagen WeiglAndreas Kramer
    • Manfred WinterHagen WeiglAndreas Kramer
    • B08B3/00
    • B01J38/14B01J23/92B01J38/06B01J38/16B01J38/20
    • A process for removing carbonaceous deposits on surfaces of catalysts and plant parts by treating the deposits with a superheated stream of steam admixed at least temporarily with an oxygenous gas is provided, which involves, in each case monitoring the offgas CO2 content after condensation of the steam, at a temperature of at least 300° C.: (a) treating the carbonaceous deposits with superheated steam at a temperature of at least 300° C. until the CO2 content of the offgas has exceeded a maximum; (b) then, with further supply of superheated steam, commencing oxygen supply, the amount of oxygen supplied being adjusted such that the CO2 content in the offgas decreases further until it has fallen to a value of
    • 提供了一种通过用至少暂时与氧气混合的过热蒸汽流处理沉积物来除去催化剂和植物部件表面上的碳质沉积物的方法,其包括在各种情况下监测蒸汽冷凝后的废气CO 2含量 ,在至少300℃的温度下:(a)在至少300℃的温度下用过热蒸汽处理碳质沉积物,直到废气的CO 2含量超过最大值; (b)然后,进一步供应过热蒸汽,开始供氧,调整供氧量,使得废气中的二氧化碳含量进一步下降,直到其下降到<1%体积的数值; 然后(c)结束过热蒸汽的供应并将氧气通过剩余量的碳质沉积物,直到沉积物被真实地除去。
    • 110. 发明授权
    • Cationic substituted 2,2,6,6-tetraalkylpiperidinyl alkoxyamines
    • 阳离子取代的2,2,6,6-四烷基哌啶基烷氧基胺
    • US07902368B2
    • 2011-03-08
    • US12535747
    • 2009-08-05
    • Andreas MühlebachPeter NesvadbaAndreas Kramer
    • Andreas MühlebachPeter NesvadbaAndreas Kramer
    • C07D211/00
    • C08F4/00C07D211/94C07D241/08C07F9/4006C07F9/59
    • Cationic 2,2,6,6-tetraalkylpiperidinyl alkoxyamines of, for example, formula (1a) and (1b) are useful as polymerization initiators/regulators in a controlled stable free radical polymerization process to produce intercalated and/or exfoliated nanoparticles from natural or synthetic clays. Compositions comprising improved nanocomposites produced by this process are useful as, for example, coatings, sealants, caulks, adhesives and plastic additives wherein Q1 is a direct bond or a —CH2— group T1, T2, T3 and T4 are independently methyl or ethyl with the proviso that at least one is ethyl; T7 and T8 are hydrogen or methyl; T5 and T6 are hydrogen or T5 and T6 together are a group ═O, ═NOH, ═NO-T9 or T5 is hydrogen and T6 is —O-T9 or —NR9-T9 T9 is hydrogen, R9 or —C(O)—R9; R9 is hydrogen, C1-C18alkyl, C3-C18alkenyl, C3-C18alkynyl, phenyl or C7-C9phenylalkyl unsubstituted or substituted by hydroxy, halogen or C1-C4alkoxy; K1 and K2 are hydrogen, C1-C18alkyl, C5-C12cycloalkyl, phenyl or C7-C9phenylalkyl and K3 is a group containing selected amine containing salts.
    • 例如式(1a)和(1b)的阳离子2,2,6,6-四烷基哌啶基烷氧基胺可用作控制稳定的自由基聚合方法中的聚合引发剂/调节剂,以产生自然或/或 合成粘土。 包含通过该方法制备的改进的纳米复合材料的组合物可用作例如涂料,密封剂,填隙剂,粘合剂和塑料添加剂,其中Q1是直接键或-CH 2 - 基团T1,T 2,T 3和T 4独立地是甲基或乙基, 条件是至少一个是乙基; T7和T8是氢或甲基; T5和T6是氢或T5和T6一起是基团= O,≡NOH,≡NO-T9或T5是氢,T6是-O-T9或-NR9-T9,T9是氢,R9或-C(O) -R9; R 9是氢,C 1 -C 18烷基,C 3 -C 18烯基,C 3 -C 18炔基,苯基或未被取代或被羟基,卤素或C 1 -C 4烷氧基取代的C 7 -C 9苯基烷基; K 1和K 2是氢,C 1 -C 18烷基,C 5 -C 12环烷基,苯基或C 7 -C 9苯基烷基,K 3是含有选择的含胺盐的基团。