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91. 发明专利

JPH0457662B2 失效
公开(公告)号：JPH0457662B2
公开(公告)日：1992-09-14
申请号：JP21034585
申请日：1985-09-25
申请人： BAYER AG
发明人： KURAUSU GUROOE
IPC分类号： C07C255/42 , C07C67/00 , C07C69/618 , C07C227/00 , C07C227/16 , C07C229/24 , C07C229/34 , C07C229/36 , C07C231/00 , C07C231/12 , C07C231/14 , C07C237/16 , C07C237/20 , C07C253/00 , C07C253/30 , C07C255/28 , C07C255/30 , C07D295/04 , C07D295/14

92. 发明专利

JPH01131143A OPTICAL RESOLUTION OF D,L-CARNITINENITRILE CHLORIDE 失效
公开(公告)号：JPH01131143A
公开(公告)日：1989-05-24
申请号：JP29021687
申请日：1987-11-16
申请人： EARTH CHEMICAL CO
发明人： HORINAKA AKIO
IPC分类号： C07B57/00 , C07C67/00 , C07C253/00 , C07C255/28
摘要： PURPOSE:To reduce the amount of an optically resolving agent used and to carry out optical resolution readily and efficiently, by using a specific amount of N-acetyl-L-glutamic acid as the optically resolving agent and another acid and subjecting dl-carnitinenitrile chloride to optical resolution. CONSTITUTION:A solution of dl-carnitinenitrile chloride is treated with N-acetyl- L (or D)-glutamic acid as an optically resolving agent and another acid such as acetic acid or conc. hydrochloric acid capable of forming a noncrystallizing salt of dl-carnitinenitrile, d-carnitinenitrile N-acetyl-acetyl-D-glutamate or l- carnitinenitrile N-acetyl-D-glutamate slightly soluble in a polar solvent is crystallized and the dl-carnitinenitrile chloride is subjected to optical resolution industrially and economically to give an optically active carnitinenitrile chloride useful as a remedy for cardiac diseases. The amount of the optically resolving agent added is 1.1-1.3 equivalent based on the theoretical amount to form the slightly soluble salt.

93. 发明专利

JPS6348262B2 失效
公开(公告)号：JPS6348262B2
公开(公告)日：1988-09-28
申请号：JP14245880
申请日：1980-10-14
申请人： UBE INDUSTRIES
发明人： FUKUI KYOSHI , KITA JUNICHIRO , FUJIMURA SUSUMU , KAKEYA NOBORU
IPC分类号： C07C255/28 , C07C67/00 , C07C229/30 , C07C229/36 , C07C231/10 , C07C253/00 , C07C255/30 , C07C255/42 , C07C313/00 , C07C327/58

95. 发明专利

JPS57171903A INSECTICIDE AND ITS PREPARATION 失效
公开(公告)号：JPS57171903A
公开(公告)日：1982-10-22
申请号：JP5040282
申请日：1982-03-29
申请人： DAINIPPON JOCHUGIKU KK
发明人： KATSUTA YOSHIO , NAKASHIMA MINORU , FUJITA TOSHIO
IPC分类号： C07D209/44 , A01N37/44 , A01N43/06 , A01N43/08 , A01N43/12 , A01N43/30 , A01N53/00 , A01N53/04 , C07C67/00 , C07C227/00 , C07C227/18 , C07C229/02 , C07C229/18 , C07C229/20 , C07C229/30 , C07C229/54 , C07C253/00 , C07C255/28 , C07C255/38 , C07C255/58 , C07C313/00 , C07C323/36 , C07D307/42 , C07D317/66 , C07D333/16 , C07D333/56
摘要： NEW MATERIAL:A compound shown by the formulaI[R1 is H, halogen, nitro, alkyl, alkenyl, alkynyl, etc.; n is 1-3; R2 is lower alkyl, lower alkenyl, etc.; R3 is a group shown by the formula II (R4 is H, aryl, etc.; R5 is H, methyl, etc. with the proviso that R4 and R5 may be linked to form trimethylene, etc.; t is 1-2; R6 is H, ethynyl, etc.; x is O, S, etc.; R7-CH2-(R7 is phthalimide, etc.), etc.]. EXAMPLE:5'-Progargyl-2'-methyl-3'-furylmethyl-alpha-isopropyl-( m-acetylanilino ) acetate shown by the formula III. USE:An insecticide. Liquid at normal temperature, effective against sanitary noxious insects, agricultural and gardening noxious insects. Having low toxicity, and stable to light rays. PROCESS:A carboxylic acid shown by the formula III or its reactive derivative is reacted with an alcohol shown by the formula R3-OH or its reactive derivative, to give a compound shown by the formulaI.

96. 发明专利

JPS5746951A Production of 2-amino-4-cyanobutyric derivative 失效
标题翻译： 2-氨基-4-氰基丁酸衍生物的生产
公开(公告)号：JPS5746951A
公开(公告)日：1982-03-17
申请号：JP12174780
申请日：1980-09-04
申请人： Toray Ind Inc
发明人： SATOU HARUYO , IMAMURA SHINZOU
IPC分类号： C07C255/28 , C07C67/00 , C07C253/00 , C07C253/30 , C07D211/88
摘要： PURPOSE: The reaction of an N-(substituted methylene) glycine ester with acrylonitrile is, when necessary, followed by hydrolysis to produce the titled compound used as a synthetic intermediate of aminoacids through the shortened process in high yield.
CONSTITUTION: A compound of formula I (R
1 is H, methyl, aryl; R
2 is 1W4C alkyl) reacts with acrylonitrile to give a compound of formula II. The reaction is preferably conducted in a binary-phase solvent system in the presence of a base and a phase transition catalyst. Then, the product is hydrolyzed in the presence of an acid to prepare 2-amino-4-cyanobutyric acid of formula III. The aldehyde or ketone formed as a by-product can be recycled to prepare the starting material. The compound of formula II is hydrolyzed in the presence of an alkali to produce 2-(substituted methylene)-4-cyanobutyric acid of formula IV. Compounds of formula IIWIV are useful, e.g., as a synthetic intermediate of ornithine.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：当需要时，N-（取代的亚甲基）甘氨酸酯与丙烯腈的反应，然后进行水解，以高产率通过缩短的方法产生用作氨基酸的合成中间体的标题化合物。构成：式I化合物（R 1是H，甲基，芳基; R 2是1-4C烷基）与丙烯腈反应得到式II化合物。反应优选在二元相溶剂体系中在碱和相变催化剂存在下进行。然后，将产物在酸的存在下水解，得到式III的2-氨基-4-氰基丁酸。作为副产物形成的醛或酮可以再循环以制备起始原料。式II的化合物在碱的存在下水解，得到式Ⅳ的2-（取代的亚甲基）-4-氰基丁酸。式II-IV的化合物是有用的，例如作为鸟氨酸的合成中间体。

97. 发明专利

JPS5287118A METHOD OF MANUFACTURING AMINOCYANOO ETHYL ACETATE 失效
公开(公告)号：JPS5287118A
公开(公告)日：1977-07-20
申请号：JP344177
申请日：1977-01-13
申请人： LONZA AG
发明人： ENRIKO KATARUSHII
IPC分类号： C07B61/00 , B01J25/00 , C07C67/00 , C07C253/00 , C07C255/24 , C07C255/28

99. 发明专利

JPS5221326A PLANT DISEASE CONTROLLING AGENT 失效
公开(公告)号：JPS5221326A
公开(公告)日：1977-02-17
申请号：JP9793075
申请日：1975-08-11
申请人： TAKEDA CHEMICAL INDUSTRIES LTD
发明人： ISHIDA YASUO , YAKUSHIJI KUNITO , AOKI ISAO , MASUMOTO KEIICHI , YAMAMOTO YASUHIRO , MURATA CHIYUUICHI
IPC分类号： A01N47/12 , A01N37/34 , A01N37/44 , A01N37/46 , C07C67/00 , C07C253/00 , C07C255/28 , C07C255/29 , C07D295/18
摘要： PURPOSE:A drug possessing poweful penetrability to plats and good controlling actions especially against diseases caused by Phycomycetes such as late blights and downy mildews, even by soil application.

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