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91. 发明专利

JPWO2014133014A1 単核ルテニウム錯体およびそれを使用した有機合成反応有权
标题翻译：单核钌络合物和有机合成反应中使用相同的
公开(公告)号：JPWO2014133014A1
公开(公告)日：2017-02-02
申请号：JP2015502958
申请日：2014-02-26
申请人：国立大学法人九州大学 , 信越化学工業株式会社
发明人：永島　英夫 , 英夫永島 , 祐輔砂田 , 祐輔砂田 , 大典堤 , 大典堤 , 橋本　徹 , 徹橋本 , 晃司作田 , 晃司作田
IPC分类号： C07F19/00 , C07C5/03 , C07C5/05 , C07C9/16 , C07C13/10 , C07C13/18 , C07C15/073 , C07C15/18 , C07C209/50 , C07C211/27 , C07C211/29 , C07C213/02 , C07C217/58 , C07D223/04 , C07F7/08
CPC分类号： B01J31/1608 , B01J31/22 , B01J2231/323 , B01J2231/643 , B01J2231/645 , B01J2531/821 , C07C5/03 , C07C9/16 , C07C13/10 , C07C13/18 , C07C15/073 , C07C15/18 , C07C29/14 , C07C209/50 , C07C213/00 , C07C2531/16 , C07C2531/22 , C07C2531/28 , C07C2601/08 , C07C2601/14 , C07D223/04 , C07F7/08 , C07F15/0046 , C07C217/58 , C07C211/29 , C07C211/27 , C07C9/18
摘要：式(1)で表されるルテニウム−ケイ素結合を有する単核ルテニウム錯体は、ヒドロシリル化反応、水素化反応、カルボニル化合物の還元反応の三反応に優れた触媒活性を発揮し得る。(式中、R1〜R6は、互いに独立して、水素原子、Xで置換されていてもよい、アルキル基、アリール基、アラルキル基等を表すか、R1〜R3のいずれかとR4〜R6のいずれかの少なくとも1組が一緒になった架橋置換基を表し、Xは、ハロゲン原子、オルガノオキシ基等を表し、Lは、COおよびホスフィン以外の二電子配位子を表し、Lが複数存在する場合、それらは互いに同一でも異なっていてもよく、Lが2個の場合、それらは互いに結合していてもよく、nおよびmは、互いに独立して1〜3の整数を表すが、n+mは3または4を満たす。)
摘要翻译：钌式（1） - 单核钌络合物具有硅键合的氢化硅烷化反应，氢化反应，可以在还原的羰基化合物的三反应显示出优异的催化活性。（式中，R1-R6各自独立地为氢原子，也可以通过X，烷基，芳基，芳烷基，任何R4〜R6与任何R1〜R3的取代表示一起交联取代基卡诺至少一对中，X表示卤原子，有机氧基，等等中，L表示除CO和膦以外的两电子配位体，L存在多个的如果，它们可以是相同的或彼此不同的，如果L是二时，它们可以彼此结合，n和m，其代表彼此独立地，n个为1〜3的整数+ 米满足3或4）

92. 发明专利

JP2006500412A Method of manufacturing a linear α- olefin oligomers using a heat exchanger 审中-公开
公开(公告)号：JP2006500412A
公开(公告)日：2006-01-05
申请号：JP2004539031
申请日：2003-09-23
申请人：シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー
发明人：アーノルデイ，ピーター , アンガー，フイリツプ・エドワード , デ・ブール，エリツク・ヨハネス・マリア , フアン・ゾン，アリー , ムーン，ロベルト
IPC分类号： C07C2/06 , C07C2/08 , B01J8/22 , C07B61/00 , C07C2/32 , C07C11/02 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00 , B01J8/22 , B01J2208/00212 , B01J2208/00247 , B01J2208/00256 , B01J2208/00274 , C07C2/32 , C07C2531/16 , C07C2531/22 , C08F110/02 , C08F2/01 , C08F2/14
摘要：本発明は、ニッケル、パラジウム、コバルト、チタン、ジルコニウム、ハフニウム、バナジウム、クロム、モリブデンまたはタングステン錯体の存在下、熱を放出しながら、エチレンを触媒作用によってオリゴマー化して平均分子量５０から３５０のα−オレフィンオリゴマーにするステップと、少なくとも一部の気相を冷媒として使用して、液相と直接接触していない熱交換器で熱を除去するステップとを含む、液相および気相を含む反応器中で直鎖状α−オレフィンオリゴマーを製造する方法に関する。本発明はさらに、前記方法を実施する装置に関する。

94. 发明申请

US20190077727A1 Methods for the Preparation and Use of Suspensions of Chemically-Treated Solid Oxides in an Olefin-Derived Liquid Medium 审中-公开
公开(公告)号：US20190077727A1
公开(公告)日：2019-03-14
申请号：US15701577
申请日：2017-09-12
申请人： Chevron Phillips Chemical Company LP
发明人： Graham R. Lief , Eric J. Haschke , Pasquale Iacono
IPC分类号： C07C2/32 , C07C5/05 , B01J31/14 , B01J31/22 , B01J8/18 , B01J21/12
CPC分类号： C07C2/32 , B01J8/02 , B01J8/06 , B01J8/10 , B01J8/1836 , B01J8/1854 , B01J21/12 , B01J27/053 , B01J27/12 , B01J31/143 , B01J31/2295 , B01J2231/20 , B01J2531/48 , B01J2531/49 , C07C2/34 , C07C5/05 , C07C2527/12 , C07C2531/14 , C07C2531/16 , C07C2531/22 , C07C11/02
摘要： The present invention discloses processes for oligomerizing an olefin feedstock containing C4 to C20 alpha olefins using a catalyst system containing a metallocene compound, an organoaluminum compound, and a suspension of a chemically-treated solid oxide. The liquid medium for the suspension of the chemically-treated solid oxide can be an alpha-olefin oligomer product formed by the oligomerization process.

95. 发明授权

US09884316B2 Mononuclear ruthenium complex and organic synthesis reaction using same 有权
公开(公告)号：US09884316B2
公开(公告)日：2018-02-06
申请号：US15124773
申请日：2015-03-03
申请人： KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION , SHIN-ETSU CHEMICAL CO., LTD.
发明人： Hideo Nagashima , Yusuke Sunada , Hajime Ogushi , Koji Sakuta
IPC分类号： C07C69/38 , B01J31/16 , C07C209/50 , C07F15/00 , C07F19/00 , C07C5/03 , C07C67/303 , C07C67/283 , C07C209/62 , C07F7/08
CPC分类号： B01J31/1608 , B01J2231/323 , B01J2231/645 , B01J2531/821 , C07C5/03 , C07C67/283 , C07C67/303 , C07C209/50 , C07C209/62 , C07C2531/16 , C07C2531/18 , C07C2601/14 , C07C2602/08 , C07F7/0829 , C07F7/0879 , C07F15/0046 , C07F15/0053 , C07F19/00 , C07C211/04 , C07C13/18 , C07C13/465 , C07C15/18 , C07C15/073 , C07C9/15 , C07C9/16 , C07C69/24 , C07C69/38 , C07C69/612
摘要： A neutral or cationic mononuclear ruthenium divalent complex represented by formula (1) can actualize exceptional catalytic activity in at least one reaction among a hydrosilylation reaction, hydrogenation reaction, and carbonyl compound reduction reaction. (In the formula, R1-R6 each independently represent a hydrogen atom or an alkyl group, aryl group, aralkyl group, organooxy group, monoorganoamino group, diorganoamino group, monoorganophosphino group, diorganophosphino group, monoorganosilyl group, diorganosilyl group, triorganosilyl group, or organothio group optionally substituted by X; at least one pair comprising any of R1-R3 and any of R4-R6 together represents a crosslinkable substituent; X represents a halogen atom, organooxy group, monoorganoamino group, diorganoamino group, or organothio group; L each independently represent a two-electron ligand other than CO and thiourea ligands; two L may bond to each other; and m represents an integer of 3 or 4.)

96. 发明授权

US09782762B2 Substituted mononuclear ruthenium complexes for catalysis of synthetic organic reactions 有权
公开(公告)号：US09782762B2
公开(公告)日：2017-10-10
申请号：US14771765
申请日：2014-02-26
申请人： KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION , SHIN-ETSU CHEMICAL CO., LTD.
发明人： Hideo Nagashima , Yusuke Sunada , Hironori Tsutsumi , Toru Hashimoto , Koji Sakuta
IPC分类号： C22C5/04 , B01J31/16 , B01J31/22 , C07C209/50 , C07C5/03 , C07C9/16 , C07C13/10 , C07C13/18 , C07F7/08 , C07C15/073 , C07C15/18 , C07F15/00 , C07C29/14 , C07C213/00 , C07D223/04
CPC分类号： B01J31/1608 , B01J31/22 , B01J2231/323 , B01J2231/643 , B01J2231/645 , B01J2531/821 , C07C5/03 , C07C9/16 , C07C13/10 , C07C13/18 , C07C15/073 , C07C15/18 , C07C29/14 , C07C209/50 , C07C213/00 , C07C2531/16 , C07C2531/22 , C07C2531/28 , C07C2601/08 , C07C2601/14 , C07D223/04 , C07F7/08 , C07F15/0046 , C07C217/58 , C07C211/29 , C07C211/27 , C07C9/18
摘要： Provided is a mononuclear ruthenium complex that comprises a ruthenium-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound. In formula (1), R1-R6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R1-R3 and one of R4-R6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO and phosphine. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4.

97. 发明授权

US07176266B2 Catalyst for vinyl compound polymerization and process for producing vinyl polymer 失效
标题翻译：用于乙烯基化合物聚合的催化剂和用于生产乙烯基聚合物的方法
公开(公告)号：US07176266B2
公开(公告)日：2007-02-13
申请号：US10889117
申请日：2004-07-13
申请人： Haruhito Sato , Masami Watanabe , Masahiko Kuramoto
发明人： Haruhito Sato , Masami Watanabe , Masahiko Kuramoto
IPC分类号： C08F4/42
CPC分类号： C07C2/32 , C07C2/04 , C07C2521/16 , C07C2531/14 , C07C2531/16 , C08F10/00 , Y10S526/943 , C08F4/7042 , C08F4/7006
摘要： A catalyst for polymerizing vinyl compounds or α-olefins according to the present invention includes (A) a transition metal complex, (B) a clay, clay mineral or ion-exchangeable layered compound, modified with at least one organic compound selected from the group consisting of quaternary ammonium salts, amine compounds, and adducts of amine and Brönsted acid, and (C) at least one aluminoxy compound. The transition metal in (A) is selected from Groups 4 to 10 or Groups 8 to 10 of the Periodic Table for catalysts for vinyl compounds or α-olefins, respectively. The aluminoxy compound is represented by the general Formula wherein a plurality of R groups are each independently C1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and z is an integer of 2 or more for catalyst for vinyl compounds and 2 to 4 for catalysts for α-olefins.
摘要翻译：根据本发明的用于聚合乙烯基化合物或α-烯烃的催化剂包括（A）过渡金属络合物，（B）粘土，粘土矿物或可离子交换的层状化合物，其被至少一种选自以下的有机化合物由季铵盐，胺化合物和胺和布朗斯台德酸的加合物组成，和（C）至少一种铝氧化合物。（A）中的过渡金属分别选自元素周期表第4至10族或第8至10族，用于乙烯基化合物或α-烯烃的催化剂。铝氧化合物由通式表示，其中多个R基团各自独立地为C 1-10烃基，并且R基团中的至少一个为具有2个或更多个碳原子的烃基; 乙烯基化合物催化剂的z为2以上，α-烯烃用催化剂为2〜4。

98. 发明授权

US06835788B2 Catalyst for vinyl compound polymerization and process for producing vinyl polymer 失效
标题翻译：用于乙烯基化合物聚合的催化剂和用于生产乙烯基聚合物的方法
公开(公告)号：US06835788B2
公开(公告)日：2004-12-28
申请号：US10204262
申请日：2002-08-20
申请人： Haruhito Sato , Masami Watanabe , Masahiko Kuramoto
发明人： Haruhito Sato , Masami Watanabe , Masahiko Kuramoto
IPC分类号： C08F442
CPC分类号： C07C2/32 , C07C2/04 , C07C2521/16 , C07C2531/14 , C07C2531/16 , C08F10/00 , Y10S526/943 , C08F4/7042 , C08F4/7006
摘要： The catalyst for polymerizing vinyl compounds according to the present invention comprises (A) a complex of Group 4 to 10 transition metal of the Periodic Table, (B) a clay, clay mineral or ion-exchangeable layered compound, and (C) at least one aluminoxy compound represented by Formula (1): wherein a plurality of R groups are each independently C1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and x is an integer of 2 or more. By using the Group 4 to 10 transition metal complex and the clay, clay mineral or ion-exchangeable layered compound in combination with the specific aluminoxy compound, vinyl polymers are produced at a high efficiency. Also, the catalyst for producing &agr;-olefins according to the present invention comprises (A′) a complex of Group 8 to 10 transition metal of the Periodic Table, (B′) an organic compound-modified clay, clay mineral or ion-exchangeable layered compound, and (C′) at least one aluminoxy compound represented by Formula (2): wherein a plurality of R groups are each independently C1-10 hydrocarbon group and at least one of the R groups is a hydrocarbon group having 2 or more carbon atoms; and y is an integer of 2 to 4. Since the organic compound-modified clay, clay mineral or ion-exchangeable layered compound absorbs other catalyst components between layers thereof, the elution of the catalyst components into liquid phase is effectively prevented, thereby facilitating the separation of the catalyst from a reaction product.
摘要翻译：根据本发明的用于聚合乙烯基化合物的催化剂包含（A）元素周期表第4至10族过渡金属的络合物，（B）粘土，粘土矿物或可离子交换层状化合物，和（C）至少一种由式（1）表示的铝氧化合物：其中多个R基团各自独立地为C 1-10烃基，并且至少一个R基团为具有2个或更多个碳原子的烃基; x为2以上的整数。通过使用4至10族过渡金属络合物和粘土，粘土矿物或可离子交换的层状化合物与特定的铝氧化合物的组合，以高效率生产乙烯基聚合物。此外，根据本发明的用于制备α-烯烃的催化剂包含（A'）元素周期表第8-10族过渡金属的络合物，（B'）有机化合物改性的粘土，粘土矿物或可离子交换的层状化合物和（C'）至少一种由式（2）表示的铝氧化合物：其中多个R基团各自独立地为C1-10烃基，并且至少一个R基团为具有2个或更多个的烃基碳原子 y为2〜4的整数。由于有机化合物改性粘土，粘土矿物或离子交换性层状化合物在其层之间吸收其他催化剂成分，因此有效地防止了催化剂成分向液相的溶出，催化剂与反应产物的分离。

99. 发明申请

US20020052537A1 Sequence of processes for olefin oligomerisation 有权
标题翻译：烯烃低聚方法的顺序
公开(公告)号：US20020052537A1
公开(公告)日：2002-05-02
申请号：US09984053
申请日：2001-10-26
申请人： Institut Francais du Petrole
发明人： Dominique Commereuc , Alain Forestiere , Francois Hugues , Helene Olivier-Bourbigou
IPC分类号： C07C002/02
CPC分类号： C07C2/30 , C07C2/32 , C07C2531/14 , C07C2531/16
摘要： A process is described for carrying out olefin oligomerisation in two catalysis steps of different types, using an organic feed containing at least one olefin. The cut to be treated, containing at least one olefin (Cn), is introduced into a first reaction zone where, in a first step, it undergoes catalytic oligomerisation either of the homogeneous liquid phase type, or of the heterogeneous type with a solid support. The effluent produced is generally sent to a heat exchanger traversed by a cold liquid, the effluent thus being cooled before being sent to a second reaction zone where it undergoes catalytic oligomerisation in a liquid-liquid two-phase medium, the invention being characterized in that at least an ethylenic hydrocarbon containing 3 to 5 carbon atoms per molecule is added to the inlet to the second reaction zone.
摘要翻译：描述了一种使用含有至少一种烯烃的有机进料在不同类型的两个催化步骤中进行烯烃低聚的方法。将要处理的含有至少一种烯烃（Cn）的切割物引入第一反应区域，其中在第一步骤中，其经历均相液相型或异相型催化低聚，具有固体支持物。所产生的流出物通常被送到由冷液体穿过的热交换器中，因此流出物在被送到第二反应区之前被冷却，在第二反应区中，其在液 - 液两相介质中经历催化低聚，本发明的特征在于每个分子至少含有3至5个碳原子的烯烃加入第二反应区的入口。

100. 发明申请

US20010051758A1 PROCESS FOR THE DIMERIZATION OF LOWER OLEFINS 无效
标题翻译：低油脂二维化方法
公开(公告)号：US20010051758A1
公开(公告)日：2001-12-13
申请号：US09155899
申请日：1998-10-08
发明人： YUKITOSHI FUKUDA , KEIICHI HASHIMOTO , SHOSHIRO MATSUSHITA
IPC分类号： C07C002/04 , C07C002/26 , C07C002/24
CPC分类号： C07C2/32 , B01J31/04 , B01J31/143 , B01J31/16 , B01J31/1805 , B01J31/2234 , B01J31/24 , B01J31/26 , B01J31/30 , B01J2231/323 , B01J2531/824 , B01J2531/828 , B01J2531/847 , C07C2/30 , C07C2527/08 , C07C2527/126 , C07C2527/135 , C07C2527/138 , C07C2531/04 , C07C2531/14 , C07C2531/16 , C07C2531/22 , C07C2531/26
摘要： The present invention relates to a process for dimerizing lower olefins characterized by the use of a catalyst comprising the following three components: (1) at least one salt or complex of a transition metal belonging to the platinum group of the periodic table, (2) at least one organoaluminum compound and (3) at least one inorganic metallic compound. The invention provides a process for dimerizing lower olefins with very high yield and selectivity and also with very high yield per unit weight of catalyst. Also provided is a catalyst to be used in said process.
摘要翻译：本发明涉及一种二烯化低级烯烃的方法，其特征在于使用包含以下三种组分的催化剂：（1）属于周期表铂族的过渡金属的至少一种盐或络合物，（2）至少一种有机铝化合物和（3）至少一种无机金属化合物。本发明提供了以非常高的产率和选择性以及每单位重量催化剂的非常高的产率使低级烯烃二聚的方法。还提供了用于所述方法的催化剂。

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