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91. 发明授权

EP0308961B1 Thiadiazines, process for production thereof, and insecticide 失效
标题翻译：三亚，其生产工艺和杀虫剂
公开(公告)号：EP0308961B1
公开(公告)日：1992-07-08
申请号：EP88115697.0
申请日：1988-09-23
申请人： MITSUI TOATSU CHEMICALS, Inc.
发明人： Nakaya, Michihiko , Fukushi, Yukiharu , Shiraishi, Shirou , Nakamura, Masahiko , Numata, Satoshi , Kodaka, Kenji , Ooka, Masayuki
IPC分类号： C07D285/34 , A01N43/88
CPC分类号： A01N43/88 , C07D285/34

92. 发明公开

EP0183173A2 3,5-dialkyl-4,6-diaryl-tetrahydro-2H-1,3,5-thiadiazine-2-thione derivative, process for its production and antihyperlipidemic agent containing it 失效
标题翻译： 3,5-二烷基-4,6-二芳基四氢-2H- 1,3,5-噻二嗪-2-硫酮衍生物，它们的制备方法和含有它们的抗高血脂药的组合物。
公开(公告)号：EP0183173A2
公开(公告)日：1986-06-04
申请号：EP85114710.8
申请日：1985-11-19
申请人： NISSAN CHEMICAL INDUSTRIES LTD.
发明人： Fujikawa, Yoshihiro , Sakashita, Mitsuaki, c/o Nissan Kagaku , Tsuruzoe, Nobutomo
IPC分类号： C07D285/34 , C07D405/14 , A61K31/54
CPC分类号： C07D417/14 , C07D285/34
摘要： A compound of the formula:

wherein R is methyl or ethyl, X is hydrogen (provided R is ethyl), lower alkyl, lower alkoxy, lower alkylthio, fluorine, bromine, phenoxy or substituted phenoxy, X m is methylenedioxy or -CH=CH-CH=CH-, and m is 1, 2 or 3.

93. 发明公开

EP1481972A4 CYCLIC COMPOUND, PROCESS FOR PRODUCING THE SAME, AND PEST CONTROL AGENT 审中-公开
标题翻译：环状化合物，PROCESS FOR THEIR和农药
公开(公告)号：EP1481972A4
公开(公告)日：2008-07-30
申请号：EP03743574
申请日：2003-03-04
申请人： SUMITOMO CHEMICAL CO
发明人： ITOH SHIGEYUKI , KONOBE MASATO , SAKAMOTO NORIHISA
IPC分类号： C07D251/08 , A01N43/64 , A01N43/707 , A01N43/88 , C07D251/10 , C07D273/04 , C07D285/00 , C07D285/15 , C07D285/34 , C07D401/06 , C07D401/12 , C07D401/14 , C07D413/06 , C07D413/12 , C07D413/14 , C07D417/06 , C07D417/12 , C07D417/14 , C07D251/22 , A01N47/06 , A01N47/16
CPC分类号： C07D413/12 , A01N43/64 , A01N43/707 , A01N43/88 , C07D251/08 , C07D251/10 , C07D273/04 , C07D285/34 , C07D401/06 , C07D401/12 , C07D417/06 , C07D417/12
摘要： A compound represented by the formula (I) [wherein A represents the formula CY1Y2OCY3Y4, CY1Y2SOnCY3Y4, CY1Y2NRCY3Y4, CY1=NCY3Y4, or CY1Y2N=CY3 (wherein n is 0, 1, or 2, and Y1, Y2, Y3, and Y4 each independently represents hydrogen, alkyl, or haloalkyl); R represents hydrogen, halogeno, an optionally substituted hydrocarbon group, etc.; Q1 represents substituted phenyl or a substituted aromatic heterocyclic group; and Q2 represents substituted phenyl, alkyl, or haloalkyl] or a salt of the compound; a process for producing the compound or salt; and an insecticide containing the compound or salt. Besides being applicable by spraying, the insecticide can be used for soil treatment and seed treatment.

94. 发明授权

EP0618912B1 VERFAHREN ZUR HERSTELLUNG EINES WEITGEHEND STAUBFREIEN TETRAHYDRO-3,5-DIMETHYL-1,3,5-THIADIAZIN-2-THION GRANULATS 有权
标题翻译：用于生产基本上无粉尘TETRA HYDRO-3,5-二甲基-1,3,5-噻二嗪-2-硫GRANULATS
公开(公告)号：EP0618912B1
公开(公告)日：1996-11-20
申请号：EP93901680.4
申请日：1992-12-15
申请人： BASF Aktiengesellschaft
发明人： APPLER, Heinz
IPC分类号： C07D285/34 , A01N43/88
CPC分类号： C07D285/34 , A01N43/88 , A01N25/12 , A01N2300/00
摘要： Described is a method of producing tetrahydro-3,5-dimethyl-1,3,5-thiadiazin-2-thion powder (I) substantially free of dust fines by reacting methylamine (II) with carbon disulphide (III) and formaldehyde (IV) or by reacting the methylammonium salt of N-methyldithiocarbamic acid (V) with formaldehyde (IV), characterized in that the reaction is carried out in the presence of at least one diaminoalkylene of the formula (VI): R1-NH-A-NH-R2, in which R?1 and R2¿, independently of each other, are hydrogen or an alkyl group and A is an optionally substituted 1,2-ethylene, 1,3-propylene or 1,4-butylene bridge.

95. 发明公开

EP0391078A1 Thiadiazine compound and method for preparing same 失效
标题翻译： Thiadiazin-Verbindungen和Verfahren zu ihrer Herstellung。
公开(公告)号：EP0391078A1
公开(公告)日：1990-10-10
申请号：EP90104242.4
申请日：1990-03-06
申请人： DIRECTOR-GENERAL OF THE AGENCY OF INDUSTRIAL SCIENCE AND TECHNOLOGY
发明人： Yasumoto, Masahiko , Tsuchiya, Tohru , Shibuya, Isao , Goto, Midori
IPC分类号： C07D285/34
CPC分类号： C07D285/34
摘要： 2,6-Bis(disubstituted amino)-4-dialkylthiocarbamoylimino-1,3,5-thiadiazines represented by the following formula (I):
wherein R₁ and R₂, which may be the same or different, each represent an alkyl group,
or R₁ and R₂ may bond together to form a ring.
摘要翻译：由下式（I）表示的2,6-双（二取代的氨基）-4-二烷基硫代氨基甲酰基亚氨基-1,3,5-噻二嗪：其中R 1和R 2可以相同或不同，各自表示烷基或R 1和R 2可以键合在一起形成环。，

96. 发明公开

EP0358416A1 S-(N-alkoxycarbonyl, N-substituted) amino-methyl isothiourea derivative 失效
标题翻译： S-（N-烷氧基羰基，N-取代的）氨基甲基异硫氰酸酯衍生物。
公开(公告)号：EP0358416A1
公开(公告)日：1990-03-14
申请号：EP89308881.5
申请日：1989-09-01
申请人： KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY
发明人： Kim, Dae-Whang , Hong, Sung-Yeap , Ryu, Jae-Wook , Woo, Jae-Chun
IPC分类号： C07C335/32 , C07D307/79
CPC分类号： C07D307/86 , C07C335/32 , C07C2601/08 , C07C2602/08 , C07C2602/10 , C07D285/34
摘要： A S-(-N-alkoxycarbonyl, N-substituted)amino methyl isothiourea derivative of the formula:
wherein, each of R 1 , R 2 , R 3 , R 4 , R 5 and R 6 , which may be the same or different, represents an alkyl group, an alkenyl group, an alkynyl group, a haloalkynyl group, a haloalkenyl group, a haloalkylnyl group, an alkoxyalkyl group, a cycloalkyl group, a cycloalkenyl group, an aryl 'group, a substituted-aryl group, an aralkyl group, a substituted-aralkyl group, a naphtyl, a pyridyl,
(wherein each of X', X 2 and X 3 , which may be the same or different, represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, an acetyl, a haloalkyl group, a halogen atom, CF 3 , N0 2 , hydroxy, a benzyl, phenyl, a phenoxy or phenylthio group) or
(wherein each of Y 1 and Y 2 , which may be the same or different, represents a hydrogen atom, a lowered alkyl group, a halogen atom, CF 3 , a lowered alkoxy group, W represents a
group, {in which each of R 7 and R 8 represents a hydrogen atom or a lowered alkyl group}, -0-group. a
or a -OCH 2 - group, and m represents an integer of 0 to 2), and each of R 2 , R 3 , R 4 , R 5 and R 6 may be a hydrogen atom. And R4 and R 5 , or R 6 forms together with -(CH 2 ) n - (wherein n is an integer of 2 to 4), -CH 2 -0-CH 2 - or -CH 2 -S-CH 2 - ; provided, however, that at least one of R 4 , R 5 and R 6 is a hydrogen atom, is disclosed. This is a useful intermediate for the production of 1,3,5-thiadiazine-4-one derivatives.
摘要翻译：其中，R 1，R 2，R 3，R 4，R 4，R 4，R 4， R 5和R 6可以相同或不同，表示烷基，烯基，炔基，卤代炔基，卤代烯基，卤代烷基，烷氧基烷基，环烷基，环烷基环烯基，芳基，取代芳基，芳烷基，取代芳烷基，萘基，吡啶基，（其中X 1，X 2和X 3各自为可以相同或不同，表示氢原子，烷基，环烷基，烷氧基，乙酰基，卤代烷基，卤素原子，CF 3，NO 2，羟基，苄基，苯基，苯氧基或苯硫基）或（其中Y 1和Y 2各自可以相同或不同，表示氢原子，降低的烷基，卤素原子，CF 3，降低的烷氧基，W表示基，其中R 7和R 8中的每一个表示氢原子或低级烷基}，-O-基。 a - @基或-OCH 2 - 基，m表示0〜2的整数），R 2，R 3，R 4，R 5，R 6， >可以是氢原子。并且R 4和R 5或R 6与 - （CH 2）n - （其中n为2至4的整数），-CH 2 -O-CH 2 - 或-CH 2 -S- CH2-; 但是，提供了R 4，R 5和R 6中的至少一个是氢原子。这是生产1,3,5-噻二嗪-4-酮衍生物的有用中间体。

97. 发明公开

EP0354297A1 Thiadiazines, process for production thereof, and insecticidal and acaricidal agents comprising the thiadiazines 失效
标题翻译：噻二嗪，其制备方法和杀虫和杀螨含有代理进程。
公开(公告)号：EP0354297A1
公开(公告)日：1990-02-14
申请号：EP89105133.6
申请日：1989-03-22
申请人： MITSUI TOATSU CHEMICALS, Inc.
发明人： Nakaya, Michihiko , Fukushi, Yukiharu , Shiraishi, Shirou , Nakamura, Masahiko , Numata, Satoshi , Kodaka, Kenji , Ooka, Masayuki, c/o Sogokenkyujo
IPC分类号： C07D285/34 , C07D417/12 , A01N43/88
CPC分类号： C07D417/12 , A01N43/88 , A01N47/02 , C07D285/34
摘要： Tetrahydro-1,3,5-thiadiazin-4-ones of the following general formula or salts thereof are useful as a component of an insecticidal and acaricidal agent.

In the formula, each of R 1 and R 2 represents a halogen atom or a C 1 -4 alkyl group, R 3 represents a C 1-4 haloalkyloxy group, a C 1-4 haloalkyloxymethyl group, a C 2-4 haloalkenyloxy group, a C 1-4 haloalkylthio group, a C 1-4 haloalkylthiomethyl group, a C 2 - 4 . haloalkenylthio group, a C 2 - s haloalkyl group, a C 2-8 haloalkenyl group, a C 1-8 alkyloxycarbonyl group, a substituted phenoxycarbonyl group or a substituted pyridyloxy group, m is 0, 1, 2 or 3, and n is 0, 1, 2 or 3.
These novel thiadiazines are produced by reacting a compound of the following general formula (II)
wherein R 1 and m are as defined above,
with a compound represented by the following formula (III)
wherein R 2 , R 3 and n are as defined above.
摘要翻译：四氢-1,3,5-噻二嗪-4-酮如下通式或其盐是作为杀虫和杀螨剂的成分有用。在该式中，每个R <1>和R <2> darstellt卤素原子或C 1-4烷基，R <3> darstellt C1-4的卤代烷氧基，C 1-4 haloalkyloxymethyl基， C 2-4卤代烯氧基，C 1-4卤代烷硫基，C 1-4 haloalkylthiomethyl基，C 2-4卤代烯硫基，C2-8卤代烷基，C2-8卤代链烯基，C1-8烷氧基羰基，substituiertem 苯氧基羰基或substituiertem吡啶氧基，m为0，1，2或3，和n为0，1，2或3。这些新的噻二嗪是通过使以下通式的化合物（Ⅱ） worin [R <1>和m如上所定义，与由下式表示的化合物（III） worinř<2> [R <3>和n如上面所定义是。

98. 发明公开

EP0183173A3 3,5-dialkyl-4,6-diaryl-tetrahydro-2H-1,3,5-thiadiazine-2-thione derivative, process for its production and antihyperlipidemic agent containing it 失效
标题翻译： 3,5-二烷基-4,6-二胺 - 四氢-2H-二氢-1,3,5-噻二嗪-2-衍生物，其生产方法和含有其的抗血小板剂
公开(公告)号：EP0183173A3
公开(公告)日：1987-03-25
申请号：EP85114710
申请日：1985-11-19
申请人： NISSAN CHEMICAL INDUSTRIES LTD.
发明人： Fujikawa, Yoshihiro , Sakashita, Mitsuaki Nissan Kagaku , Tsuruzoe, Nobutomo
IPC分类号： C07D285/34 , C07D405/14 , A61K31/54
CPC分类号： C07D417/14 , C07D285/34
摘要： A compound of the formula:

wherein R is methyl or ethyl, X is hydrogen (provided R is ethyl), lower alkyl, lower alkoxy, lower alkylthio, fluorine, bromine, phenoxy or substituted phenoxy, X m is methylenedioxy or -CH=CH-CH=CH-, and m is 1, 2 or 3.

99. 发明公开

EP0135186A3 3,6-Disubstituted-1,3,5-thiadiazine-3-thioxo-3-ones 失效
标题翻译： 3,6-二取代-1,3,5-噻二嗪-3-硫代-3-酮
公开(公告)号：EP0135186A3
公开(公告)日：1985-10-09
申请号：EP84110760
申请日：1984-09-10
申请人： BAYER AG
发明人： Brandes, Wilhelm, Dr. , Bunnenberg, Rolf, Dr. , Hänssler, Gerd, Dr. , Reinecke, Paul, Dr. , Wedemeyer, Karlfried, Dr.
IPC分类号： C07D285/34 , C07D417/12 , A01N43/88
CPC分类号： C07D417/12 , A01N43/88 , C07D285/34
摘要： 3,6-Disubstituierte 1,3,5-Thiadiazin-2-thioxo-4-one der allgemeinen Formel (I) in welcher
R¹ für Wasserstoff, für gegebenenfalls einfach bei mehr fach, gleich oder verschieden substituiertes Alkyl, für gegebenenfalls einfach bis mehrfach, gleich oder ver schieden substituiertes Alkenyl, für gegebenenfalls ein fach bis mehrfach substituiertes Alkinyl, für gegebenen falls einfach bis mehrfach, gleich oder verschieden substituiertes Cycloalkyl oder Cycloalkenyl, für gegeben enfalls einfach bis mehrfach, gleich oder verschieden substituiertes Aralkyl oder Aryl oder für einen einfach oder mehrfach, gleich oder verschieden substituierten Heterocyclus steht,
R² für gegebenenfalls einfach bis mehrfach, gleich oder verschieden substituiertes Alkyl oder Alkenyl; für gege benenfalls einfach bis mehrfach, gleich oder verschie den substituiertes Cycloalkyl oder Cycloalkenyl, für einfach bis mehrfach, gleich oder verschieden substitu iertes Aralkyl oder den Fluorenylrest steht und
X für Sauerstoff oder SChwefel steht, sowie ihre Verwendung als Schädlingsbekämpfungsmittel, vor allem als Fungizide.
Die neuen 3,6-disubstituierten 1,3,5-Thiadiazin-2-thioxo- 4-one können hergestellt werden, wenn man geeignete 6-substituierte 1,3,5-Thiadiazin-2-thioxo-4-one mit geeigne ten Diazoverbindungen umsetzt.

100. 发明授权

US09296940B2 Dithiazine derivatives 有权
标题翻译：二噻嗪衍生物
公开(公告)号：US09296940B2
公开(公告)日：2016-03-29
申请号：US13726423
申请日：2012-12-24
申请人： Baker Hughes Incorporated
发明人： Grahame Nigel Taylor
IPC分类号： C09K8/54 , C07D285/34 , C07D285/15
CPC分类号： C09K8/54 , C07D285/15 , C07D285/34
摘要： Corrosion of metallic tubulars in an oil, gas or geothermal well may be inhibited by introducing into the well a dithiazine derivative of the formula: wherein R14 is a C1-C24 straight chain or branched alkyl group; or a C6-C24 aryl or arylalkyl group; R15 is a C1-C6 alkyl or a C6-C30 aryl or alkylaryl group; and X is chlorine, bromine or iodine. The dithiazine may be isolated from a whole spent fluid (WSF) formed by reaction of hydrogen sulfide and a triazine. Alternately, the whole spent fluid containing dithiazine or dithiazine derivative and a corrosion inhibiting formulation may be used to inhibit corrosion in the well.
摘要翻译：通过向井中引入下式的二硫嗪衍生物可以抑制金属管在油，气或地热井中的腐蚀：其中R14是C1-C24直链或支链烷基; 或C 6 -C 24芳基或芳烷基; R 15是C 1 -C 6烷基或C 6 -C 30芳基或烷芳基; X是氯，溴或碘。二硫嗪可以与通过硫化氢和三嗪的反应形成的整个废流体（WSF）分离。或者，可以使用含有二硫嗪或二噻嗪衍生物和腐蚀抑制剂的整个废流体来抑制井中的腐蚀。

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