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    • 95. 发明授权
    • Process for isomerization of xylene
    • 二甲苯异构化方法
    • US4300014A
    • 1981-11-10
    • US204018
    • 1980-11-04
    • Yasuo YamasakiTokuji SakaiTamio OnoderaKiji Sumitani
    • Yasuo YamasakiTokuji SakaiTamio OnoderaKiji Sumitani
    • B01J23/32B01J23/90B01J29/44B01J29/90B01J38/12B01J38/20C07B61/00C07C1/00C07C5/27C07C15/08C07C67/00C07C5/24
    • B01J29/90B01J23/32B01J29/44C07C5/2724Y02P20/52Y02P20/584
    • A process for isomerizing xylenes, which comprisescontacting an aromatic hydrocarbon feedstock containing mainly a xylene isomeric mixture containing ethylbenzene with a catalyst of a palladium-containing crystalline aluminosilicate in the vapor phase in the presence of hydrogen to continuously isomerize xylenes and simultaneously de-ethylate the ethylbenzene selectively;interrupting the isomerization reaction;introducing an oxygen-containing gas into a bed of the catalyst in which coke has been deposited during the isomerization reaction, to contact the catalyst with the oxygen-containing gas;burning off the coke deposits on the catalyst with the oxygen-containing gas by gradually increasing the temperature of introduction of the oxygen-containing gas from not more than 200.degree. C. to a temperature in the range of 330.degree. to 390.degree. C. with no part of the catalyst bed exceeding a maximum temperature of 400.degree. C. while controlling the hot spot temperature of the catalyst bed not to exceed 50.degree. C. throughout the burn-off period;reducing in hydrogen the catalyst from which the burnable coke deposits have been removed at least partly;andthereafter resuming the isomerization reaction in the presence of the regenerated catalyst.
    • 异构化二甲苯的方法,其包括在氢气存在下使主要含有乙苯的二甲苯异构体混合物的芳族烃原料与气相中的含钯结晶硅铝酸盐的催化剂接触,以连续异构化二甲苯,同时使二甲苯脱乙基化 乙苯选择性; 中断异构化反应; 在异构化反应期间将含氧气体引入已经沉积焦炭的催化剂床中,以使催化剂与含氧气体接触; 通过逐渐将含氧气体的引入温度从不高于200℃升温到330℃至390℃的温度,用含氧气体燃烧催化剂上的焦炭沉积物, 在整个燃烧期间,催化剂床的热点温度不超过50℃,催化剂床的任何部分超过最高温度400℃。 减少氢气,至少部分地将可燃焦炭沉积物从其中除去的催化剂; 然后在再生催化剂存在下恢复异构化反应。