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    • 101. 发明申请
    • FOAMABLE THERMOPLASTIC REACTOR BLENDS AND FOAM ARTICLE THEREFROM
    • 可发泡的热塑性反应器共混物及其泡沫制品
    • WO2012094099A2
    • 2012-07-12
    • PCT/US2011/064139
    • 2011-12-09
    • EXXONMOBIL CHEMICAL PATENTS INC.JIANG, PeijunSAHNOUNE, AbdelhadiDEKMEZIAN, Armenag
    • JIANG, PeijunSAHNOUNE, AbdelhadiDEKMEZIAN, Armenag
    • C08J9/04C08J9/06C08L23/10C08F10/06
    • C08L23/10C08F255/02C08J9/0061C08J2205/052C08J2323/10C08J2423/12C08L23/12C08L23/142C08L2203/14C08L2205/02C08L2205/025C08L2666/06
    • This invention relates to a foamable blend comprising an in-reactor polymer blend comprising: (a) a first propylene polymer component comprising 90 to 100 wt% propylene and from 0 to less than 10 wt% comonomer, said first propylene component having a Tm of 120°C or more; and (b) a second propylene polymer component comprising from 30 to 90 wt% propylene and 70 to 10 wt% comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend, prior to combination with a foaming agent, has: (i) a Tm of at least 120°C; (ii) a MFR of 10 dg/min or more; (iii) a tensile strength of at least 8 MPa; (iv) an elongation at break of at least 200%; and (v) a ratio of elongational viscosity at break to linear viscosity of 5 or more when the elongational viscosity is measured at a strain rate of 1 sec -1 and temperature of 180°C; and where when the blend is foamed with a foaming agent, the foamed article has a density of 800 kg/m 3 or less.
    • 本发明涉及包含反应器内聚合物共混物的可发泡共混物,其包含:(a)第一丙烯聚合物组分,其包含90至100wt%的丙烯和0至小于10wt%的共聚单体, 所述第一丙烯组分的Tm为120℃或更高; 和(b)包含30-90重量%丙烯和70-10重量%共聚单体的第二丙烯聚合物组分,所述第二丙烯聚合物具有30,000g / mol或更高的Mw,并且所述第二含丙烯聚合物具有结晶度 与第一聚合物相差至少5%,其中聚合物共混物在与发泡剂结合之前具有:(i)至少120℃的Tm; (ii)10dg / min或更高的MFR; (iii)至少8MPa的拉伸强度; (iv)至少200%的断裂伸长率; 和(v)当在1秒-1的应变速率和180℃的温度下测量伸长粘度时,断裂伸长粘度与线性粘度之比为5或更大; 当混合物用发泡剂发泡时,发泡制品的密度为800kg / m 3或更低。
    • 106. 发明申请
    • CATALYST SYSTEM AND PROCESS FOR OLEFIN POLYMERIZATION
    • 催化剂体系和烯烃聚合方法
    • WO2010014344A2
    • 2010-02-04
    • PCT/US2009/049528
    • 2009-07-02
    • EXXONMOBIL CHEMICAL PATENTS INC.CROWTHER, Donna, J.JIANG, PeijunRODRIGUEZ, George
    • CROWTHER, Donna, J.JIANG, PeijunRODRIGUEZ, George
    • C08F10/06C08F4/6592B01J31/02B01J31/14B01J31/16B01J31/22
    • C08F10/06B01J31/0239B01J31/0268B01J31/146B01J31/1616B01J31/2295B01J2231/122B01J2531/48B01J2531/49C08F4/65912C08F4/65916C08F4/65927C08F110/06C08F210/06C08F210/16Y10S526/943C08F4/65908C08F2500/08C08F2500/20C08F2500/03C08F2500/17
    • The present application relates to a new catalyst system for the polymerization of olefins, comprising a new ionic activator having the formula: [R 1 R 2 R 3 AH] + [Y]", wherein [Y] - is a non- coordinating anion (NCA), A is nitrogen or phosphorus, R 1 and R 2 are hydrocarbyl groups or heteroatom-containing hydrocarbyl groups and together form a first, 3- to 10-membered non- aromatic ring with A, wherein any number of adjacent ring members may optionally be members of at least one second, aromatic or aliphatic ring or aliphatic and/or aromatic ring system of two or more rings, wherein said at least one second ring or ring system is fused to said first ring, and wherein any atom of the first and/or at least one second ring or ring system is a carbon atom or a heteroatom and may be substituted independently by one or more substituents selected from the group consisting of a hydrogen atom, halogen atom, C 1 to C 10 alkyl, C 5 to C 15 aryl, C 6 to C 25 arylalkyl, and C 6 to C 25 alkylaryl, and R 3 is a hydrogen atom or C 1 to C 10 alkyl, or R 3 is a C 1 to C 10 alkylene group that connects to said first ring and/or to said at least one second ring or ring system. The present application also relates to a process for the polymerization of olefins, preferably propylene, using this and other catalyst systems, as well as to polymers made by said process.
    • 本申请涉及用于烯烃聚合的新型催化剂体系,其包含具有下式的新的离子活化剂:[R 1 R 2 R 3 A H] + [Y]“,其中[Y] - 为非配位阴离子(NCA),A为 氮或磷,R 1和R 2是烃基或含杂原子的烃基,并且与A一起形成第一个3至10元非芳族环,其中任何数量的相邻环成员可以任选地是至少一个 第二个是两个或更多个环的芳族或脂族环或脂族和/或芳族环系,其中所述至少一个第二环或环系与所述第一环稠合,并且其中第一和/或至少一个 第二环或环系是碳原子或杂原子,并且可以被一个或多个选自氢原子,卤素原子,C 1至C 10烷基,C 5至C 15芳基,C 6至C 25芳烷基, 和C 6至C 25烷基芳基,R 3是氢 基原子或C1至C10烷基,或R3是连接到所述第一环和/或所述至少一个第二环或环系统的C1至C10亚烷基。 本申请还涉及使用这种和其它催化剂体系以及通过所述方法制备的聚合物来聚合烯烃,优选丙烯的方法。
    • 107. 发明申请
    • SEMI-RIGID LINKED DIAMINES, PRECURSORS THERFOR, AND TRANSITION METAL DIAMIDO COMPLEXES AS CATALYSTS FOR OLEFIN POLYMERIZATION PROCESSES
    • 半刚性连接芯片,前驱体和过渡金属DIAMIDO复合材料作为烯烃聚合工艺的催化剂
    • WO2009129004A1
    • 2009-10-22
    • PCT/US2009/037003
    • 2009-03-12
    • EXXONMOBIL CHEMICAL PATENTS INC.HAGADORN, John, R.
    • HAGADORN, John, R.
    • B01J31/12C07F7/00C07F7/10C07F7/12C08F4/642C08F10/02C08F10/14
    • C07F7/10B01J31/1805B01J2231/20B01J2531/0241B01J2531/46B01J2531/48B01J2531/49C08F10/00C08F110/02C08F210/16C08F4/64072C08F2500/03C08F210/14
    • The invention relates to a process for producing a complex for use in olefin polymerization and oligomerization of the general formula (III): wherein M t is a group 3 to 12 element in a +2 to +6 oxidation state with between 1 to 4 additional ligands (anionic and/or neutral) coordinated, wherein R 1 and R 2 are hydrogen, halogen, alkoxy, or a hydrocarbon group containing between 1 to 12 carbon atoms; E is a group 16 element, preferably O; Z is a direct bond between carbon atoms of the adjacent aromatic rings or a -CR 3 R 4 - or -SiR 3 R 4 - bridge between those carbon atoms, where R 3 and R 4 are hydrogen or a hydrocarbon groups with 1 to 10 carbons, R 5 , R 6 , R 7 and R 8 are hydrogen, halogen, alkoxy, or a hydrocarbon group containing between 1 to 10 carbon atoms and J 1 and J 2 are -NR 9 R 10 or -PR 9 R 10 , where R 9 is H or SiMe 3 group and R 10 is selected from a group consisting of alkyl, aryl, substituted aryl, heteroalkyl, and heteroaryl containing between 1 to 30 non-hydrogen atoms through a route involving novel precursors such as compounds represented by the general formula (I): and (II): where the various substitution options are adapted to produce the substituents shown for formula (III) above.
    • 本发明涉及一种用于制备用于通式(III)的烯烃聚合和低聚的络合物的方法:其中Mt是+2至+6氧化态的3至12族元素,具有1至4个另外的配体 (阴离子和/或中性)配位,其中R 1和R 2是氢,卤素,烷氧基或含有1至12个碳原子的烃基; E是16族元素,优选O; Z是相邻芳环的碳原子之间的直接键或这些碳原子之间的-CR 3 R 4 - 或-SiR 3 R 4 - 桥,其中R 3和R 4是氢或具有1至10个碳的烃基,R 5,R 6,R 7和 R8是氢,卤素,烷氧基或含有1至10个碳原子的烃基,J1和J2是-NR9R10或-PR9R10,其中R9是H或SiMe3基团,R10选自烷基,芳基, 取代的芳基,杂烷基和含有1至30个非氢原子的杂芳基通过涉及新型前体的途径,例如由通式(I)表示的化合物:和(II):其中各种取代选项适于产生取代基 如上述式(III)所示。
    • 109. 发明申请
    • CATALYST COMPOUNDS AND USE THEREOF
    • 催化剂化合物及其用途
    • WO2009082556A1
    • 2009-07-02
    • PCT/US2008/083128
    • 2008-11-11
    • EXXONMOBIL CHEMICAL PATENTS INC.GIESBRECHT, Garth, R.SOLAN, Gregory, A.DAVIES, Christopher, J.
    • GIESBRECHT, Garth, R.SOLAN, Gregory, A.DAVIES, Christopher, J.
    • C08F4/64C08F4/659C08F10/02C07F7/00
    • C08F10/00C08F110/02C08F210/16C08F4/64151C08F4/659C08F2500/03C08F2500/04C08F210/14C08F4/025
    • This invention relates to a transition metal catalyst compound represented by the structure: Formula(I) wherein: each X is, independently, a hydride, a halogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, or a substituted halocarbyl; w is 2; each R 1 , R 2 , R 3 , and R 4 is, independently, a hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl, a halogen, an alkoxide, a sulfide, an amide, a phosphide, a silyl or another anionic heteroatom-containing group, or independently, may join together to form a C 4 to C 62 cyclic or polycyclic ring structure; each R 5 , R 6 , and R 7 is, independently, a hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl, a halogen, an alkoxide, a sulfide, an amide, a phosphide, a silyl or another anionic heteroatom- containing group, or independently, may join together to form a C 4 to C 62 cyclic or polycyclic ring structure; each R 8 and R 9 , is, independently, a hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, or a substituted halocarbyl, a halogen, an alkoxide, a sulfide, an amide, a phosphide, a silyl or another anionic heteroatom-containing group; R 10 is a hydrogen, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, or a substituted halocarbyl, a halogen, an alkoxide, a sulfide, an amide, a phosphide, a silyl or another anionic heteroatom-containing group; x is 1, 2, 3 or 4; L is a neutral ligand bonded to M; M is titanium, zirconium or hafnium; and m is 0, 1 or 2.
    • 本发明涉及由以下结构表示的过渡金属催化剂化合物:式(I)其中:各X独立地为氢化物,卤素,烃基,取代的烃基,卤代烃基或取代的卤代烃基; w为2; 每个R 1,R 2,R 3和R 4独立地为氢,烃基,取代的烃基,卤代烃基,取代的卤代烃基,卤素,醇盐,硫化物,酰胺,磷化物,甲硅烷基或其它阴离子 含杂原子的基团或独立地可以连接在一起以形成C 4至C 62环状或多环结构; 每个R 5,R 6和R 7独立地是氢,烃基,取代的烃基,卤代烃基,取代的卤代烃基,卤素,醇盐,硫化物,酰胺,磷化物,甲硅烷基或另一个阴离子杂原子 - 或独立地可以连接在一起形成C 4〜C 62环状或多环结构; 每个R 8和R 9独立地是氢,烃基,取代的烃基,卤代烃基或取代的卤代烃基,卤素,醇盐,硫化物,酰胺,磷化物,甲硅烷基或另外含阴离子的含杂原子的 组; R 10是氢,烃基,取代的烃基,卤代烃基或取代的卤代烃基,卤素,醇盐,硫化物,酰胺,磷化物,甲硅烷基或另一个阴离子含杂原子的基团; x为1,2,3或4; L是与M结合的中性配体; M是钛,锆或铪; m为0,1或2。