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    • 99. 发明授权
    • Heat stabilizer for halogen-containing polymers
    • 含卤聚合物的热稳定剂
    • US09587088B2
    • 2017-03-07
    • US14910627
    • 2014-07-15
    • Galata Chemicals LLC
    • Peter FrenkelMichael DenouxGarrett MineoJoseph Anthony Di Maio
    • C08K5/58C08K5/37C09K15/12C09K15/32C07F7/22C08K5/00
    • C08K5/58C07F7/226C08K5/005C08K5/37C09K15/12C09K15/32C08L27/06
    • A stabilizer composition having low volatility and high efficiency comprising: (i.) 25.000% to 99.997% by weight of at least one dimethyltin compound of formula (CH3)2Sn(S(CH2)mCOOR1)2 wherein R1 is a linear, branched or cyclic C10-C20 alkyl group and m is 1 or 2, optionally containing unsaturations in the form of double or triple bonds; (ii.) 0.001% to 50.000% by weight of at least one mono-methyltin compound of formula CH3Sn(S(CH2)nCOOR2)3 wherein R2 is a linear, branched or cyclic C10-C20 alkyl group and n is 1 or 2, optionally containing unsaturations in the form of double or triple bonds; (iii.) 0.001% to 10.000% by weight of at least one tri-methyltin compound of formula (CH3)3Sn(S(CH2)pCOOR3) wherein R3 is a linear, branched or cyclic C10-C20 alkyl group and p is 1 or 2, optionally containing unsaturations in the form of double or triple bonds; and (iv.) 0.001% to 15.000% by weight of at least one thioester of formula HS(CH2)qCOOR4 wherein R4 is a linear, branched or cyclic C10-C20 alkyl group and q is 1 or 2, optionally containing unsaturations in the form of double or triple bonds.
    • 具有低挥发性和高效率的稳定剂组合物,其包含:(i)25.000%至99.997%重量的至少一种式(CH3)2Sn(S(CH2)mCOOR1)2的二甲基锡化合物,其中R 1是直链,支链或 环状C 10 -C 20烷基,m为1或2,任选地含有双键或三键形式的不饱和键; (ii)0.001重量%至50.000重量%的至少一种式CH 3 Sn(S(CH 2)n COOR 2)的单甲基锡化合物,其中R 2是直链,支链或环状的C 10 -C 20烷基,n是1或2 ,任选地含有双键或三键形式的不饱和键; (iii)0.001重量%至10.000重量%的至少一种式(CH 3)3 N(S(CH 2)p COOR 3)的三甲基锡化合物,其中R 3是直链,支链或环状的C 10 -C 20烷基,p是1 或2,任选地含有双键或三键形式的不饱和键; 至少一种式HS(CH 2)q COOR 4的硫酯,其中R 4是直链,支链或环状的C 10 -C 20烷基,q是1或2,(iv)0.001%至15.000% 双重或三重键的形式。